Omya Consumer Goods omya.com. Oral Care. Natural Minerals for Toothpaste Formulations

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Omya Consumer Goods omya.com Oral Care Natural Minerals for Toothpaste Formulations

About Omya Omya is a leading global producer of Calcium Carbonate and a worldwide distributor of specialty chemicals. With more than 130 years of experience and 175 plants in over 50 countries, Omya is a leader in research and development, innovation and support. Oral Care Excellent cleaning performance, remineralization and whitening for toothpaste After many years of research, our expertise in dental care meets manufacturers expectations based on consumer needs for dental care formulations. The focus of toothpaste formulators continues to be on all-in-one / total care products comprising cavity protection, prevention of gingivitis and plaque, extra fresh breath, tartar control, tooth whitening properties, enamel strengthening and sensitivity relief. In oral care, Omya minerals are known as multifunctional ingredients, providing enamel remineralization in addition to excellent cleansing. Benefits Gentle cleansing Remineralization & repair Whiter teeth 2

Omya offers a wide portfolio of oral care ingredients, including two mineral product ranges: High purity natural Calcium Carbonate Functionalized Calcium Carbonate Omyacare Omyadent Excellent cleaning performance with adjustable abrasivity Texture & mouthfeel Remineralization Whitening 3

Omyacare Natural Calcium Carbonate with adjustable abrasivity levels With Omyacare, we offer a range of natural Calcium Carbonate with adjustable abrasivity levels, that suits the needs of modern toothpaste formulations, a pure and natural ingredient providing multifunctional benefits. Omyacare is manufactured under clean and controlled production conditions which means a low carbon footprint. Excellent cleaning performance The cleaning result is due to the use of abrasives in toothpaste compositions providing the polishing effect of surface. However, not all consumers need the same abrasiveness level. For instance, low abrasion toothpaste would be recommended for children or sensitive teeth. Whereas a toothpaste with elevated abrasivity delivers enhanced stain removal and enables formulations with teeth whitening properties. The variety of particle sizes within the Omyacare product range and Omya s expert advice, guarantee the achievement of the exact desired abrasion level in the final formula. Omyacare meets the desired abrasivity level in your formulation 4

Technical facts The abrasive activity of the Omyacare range is compared to two silica grades commonly used in formulas. Omya can offer cleaning particles to formulate efficient toothpastes from low, over medium to high abrasion at very precise and achievable levels. Silica low abrasion Silica high abrasion Omyacare S 100 - AV Omyacare S 80 - AV Omyacare S 70 - KP Omyacare S 70 - AZ Omyacare Extra 35 - OG Omyacare HP 900 - OG 0 20 40 60 80 100 120 140 Table 1: Abrasion and cleaning performance depending on the selected Omyacare grade. Relative Dentin Abrasivity (RDA) is a method for measuring the abrasive action of a toothpaste on the tooth dentin. It is calculated by using standardized abrasives compared to the test sample and depends on the size, quantity and surface structure of abrasives used in toothpastes. The values have been obtained through Omya in-house technology that is available to customers in joint development projects. Texture & Mouthfeel Mouthfeel is an important property and it is highly considered by consumers in the final formula. Factors such as the concentration of the cleaning ingredient and particle size directly affect texture and mouthfeel. Omyacare, at the recommended concentration and right combination of grades, is suitable for adjusting organoleptic properties such as texture, color, opacity and viscosity besides cleaning performance, in order to meet the customer s needs. Omyacare can adjust texture, color and cleaning performance in formulations 5

High purity and perfect performance Omyacare is chemically pure and has high microbiological quality. It complies with the most stringent quality requirements. In addition, Omyacare minerals are suitable for fluoridized toothpastes which, formulated at the right ph value, provide remineralization properties in the final product. Calcium Carbonate provides remineralization and lasting protection, when formulated with sodium monofluorophosphate (SMFP), thanks to particles retained in plaque for neutralizing harmful acids. Omyacare is suitable for fluoridized toothpastes 6 6

Gentle toothpaste containing 45% Omyacare S 80 - AV for smooth cleaning effect Ingredients INCI Nomenclature % w / w A Phoskadent NA 211 Sodium Saccharin Sorbitol 70% Aqua dem. Carrageenan Sodium Benzoate Sodium Monofluorophosphate Sodium Saccharin Sorbitol Aqua (Water) Carrageenan Sodium Benzoate 1.10 0.20 22.00 add. 100 0.80 0.20 B Omyacare S 80 - AV Titanium Dioxide Calcium Carbonate Titanium Dioxide 45.00 0.50 C Sorbosil TC15 Hydrated Silica 4.00 D Galaxy 796G Galaxy CAPB DC Sodium Lauryl Sulfate Cocamidopropyl Betaine 1.15 1.25 E Flavor Aroma q.s. Procedure 1 Phase A: Into a beaker combine sorbitol with all powders and mix under strong agitation. Add water and stir to make a homogeneous texture. 2 Add part B step by step to part A. 3 Add part C step by step under strong agitation and homogenize. 4 Stir slowly and cool down to room temperature 5 Add part D under slow agitation, optionally under vacuum. 6 Finally add flavorings also under slow agitation. 7

