MATERIAL SAFETY DATA SHEET DESCRIPTION BLACK POLYURETHANE ADHESIVE 310ML ORDER CODE S 136 MSDS SECTION 1: Identification of the substance / preparation and company 1.1 Product identifier S136 1.2 Relevant identified uses of the substance or mixture and uses advised against Adhesives Sealants 1.3 Details of the supplier of the safety data sheet: Seals + Direct LTD Unit 6, Milton Business Centre Wick Drive, New Milton Hants, BH25 6RH Tel: 01425 617722 Fax: 01425 610967 Email: sales@sealsplusdirect.co.uk 1.4 Emergency telephone number Tel: 01425 617722 (Mon Fri 8:30am 5pm) SECTION 2: Hazards Identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 This information and our technical advice, whether verbal, in writing or by way of trials, is given in good faith but without warranty. This also applies where proprietary rights are involved. Our advice does not release you from the obligations to check its validity and to test our products as to their suitability for the intended use. The storage, application and use of our products are beyond our control and, therefore, entirely your own responsibility. Our products are sold in accordance with our General Conditions of Sale. The information contained within this data sheet is subject to change without notice. Page 1 of 14 Issue date: 06.03.17
The product is classified and labelled according to the CLP regulation. Hazard pictograms Signal word Danger GHS08 Hazard-determining components of labelling methylenediphenyl diisocyanate, isomeres and homologues Hazard statements H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Precautionary statements P261 Avoid breathing mist/vapours/spray. P280 Wear protective gloves. P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. Additional information EUH204 Contains isocyanates. May produce an allergic reaction. 2.3 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. SECTION 3: Composition / information on ingredients 3.2 Chemical characterisation Mixtures Description Mixture of several substances Page 2 of 14 Issue date: 06.03.17
CAS: 1330-20-7 EINECS: 215-535-7 Reg.nr.: 01-2119488216-32-xxxx CAS: 90622-57-4 EC number: 918-167-1 Reg.nr.: 01-2119472146-39-xxxx CAS: 28553-12-0 EINECS: 249-079-5 Reg.nr.: 01-2119430798-28-xxxx CAS: 101-68-8 EINECS: 202-966-0 Reg.nr.: 01-2119457014-47-xxxx CAS: 25686-28-6 NLP: 500-040-3 Reg.nr.: 01-2119457013-49-xxxx Dangerous components xylene, mixed isomers, pure Flam. Liq. 3, H226; STOT RE 2, H373; Asp. Tox. 1, H304; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335 hydrocarbons, C11-C12 Flam. Liq. 3, H226; Asp. Tox. 1, H304; Aquatic Chronic 4, H413 di-''isononyl'' phthalate substance with a workplace exposure limit diphenylmethane-4,4'-diisocyanate Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 4,4'-methylenediphenyl diisocyanate, oligomers Resp. Sens. 1, H334; Carc. 2, H351; STOT RE 2, H373; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 < 5.0% < 2.0% < 2.0% < 0.5% < 0.2% SVHC Doesn t contain SVHC-substances Additional information For the wording of the listed hazard phrases refer to section 16. SECTION 4: First Aid Measures 4.1 Description of first aid measures After inhalation Supply fresh air; consult doctor in case of complaints. In case of unconsciousness bring patient into a stable side position for transport. After skin contact Treat affected skin with cotton wool or cellulose. Then wash and rinse thoroughly with water and a mild cleaning agent. After eye contact Rinse opened eye for several minutes under running water. Then consult doctor. After swallowing Do not induce vomiting; call for medical help immediately. Page 3 of 14 Issue date: 06.03.17
4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed SECTION 5: Fire-fighting Measures 5.1 Extinguishing media Suitable extinguishing agents Water spray Alcohol-resistant foam Fire-extinguishing powder Carbon dioxide For safety reasons unsuitable extinguishing agents Water with full jet. 5.2 Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. 5.3 Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. SECTION 6: Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation 6.2 Environmental precautions Do not allow to enter sewers / surface or ground water. 6.3 Methods and material for containment and cleaning up Pick up mechanically. 6.4 Reference to other sections Page 4 of 14 Issue date: 06.03.17
