SPECIFICATION SHEET CUMIN SEED OIL BOTANICAL NAME SOURCE APPEARANCE ODOUR : CUMINUM CYMIMUM L : OBTAINED BY THE STEAM DISTILLATION OF DRIED RIPE FRUIT OF CUMINUM CYMIMUM. : PALE YELLOW TO BROWNISH YELLOW LIQUID. : EXTREMELY POWERFUL, DIFFUSIVE GREEN SPICY, SLIGHTLY FATTY, SOFT & MELLOW. REF. INDEX : 1.494 TO 1.506 AT 20 C SP. GRAVITY AT 25 /25 C : 0.905 TO 0.925 OPT. ROTATION : +2 TO +8, MAIN CONSITUENTS SOLUBILITY USES : CUMINIC ALDEHYDE 22-35% & DYEHYDRO CUMINA ALDEHYDE & MONOTERPENES. : SOLUBLE IN ALCOHOL & OTHER ORGANICS SOLVENTS. : PERFUMERY COMPOUNDS, FRAGRANCES, PICKLES, MEAT, SAUCES, SEASONINGS & FLAVORS ETC. IN THE OPINION OF THE UNDERSIGNED THE SAMPLE COLLECTED FROM PRODUCTION UNIT IS COMPLIES WITH ABOVE SPECIFICATIONS/INTERNATIONAL STANDARD QUALITY. FURTHER IT IS CERTIFIED THAT 10 KG CUMIN SEED OIL PACKED IN 5 KG ALUMINUM BOTTLE AGAINST OUR INVOCIE NO. SI/ES/024/01-02 DT. 24.09.2001 AND AWB.NO. 077-28619076 DT. 25.05.2001 ARE OF FOOD GRADE. Page 1
MATERIAL SAFETY DATA SHEET Section 1 Natural Essential Oils CUMIN SEED OIL MSDS Name : Natural Oil Section 2 Composition, information on ingredients Cuminum Cyminum Seed Oil is the volatile oil expressed form the seeds of the Cumin, Cuminum cyminum L., Umbelliferae CAS No: 8014-13-9 EC No: 283-881-6 EINECS-CAS No: 84775-51-9 Status: Natural Additives: None Application: Aromatherapy, skin care etc IFRA: See Section 16 INCI name: Cuminum Cyminum (Cumin) Seed Oil CAS# Chemical Name Concentration HERBAL BOTANICALS Section 3 Hazards Identification Emergency Overview Appearance : Pale yellow, liquid. Caution : The toxicological properties of this compound have not been full investigated. May cause eye and skin irritation. May cause respiratory and digestive tract irritation. Target Organs : None Potential Health Effects Eye : May cause eye irritation. Skin : May cause skin irritation. Ingestion : May cause irritation of digestive tract. The toxicological properties of this substance have not been full investigated. Inhalation : May cause respiratory tract irritation. The toxicological properties of this substance have not been full investigated. Chronic : No information found. Section 4 First Aid Measures Eyes : Flush eyes with plenty of water at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin : Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion : If victim is conscious and alert, give 2-4 cupfuls of milk and water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation : Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician : Treat symptomatically and supportively. Page 2
Section 5 Firefighting Measures General Information : As in any fire, wear self-contained breathing apparatus in pressure demand,msha/niosh (approved or equivalent) and protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing Media :Use water spray,dry chemical, carbon dioxide or appropriate foam. Section 6 Accidental Release Measures General Information : Use proper personal protective equipment as indicated in Section-8. Spills / Leaks : Clean up spill immediately, observing precaution in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Section 7 Handling and Storage Handling : Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin and clothing. Avoid ingestion and inhalation. Use with adequate ventilation. Storage : Store in cool, dry place. Keep container closed when not in use. Section 8 Exposure Controls, Personal Protection Engineering Controls:Facilities storing or utilizing this should be equipped with eyewash & safety shower.use adequate ventilation to keep airborne concentration low. Exposure Limits : Chemical Name ACGIH NIOSH OSHA Final PELS Natural Essential Oil None listed None listed None listed OSHA Vacated PELs : No OSHA Vacated PELs are listed for this compound. Personal Protective Equipment Eyes : Wear appropriate protective glasses or chemical safety goggles as described by OSHA,s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin : Wear appropriate protective gloves to prevent skin exposure. Clothing : Wear appropriate protective clothing to minimize contact with skin. Respirators : A respiratory protective program that meet OSHA,s 29 CFR 1910.134 and ANSI 288.2 requirements or European Standard EN 149 must be followed whenever conditions warrant a respirator s use. Page 3
