Sr. No Annexure-I List of Products Name of Products CAS Number Quantity (MT/month) Existing Proposed Total 1. Para Nitro Benzoic 62-12-7 4.00 38.00 42.00 2. Meta Nitro Benzoic 121-92-6 0.0 3. Para chloro benzoic 74-11-3 4. 2 chloro 4 nitro benzoic 5. 2,4 - Di chloro benzoic 99-60-5 50-84-0 6. Ortho Chloro Benzoic 118-91-2 Acid 7. Para amino Benzoic 150-13-0 0.0 24.0 24.0 8. Meta amino Benzoic 99-05-8 9. 3,5 - Diamino benzoic 535-87-5 10. 3- amino 4 - chloro benzoic 11. Para amino benzoic Methyl Ester 12. Para amino benzoic Ethyl Ester 13. Para nitro benzoic Methyl Ester 14. Para nitro benzoic Ethyl Ester 15. Sodium salt of 4 Amino benzoic 16. Potassium salt of 4 Amino benzoic 17. Sodium salt of 4 nitro benzoic 18. Potassium salt of 4 nitro benzoic 19. Ammonium salt of 4 Nitro benzoic 2840-28-0 619-45-4 0.0 8.0 8.0 94-09-7 619-50-1 99-77-4 555-06-6 0.0 8.0 8.0 138-84-1 3847-57-2 15922-01-7 19416-70-7 Total: 4.0 78.0 82.0 M/s. Shri Hari Chemicals - 1 -
List of Raw Materials Sr. No. Name of Products Name of Raw Materials Quantity MT/MT 1. Para Nitro Benzoic Nitric Acid 1.80 Pera Nitro Toluene 1.00 2. Meta Nitro Benzoic Nitric Acid 1.70 Meta Nitro Toluene 1.00 3. Nitric Acid 1.60 Para chloro benzoic Pera Chloro Toluene 1.00 4. 2 chloro 4 nitro benzoic 2 - Chloro - 4 - Nitro Toluene 0.90 Nitric Acid 1.50 5. 2,4 - Di chloro benzoic 2,4 - Di Chloro Toluene 1.00 Nitric Acid 1.10 6. Ortho Chloro Benzoic Acid Nitric Acid 1.30 Ortho Chloro Toluene 0.90 7. Para amino Benzoic PNBA 1.40 Iron Powder 2.34 Acetic Acid 0.04 Sodium Hydroxide 0.23 HCl 0.53 8. Meta amino Benzoic MNBA 1.40 Iron Powder 2.34 Acetic Acid 0.04 Sodium Hydroxide 0.23 HCl 0.53 9. 3,5 - Diamino benzoic 3,5 Di Nitro benzoic 1.53 Catalyst 0.01 Hydrogen 0.06 Sulphuric 0.37 Nitrogen 0.02 10. 3- amino 4 - chloro benzoic 3 Nitro 4 Chlro benzoic 1.22 Catalyst 0.01 Hydrogen 0.03 Sulphuric 0.37 Nitrogen 0.02 11. Para amino benzoic Methyl Para Amino benzoic Ester 0.90 Methanol 0.12 Sulphuric 0.38 12. Para amino benzoic Ethyl Ester Para Amino benzoic 0.90 Ethanol 0.13 Sulphuric 0.38 M/s. Shri Hari Chemicals - 2 -
Sr. No. Name of Products Name of Raw Materials Quantity MT/MT 13. Para nitro benzoic Methyl Para Nitro benzoic 0.90 Ester Methanol 0.12 Sulphuric 0.38 14. Para nitro benzoic Ethyl Ester Para Nitro benzoic 0.90 Ethanol 0.13 Sulphuric 0.36 15. Sodium salt of 4 Amino benzoic Para Amino benzoic 0.80 Salt 0.42 Sodium Hydroxide 0.14 16. Potassium salt of 4 Amino benzoic Para Amino benzoic 0.80 Salt 0.31 Potassium Hydroxide 0.24 17. Sodium salt of 4 nitro benzoic 18. Potassium salt of 4 nitro benzoic 19. Ammonium salt of 4 Nitro benzoic Para Nitro benzoic 0.80 Salt 0.32 Sodium Hydroxide 0.24 Para Nitro benzoic 0.80 Salt 0.28 Potassium Hydroxide 0.14 Para Amino benzoic 0.80 Salt 0.52 Ammonium Hydroxide 0.24 M/s. Shri Hari Chemicals - 3 -
1. Para Nitro Benzoic Acid: Annexure-II Manufacturing Process Charge water into vessel and then heat to certain temperature. Charge Para Nitro Toluene and Nitric Acid. For Filtration add water in vessel and final product is received at the end after drying. CH 3 + H 2 O + HNO + H 2 O 3 + NOx Para Nitro Benzoic Acid Mass Balance of Para Nitro Benzoic Water 600 NOx 350 Nitric Acid 1800 Oxidation Pera Nitro Toluene 1000 Water 446 Filtration & Effluent 2096 Evaporatio Loss 400 Para Nitro Benzoic 1000 Total: 3846 3846 M/s. Shri Hari Chemicals - 4 -
