HEALTH 2 FLAMMABILITY 3 REACTIVITY 0 SAFETY DATA SHEET Prepared by Duro Dyne December 27, 2013 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade name: DURO DYNE SOLVENT BASED ADHESIVE Product Identifier: RPG-1, RPG-5, RPG-55 Item #: 5047, 5048, 5049 Supplier Details: DURO DYNE CORPORATION 81 Spence Street Bay Shore, NY 11706 Information Phone No: 800-899-3876 Emergency Phone No: 2. HAZARD IDENTIFICATION 800-255-3924 (CHEMTREC) Permissible Exposure Level: Threshold Limit Value: Effects of Acute Overexposure: Eyes: Skin: Breathing: Swallowing: Effects of Chronic Overexposure: Can cause severe irritation, redness, tearing, blurred vision. Prolonged or repeated contact can cause moderate irritation, defatting, dermatitis. Excessive inhalation or vapors can cause nasal and respiratory irritation, central nervous system effects including dizziness, weakness, fatigue, nausea, headache and possible unconsciousness, and even death. Can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Aspiration of material into the lungs can cause chemical pneumonitis, which can be fatal. Prolonged or repeated exposure to N-Hexane may damage peripheral nerve tissue (that of the arms and legs) and result in muscular weakness and loss of sensation in the extremities (Peripheral Neuropathy). Methyl Ethyl Ketone may potentate (shorten time of onset) peripheral neuropathy caused by N-Hexane. Prolonged and repeated inhalation of high levels of mixed isomers of Hexane resulted kidney damage in male rats. The effects observed are the same of those seen in male rats exposed to other hydrocarbons. The mechanism by which these chemicals cause the characteristics kidney toxicity is unique to the male rat and the kidney effects are not expected to occur in man. Overexposure to this material (or its components) has been suggested as a cause of the following effects in Page 1 of 4
humans and may aggravate pre-existing disorders of these organs, central nervous system, and visual impairment. 3. COMPOSITION/INFORMATION ON INGREDIENTS PRINCIPAL HAZARDOUS COMPONENTS % BY CAS# WEIGHT Toluene 12.5% 108-88-3 100 ppm Hexane 55.5% 110-54-3 THRESHOLD LIMIT VALUE These chemicals are subject to the reporting requirements of Section 313 of Sara Title III. OSHA, NTP or IARC does not class the ingredients in this product as carcinogens. All ingredients in this product are on the TSCA Inventory. 4. FIRST AID MEASURES Skin: Eyes: Ingested: Inhalation: Primary Routes of Entry: Effects of Chronic Overexposure: Thoroughly wash exposed area with soap and water. Remove contaminated clothing. Launder contaminated clothing before re-use. Flush with large amounts of water. Lifting upper and lower lids occasionally, Get medical attention. Do not induce vomiting. Keep person warm, quiet and get medical attention. Aspiration of material into the lungs due to vomiting can cause chemical pneumonits, which can be fatal. If affected remove individual to fresh air. If breathing is difficult, administer oxygen. If breathing has stopped give artificial respiration. Keep person warm, quiet and get medical attention. Inhalation, skin contact. Prolonged or repeated exposure to N-Hexane may Damage peripheral nerve tissue(that of the arms and legs) and result in muscular weakness and loss of sensation in the extremities (Peripheral Nauropathy). Methyl Ethyl Ketone may potentate (shorten the time of onset) peripheral neuropathy caused by N-Hexane. Prolonged and repeated inhalation of high levels of mixed isomers of Hexane resulted kidney damage in male rats. The effects observed are the same of those seen in male rats exposed to other hydrocarbons. The mechanism by which these chemicals cause the characteristic kidney toxicity is unique to the male rat and the kidney effects are not expected to occur in man. Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans and may aggravate pre-existing disorders of these organs, central nervous system, and visual impairment. Page 2 of 4
