Page 1 of 7 1. IDENTIFICATION OF THE SUBSTANCE / APPLICATION AND THE COMPANY Supplier: Product Name: Coolanol Maxima Racing Oils Article Number: 82964 9266 Abraham Way Santee, CA 92071 Applications: Engine Coolant/Antifreeze USA +1 619 449 5000 Emergency Telephone: In USA: CHEMTREC +1 703 527 3887 (24 hours) Outside USA: +1 619 449 5000 2. HAZARDS IDENTIFICATION GHS Classification Acute Toxicity: Category 4 (Oral) Specific Target Organ Toxicity Repeated Exposure: Category 2 GHS Pictogram Signal Word Hazard Statements Precautionary Statements Prevention Other Hazards Response Storage Disposal Warning! H302 Harmful if swallowed. H373 May cause damage to kidneys through prolonged or repeated exposure. P260 Do not breathe mist, vapors or spray. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell. P330 Rinse mouth. P308 + P311 IF exposed or concerned: Call a POISON CENTER or doctor. P405 Store locked up. P501 Dispose of contents and container in accordance with local and national regulations. None 3. COMPOSITION / INFORMATION ON INGREDIENTS Components Content % CAS Number Ethylene Glycol 45-50 107-21-1 Diethylene Glycol 1-5 111-466 Denatonium benzoate (bittering agent) 30-50ppm 3734-33-6
Page 2 of 7 The specific identity and/or exact percentage has been withheld as a trade secret. 4. FIRST-AID MEASURES Inhalation Skin Contact Eye Contact Ingestion Most Important Symptoms Indication of Immediate Medical Attention Needed Notes to Physician If inhaled remove to fresh air. If irritation or difficulty in breathing occurs, get medical attention. Wash skin with soap and water. Remove clothing and shoes if contaminated. Launder clothing before reuse. Flush eyes with water for several minutes. Remove contact lenses, if present and easy to do so. If eye irritation persists, get medical attention. If conscious, rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention. May cause eye irritation. Inhalation of vapors or mists may cause nose, throat and upper respiratory tract irritation. Swallowing may cause gastrointestinal irritation, nausea, vomiting, blurred vision, irritability, back pain, and central nervous system effects. Get immediate medical attention if large amounts are swallowed. Treat appropriately. The currently recommended medical management of ethylene glycol poisoning includes elimination of ethylene glycol and metabolites, correction of metabolic acidosis and prevention of kidney injury. It is essential to have immediate and follow up urinalysis and clinical chemistry. There should be particular emphasis on acid-base balance and renal function tests. A continuous infusion of 5% sodium bicarbonate with frequent monitoring of electrolytes and fluid balance is used to achieve correction of metabolic acidosis and forced diuresis. As a competitive substrate for alcohol dehydrogenase, ethanol is antidotal. Given in the early stages of intoxication, it blocks the formulation of nephrotoxic metabolites. A therapeutically effective blood concentration of ethanol is in the range 100-150 mg/dl, and should be achieved by a rapid loading dose and maintained by intravenous infusion. For severe and/or deteriorating cases, hemodialysis may be required. Dialysis should be considered for patients who are symptomatic, have severe metabolic acidosis, a blood ethylene glycol concentration greater than 25 md/dl, or compromise of renal functions. 5. FIRE FIGHTING MEASURES Suitable Extinguishing Media Use water fog, alcohol foam, dry chemical or carbon dioxide (CO2) to extinguish flames. A solid stream of water or foam can cause frothing.
Page 3 of 7 Specific Hazards Arising From The Chemical Special Protective Equipment And Precautions For Fire- Fighters This product is not flammable but may form explosive mixtures in air. Combustion will produce carbon oxides, aldehydes and ethers. Firefighters should wear full emergency equipment and a NIOSH approved positive pressure self-contained breathing apparatus. Cool exposed intact containers with water 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Environmental Hazards Methods/Materials for Cleaning up Wear appropriate protective equipment. Wash thoroughly after handling. See also: Personal Protection "section 8. Avoid release into the environment. Report spill as required by local and federal regulations. Dike spill and collect with an inert absorbent. Place into closable containers for disposal. Collected material is handled in accordance with section 13 "Disposal Considerations". 7. HANDLING AND STORAGE Precautions for Safe Handling: Conditions for Safe Storage Harmful if swallowed. Do not drink antifreeze. Avoid contact with eyes and prolonged or repeated contact with skin and clothing. Avoid breathing vapors and mists. Wash thoroughly after handling. Remove contaminated clothing and launder before re-use. Store in a cool area away from oxidizing agents. Protect containers from physical damage. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Limits Ethylene Glycol 100 mg/m 3 Ceiling ACGIH TLV Diethylene Glycol 10 mg/m 3 TWA AIHA WEEL Appropriate Engineering Controls Personal Protection Respiratory Protection: Good general room ventilation (equivalent to outdoors) should be adequate under normal conditions. If the recommended exposure limit is exceeded increased mechanical ventilation such as local exhaust may be required. None needed under normal use conditions with adequate ventilation. If exposure limits are exceeded, use a NIOSH approved respirator with organic vapor cartridges and particulate pre-filter. Selection of respiratory protection depends on the contaminant type, form and concentration. Select in accordance with OSHA 1910.134 and good Industrial Hygiene practice.