2. Meta Nitro Benzoic : Charge water into vessel and then heat to certain temperature. Charge Meta Nitro Toluene and Nitric Acid. For Filtration add water in vessel and final product is received at the end after drying. CH 3 + H 2 O + HNO + H 2 O 3 + NOx Meta Nitro Benzoic Acid Mass balance: Mass Balance of Meta Nitro Benzoic Water 640 NOx 320 Nitric Acid 1700 Oxidation Meta Nitro Toluene 1000 Water 355 Filtration & Effluent 1925 Evaporation Loss 450 Para Nitro Benzoic 1000 Total: 3695 3695 M/s. Shri Hari Chemicals - 5 -
3. Para Chloro Benzoic Acid: Charge water into vessel and then heat to certain temperature. Charge Para Chloro Toluene and Nitric Acid. For Filtration add water in vessel and final product is received at the end at the end after drying. CH 3 + HNO + H 2 O 3 + H 2 O + NOx Cl Cl Para Chloro Benzoic Acid Mass Balance of Para chloro benzoic Water 650 NOx 320 Nitric Acid 1600 Oxidation Pera Chloro Toluene 1000 Water 438 Filtration & Effluent 1958 Evaporation Loss 410 Para Chloro Benzoic 1000 Total: 3688 3688 M/s. Shri Hari Chemicals - 6 -
4. 2 chloro 4 nitro benzoic : Charge water into reducer and then heat to certain temperature and then add Nitric Acid. Then add 2 - Chloro - 4 - Nitro Toluene. For Filtration add water in vessel and final product is received at the end at the end after drying. CH 3 Cl Cl + H 2 O + HNO + H 2 O 3 + NOx Mass Balance of 2 - Chloro - 4 - Nitro Benzoic 2 - Chloro - 4 - Nitro T 900 Nitric Acid 1500 Oxidation NOx 320 Water 900 Water 450 Filtration & Effluent 2030 & Packing 2 - Chloro - 4 - Nitro Benzoic 1000 Evaporation loss 400 Total: 3750 3750 M/s. Shri Hari Chemicals - 7 -
5. 2,4 - Di chloro benzoic : Charge water into reducer and then heat to certain temperature and then add Nitric Acid. Then add 2,4 Di-Chloro Nitro Toluene. For Filtration add water in vessel and final product is received at the end at the end after drying. CH 3 Cl + HNO + H 2 O 3 Cl + H 2 O + NOx Cl Cl 2, 4 Di Chloro Benzoic Acid2 Mass Balance of 2,4 - Di Chloro Benzoic 2,4 - Di Chloro Toluene 1000 Nitric Acid 1100 Nitration NOx 290 Water 900 Water 350 Filtration & Evaporation& Packing Effluent 1660 Evaporation loss 400 2 - Chloro - 4 - Nitro Benzoic 1000 Total: 3350 3350 M/s. Shri Hari Chemicals - 8 -
6. Ortho Chloro Benzoic Acid: Charge water into reactor and then heat to certain temperature and then add Nitric Acid. Then slowly add Para Chloro Toluene. For Filtration add water in vessel and final product is received at the end after drying. CH 3 Cl + HNO + H 2 O 3 Cl + H 2 O + NOx Ortho chloro Benzoic Acid Mass Balance of Ortho chloro benzoic Water 900 Nitric Acid 1300 Oxidation NOx 320 Para Chloro Toluene 900 Water 350 Filtration & Effluent 1928 Evaporation Loss 202 Ortho Chloro Benzoic 1000 Total: 3450 3450 M/s. Shri Hari Chemicals - 9 -
7. Para amino Benzoic Charge water into reactor and then heat to certain temperature and then add iron powder and. Then add Pera Nitro Benzoic Acid in vessel. For crystallization add HCl. Again mass is filtered and spray dried. Product is received at the end. + Fe + H 2 O HCl + H 2 O + Fe(OH) NH2 Para Amino Benzoic Acid Mass Balance of Para amino Benzoic PNBA 1400 Iron Powder 2340 Acetic Acid 40 Water 1200 Sodium Hydroxide 230 Reduction Filtration Iron Sludge 3700 HCl 530 Crystalization Water 265 Filtration Effluent 1030 Evaporation Loss 275 PABA 1000 Total 6005 6005 M/s. Shri Hari Chemicals - 10 -
