Libranol RDG-LA Rapeseed Diethanolamide Providing Sustainable Cleaning
Libranol RDG-LA Green/sustainable Raw material Rapeseed oil is a sustainable Biggest producer is the EU Provides excellent: Foam stability Cold flow properties Thickening Cost stability
Libranol RDG-LA Rapeseed DEA, or Rapeomide diethanolamine, is a diethanolamide made by reacting the mixture of fatty acids from Rapeseed oil with diethanolamine. It is a viscous liquid and is used as a foaming stabilisation agent in bath products like shampoos and hand soaps, and in cosmetics as an emulsifying agent.
Physical Properties Typical properties % Product Name Coconut Oil Rapeseed Oil Free Fatty Acid 0-0.06 0.037 Moisture % Melting Point Degrees C Pour Point / solidification point Degrees C 0-0.05 0.07 Max 30-35 <0 30-35 <0 Viscosity 25 C / CPS SOLID 137 Viscosity 5 C / CPS SOLID 206 Colour Lovibond 5.25" Red 1.5 Max 1.5 Max C8 Caprylic Acid 5-9 C10 Capric Acid 5-9 C12 Lauric Acid 45-48 C14 Myristic Acid 16-20 C16 Palmitic Acid 8-11 2.5-7 C16 Palmitoleic Acid 0-0.6 C18 Stearic Acid 2-4 0.8-3.0 C18:1 Oleic Acid 6-9 51-70 C18:2 Linoleic Acid 1-3 15-30 C18:3 Alpha Linoleic Acid 5-14 Available in two forms Libranol RDG Lubricants Household I&I Libranol RDG-LA Personal care Household I&I
Why use Libranol RDG-LA Excellent foam stabilisation properties Example High Active Dishwash Concentrate Ingredients Librateric AA30 Tensagex EOC928 HPH (Sodium laureth sulfate SLES 3 mole 27%) Concentrate %) 10% Active 30% Active 8-15 0.8-1.5 2.4-4.5 45-49 4.5-4.9 13.5-14.7 Dense foaming profiles Stable foams at low and high temperatures Sodium dodecylbenzenesulfonat es 37-40 3.7-4 11.1-12 Libranol RDG- LA 4-6 0.4-0.6 1.2-1.8 Citric Acid n/a 1-2 1-2 Water n/a balance balance Figure 1: foam generation of active dish wash
Why use Libranol RDG-LA Excellent thickening and gel properties Libradet 105 ( Libranol RDG and produces a thick cleaning gel Example properties 20% Libradet 105 15% Libradet 105 % solids 19.52 15.08 Cloud point Degrees C Pour Point / solidification point Degrees C 64 >85 10 <0 Viscosity 25 C 22000 6150 Viscosity 5 C 40000 10800 Foam Stability ( sec) >300 >300 Figure 2: Libradet 105 appearance
GBP per tonne Why use Libranol RDG-LA 1,600.00 1,400.00 1,200.00 1,000.00 Comparision between Coconut Oil and Rapeseed Oil prices 800.00 600.00 Coconut oil Rapeseed oil 400.00 200.00 0.00 Mar-16 Apr-16 May-16 Jun-16 Jul-16 Aug-16 Sep-16 Oct-16 Nov-16 Dec-16 Jan-17 Feb-17 Mar-17 Figure 1: Price Variation( /tonne) between Coconut Oil and Rapeseed Oil Sources http://www.indexmundi.com/ Excellent cost stability Rapeseed oil world production 7.8 times larger than Coconut oil in 2016 Sustainable crop largest producer is the EU
Example formulations High Foaming Dish wash % w/w Di Water To balance Sodium Laureth Sulphonate (SLES 39-42 27%, 3 EO) Cocamidopropyl betaine (37% 4-6 CAPB) Libranol RDG-LA (Rapeseed DEA + 2-4 Glycerol) MPG 1-3 NaOH 32% 1-2 Citric Acid 0.1-0.5 Dodecylbenzenesulfoic acid 4-6 (DDBSA/LABSA) sodium xylene sulfonate (40% 0.85 active) Minors (dye/ fragrance) As needed 100% Start with desired water amount Introduce all other actives and stir until clear and homogenous. Cool and add perfume, dye & preservative. Adjust to desired viscosity using Libranol RDG-LA typically 7,000 10,000 cps @ 20 C (Spindle 3, speed 10). High Hair Care Di Water Sodium Laureth Sulphonate (SLES 27%, 3 EO) Cocamidopropyl betaine (37% CAPB) Libranol RDG-LA (Rapeseed DEA + Glycerol) % w/w To balance 23-28 7-11 2-4 Citric Acid 0.1-0.5 Salt (sodium chloride) 1-2 % Minors (dye/ fragrance) As needed 100% Start with desired water amount Introduce all other actives and stir until clear and homogenous. Cool and add perfume, dye & preservative. Adjust to desired viscosity using salt typically 7,000 10,000 cps @ 20 C (Spindle 3, speed 10).
Example formulations Shower Gel % w/w Di Water To balance Sodium Laureth Sulphonate (SLES 39-42 27%, 3 EO) Cocamidopropyl betaine (37% 9-11 CAPB) Libranol RDG-LA (Rapeseed DEA + 2-4 Glycerol) Sodium C14-C16 olefin sulfonate 13-17 PEG6000 distearate 1-2 Citric Acid 0.1-0.5 Minors (dye/ fragrance) As needed 100% Manufacturing Process: Melt PEG6000 Distearate at 70 o C and add it to the water, preheated at 70 o C. Introduce all other actives and stir until clear and homogenous. Cool and add perfume, dye & preservative. Bath bubble Care Di Water Sodium Laureth Sulphonate (SLES 27%, 3 EO) Cocamidopropyl betaine (37% CAPB) Libranol RDG-LA (Rapeseed DEA + Glycerol) % w/w To balance 19-21 11-15 2-4 Citric Acid 0.1-0.5 sodium chlolride 0.85 Minors (dye/ fragrance) As needed 100% Start with desired water amount Introduce all other actives and stir until clear and homogenous. Cool and add perfume, dye & preservative. Adjust to desired viscosity typically 5,000 8,000 cps @ 20 C (Spindle 3, speed 10).