P a g e 1 of 8 MATERIAL SAFETY DATA SHEET 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product Identifier: STV124 THE BIG CHEESE RAT KILLER 12 x 100g BAIT SACHETS STV125 THE BIG CHEESE RAT & MOUSE KILLER 1kg STV127 THE BIG CHEESE RAT & MOUSE KILLER 2.5kg STV128 THE BIG CHEESE RAT & MOUSE KILLER 400g STV129 THE BIG CHEESE RAT & MOUSE KILLER 5kg STV143 THE BIG CHEESE RAT & MOUSE KILLER BAIT PACK SACHETS 40g STV144 THE BIG CHEESE RAT & MOUSE KILLER BAIT PACK SACHETS 200g STV145 THE BIG CHEESE RAT & MOUSE KILLER BAIT PACK SACHETS 400g STV146 THE BIG CHEESE RAT & MOUSE KILLER BAIT PACK SACHETS 800g 1.2 Relevant uses of the substance or mixture and uses advised against: 1.3 Details of the supplier of the safety data sheet: Supplier: STV International Limited Forge House Little Cressingham Thetford Norfolk IP25 6ND 1.4 Emergency phone number: +44 (0) 1953 881 580
P a g e 2 of 8 2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture 2.2 Label Elements 2.3 Other Hazards The preparation is non-dangerous in accordance with Directive 1999/45/EC. Unlikely to cause harmful effects under normal conditions of handling and use. Harmful to Wildlife. Wild mammals and birds may be at greater risk if the product is not used in accordance with its label. 3.COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Product Code: STV124, STV125, STV127, STV128, STV129 3.2 Hazardous components: Propylene glycol 1-10% 57-55-6 Wheat Grain 90-100% Difenacoum 0.005% 56073-07-5 T+;R28 T;R48/25 N;R50/53 4.FIRST AID MEASURES 4.1 Description of first aid measures Inhalation Unlikely to present an inhalation hazard unless excessive dust is present. Move to fresh air. Obtain medical advice immediately. Ingestion If swallowed, seek medical advice immediately and show this container or label. Skin contact May cause skin irritation in susceptible persons. Remove contaminated clothing Wash off immediately with soap and plenty of water. If irritation persists obtain medical attention Contaminated clothing should be washed and dried before re-use. Eye contact May cause eye irritation with susceptible persons. Rinse immediately with plenty of water and seek medical advice.
P a g e 3 of 8 General Advice In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). ADVICE FOR DOCTORS: Difenacoum is an indirect anticoagulant. Phytomenadione, Vitamin K1, is antidotal. Determine prothrombin times not less than 18 hours after consumption. If elevated, administer Vitamin K1 until prothrombin time normalises. Continue determination of prothrombin time for two weeks after withdrawal of antidote and resume treatment if elevation occurs in that time. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed. 5.FIRE-FIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media Keep fire exposed containers cool by spraying with water if exposed to fire. Carbon dioxide (CO2) alcohol-resistant foam, dry powder, water spray mist or foam. Unsuitable extinguishing media Do not use water jets 5.2 Special Hazards arising from the substance or mixture 5.3 Advice for fire-fighters In the event of fire, wear self-contained breathing apparatus, suitable gloves and boots. 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Wear suitable protective clothing, gloves and eye/face protection. See section 8. 6.2 Environmental Precautions Prevent further leakage or spillage if safe to do so. 6.3 Methods and material for containment and cleaning up Clean up promptly by sweeping or vacuum. Transfer to a suitable labelled container. Subsequently, wash the contaminated area with water, taking care to prevent the washings entering sewers or drains.