8. Meta amino Benzoic : Charge water into reactor and then heat to certain temperature and then add iron powder and. Then add Pera Nitro Benzoic Acid in vessel. For crystallization add HCl. Again mass is filtered and spray dried. Product is received at the end. + Fe + H 2 O HCl + H 2 O + Fe(OH) NH 2 Meta Amino Benzoic Acid Mass Balance of Meta amino Benzoic MNBA 1400 Iron Powder 2340 Acetic Acid 40 Water 1200 Sodium Hydr 230 Reduction Filtration Iron Sludge 3700 HCl 530 Crystallization Water 260 Filtration Waste Water 1005 MABA 1000 Evaporation Loss 295 Total 6000 6000 M/s. Shri Hari Chemicals - 11 -
9. 3, 5 Di amino benzoic : Charge water into reactor and add Sulphuric along with 3, 5 Di Nitro benzoic and catalyst. And Catalyst is recovered at the end of Hydrogenation Process. For Filtration add water in vessel and final product is received at the end. + H 2 + N 2 + H 2 SO 4 Catalyst + H 2 O NH2 NH2 Mass Balance of 3,5 - Diamino benzoic 3,5 - DiNitro benzoic 1530 Catalyst 7 Catalyst Recovery 7 Hydrogen 64 Hydrogination Sulphuric 365 Nitrogen 22 Water 250 Filtration & Effluent 996 Evaporation Loss 235 3,5 - Diamino benzoic 1000 Total: 2238 2238 M/s. Shri Hari Chemicals - 12 -
10. 3- amino 4 - chloro benzoic Charge water into reactor and add Sulphuric along with 3 Nitro 4 Chloro Benzoic and catalyst. And Catalyst is recovered at the end of Hydrogenation Process. For Filtration add water in vessel and final product is received at the end. + H 2 + N 2 + H 2 SO 4 Catalyst + H 2 O Cl Cl NH 2 Mass Balance of 3- amino 4 - chloro benzoic 3 Nitro 4 Chlro benzoic ac 1220 Catalyst 7 Catalyst recovery 7 Hydrogen 32 Hydrogination Sulphuric 365 Nitrogen 22 Water 350 Filtration & Effluent 754 3- amino 4 - chloro benzoic 1000 Evaporation Loss 235 Total: 1996 1996 M/s. Shri Hari Chemicals - 13 -
11. Methyl Ester of Para amino benzoic Charge water into vessel and then add Para Amino benzoic, Methanol and Sulphuric. Methanol is recovered during distillation process. For Filtration add water in vessel and product is dried at the end product is received. O C O CH 3 + CH 3 OH + H 2 SO 4 CH 3 OH + H 2 O + NH 2 Methyl Easter of PABA Mass Balance of Para amino benzoic Methyl Ester Para Amino benzoic 900 Methanol (fresh) 2885 Effluent 510 Esterification Sulphuric 380 Water 310 Distillation Distillation residue 14 Methanol Recovery 2770 Water 370 Filtration & Aquaceous Layer to ETP 321 Evaporation Loss 230 Para amino benzoic Methyl Es 1000 Total: 4845 4845 M/s. Shri Hari Chemicals - 14 -
12. Ethyl Ester of Para amino benzoic Charge water into vessel and then add Para Amino benzoic, Ethanol and Sulphuric. Methanol is recovered during distillation process. For Filtration add water in vessel and product is dried at the end product is received. O C O CH 2 CH 3 + CH 3 CH 2 OH + H 2 SO 4 CH 3 CH 2 OH + + H 2 O NH 2 NH 2 Ethyle Easter of PABA Mass Balance of Para amino benzoic ethyl Ester Para Amino benzoic 900 Ethanol (fresh) 2990 Esterification Sulphuric 380 Water 310 Effluent 510 Distillation Distillation residue 10 Recovered Ethanol 2860 Water 370 Filtration & Aquaceous Layer to ETP 330 Evaporation Loss 240 Para amino benzoic ethyl Este 1000 Total: 4950 4950 M/s. Shri Hari Chemicals - 15 -
13. Methyl Ester of Para Nitro benzoic Charge water into vessel and then add Para Nitro benzoic, Methanol and Sulphuric. Methanol is recovered during distillation process. For Filtration add water in vessel and product is dried at the end product is received. O C O CH 3 + CH 3 OH + H 2 SO 4 CH 3 OH + H 2 O + NH 2 NH 2 Mass Balance of Para Nitro benzoic ethyl Ester Para Nitro benzoic 900 Methanol (fresh) 2885 Effluent 510 Esterification Sulphuric 380 Water 310 Distillation Distillation residue 14 Recovered Methanol 2770 Water 370 Filtration & Effluent to ETP 342 Evaporation Loss 209 Para Nitro benzoic ethyl Ester 1000 Total: 4845 4845 M/s. Shri Hari Chemicals - 16 -
14. Ethyl Ester of Para Nitro benzoic Charge water into vessel and then add Para Nitro benzoic, Ethanol and Sulphuric. Methanol is recovered during distillation process. For Filtration add water in vessel and product is dried at the end product is received. O C O CH 2 CH 3 + CH 3 CH 2 OH + H 2 SO 4 CH 3 CH 2 OH H + 2 O + Ethyle Easter of PNBA Mass Balance of Para Nitro benzoic ethyl Ester Para Nitro benzoic 900 Ethanol (fresh) 2990 Effluent 510 Esterification Sulphuric 360 Water 330 Distillation Distillation residue 14 Recovered Ethanol 2860 Water 370 Filtration & Effluent to ETP 331 Evaporation Loss 235 Para Nitro benzoic ethyl Ester 1000 Total: 4950 4950 M/s. Shri Hari Chemicals - 17 -
15. Sodium salt of 4 Amino benzoic Add water, Caustic Soda and Salt into the vessel. Then slowly add Pera Amino Benzoic Acid Slowly.For Filtration add water into the Vessel. At the end Sodium salt of 4 amino benzoic is received. COONa + NaOH + H 2 O + NaCl + H 2 O NH 2 NH 2 Salts of Sodium PABA Mass Balance of Sodium salt of 4 Amino benzoic Para Amino benzoic 800 Salt 420 Sodium Hydroxide 140 Water 600 Reaction Vessel Water 250 Filtration & Waste Water 890 Evaporation Loss 320 Sodium salt of 4 Amino benzoic ac 1000 Total: 2210 2210 M/s. Shri Hari Chemicals - 18 -
16. Potassium salt of 4 Amino benzoic Add water, Potassium Hydroxide and Salt into the vessel. Then slowly add Pera Amino Benzoic Acid Slowly.For Filtration add water into the Vessel. At the end Potassium salt of 4 amino benzoic is received. COOK + KOH + H 2 O + NaCl + H 2 O NH 2 Salt of Potassium PABA Mass Balance of Potassium salt of 4 Amino benzoic Para Amino benzoic 800 Salt 310 Potassium Hydroxide 240 Water 600 Reaction Vessel Water 250 Filtration & Waste Water 880 Evaporation Loss 320 Potassium salt of 4 Amino benzoic 1000 Total: 2200 2200 M/s. Shri Hari Chemicals - 19 -
17. Sodium salt of 4 nitro benzoic Add water, Sodium Hydroxide and Salt into the vessel. Then slowly add Pera Nitro Benzoic Acid Slowly.For Filtration add water into the Vessel. At the end Potassium salt of 4 nitro benzoic is received. COONa + NaOH + H 2 O + NaCl + H 2 O Salts of Sodium PNBA Mass Balance of Sodium salt of 4 nitro benzoic Para Nitro benzoic 800 Salt 320 Sodium Hydroxide 240 Water 550 Reaction Vessel Water 250 Filtration & Waste Water 810 Evaporation Loss 350 Sodium salt of 4 nitro benzoic 1000 Total: 2160 2160 M/s. Shri Hari Chemicals - 20 -
18. Potassium salt of 4 nitro benzoic Add water, Potassium Hydroxide and Salt into the vessel. Then slowly add Pera Nitro Benzoic Acid Slowly.For Filtration add water into the Vessel. At the end Potassium salt of 4 nitro benzoic is received. COOK + KOH + H 2 O + NaCl + H 2 O Salts of Sodium Pottasium PNBA Mass Balance of Potassium salt of 4 Nitro benzoic Para Nitro benzoic 800 Salt 280 Potassium Hydroxide 140 Water 700 Reaction Vessel Water 250 Filtration & Waste Water 870 Evaporation Loss 300 Potassium salt of 4 Nitro benzoic a 1000 Total: 2170 2170 M/s. Shri Hari Chemicals - 21 -