See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. SECTION 7: Handling and Storage 7.1 Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Information about protection against explosions and fires The product contains small quantities of organic solvents. The possibility of an ignitable vapour / air mixture forming is very slight but, under certain local conditions, this should not be overlooked. Keep ignition sources away - Do not smoke. 7.2 Conditions for safe storage, including any incompatibilities Storage requirements to be met by storerooms and receptacles Prevent any seepage into the ground. Information about storage in one common storage facility Store away from foodstuffs. Further information about storage conditions Protect from frost. Keep receptacle tightly sealed. Protect from heat and direct sunlight. Store receptacle in a well ventilated area. Store in dry conditions. Storage class (according german VCI-concept) 13 7.3 Specific end use(s) SECTION 8: Exposure Controls / Personal Protection Additional information about design of technical systems No further data; see item 7. Page 5 of 14 Issue date: 06.03.17
8.1 Control parameters Additional information about design of technical systems No further data; see item 7. 8.1 Control parameters Components with limit values that require monitoring at the workplace 28553-12-0 di-''isononyl'' phthalate WEL (Great Britain) Long-term value: 5 mg/m³ 8.2 Exposure controls WEL (Great Britain) 101-68-8 diphenylmethane-4,4'-diisocyanate Short-term value: 0.07 mg/m³ Long-term value: 0.02 mg/m³ Sen; as -NCO 25686-28-6 4,4'-methylenediphenyl diisocyanate, oligomers WEL (Great Britain) BMGV (Great Britain) Personal protective equipment Short-term value: 0.07 mg/m³ Long-term value: 0.02 mg/m³ Sen; as -NCO Ingredients with biological limit values 1330-20-7 xylene, mixed isomers, pure 650 mmol/mol creatinine Medium: urine Sampling time: post shift Parameter: methyl hippuric acid General protective and hygienic measures The usual precautionary measures should be adhered to when handling chemicals. Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of the work. Immediately remove all soiled and contaminated clothing. Breathing equipment Not required with good ventilation and/or adequate extractor facilities. In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Short term filter device A2 (DIN EN 14387 / DIN EN 141) Page 6 of 14 Issue date: 06.03.17
Protection of hands Direct contact with the chemical preparation must be avoided by organizational measures. Apply skin protectant before working with gloves to avoid skin swellings and use a skin cleansing and skincare product after the work. Compliance with the stated penetration time (starts with the first product contact) must be ensured! The gloves need to be disposed of after the penetration time and new gloves used! For the permanent contact gloves made of the following materials are suitable If longer exposure to the chemical preparation is necessary, a sturdy overglove against mechanical strain is recommended in combination with the Barrier 02-100 underglove from Ansell (penetration time 480 min). For the permanent contact of a maximum of 15 minutes gloves made of the following materials are suitable Fluorinated rubber (Viton) (0.7mm - penetration time 15 min) As protection from splashes gloves made of the following materials are suitable Recommended for protection from splashes: disposable nitrile gloves (minimum thickness 0.12 mm) with long cuffs. After contact with the chemical preparation, take the disposable nitrile glove off immediately and put on a new disposable nitrile glove. Eye protection Safety glasses SECTION 9: Physical and Chemical Properties 9.1 Information on basic physical and chemical properties Appearance Form Colour Odour Pasty Penetrometer test according ADR 2.3.4.3 Test result: solid (penetration after 5s < 15mm) Black Solvent-like Change in condition Boiling point/boiling range Not applicable Flash point Not applicable Ignition temperature > 200 C Explosion limits Lower: 0.4 Vol % Page 7 of 14 Issue date: 06.03.17
Upper: 7.6 Vol % Vapour pressure at 20 C < 100 hpa Specific gravity at 20 C Solubility in / Miscibility with water 1.17 g/cm³ Insoluble reacts with water Solvent content Organic solvents 5.9 % VOC (EU) 68.9 g/l VOC (EU) 5.90 % VOC (CH) 5.90 % 9.2 Other information Burning test according 33.2.1.4 "Manual of Test and Criteria" [Recommendations on the TRANSPORT OF DANGEROUS GOODS (United Nations)] Burning rate:- 2,2mm/s [Not a dangerous good according class 4.1(ADR)] SECTION 10: Stability and Reactivity 10.1 Reactivity 10.2 Chemical stability Thermal decomposition / conditions to be avoided. No decomposition if used according to specifications. 10.3 Possibility of hazardous reactions Reacts with alcohols, amines, aqueous acids and alkalis. Reacts with water forming carbon dioxide. In closed containers there is a danger of bursting, due to build up of pressure. 10.4 Conditions to avoid 10.5 Incompatible materials Page 8 of 14 Issue date: 06.03.17
