Clean Label Antifoam and Defoamers

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Clean Label Antifoam and Defoamers Clean Label Conference March 26-28 2018

Drive for Cleaner Label Products Food Market Growing 3% Annually Consumer demand for Clean Label Organic Market grew 11% in 2015 to $43.4 Billion Non-GMO growth outpacing Organic for the first time in 2015 Vermont GMO Labeling, Senate Passes GMO Labeling Standard Sources: U.S. organic sales post new record of $43.3 billion in 2015. Organic Trade Association. Web. 19 May 2016. Schweizer, Errol. Organic and Non GMO Market Growth 2015. USDA Stakeholder Workshop on Coexistence. North Carolina State. Raleigh, NC. 12 March 2015. Keynote Address.

What is foam? Foam is entrapped air/gas in liquid Food is naturally foamy! Primarily caused by proteins or starch Mixing generates additional foam

Defoamers vs. Antifoams Antifoams Prevents Foam or Hold Down proactive Add early in process to prevent foam formation Defoamers Holds Foam or Knock-down reactive Add later in process to destroy foam Terms used interchangeably

Chemistry Core materials: silicone, mineral oil and vegetable oil (soy & canola based) Concentration Antifoams 100% Active (better hold down ideal for continuous processing) Defoamers - Emulsions (spread better, faster knock down) Other Products Enhanced Polyol (polyalkylene) formulations Powdered Antifoams (silicone and/or vegetable oil based) Organic-Certified & Organic Compliant Non-GMO Project Verified

Why use Defoamer/Antifoam? Maximize capacity & yield enhancement Improved pumping and mixing Prevent air entrainment Prevent product loss in overflowing containers and shutdowns Improved container filling Plant Safety & housekeeping Improved final product quality, low foam

Antifoam Applications Protein Fruit & Vegetable Beverages & Dairy Jams, Jellies, Syrup Fermentation Sweeteners Powdered Products

Starting Point Formulations - Examples Formulation Protein RTD % Water 80.485 Whey Protein 14.1 Dietary Fiber 4.1 Flavor 0.5 Phosphoric Acid 0.36 Masking Flavor 0.3 Caffeine 0.1 Sucralose 0.04 Color 0.004 Magrabar Antifoam 0.01 Total 100.00 Formulation Protein Shake % Water 87.3 Milk Protein 4.1 Whey Protein 2.15 Sodium Caseinate 1.53 Cocoa Powder 1.5 Creamer 1.0 Flavor 0.85 Soluble Fiber 0.70 Vegetable Oil 0.44 Masking Flavor 0.25 Gum 0.10 Lecithin 0.03 Sucralose 0.03 Carrageenan 0.01 Magrabar Antifoam 0.01 Total 100.00 Formulation Oatmeal % Water 74.49 Oats 11.3 Cream 5.0 Dried Fruit 2.8 Sugar 2.5 Whey 2.5 Food Starch 1.0 Omega 3 0.10 Cinnamon 0.10 Sat 0.10 Flavor Extract 0.10 Magrabar Antifoam 0.01 Total 100.00

Challenges Regulatory The primary regulation is Defoaming Agents listed in 21 CFR 173.340 No FDA Natural definition USDA Defines Natural as: No synthetic ingredients Minimally processed Use askfsis as a resource Health Food Stores Most have Quality Standards Photo by: https://www.ams.usda.gov

Challenges Limitations on usage Silicone (dimethylpolysiloxane) limited to 10 ppm in most ready-to-eat foods Silicone Defoamers not allowed for Organic Many vegetable oil antifoams only practical limitation is GMPs Refer to 21 CFR 173.340

Challenges Marketing USDA Organic Certification Made with Organic, Organic, 100% Organic Canadian Food Inspection Agency (CFIA) reciprocity Nearly 80 Authorized Organic Certifying Agents https://www.ams.usda.gov/sites/default/files/media/organiccertifyingagents.pdf Refer to National Organic Program 7 CFR 205.605 Non-GMO Certifications e.g. Non-GMO Project Verification, Eurofins, True North, etc. Photo by: https://www.ams.usda.gov Health Food Stores Most have prohibited or allowed ingredient lists

Challenges Labeling Processing Aid vs. Food Ingredient Liquid antifoams sometimes considered processing aid Most powdered antifoams are ingredients and need to be labeled 21 CFR 101.100 Food; exemptions from labeling Many consider liquid antifoams to be exempt from labeling

Challenges Labeling Labeling regulations are complex Ultimately you must decide what to label Based on how and where antifoam is added Example of Carbonated Soft Drink Fountain Drink labeling:

Challenges Defoamer Performance Application Protein & Starch Transport & Storage Formulation Processing Viscosity

Challenges Selecting Right Product Defoamers are Product/Application Specific What to consider: What is the Application? Determine Finished Product Marketing Certifications/Claims Define natural Define allowable or prohibited ingredients Pick a test method that replicates production process

Challenges Storage and Usage General rule to add before foam occurs, where mixing is present Think of boiling pasta on stove, what do you add to eliminate foam? Storage: Over time defoamers will separate (thermodynamically favored) Mixing before use ensures homogeneity of the dispersion and thus product performance Ensure good vortex, bigger and slower blades are preferable to smaller/faster blades Store as described by Manufacturer

Magrabar Antifoams & Defoamers QAI Organic Certified & WSDA Organic Compliant Liquid & Powder Antifoams Non-GMO Project Verified Liquid and Powder Defoamers Conventional Liquid and Powder Defoamers

Contact Information Dr. Ravi G. Joshi Business Development Director 6100 Madison Court Morton Grove, IL 60053 Phone: +1 (847) 595-1810 Email: RJoshi@Munzing.US www.munzing.com Jennifer Dingman Sales Director 1455 Broad Street, 3 rd Fl. Bloomfield, NJ 07003 Phone: +1 (989) 488-7085 Email: JDingman@Munzing.US www.munzing.com Nader Mazloom Mid-West Regional Sales Manager 1455 Broad Street, 3 rd Fl. Bloomfield, NJ 07003 Phone: +1 (989) 330-2189 Email: NMazloom@Munzing.US www.munzing.com