P a g e 4 of 8 7.HANDLING AND STORAGE 7.1 Precaution for safe handling Avoid contact with skin and eyes. Avoid dust formation. Do not smoke eat or drink while handling this product. Always use good personal hygiene procedures when handling chemicals. Wash hands and face before eating, drinking or smoking. Read the label before use. Unlikely to produce much dust as the product is a low dust whole wheat grain. 7.2 Conditions for safe storage, including any incompatibilities Keep in a cool, well-ventilated place. Keep out of reach of children. Keep away from food and animal feedstuffs. Keep away from oxidising agents 7.3 Specific end use(s) N/A 8.EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control Parameters STD TWA TWA Notes Propylene glycol WEL (ppm): 150 (mg/m3): 470 Whole Wheat Grain Dust WEL (mg/m3): 10 as dust (MEL) Difenacoum WEL (mg/m3): 0.002 WEL = Workplace Exposure Limit. 8.2 Exposure controls Protective equipment
P a g e 5 of 8 Respiratory protection Unlikely to present an inhalation hazard unless excessive dust is present. If dust levels approach the standards then suitable approved respiratory protection should be worn. Hand protection Impervious gloves Eye protection Tight fitting goggles if exposed to excessive dust. Skin and body protection Impervious clothing boots 9.PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Colour Blue Odour slight Bulk density 0.65-0.75 9.2 Other Information No information required. 10. STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability Stable at normal conditions 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials Materials To Avoid Oxidising agents
P a g e 6 of 8 10.6 Hazardous decomposition products Combustion or thermal decomposition will produce toxic and irritant fumes 11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute toxicity ORL RAT LD50 approx. 30 g/kg (calculated) Primary irritation No eye irritation No skin irritation Sensitization Grain dust is a respiratory sensitiser causing asthma. As the product is a low dust whole wheat grain, it is unlikely to create sufficient dust to cause any problems. mutagenic effects No evidence to suggest anticoagulant rodenticides are mutagenic carcinogenic effects No evidence to suggest anticoagulant rodenticides are carcinogenic. 12.ECOLOGICAL INFORMATION 12.1 Toxicity As the product contains 50ppm difenacoum, unlikely to be hazardous to aquatic life. Harmful to wildlife. Read All Precautions before use. 12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vpvb 12.6 Other adverse effects 13.DISPOSAL CONSIDERATIONS 13.1 Waste Treatment Methods
P a g e 7 of 8 Dispose of in accordance with local regulations. Contaminated packaging should be disposed of as unused product. 14. TRANSPORT INFORMATION 14.1 UN number: UN No. (ADR/RID/ADN) UN No. (IMDG) UN No. (ICAO) Not classified as dangerous for transport. 14.2 UN proper shipping name: 14.3 Transport hazard class(es): 14.4 Packing group: 14.5 Environmental hazards: 14.6 Special precautions for user: 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code 15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture. The preparation is non-dangerous in accordance with Directive 1999/45/EC. Covered by the Control of Pesticides Regulations (1986). It has been labelled in accordance with those regulations. Read the Label before use. 15.2 Chemical Safety Assessment 16. OTHER INFORMATION Revision Date 13/01/12 Revision 1 Recommended restrictions: Risk Phrases In Full R28 Ready for use rodenticide containing 50ppm difenacoum Very toxic if swallowed R48/25 Toxic: danger of serious damage to health by prolonged exposure if swallowed.
P a g e 8 of 8 R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Sources of key data used to compile the datasheet Raw material suppliers Safety Data Sheets. CHIP 2002 EH40 MSDS information: Use only in accordance with label instructions. The information contained in this data sheet does not constitute the user s own assessment of workplace risks as required by legislation. The information in this data sheet should be considered when undertaking a risk assessment under the COSHH regulations. The information contained within this data sheet is strictly for general guidance only and should not be relied upon over and above this. This data sheet is intended to provide general health and safety guidance on the storage and transportation of the preparation. The information in this data sheet is accurate at the date of publication and will be updated as and when appropriate. No liability will be accepted by STV International Limited for any loss, injury or damage arising from any failure to comply with the information and advice contained within this data sheet and/or failure to comply with the manufacturer s guidelines, product label data and any associated technical usage literature. This Material Safety data sheet is compiled using data submitted for raw materials and practical experience. This product is intended for amateur users only. This Safety Data Sheet is prepared in compliance with Directive 1999/45/EC and Annex II of the REACH regulation 1097 of 2006. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.