Page 4 of 7 Eye Protection: Skin/Body Protection: Hand Protection: Safety goggles recommended if splashing is possible. Appropriate protective clothing as needed to minimize skin contact. Suitable eye flushing facilities should be available in the work area. Contaminated clothing should be removed and laundered before re-use. Use neoprene or PVC gloves for prolonged or repeated skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Liquid Color Green Odor Slightly Sweet odor Odor Threshold No data available ph 10.5-11 (50% solution) Freezing Point 0 F (-18 C) Boiling Point 225 F (107 C) Flash Point 241 F / 116 C (ethylene glycol) Evaporation Rate Nil Flammability (solid, gas) No data available Upper Explosion Limit 15.3% (ethylene glycol) Lower Explosion Limit 3.2% (ethylene glycol) Vapor Pressure <0.1 mmhg @68 F (20 C) Vapor Density (Air=1) No data available Relative Density 1.12 Solubility Insoluble in hydrocarbons; Completely soluble in water Partition Coefficient: n- No data available octanol/water Auto Ignition 748 F (398 C) (ethylene glycol) Temperature Decomposition No data available Temperature Volatile Organic No data available Compounds (VOC) Viscosity No data available 10. STABILITY AND REACTIVITY Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Incompatible Materials Not expected to be reactive. Stable. None known. None known. Avoid contact with strong oxidizing agents, bases and acids.
Page 5 of 7 Hazardous Decomposition Product Thermal decomposition may produce carbon oxides, aldehydes and ethers. 11. TOXICOLOGICAL INFORMATION Potential Health Hazards Eye Contact: May cause irritation with redness and tearing. Skin Contact: Prolonged or repeated contact may cause mild irritation. Inhalation: Excessive inhalation of vapors or mists may cause nausea, vomiting, headache, dizziness and irregular eye movements. Ingestion: Swallowing large amounts may cause gastrointestinal irritation or pain, nausea, vomiting, central nervous system effects, irregular eye movements, convulsions and coma. May cause severe kidney damage which may be fatal. Chronic Effects of Overexposure: None known. Sensitization: None of the components have been found to cause sensitization in animals or humans. Mutagenicity: This product is not expected to cause mutagenic activity. Reproductive Toxicity: A three-generation study indicated that ethylene glycol did not affect reproductive parameters at dietary concentrations up to 1.0 gm/kg/day in any generation. Carcinogenicity: None of the components of this product are listed as a carcinogen or suspected carcinogen by IARC, NTP, or OSHA. Acute Toxicity: Ethylene Glycol: Diethylene Glycol: Oral rat LD50 4700 mg/kg, Dermal rat LD50 9530 mg/kg, Oral rat LD50 12565 mg/kg, Dermal rabbit LD50 11890 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity Ethylene Glycol Diethylene Glycol: Biodegradation Bioaccumulation Mobility in soil Other adverse effects: 96 hr LC50 Pimephales promelas 53,000 mg/l, 48 hr EC50 daphnia magna >10,000 mg/l, 72 hr EL50 Scenedesmus quandricauda >10,000 mg/l 96 hr LC50 western mosquitofish >32,000 mg/l Ethylene glycol and diethylene glycol are readily biodegradable. Ethylene glycol has a BCF of 10. Diethylene glycol has a BCF of 3. This suggests the potential for bioaccumulation is low. Ethylene glycol and diethylene glycol are highly mobile in soil None known. 13. DISPOSAL CONSIDERATIONS Disposal Dispose in accordance with all local, state and federal regulations.
Page 6 of 7 14. TRANSPORT INFORMATION DOT <10,000 lbs. DOT >10,000 lbs TDG IMDG IATA UN Number UN3082 Proper shipping name RQ, Environmentally hazardous substance, liquid, n.o.s. (Ethylene glycol) Hazard Class Packing Group Environmental Hazard 9 PGIII RQ 10,000 lbs. Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code): Not applicable product is transported only in packaged form Special precautions: None known. 15. REGULATORY INFORMATION CERCLA: Spills of this product over the RQ (reportable quantity) must be reported to the National Response Center. The RQ for this product, based on the RQ for Ethylene Glycol (50% maximum) of 5,000 lbs, is 10,000 lbs. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations EPA SARA 302: This product does not contain chemicals regulated under SARA Section 302. EPA SARA 311 Hazard Classification: Acute Health, Delayed Health EPA SARA 313: This product contains the following chemicals that are regulated under SARA Title III, section 313: Ethylene Gylcol 107-21-1 45-50% California Proposition 65: This product contains the following chemicals known to the State of California to cause cancer and reproductive toxicity: Warning: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Ethylene Glycol 107-21-1 45-50% reproductive toxicity Chemical Inventories Toxic Substances Control Act: All of the components of this product are listed on the TSCA inventory
Page 7 of 7 16. OTHER INFORMATION NFPA Rating (NFPA 704): Health: 1 Fire: 1 Instability: 0 HMIS Rating: Health: 2* Fire: 1 Physical Hazard: 0 *Chronic Health Hazard Date of Revision: January 8, 2018 Date of Previous Revision: November 2017 Revision History: 7/13/15: Converted to GHS format. All section revised 2/9/16: Updated boiling point 3/16/16: Added additional California Prop 65 statement for reproductive toxicity 11/2/17: Updated emergency telephone # 1/8/18: Added denatonium benzoate to section 3 The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose.