SECTION 1 IDENTIFICATION GHS Product Identifier Trade Name: Cola Dry N4 CAS Number: Proprietary Uses of the Substance / Mixture: Surfactant for various applications Company Name: Colonial Chemical, Inc. Company Address: 225 Colonial Drive, South Pittsburg, TN 37380 USA Phone Number: (P) 423.837.8800 (F) 423.837.3888 Emergency Phone Number: Colonial Chemical: 423.837.8800 Chemtrec: 800.424.9300 SECTION 2 HAZARDOUS IDENTIFICATION GHS Hazard Classification Acute Toxicity (oral), Category 4 Aspiration Hazard, Category 1 Skin Irritation, Category 2 Eye Damage, Category 1 H302: Harmful if swallowed H304: May be fatal if swallowed and enters the airways H315: Causes skin irritation H318: Causes serious eye damage Label Elements: Hazardous products which must be listed on the label: 2-Butoxyethanol CAS# 111-76-2 Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Pictogram: Signal word: Danger Hazard statements: H302 Harmful if swallowed H304 May be fatal if swallowed and enters the airways H315 Causes skin irritation H318 Causes serious eye damage Precautionary statements: General None Prevention P261 P264 P270 P271 P280 Avoid breathing dust/fumes/gas/mist/vapours/spray. Wash hands and exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area Wear protective gloves/eye protection/face protection. Response P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor P302+P352 IF ON SKIN: Wash with plenty of water P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician P330 Rinse mouth. Colonial Chemical, Inc. 225 Colonial Drive South Pittsburg, TN 37380 Emergency: 423-837-8800 Chemtrec: 800 424-9300 Issue date: 04/17/2017 1 of 6
P331 P332+P313 P362+P364 Storage P403+P233 P404 P405 Disposal P501 Do NOT induce vomiting. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse Store in a well ventilated place. Keep container tightly closed. Store in a closed container Store locked up Dispose of contents and/or container in accordance with local, regional, national, and/or international regulations. SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS Substance Chemical nature: Surfactant Information on Components and Impurities Chemical Name CAS No. GHS Classification Concentration (%) Cola Dry N4* Proprietary* Acute toxicity (Oral), Cat 4 H302 Harmful if swallowed Skin Irritation, Cat 2 H315: Causes skin irritation Eye Damage, Cat 1 H318: Causes serious eye damage >40%* Mineral Spirits Oil 64742-47-8 Aspiration Hazard, Cat 1 H304: May be fatal if swallowed and enters the airways <50%* 2-Butoxyethanol 111-76-2 Flammable liquids, Cat 4 H227 Combustible liquid Acute toxicity (Oral), Cat 4 H302 Harmful if swallowed Skin irritation, Cat 2 H315: Causes skin irritation Eye irritation, Cat 2 H319: Causes serious eye irritation Aspiration hazard, Cat 1 H304 May be fatal if swallowed and enters airways. <10% *The specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of 1910.1200. SECTION 4 FIRST AID MEASURES Description of necessary first-aid measures Inhalation: Skin contact: Remove to fresh air, give artificial respiration if not breathing. Oxygen may be given by qualified personnel if necessary. Immediately flush with copious amounts of soap and water for at least 5 minutes. If irritation persists, contact physician. Eye contact: Immediately flush with copious amounts of water for at least 15 minutes. Consult physician Ingestion: Contact physician or poison control center immediately. If victim is conscious and able to swallow, quickly give milk or water to dilute. SECTION 5 FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media: Use water spray, CO2, or foam Special hazards arising from the substance or mixture Specific hazards during firefighting: None known Colonial Chemical, Inc. 225 Colonial Drive South Pittsburg, TN 37380 Emergency: 423-837-8800 Chemtrec: 800 424-9300 Issue date: 04/17/2017 2 of 6
Advice for firefighters Special protective equipment: Use protective clothing, eye protection and self contained breathing apparatus SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Methods for Cleaning or Taking Up Soak up material with absorbent, shovel into waste container, flush area with water. Additional advice Spilled material is slippery. Wash thoroughly after handling. SECTION 7 HANDLING AND STORAGE Handling Advice on safe handling and usage: Storage Recommended: Avoid overheating or freezing. Avoid overheating or freezing. SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Components with workplace control parameters CAS No. Components Value type (Form of exposure) Control parameters/permissible Concentration Basis 111-76-2 2-Butoxyethanol TWA 20ppm ACGIH TWA 5ppm 24 mg/m3 NIOSH REL TWA 50 ppm 240 mg/m3 OSHA Z-1 TWA 25ppm 120 mg/m3 OSHA P0 Control Measures Engineering measures: Personal protective equipment Respiratory protection: Hand protection: Eye protection: Skin and body protection: None known General and local exhaust ventilation is recommended to maintain vapor exposures below recommended limits. Where concentrations are above recommended limits or are unknown, appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29 CFR 1910.134) and use NIOSH/MSHA approved respirators. Protection provided by air purifying respirators against exposure to any hazardous chemical is limited. Use a positive pressure air supplied respirator if there is any potential for uncontrolled release, exposure levels are unknown, or any other circumstance where air purifying respirators may not provide adequate protection PVC-coated/rubber protective gloves Mono-goggles Wear a chemical resistant apron. Hygiene measures: When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. Protective measures: Eye wash and safety shower in the work area. Wear a chemical resistant apron. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Colonial Chemical, Inc. 225 Colonial Drive South Pittsburg, TN 37380 Emergency: 423-837-8800 Chemtrec: 800 424-9300 Issue date: 04/17/2017 3 of 6