5. FIRE-FIGHTING MEASURES Flash Point (Test Method): Tag closed cup. <0 F Flammable Limits: LEL: 1.2% UEL: 6.9% Extinguishing Media: Foam, dry chemical CO2, water fog or spray. Special Fire Fighting Procedures: Use air supplied breathing equipment for enclosed areas. Avoid breathing of vapor or fumes. Unusual Fire & Explosion Hazards: Heat may build up pressure in closed containers. Cool with water spray. 6. ACCIDENTAL RELEASE MEASURES Spill Response: Remove all ignition sources. Keep people away. Recover liquid. Add absorbent sawdust, etc. Ventilate, wipe up. Place in sealed containers. 7. HANDLING AND STORAGE Hygienic Practices in Handling & Storage: Flammable mixture. Do not store near heat, sparks or open flame. Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor or contact with skin. Do not take internally, in an emergency call a physician. Keep out of reach of children. Do not store with strong oxidants like liquid chlorine or concentrated oxygen. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection: Skin Protection: Respiratory Protection (Specific Type): Ventilation Recommended: Other Protection: Splash goggles or safety glasses. Chemical resistant gloves. NIOSH approved dual cartridge respirator with cartridges suitable for organic solvent vapor. Adequate = to outdoors. Eye wash, safety shower. 9. PHYSICAL AND CHEMICAL PROPERTIES Boiling Point: 150 F Specific Gravity (Water = 1):.77 Vapor Pressure (mmhg): 180 Percent Volatile: 68% by weight Vapor Density (Air = 1): 3 Evaporation Rate (N-Butyl Aceate = 1): 8 Solubility in Water: Not Soluble. Appearance & Odor: Amber colored syrup, mild odor. Volatile Organic Content: 4.43 lbs/gal or 531 grams/liter 10. STABILITY AND REACTIVITY Stability: Conditions to Avoid: Stable None Page 3 of 4
Incompatibility/Materials to Avoid: Hazardous Polymerization: Conditions to Avoid: Hazardous Decomposition of Products: Strong oxidants like liquid chlorine. Will not occur. None If burned, fumes could contain oxides of carbon and nitrogen. 11. TOXICOLOGICAL INFORMATION No information available. 12. ECOLOGICAL INFORMATION No information available. 13. DISPOSAL METHOD Waste Disposal Method: 14. TRANSPORT INFORMATION Proper DOT Shipping Name: Approved site. Obey local, state and federal regulations. Adhesive Containing Flammable Liquid,3, PG II. 15. REGULATORY INFORMATION Chemical Family: Solvent Based Adhesive DOT Hazard Classification: UN 1133 16. OTHER INFORMATION Warning: This product contains chemicals known to the State of California to cause cancer. Hazard Rating: Health: 2 Flammability: 3 Reactivity: 0 Date SDS Prepared: April 3, 2012 THE INFORMATION AND RECOMMENDATIONS SET FORTH HEREIN ARE BELIEVED TO BE ACCURATE. BECAUSE SOME OF THE INFORMATION IS DERIVED FROM INFORMATION PROVIDED TO DURO DYNE CORPORATION FROM ITS SUPPLIERS, DURO DYNE CORPORATION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SINCE THE USE OF THIS INFORMATION AND THE CONDITIONS AND USE OF THIS PRODUCT ARE CONTROLLED BY THE USER, IT IS THE USER'S OBLIGATION TO DETERMINE THE CONDITIONS OF SAFE USE OF THE PRODUCT. THE INFORMATION IS SUPPLIED FOR YOUR INFORMATION AND CONSIDERATION AND DURO DYNE CORPORATION ASSUMES NO RESPONSIBILITY FOR USE OR RELIANCE THEREON. IT IS THE RESPONSIBILITY OF THE USER OF DURO DYNE CORPORATION PRODUCTS TO COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS. Page 4 of 4
DURO DYNE CORPORATION n...". 81 SPENCE STREET HEALTH 2 BAY SHORE, N.V. 11706 FLAMMABILITY 3 EMERGENCY PHONE NO. 800-424 9300 (CHEMTREC) REACTIVITY 0 INFORMATION PHONE NO. 800 899 3876 PERSONAL PROTECTION See Below These ratings should be used only as part of fully implemented H.M.I.S. program. MATERIAL SAFETY DATA SHEET PREPARED BY DURO DYNE 11/2008 REVISED 412008 TRADE NAME: DURO DYNE SOLVENT BASED ADHESIVE MANUFACTURER CODE I.D.: RPG Principal Hazardous Components CAS # Threshold Limit Value Hexane 55.5% by wi. 110-54-3 Toluene 12.5% by wi. 108-88 3 100 ppm These chemicals are subject to the reporting requirements of Section 313 of SARA Title III. OSHA, NTP or IARC does not class the ingredients in this product as carcinogens. All ingredients in this producl are on the TSCA inventory. PERMISSABLE EXPOSURE LEVEL: THRESHOLD LIMIT VALUE: EFFECTS OF ACUTE OVEREXPOSURE: EYES: Can cause severe irritation, redness, tearing, blurred vision. SKIN: Prolonged or repeated contact can cause moderate irritation, defatting, dermatitis. INHALATION: Excessive Inhalation of vapors can cause nasal and respiratory irritation, central nervous system effects including dizziness, weakness, fatigue, nausea, headache, and possible unconsciousness and even death. If breathing is affected, remove individual to fresh air. If difficult breathing, administer oxygen. Give artifical respiration if breathing stopped. INGESTION: Can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Aspiration of material into the lungs can cause chemical pneumonitis, which can be fatal. EFFECTS OF CHRONIC OVEREXPOSURE: Prolonged or repeated exposure to N-Hexane may damage