Material Safety Data sheet Issuing date: May 8, 2006 1. IDENTIFICATION OF SUBSTANCE: Product name: Dorfen Producer : Dor.Ky D&D LTD P.O.B 232 Ness Ziona 70400 Israel 2. COMPOSITION\ DATA ON COMPOSITION a. Imidacloprid (95%) 10% IUPAC name: 1-chloro-3-pyridylmethyl)-N-nitroomidazolidin-2-ylideneamine CAS Registry Num: 138261-41-3 b. Pyriproxyfen (98%) 2% IUPAC name: 2-(1-Methyl-2-(4-phenoxyphenoxy)ethoxy)pyridine CAS Registry Num: 95737-68-1 Molecular Weight:321.40 Molecular Formula: C20H19.NO3 c. Not Hazardous ingredients Up to 100% 3. HAZARDS IDENTIFICATION: NON-HAZARDOUS SUBSTANCE NON-DANGEROUS GOOD May irritate slightly eyes and skin. Not flammable. Hazard designation: Not hazardous. Risk phrases: Not applicable. Safety phrases: Not applicable. HMIS Ratlngs: Health =1 Flammability = 0 Reactivity = 0
4. FIRST AID MEASURES If poisoning occurs, immediately contact a doctor, and follow the advice given. Show this Material Safety Data sheet to a doctor. Inhalation: Remove patient to fresh air. Keep rested and warm. Skin contact: Remove patient s clothing and wash skin thoroughly with soap and water. Eye contact: Irrigate eyes immediately with copious quantities of water for 15 minutes. Ingestion: give plenty of water to drink. Never give anything by mouth to an unconscious person. Seek medical assistance. First Aid Facilities: Provide washing facilities in the workplace. Symptoms: Include: apathetic state, depressed muscular tone, respriatory disturbance and trambling. Muscular cramps are also possible in severe cases of poisoning. Medical attention: Treat symptoms (nicotine-like effects). No spesific antidote knowen. Check blood pressure and pulse frequently since bradycardia and hypotension are possible. Provide supportive measures for the respiratory function and cardiac action. Give artificial respiation if sighns of paralysis appear. Additional therapeutic measures involve elimination of the substance from the body or acceleration of its excretion (gastric lavage, saline laxatives). Contra-indications: Absorption promoting agents such as alcoholic beverages and milk. 5. FIRE FIGHTIN MEASURES: Suitable extinguishing agent: water spray, carbon dioxide, dry chemical powder or foam. Protective equipment: wear self-containd breathing apparatus and protective clothing to prevent contact with skin and eyes. Unusual fire hazard: may emit toxic fumes under fire conditions.
6. ACCIDENTAL RELEASE MEASURES: Person-related safety precautions: cordon off area of spill; wear self-contained breathing apparatus, protective clothing and heavy rubber gloves. Measures of cleaning \collecting: absorb solution with finely- powdered liquid-binding material (diatomite, universal binders);decontaminate surfaces and equipment by scrabbing with alcohol. Dispose of contaminated material according to Section 13 7. HANDLING AND STORAGE: Information for safe handling: avoid contact with skin, eyes and clothing; material may be an irritant. Storage: Stable on exposur to air. Stable =190 0 C. Under U.V. irradiation and in sunlight, a cis-trans isometerisation, splitting of the ester bond, and loss of bromine occur. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION: Personal protective equipment as follows: Breathing equipment: approved respirator. Hands protection: chemical-resistant rubber gloves. Eye protection: chemical safety goggles Other: Do not eat, drink or smoke until after washing. Wash thoroughly after handling. After each day s wash contaminate clothing. 9. PHISICAL AND CHEMICAL PROPERTIES: Form: Liquid suspension. Color: White opaque. Odor: slight specific odor. Boiling point - Water solubility: create suspension. Oil solubility: slightly soluble. ph value: (in a 10 % diluted sol 7.5
10. STABILITY AND REACTIVITY: Flammability Product is stable under normal conditions. Keep away from flames. Dangerous decomposition or Combustion Product No data available. Thermal decomposition Flash point : No flashpoint up to 100 c. 11. TOXICOLOGICAL INFORMATION: Acute Oral Toxicity :LD50 rats > 2000 mg/kg body weight. Acute Dermal Toxicity :LD50 rats > 2000 mg/kg body weight. Acute Inhalation Toxicity :LC50 rats > 0.1.276 mg/l air. Acute Dermal Irritation/Corrosion - not irritant to the skin of rabbit. Acute Eye Irritation/Corrosion - not irritant to the eyes. Skin sensitization test in Guinea- Pig non sensitizer as observed by the method of Guinea pig. 12. ECOLOGICAL INFORMATION: Very toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment. Fish: LC 50 (96h) for rainbow trout > 0:325 mg/l. Daphnia: EC50(48h) 0.40 mg\l. Toxicity to algas: Not available Birds: Not available. 13. DISPOSAL CONSIDERATION: In case of spill (liquid), wash it immediately with an industrial vacuum cleaner. Then scrab contaminated area with detergent and water. Put wastes in disposal container. During the cleanup operation, wear protectiv clothing and equipment such as overalls, hat, face shield, safety glasses, mask, rubber
gloves, rubber or plastic apron and boots. Do wash residues into drains or other waterways. Disposal (1) After intended use: This product should be disposed of as hazardous waste. Dispose of sealed containers at approved hazardous waste disposal site. (2) After spill or accident This material should be disposed of as hazardous waste. Dispose of sealed containers at approved hazardous waste disposal site. 14. TRANSPORTATION INFORMATION Do not transport with food and feedstuffs. UN no 3082 Proper Shipping name : Environmentally hazardous substance liquid N.O.S ( containing Imidacloprid ) Class : 9 Packing group : III 15. REGULATIONS: Safety phrases: in case of accident, flush eyes or skin with copious amounts of water, remove contaminated clothing and shoes; call a phisician. 16. OTHER INFORMATION The above information is belived to be correct based on our present knowledge. For research use only by trained personnel. The burden of safe use of this material rests entirely with the user.