19. Ammonium salt of 4 nitro benzoic Add water, Ammonium Hydroxide and Salt into the vessel. Then slowly add Pera Nitro Benzoic Acid Slowly.For Filtration add water into the Vessel. At the end Potassium salt of 4 nitro benzoic is received. COONH 2 + NH 4 OH+ H 2 O + NaCl + H 2 O Ammonium salt of 4 nitro benzoic A Mass Balance of Ammonium salt of 4 Nitro benzoic Para Amino benzoic 800 Salt 520 Ammonium Hydroxide 240 Water 1500 Reaction Vessel Filtration & Water 250 Waste Water 2090 Evaporation Loss 220 Ammonium salt of 4 Nitro benzoic 1000 Total: 3310 3310 M/s. Shri Hari Chemicals - 22 -
Annexure-III Water Balance Diagram Total fresh water consumption 25 KLD (fresh water 19.2 + 5.8 Recycle water) Domestic 2.0 Process 8.0 Scrubber 5.5 5.0 Utility 3.5 Greenbelt 1.0 Soak pit 1.6 Process 12.5 Water retained with 4.5 RM Boiler 3.0 Loss 2.0 Retain as moisture with Iron Sludge 6.0 Sodium Nitrite 25% 5.2 Water/steam loss 0.5 Blow down 0.5 4.5 ETP 4.5 + 0.3 + 5.0 + 0.5 + 0.5 =10.8 RO 10.8 5.8 Permeate reuse 5.0 CETP- Vatva M/s. Shri Hari Chemicals - 23 -
Sr. No. Source Water Consumption Water Consumption Existing (KL/day) Water Consumption After expansion (KL/day) 1. Domestic 0.6 2.0 2. Green Belt -- 1.0 3. Industrial A Water treatment 0.0 0.5 B Process 3.0 8.0 C Scrubber 1.0 5.5 D Boiler 0.0 3.0 2.0 5.0 Total Industrial 6.0 22.0 TOTAL (1 +2 + 3) 6.6 25.0 Recycle water -- 5.8 Fresh water requirements 6.6 19.2 Sr. No. Source Wastewater Generation W/w Generation Existing (KL/day) W/w Generation After expansion (KL/day) 1. Domestic 0.5 1.6 2. Industrial A Water treatment 0.0 0.5 B Process 1.9 4.5 C Scrubber 0.1 0.3 D Boiler 0.0 0.5 E 3.0 5.0 Total Industrial 5.0 10.8 TOTAL (1 +2) 5.5 12.4 M/s. Shri Hari Chemicals - 24 -
Annexure-IV Hazardous Waste Details Sr. No. Type of Waste 1. ETP Waste 2. Iron Sludge 2. Discarded Containers / Liners Category No. as per HWM rules, 2016 35.3 12 MT/Month 28.1 0 MT/Month 33.1 30 Nos./year Quantity Existing Proposed Total 50 kg/month 3. Used Oil 5.1 10 liter/year 4. Distillation Residue 5. Spent Catalyst 6. Sodium Nitrite (25%) (From Scrubber) 8 MT/Month 90 MT/Month 470 Nos./year 450 kg/month 30 liter/year 20.3 -- 0.15 Mt/Month 28.2-0.800 Mt/Year --- -- 30 Mt/ Month 20 MT/Month 90 MT/Month 500 Nos./year 500 kg/month 40 liter/year 0.15 Mt/Month 0.800 Mt/Year 30 Mt/ Month Method of Disposal Collection, Storage, Transportation, Disposal at TSDF approved by board. Collection, Storage, Transportation, sell to cement manufacturer. Collection, Storage, Transportation, Disposal by selling to authorized recycler. Collection, Storage, Transportation, Disposal by selling to authorized recycler. Collection, storage & disposal at CHWIF or coprocessing. Collection, storage & return back to supplier for regeneration. Collection, Storage, Transportation, sell to actual user. M/s. Shri Hari Chemicals - 25 -
Sr. No. Stack attached to Existing Flue Gas Stacks 1. Thermo Pack Boiler ( 5 Lakhs Kcal/h) Process Gas Stacks Fuel Type Diesel (80 Lt/h) Annexure-V Details of Air Pollution Stack Height, in m APC measures Probable emission 11 ---- PM:150 mg /Nm 3 SO2:100 PPM NO x :50 PPM 1. Reactor Vessel ---- 18 Three Stage Alkali Rubber Proposed addition after expansion NO x: 25 mg /Nm 3 Flue Gas Stacks 1 Boiler(500 Kg) Agro Briquettes (1.5 Mt/Day) Process Gas Stacks 21 Cyclone & Bag filter PM:150 mg /Nm 3 SO2:100 PPM NO x :50 PPM 1. Reactor Vessel ----- 18 Two stage ic and one stage alkaline Scrubber NO x: 25 mg /Nm 3 M/s. Shri Hari Chemicals - 26 -