Appearance Physical state: Color: Odor: Odor Threshold: Liquid Clear, red liquid characteristic Safety data ph (20% aq): 5.0 7.0 Melting point/range: Boiling point/boiling range: Flash point: >95 C Flammability (solid, gas): Auto-ignition temperature Water solubility: dispersible Solubility in other solvents Partition coefficient: n-octanol/water: Vapor pressure: Evaporation rate: Relative vapor density: Specific Gravity: 0.966 @ 25 C Oxidation/Reduction Potential: Viscosity: < 1000cps Explosive properties: Thermal decomposition: Lower explosion limit: Upper explosion limit: %VOC: <10% SECTION 10 STABILITY AND REACTIVITY Chemical Stability Stable Hazardous reactions Conditions to avoid Materials to avoid None known Avoid contamination with strong acids and strong bases SECTION 11 TOXICOLOGICAL INFORMATION Acute toxicity Acute oral toxicity: Acute inhalation toxicity: Acute dermal toxicity: Other routes of administration: Aspiration toxicity: Skin corrosion/irritation Skin irritation: Serious eye damage/eye irritation Eye irritation: Respiratory or skin sensitization Sensitization: Repeated dose toxicity Repeated dose toxicity: STOT STOT - single exposure: STOT - repeated exposure: Carcinogenicity Carcinogenicity: Harmful if swallowed May be fatal if swallowed and enters the airways Irritant Eye damage possible May cause respiratory irritation Colonial Chemical, Inc. 225 Colonial Drive South Pittsburg, TN 37380 Emergency: 423-837-8800 Chemtrec: 800 424-9300 Issue date: 04/17/2017 4 of 6
Mutagenicity Genotoxicity in vitro: Genotoxicity in vivo: Reproductive toxicity Reproductive toxicity: SECTION 12 ECOLOGICAL INFORMATION Ecotoxicity assessment Ecotoxicity assessment: Persistence and degradability Biodegradability: Bioaccumulation Bioconcentration factor (BCF): Other adverse effects Environment assessment: SECTION 13 DISPOSAL CONSIDERATIONS Product Disposal Advice on Disposal: Dispose of in accordance with local regulations. SECTION 14 TRANSPORTATION INFORMATION DOT IMDG IATA not regulated not regulated not regulated Note: The above regulatory prescriptions are those valid on the date of publication of this sheet. Given the possible evolution of transport regulations for hazardous materials, it would be advisable to check their validity with your sales office. SECTION 15 REGULATORY INFORMATION TSCA: Canada (NDSL): Australia (AICS): China (IECSC): Follow all regulations in your country or region. Colonial Chemical, Inc is unable to confirm all regulatory information in regard to the substances in your country or region, and this information is subject to change without notice. California Proposition 65: This product contains the following chemicals known to the state of California to cause cancer and/or birth defects or reproductive harm. Ethylene oxide CAS # 75-21-8 SECTION 16 OTHER INFORMATION Full text of H-Statements referred to under sections 2 and 3. H315 Causes skin irritation H318 Causes serious eye damage Full text of P-Statements referred to under sections 2 and 3. P264 Wash hands and exposed skin thoroughly after handling. P280 Wear protective gloves/eye protection/face protection. P302+352 IF ON SKIN: Wash with plenty of water P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician Colonial Chemical, Inc. 225 Colonial Drive South Pittsburg, TN 37380 Emergency: 423-837-8800 Chemtrec: 800 424-9300 Issue date: 04/17/2017 5 of 6
P332+P313 P362+P364 P404 P405 P501 If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse Store in a closed container Store locked up Dispose of contents and/or container in accordance with local, regional, national, and/or international regulations. HEALTH 2 FLAMMABILITY 1 REACTIVITY 0 PERSONAL PROTECTION B The information provided in this Safety Data Sheet is accurate to the best of Colonial Chemical, Inc.'s knowledge. No guarantees or liabilities are expressed or implied. Because users are most aware of the application of the product, they must ensure that proper personal protective equipment (PPE) is provided consistent with the information contained in the product SDS. This information is intended solely for the use of individuals trained in the particular hazard rating system. It does not release users from ensuring they are in conformity with all regulations linked to its activity. Colonial Chemical, Inc. 225 Colonial Drive South Pittsburg, TN 37380 Emergency: 423-837-8800 Chemtrec: 800 424-9300 Issue date: 04/17/2017 6 of 6