peripheral nerve tissue (that of the arms and legs) and result in muscular weakness and loss of sensation in the extremities (Peripheral Neuropathy). Methyl Ethyl Ketone may potentate (shorten the time of onset) peripheral neuropathy caused by N-Hexane. Prolonged and repeated inhalation of high levels of mixed isomers of Hexane resulted in kidney damage in male rats. The effects observed are the same of those seen in male rats exposed to other hydrocarbons. The mechanism by which these chemicals cause the characteristic kidney toxicity is unique to the male rat and the kidney effects are not expecled to occur in man. Overexposure to this material (or its components) has been suggested as a cause of the following effects in humans and may aggravate pre-existing disorders of these organs, central nervous system and visual impairment EYES: Flush with large amounts of water, lifting upper and lower lids occasionally. Get medical attention. SKIN: Thoroughly wash exposed area with soap and water. Remove and launder contaminated clothing before reuse. INHALATION: Remove to fresh air. If breathing is difficult, administer oxygen. If breathing has stopped, give artifical respiration. Keep person warm, quiet and get medical attention. INGESTION: Do not induce vomiting. Keep person warm, quiet and get medical attention. Aspiration of material into the lungs due to vomiting can cause chemical pneumonitis which can be fatal. RPG MSDS PAGE 1 OF 3
APPEARANCE & ODOR: Amber colored syrup, mild odor BOILING POINT: 150 F VAPOR PRESSURE (mm Hg): 180 VAPOR DENSITY (AIR=1): 3 SOLUBILITY IN WATER: Not Soluble EVAPORATION RATE (N-Butyl Acetate=1): 8 PERCENT VOLATILE: 68% By Weight VOLATILE ORGANIC CONTENT: 4.43 Ibs/gal or 531 grams/liter SPECIFIC GRAVITY (WATER=1):.77 FLASH POINT (TEST METHOD): Tag Closed Cup. <O'F FLAMMABLE LIMITS: UEL: 6.9% LEL: 1.2% EXTINGUISHING MEDIA: Water Fog or Spray, Foam, Dry Chemical CO2. SPECIAL FIRE FIGHTING PROCEDURES: Use air-supplied breathing equipment for enclosed areas. Avoid breathing of vapor or fumes. UNUSUAL FIRE AND EXPLOSION HAZARDS: Heat may build up pressure in closed containers. Cool with water spray. STABILITY: Stable. CONDITIONS TO AVOID: None MATERIALS TO AVOID: Strong oxidants like liquid chlorine. HAZARDOUS DECOMPOSITION OF PRODUCTS: If burned, fumes could contain oxides of carbon and nitrogen. HAZARDOUS POLYMERIZATION: Will not occur SPILL RESPONSE: Remove all ignition sources. Keep people away. Recover liquid. Add absorbent sawdust, etc. Place in sealed containers. WASTE DISPOSAL METHOD: Approved site. Obey Local, State and Federal regulations. Ventilate wipe up. EYES: Wear splash goggles or safety glasses. SKIN: Use chemical resistant gloves. RESPIRATORY PROTECTION (SPECIFIC TYPE): Use NIOSH approved dual cartridge respirator with cartridges suitable for organic solvent vapor. VENTILATION RECOMMENDED: Adequate = to outdoors. OTHER PROTECTION: Eye wash, safety shower. HYGIENIC PRACTICES IN HANDLING & STORAGE: Flammable mixture. Do not store near heat, sparks or open flame. Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor or contact with skin. Do not take internally. In an emergency, call a physician. Keep out of reach of children. STORAGE Do not store with strong oxidants like liquid chlorine or concentrated oxygen. RPG MSDS PAGE 2 OF 3
PROPER DOT SHIPPING NAME: DOT HAZARD CLASSIFICATION: Adhesive Containing Flammable Liquid, 3, PG 11. UN 1133 WARNING: This product contains chemicals known to the State of California to cause birth defects or other reproductive harm. Do not store with strong oxidants like liquid chlorine or concentrated oxygen. THE INFORMATION AND RECOMMENDATIONS SET FORTH HEREIN ARE BELIEVED TO BE ACCURATE. BECAUSE SOME OF THE INFORMATION IS DERIVED FROM INFORMATION PROVIDED TO DURO DYNE CORPORATION FROM ITS SUPPLIERS, DURO DYNE CORPORATION MAKES NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OF THE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SINCE THE USE OF THIS INFORMATION AND THE CONDITIONS AND USE OF THIS PRODUCT ARE CONTROLLED BY THE USER, IT IS THE USER'S OBLIGATION TO DETERMINE THE CONDITIONS OF SAFE USE OF THE PRODUCT. THE INFORMATION IS SUPPLIED SOLELY FOR YOUR INFORMATION AND CONSIDERATION AND DURO DYNE CORPORATION ASSUMES NO RESPONSIBILITY FOR USE OR RELIANCE THEREON. IT IS THE RESPONSIBILITY OF THE USER OF DURO DYNE CORPORATION PRODUCTS TO COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL LAWS AND REGULATIONS. RPG MSDS PAGE 3 OF 3 BJ005431