Chemistry. CAS Number : Kao Chemicals Europe O R N H R = C 17 H AMIDET N In-Cosmetics th April 2012

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Transcription:

AMIDET N

Chemistry O R N H O 2.5 H R = C 17 H 33 INCI Name : PEG-4 Rapeseedamide CAS Number : 85536-23-8 Character : non-ionic

Characteristics Appearance (20ºC) : Clear Yellowish Liquid Colour (Gardner) : < 4 ph ( 1 % product + 99 % H 2 O ) : 9.2 10.2 Amide (mv/g) : 1.64 1.75 Free Amine (mv/g) : 0.11 0.23 Water Content (KF; %) : 6.5 8.5 Viscosity (mpa. s/20ºc) : < 500 Refractive Index (n 25 D ) : 1.4675 1.4705 1,4-Dioxane (ppm) : < 1 Products & Application ( 3)

Ecological Toxicity Properties SNF approval : Good Environmental Choice Fish Toxicity (OECD 203 : Zebra fish) : LC 50 = 13 mg/l (96 h) Daphnia Toxicity (OECD 404 : Daphnia Magna) : EC 50 = 7 mg/l (48 h) Aerobic Biodegradability (OECD 301B) : Anaerobic Biodegradability (ISO 11734) : 71 % after 28 days 81 % after 56 days Suitable for Eco-label and Nordic Swan labeled formulations

LAUNCHED PRODUCTS Products with AMIDET N in its formula

Application Properties Liquid Nitroso-amine free Better than cocamide DEA SNF approval : Good Environmental Choice Refatting Agent Products & Application ( 6)

Thickening Agent : SLES/Thickener (3:1; 15 % a.m.)

visc. (mpas at 20 C) Thickening Agent : SLES free formulations 1200 1100 1000 900 800 700 600 500 400 300 200 100 0 Sodium Laureth-6 Carboxylate 7.5% 7.5% Decyl Glucoside 7.5% 7.5% Cocamide DEA 5.0% - AMIDET N - 5.0 % B A 0 1 2 3 4 5 % NaCl B A

foam height (mm) Foam Booster 250 Amidet N FOAM VOLUME versus Cocamide DEA Ross Miles : 0.1% a.m. SLES/Cosft.; 37 C ; 15 gh 200 150 100 50 0 0 5 10 15 time (min.) AMINOL Amidet N cocos-dea Cocamide DEA

Foam Booster for mixtures SLES / CAPB Ross Miles Test : 0.1 % a.m.; 15 gh; 25 C; ph : 6.5 220 200 180 160 185 195 210 192 140 120 100 80 60 40 20 3 SLES 1 CAPB 3 SLES 1 CAPB 0.25 AMIDET N 3 SLES 1 CAPB 0.50 AMIDET N 3 SLES 1 CAPB 0.75 AMIDET N 0 SLES = Sodium Laureth Sulfate CAPB = Cocamidopropyl Betaine

MIOI values Mild Surfactant : mixtures with SLES 30 25 SLES Red Blood Cell Test (Ocular Irritation Potential) AMIDET N Cocamidopropyl Betaine 20 15 CO-SURFACTANT 10 5 0 0 10 20 30 40 50 60 70 80 90 100 % CO-SURFACTANT

Solubilizing properties AMIDET N vs commonly used non-ionic solubilizers %w/w of solubilizer required to solubilize 1% of cosmetic oils Cosmetic Oils AMIDET N Polysorbate-20 PEG-40 Hydrogenated Castor Oil Olive oil 5 >10 5 Jojoba oil 10 >10 5 Isopropyl Myristate 1 5 1 Mineral Oil 10 >10 5 Cold-processable Hot-processable AMIDET N performs better than Polysorbate-20 and similar than PEG-40 Hydrogenated Castor Oil but with the advantage of the cold processing

Solubilizing properties Synergistic combination between AMIDET N and PEG-40 Hydrogenated Castor Oil 12:7:1 AMIDET N : PEG-40 Hydrogenated Castor Oil : Water Solubilizer 0.5% Jojoba Oil 2% Jojoba Oil PEG-40 H Castor Oil Turbid White AMIDET N Turbid White Blend Clear Clear These formulations have good foamability and good skin-care properties.

AMIDET N as Liquid Co-emulsifier Due to its emulsifying properties in O/W systems, AMIDET N can help to incorporate dimethicones efficiently into formulations. The best combination to emulsify silicones is: 3:1:1 Silicone : AMIDET N : Water This blend is a clear viscous gel, easily incorporated into formulations at room temperature.

Product Application Liquid Soap Baby Shampoo Foaming Bath Oil Hand Cleanser Products & Application ( 15)

KAO Formulations

KAO Formulations

KAO Formulations

Summary Thickening agent (Nitrosamines free) for SLES based formulations Thickening agent for very mild SLES free formulations Foam Volume Booster for SLES / Betaine Solubilizer for fatty alcohols into aqueous surfactant solutions Solubilizer for oils into non-aqueous surfactant solutions Emulsifier for silicone, paraffin & vegetable oils Anti-cracking agent for soap & syndet bars Products & Application ( 19)