Omyadent Large surface area which ensures high reactivity and excellent remineralization Omyadent particles have a core of Calcium Carbonate and a shell of hydroxyapatite, the main constituent of the enamel and dentin in our teeth. Omyadent s tailor-made particles have large surface areas which assure high reactivity and excellent remineralization. Omyadent is produced using Omya proprietary technology, in which the mineral is modified such that new surface features develop and particles become porous. This allows for a variety of products with a broad spectrum of properties, capabilities and applications. CALCIUM CARBONATE Omyadent particles in Scanning Electron Microscopy (SEM) images. An increased surface area is shown. HYDROXYAPATITE 8

Remineralize and repair for a whiter, healthier smile Remineralization & Whitening Omyadent 100 - OG is a source of calcium and phosphate with a large surface area, ensuring high reactivity and efficient remineralization of the enamel by repairing microscopic defects. The result of applying Omyadent 100 - OG is a smoother and whiter tooth surface. Remineralization & Whitening Mechanism of action Enamel surface lesions can be effectively repaired with Omyadent 100 - OG. The large surface area of Omyadent 100 - OG ensures high reactivity and efficient remineralization. As a result, Omyadent 100 - OG improves tooth whiteness while smoothening the surface of the teeth. Before treatment After treatment Bovine tooth enamel treated with Omyadent 100 - OG and 1450 ppm of sodium monofluorophosphate, provide a smoother tooth surface as defects have been repaired by a remineralization process (Images 1000x). 9

Gentle toothpaste containing 5% Omyadent 100 - OG for remineralization & whitening A B Ingredients INCI Nomenclature % w / w Phoskadent SF Sodium Saccharin Sorbitol 70% Aqua dem. Cellulose Gum Propylene Glycol Glycerin Omyadent 100 OG Sorbosil AC35 Titanium Dioxide Sodium Fluoride Sodium Saccharin Sorbitol Aqua (Water) Cellulose Gum Propylene Glycol Glycerin Calcium Hydroxyapatite (&) Calcium Carbonate Hydrated Silica Titanium Dioxide 0.32 0.15 23.00 add. 100 0.65 10.00 10.00 5.00 20.00 1.00 C Sorbosil TC15 Hydrated Silica 5.50 D Galaxy 796G Galaxy CAPB DC Sodium Lauryl Sulfate Cocamidopropyl Betaine 1.15 1.25 E Flavor Aroma q.s. Procedure 1 Phase A: Into a beaker combine sorbitol with all powders and mix under strong agitation. Add water and stir to make a homogeneous texture. 2 Add part B step by step to part A. 3 Add part C step by step under strong agitation and homogenize. 4 Stir slowly and cool down to room temperature 5 Add part D under slow agitation, optionally under vacuum. 6 Finally add flavorings also under slow agitation. 10

Product offering Finding the right solution Product Material RDA Indicated for Usage level (%) Omyacare S 80 - AV Natural Calcium Carbonate Medium - High All-purpose formulas 30 45 Omyacare S 70 - KP Omyacare S 70 - AZ Natural Calcium Carbonate Medium - High All-purpose formulas 30 45 Omyacare S 100 - AV Natural Calcium Carbonate Medium Whitening formulas 30 45 Omyacare S 90 - KP Natural Calcium Carbonate Medium Whitening formulas 30 45 Omyacare Extra 35 - OG Natural Calcium Carbonate Medium Sensitive teeth 30 45 Omyacare S 110 - KP Natural Calcium Carbonate Medium Sensitive teeth 30 45 Omyacare HP 900 - OG Natural Calcium Carbonate Low Sensitive teeth 30 45 Omyacare S 80 - AL * Natural Calcium Carbonate Medium Organic toothpastes 30 45 Omyacare S 90 - AL * Natural Calcium Carbonate Low - Medium Organic toothpastes 30 45 Omyadent 100 - OG ** Funcionalized Calcium Carbonate Non - Abrasive Premium repairing formulas and whitening 5 * COSMOS certified ** COSMOS and NATRUE certified 11

09/2018 Omya Consumer Goods +41 62 789 21 91 info.cosmetics@omya.com Omya International AG CH-4665 Oftringen www.omya.com Omya has taken every possible care to ensure that the information herein is correct in all aspects. However, Omya cannot be held responsible for any errors or omissions which may be found herein, nor will it accept responsibility for any use which may be of the information, the same having been given in good faith, but without legal responsibility. This information does not give rise to any warranties of any kind, expressed or implied, including fitness for purpose and non-infringement of intellectual property. The technical information presented comprises typical data and should not be taken as representing a specification. Omya reserves the right to change any of the data without notice.