10.6 Hazardous decomposition products In case of fire, the following substance(s) may occur: Hydrogen chloride (HCl) Nitrogen oxides Sulphur oxides (SOx) SECTION 11: Toxicological Information 11.1 Information on toxicological effects Acute toxicity LD/LC50 values that are relevant for classification Dermal Inhalative ATE (Acute Toxicity Estimates) LD50 LD50/4 h 29891 mg/kg 299 mg/l Oral Dermal Inhalative 1 330-20-7 xylene, mixed isomers, pure LD50 LD50 LC50/4 h 3523 mg/kg (rat) 1100 mg/kg (ATE) 11 mg/l (ATE) Primary irritant effect Skin corrosion/irritation Prolonged or repeated contact with the skin may cause skin irritation. Serious eye damage/irritation Respiratory or skin sensitisation May cause allergy or asthma symptoms or breathing difficulties if inhaled. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Germ cell mutagenicity Page 9 of 14 Issue date: 06.03.17
Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard SECTION 12: Ecological Information 12.1 Toxicity Aquatic toxicity 12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil Additional ecological information General notes Do not allow product to reach ground water, water course or sewage system. 12.5 Results of PBT and vpvb assessment PBT vpvb Not applicable. Not applicable. Page 10 of 14 Issue date: 06.03.17
12.6 Other adverse effects SECTION 13: Disposal Consideration 13.1 Waste treatment methods Recommendation Disposal in accordance with official regulations EWC-Code(s) To be treated as industrial waste: do not dispose of in or on soil, in watercourses or bodies, or through a sewage system. These EU refuse code numbers are recommendations for waste accruing through the use of adhesives and sealants. Any waste produced from organic solvents or other dangerous substances listed under item 3 of this safety datasheet is itself classified as dangerous (*). Waste accruing during application 080409* waste adhesives and sealants containing organic solvents or other dangerous substances 080410 waste adhesives and sealants other than those mentioned in 080409 Waste accruing during cleaning 08 04 11* adhesive and sealant sludges containing organic solvents or other dangerous substances 08 04 12 adhesive and sealant sludges other than those mentioned in 080411 Soiled waste packaging 15 01 10* packaging containing residues of or contaminated by dangerous substances. Clean waste packaging 15 01 01 paper and cardboard packaging 15 01 02 plastic packaging 15 01 04 metallic packaging Uncleaned packagings Recommendation Disposal must be made according to official regulations. Page 11 of 14 Issue date: 06.03.17
SECTION 14: Transport Information 14.1 UN-Number ADR,RID,ADN, ADN, IMDG, IATA Void 14.2 UN proper shipping name - ADR,RID,ADN, ADN, IMDG, IATA Void 14.3 Transport hazard class(es) - ADR,RID,ADN, ADN, IMDG, IATA - Class Void 14.4 Packing group ADR,RID,ADN, IMDG, IATA Void 14.5 Environmental hazards Marine pollutant No 14.6 Special precautions for user Not applicable 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Transport/Additional information UN "Model Regulation" Not applicable. Protect from moisture Void SECTION 15: Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3, 20, 52a, 56a 15.2 Chemical safety assessment A Chemical Safety Assessment has not been carried out. Page 12 of 14 Issue date: 06.03.17
SECTION 16: Other Information Revision date Refer to the date at bottom of sheet For industrial use only. Legend of H- and R-phrases, concerning the in chapter 3 mentioned substances (marking of product please see chapter 2) H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. H413 May cause long lasting harmful effects to aquatic life. Abbreviations and acronyms RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organisation ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOCV: Lenkungsabgabe auf flüchtigen organischen Verbindungen, Schweis (Swiss Ordinance on volatile organic compounds) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic Page 13 of 14 Issue date: 06.03.17
SVHC: Substances of Very High Concern vpvb: very Persistent and very Bioaccumulative Flam. Liq. 3: Flammable liquids Category 3 Acute Tox. 4: Acute toxicity Category 4 Skin Irrit. 2: Skin corrosion/irritation Category 2 Eye Irrit. 2: Serious eye damage/eye irritation Category 2 Resp. Sens. 1: Respiratory sensitisation Category 1 Skin Sens. 1: Skin sensitisation Category 1 Carc. 2: Carcinogenicity Category 2 STOT SE 3: Specific target organ toxicity (single exposure) Category 3 STOT RE 2: Specific target organ toxicity (repeated exposure) Category 2 Asp. Tox. 1: Aspiration hazard Category 1 Aquatic Chronic 4: Hazardous to the aquatic environment - long-term aquatic hazard Category 4 Page 14 of 14 Issue date: 06.03.17