Section 9 Physical and Chemical Properties Physical State : Liquid Appearance : Broenish liquid. Odor : cumin like. PH : Not available Vapor Pressure : Not available Vapor Density : Not available Evaporation Rate : Not available Viscosity : Not available Boiling Point : 150deg.Centgrade. Decomposition Temperature : Not available Auto ignition Temperature : Not available Flash Point : 190deg. NFPA Rating : Not published Explosion Limits, Lower : Not available Upper : Not available Solubility : Not available Specific Gravity / Density : Not available Section 10 Stability and Reactivity Chemical Stability : Stable under normal temperature and pressure. Conditions to Avoid : Incompatible material, dust generation, strong oxidants. Incompatibility : Oxidizing agent. Hazardous Decomposition Products : Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon dioxide. Hazardous Polymerization : Has not been reported. Section 11 Toxicological Information RTECS# : CAS# : LD50/LC50 : Not available Carcinogenicity Epidemiology Teratogeniety Reproductive Effects Neurotoxicity Mutagenicity Other Studies : Page 4
Section 12 Ecological Information Section 13 Disposal Considerations Compound waste generators must determine whether a discarded oil is classified as a hazardous waste. US EPA guidelines for the classification are listed in 40 CFR parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series RCRA U-Series : None listed : None listed Section 14 Transport Information Shipping Name Hazard Class : UN Numbering : Packing Group : RID / ADR IMO Canada TDG Non Haz. Non Haz. Non Haz. Non Haz. Non Haz. Not Regulated to DGR goods Not Regulated to DGR goods Not Regulated to DGR goods Not Regulated to DGR goods Not Regulated to DGR goods Section 15 Regulatory Information US FEDERAL TSCA CAS# : Health & Safety Reporting List : None of the compound in this product are on the Health and Safety reporting list. Chemical Test Rules : None of the chemicals in this product are under Chemical Test Rule. Section 12b : None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule : None of the chemicals in this material have a SNUR under TSCA.SARA Page 5
Section 302 (RQ)None of the chemicals in this material have an RQ. Section 302 (TPQ)None of the chemicals in this material have a TPQ. Section 313No chemicals are reportable under Section 313. Clean Air Act This material does not contain any hazardous pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any class 2 Ozone depletors. Clean Water Act None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of chemicals in this product are listed as Priority Pollution under the CWA. None of chemicals in this product are listed as Toxic pollutants under the CWA. OSHA None of chemicals in this product are considered highly hazardous by OSHA. STATE CAS# : NA, is not present on state lists from CA, PA, MN, MA, FL OR NJ. California No Significant Risk Level : None of the chemicals in this product are listed. European / International Regulations European Labeling in Accordance with EC Directives Hazard Symbols : Not available Risk Phrases : Safety Phrases : S 24/25 Avoid contact with skin and eyes. WGK (Water Danger / Protection) CAS# : NA, No information available CAS# : is listed on Canada s DSL/NDSL list. WHMIS : Not available CAS# : NA, is not listed on Canada s Ingredient Disclosure list.exposure Limits Section 16 Additional Information The above information is believed to be accurate and represent the best information available to us. However, we make no warrant of merchantability or any other warranty, express or implied, with respect to such information and we assume no liability from its use. User should make their own investigations to determine the suitability of the information for their particular purpose. In no way shall Madar Corporation be liable for any claims, losses or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Madar Corporation has been advised of the possibility of such damages. Page 6
DECLARATION OF ALLERGENS PRODUCT Cumin Seed Oil MATERIAL CAS NUMBER AMYL CINNAMAL 122-40-7 - BENZYL ALCOHOL 100-51-6 - CINNAMYL ALCOHOL 104-54-1 - CITRAL 5392-40-5 - EUGENOL 97-53-0 - HYDROXYCITRONELLAL 107-75-5 - ISO EUGENOL 97-54-1 - AMYL CINNAMYL ALCOHOL 101-85-9 - BENZYL SALICYLATE 118-58-1 - CINNAMAL 104-55-2 - COUMARIN 91-64-5 - GERANIOL 106-24-1 - HYDROXYISOHEXYL 3-CYCLOHEXENE CARBOXALDEHYDE 31906-04-4 - ANISE ALCOHOL 105-13-5 - BENZYL CINNAMATE 103-41-3 - FARNESOL 4602-84-0 - BUTYLPHENYL METHYLPROPIONAL 80-54-6 - LINALOOL 78-70-6 - BENZYL BENZOATE 120-51-4 - CITRONELLOL 106-22-9 - HEXYL CINNAMAL 101-86-0 - LIMONENE 5989-27-5 - METHYL 2-OCTYNOATE 111-12-6 - ALPHA-ISOMETHYL IONONE 127-51-5 - EVERNIA PRUNASTRI EXTRACT 90028-68-5 - TOTAL ALLERGEN INCLUSION LEVEL (%) EVERNIA FURFURACEA EXTRACT 90028-67-4 - NO ALLERGEN Page 7