Date of issue: 05/31/2018 Revision date: 08/27/2018 Version: 5.0 SECTION 1: Identification 1.1. Product identifier Product form : Article Product name : 1.2. Recommended use and restrictions on use Recommended use : Brake lining 1.3. Supplier Manufacturer Hitachi Chemical Mexico, S.A. de C. V. Av. Encino No.1020, Montemorelos Industrial Park, Montemorelos, Nuevo Leon, C.P.67500, Mexico T 52-826-263-0100 Distributor Hitachi Chemical Co.,Ltd. Advanced Functional Materials R&D Dept. 4-29-1, Nakanokami-cho, Hachioji-shi, Tokyo, 192-0041 Japan T 81-42-627-8315 1.4. Emergency telephone number Emergency number : 81-42-627-8311 SECTION 2: Hazard identification 2.1. Classification of the substance or mixture Classification (GHS-CA) Manufactured Article: GHS classification and labelling not applicable. This product is exempt from classification and labelling as per the Hazardous Products Act, Paragraph 12(i). 2.2. GHS Label elements, including precautionary statements GHS-CA labelling 2.3. Other hazards This molded article is not considered hazardous under normal conditions. Dust produced by friction or impact may cause skin corrosion or irritation, serious eye damage, and damage to the respiratory system. 2.4. Unknown acute toxicity (GHS-CA) SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % Phenol resin (CAS-No.) 9003-35-4 8-12 Calcium carbonate (CAS-No.) 471-34-1 33-43 Calcium hydroxide (CAS-No.) 1305-62-0 5-10 Graphite (CAS-No.) 7782-42-5 1-5 Aluminium (CAS-No.) 7429-90-5 1-5 Zinc (CAS-No.) 7440-66-6 3-7 Block copolymer (Trade secret) 0.5-1.5 Lubricant (Trade secret) 1-3 Others 25.5 35.5 *Chemical name, CAS number and/or exact concentration have been withheld as a trade secret SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. : IF ON SKIN: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. : Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Get medical advice/attention if you feel unwell. 08/27/2018 EN (English) Hitachi Chemical Company Ltd,. 1/5
4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion : May cause irritation to the respiratory tract. 4.3. Immediate medical attention and special treatment, if necessary Other medical advice or treatment : Causes skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. May cause burns. : May be harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting and diarrhea. : Symptoms may be delayed. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Suitable extinguishing media 5.2. Unsuitable extinguishing media Unsuitable extinguishing media : Carbon dioxide (CO2). Foam. Dry chemical powder. Dry sand. : Do not use a direct water stream. 5.3. Specific hazards arising from the hazardous product Fire hazard 5.4. Special protective equipment and precautions for fire-fighters Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures 6.2. Methods and materials for containment and cleaning up For containment Methods for cleaning up 6.3. Reference to other sections For further information refer to section 8: "Exposure controls/personal protection" SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Products of combustion may include, and are not limited to: oxides of carbon. : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. : Contain spill, then place in a suitable container. Minimize dust generation. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). : Scoop up material and place in a disposal container. Provide ventilation. : Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not swallow. Handle and open container with care. When using do not eat, drink or smoke. : Wash contaminated clothing before reuse. Always wash hands after handling the product. : Keep out of the reach of children. Keep container tightly closed. Keep away from heat and direct sunlight. Prevent getting product wet. USA - ACGIH ACGIH TWA (mg/m³) 5 mg/m³ 8.2. Appropriate engineering controls Appropriate engineering controls Environmental exposure controls : Ensure good ventilation of the work station. : Avoid release to the environment. 8.3. Individual protection measures/personal protective equipment Hand protection: Wear suitable gloves resistant to chemical penetration Eye protection: Wear eye/face protection 08/27/2018 EN (English) Hitachi Chemical Company Ltd,. 2/5
Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. : Handle in accordance with good industrial hygiene and safety procedures. Do not eat, drink or smoke when using this product. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Relative evaporation rate (ether=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Vapour pressure at 50 C Relative density Solubility Partition coefficient n-octanol/water Viscosity, kinematic Explosive limits 9.2. : Solid : Molded article : Gray. : Slight aromatic. : Not flammable : Insoluble in water SECTION 10: Stability and reactivity 10.1. Reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : No dangerous reactions known under normal conditions of use. : Stable under normal conditions. : No dangerous reactions known under normal conditions of use. : Heat. Prevent getting product wet. : None known. : May include, and are not limited to: oxides of carbon. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) LD50 oral rat Zinc (7440-66-6) LD50 oral rat Skin corrosion/irritation 7340 mg/kg 630 mg/kg 08/27/2018 EN (English) Hitachi Chemical Company Ltd,. 3/5
Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion SECTION 12: Ecological information 12.1. Toxicity Ecology - general Zinc (7440-66-6) LC50 fish 1 LC50 fish 2 EC50 Daphnia 1 EC50 72h algae (1) EC50 96h algae (1) 12.2. Persistence and degradability Persistence and degradability 12.3. Bioaccumulative potential Bioaccumulative potential BCF fish 1 : May cause irritation to the respiratory tract. : Causes skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. May cause burns. : May be harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting and diarrhea. : Likely routes of exposure: ingestion, inhalation, skin and eye. : May cause long-term adverse effects in the aquatic environment. 2.16-3.05 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) 0.211-0.269 mg/l (Exposure time: 96 h - Species: Pimephales promelas [semi-static]) 0.139-0.908 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) 0.09-0.125 mg/l (Species: Pseudokirchneriella subcapitata [static]) 0.11-0.271 mg/l (Species: Pseudokirchneriella subcapitata [static]) Not established. Not established. (no bioaccumulation) 12.4. Mobility in soil 12.5. Other adverse effects Ozone : Not classified. : No other effects known. SECTION 13: Disposal considerations 13.1. Disposal methods Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. SECTION 14: Transport information 14.1. Basic shipping description In accordance with TDG Transportation of Dangerous Goods Not regulated for transport 14.2. Transport information/dot 08/27/2018 EN (English) Hitachi Chemical Company Ltd,. 4/5
14.3. Air and sea transport SECTION 15: Regulatory information 15.1. National regulations All components of this product are listed, or excluded from listing, on the Toxic Substances Control Act (TSCA) Chemical Substance Inventory. 15.2. International regulations All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic Substances List) inventories. SECTION 16: Date of issue : 05/31/2018 Revision date : 08/24/2018 : None. Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the suitability and completeness of this information for the user s own particular use. 08/27/2018 EN (English) Hitachi Chemical Company Ltd,. 5/5