PRODUCTION OF CANNED RED BROWN RICE GRUEL: EFFECT OF SOAKING TIME

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PRODUCTION OF CANNED RED BROWN RICE GRUEL: EFFECT OF SOAKING TIME 1 PLOYPAILIN CHUMNIWIKRI, 2 YUPORN PEUCHKAMUT 1,2 Faculty of Agro-Industry, King Mongkut s Institute of Technology Ladkrabang, Chalongkrung Road, Ladkrabang, Bangkok, Thailand 10520. Tel/fax: +66(0) 2329 8526 E-mail; 1 misssunns@gmail.com, 2 cayongyuth@yahoo.com Abstract The cooking quality and chemical properties of red jasmine brown rice (Mali Gomain Surin) was studied. The cooked rice had optimum cooking time, volume expansion ratio and water uptake ratio of 19 minutes, 2.22 ± 0.09 and 1.71 ± 0.01, respectively. The moisture content and amylose content were 10.77 ± 0.20 % and 20.44 ± 0.61%, respectively. The calculation of sterilization time to produce canned red jasmine brown rice gruel was determined. The canned gruel was prepared by filled 20 gram of washed rice and 150 ml saline solution (0.20%), exhausting at 85 degree Celsius and sealed it immediately. The water spray overpressure retort at 120 C and 2 bar was used to sterilize the can. The calculated result found that F 0 was 11.2. Then the effect of soaking duration on the qualities of canned rice gruel was studied. The raw rice in the seamed cans was placed until the raw rice absorbed water till 0, 75, 90 and 100 percent of their saturated absorption before put into the retort. The result shown that if the raw rice absorbed more water, the hardness and stickiness of the canned gruel became softer and the turbidity of liquid in the can was greater. The soaking times did not affect the color (L *, a *, b * ) and the water absorption of gruel significantly. The result of sensory evaluation found that all attributes which were range of like slightly to like moderated. Regarding chemical composition of red jasmine brown rice gruel, there was 8.66 percent of carbohydrate. This canned rice gruel could be useful food for elderly and during disaster. Keywords Red jasmine brown rice, Gruel, Canning process, Cooking quality. I. INTRODUCTION Rice (Oryza sativa L.) is one of the oldest food crops in the world and is a staple food of over approximately one-half of the world population, especially those living in populous countries in Asia. It is the major export cultivar in Thailand. In 2009, Thailand exported rice to US, Europe, Africa and Japan accounted for 2.9 million tones [1]. Red jasmine brown rice is developed from Thai white jasmine rice 105. It is covered by dark-red arils. Due to its pure peeling process, rice germ and rice bran are still remained as thin-layered coverings. It is recognized as a healthy cereal and more nutritious than white rice [2]. Especially Rice germ and rice bran are essential for vitamin B and vitamin E which help in Beriberi and ariboflavinosis prevention [3]. Moreover, the starch in red jasmine brown rice is considered as complex carbohydrate with slow decomposition. As a result, sugar in blood is in controlled condition which promotes diabetes prevention and treatment. Also, it gives low energy and has high fibers. It increases fibers in digestion system, prevents constipation and colorectal cancer. Moreover, it contains minerals and vitamins, especially anti-oxidants from red arils. Due to its modified breeding, red jasmine brown rice has unique aroma with soft texture and good taste. At present, there are many kinds of food processing. One of them is thermal processing. Thermal processing has long been used as a common preservation technique in the food industry, which allows the stable and secure production of food [4]. The advantages include cleanliness, easy to consumption convenience and long preservation. After consumption, the packaging can be recycled leading to waste reduction. Rice gruel is easy to eat and easily digestible with high nutrition. It is eatable for people at all ages and genders. Thus, canned red jasmine brown rice gruel is an interesting alternative for product development and product value creation. The canned rice gruel also can be a very useful food source during a disaster crisis. Therefore, the purpose of this study is to analyze the physicochemical and cooking quality of raw red jasmine brown rice, calculate the time of sterilization (F 0 ) and effect of soaking duration on physical property of canned gruel. II. MATERIAL AND METHODS 2.1 Material Freshly harvested, red jasmine brown rice (Mali Gomain Surin), (procured from Surin province, Thailand). Stored in vacuum polyethylene bags at room temperature till the experimentation. 2.2 Physicochemical properties of cooked red jasmine brown rice Physicochemical properties, namely, amylose content (AC) was determined by iodine colorimetry method as recommended by Thai agricultural standard [5]. Moisture content was determined following method by AOAC [6], Hardness and stickiness of cooked rice was analyzed by Back extrusion test (Texture Analyzer, TA-XT Plus, UK) Samples were prepared by stirring rice in water for one time and cooked with Electrical Rice Cooker (Oxygen, RC-115, Thailand) with the proportion of 1:8 (rice: water). Then, perform back extrusion test according to Leelayuthsoontorn and Thipayarat [7]. Color appearance of cooked rice measured by the CIELAB 25

color system with colormeter (Minalta, CR-400, Japan), prepare 40 grams of cooked rice and put it in aluminum cans (diameter of 5 centimeters and height of 3 centimeters) record lightness (L*), red value (a*) and yellow value (b*). And grain elongation measured by using Vernier caliper, modified from the method of Juliano and Perez [8], ten grains of random raw rice and cooked rice are randomly measure in length (millimeters). Then, calculate the average value and find grain elongation from the equation. 2.3 Cooking Quality Optimum Cooking Time Analysis Follow the principles of Mohapatra and Bal [9] by weighting 5 grams of red jasmine brown rice and putting it into 250-mL beaker. Fill in 100-mL distilled water. Then, boil until it reaches the boiling point. Ten minutes later, separate 10 grains of rice in boiling water and put it on clear glass dish. Repeat the method every one minute. The cooking time is recorded when at least 90 percent of rice samples do not have white centers. When the rice is well-cooked, boil it for another two minutes to ensure gelatinization. So, the optimum cooking time is the real time plus two minutes. Volume Expansion Ratio Analysis Weigh 2.5 grams of red jasmine brown rice and put it into a 15-mL test tube. Then, measure the height (H 1 ) and fill 5-mL distilled water. Close the test tube with a marble. Then, boil it in the boiling point for the duration of optimum cooking time. When the time is completed, measure the height (H 2 ) of the rice in the test tube and later calculate the expansion ratio using the equation. Water Uptake Ratio Analysis Modify from [9]. Weight 10 grains of red jasmine brown rice with 4-decimal weighing scale. The rice weight (W 1 ) is recorded before cooking. Then, boil 10 grains of red jasmine brown rice and boil it in 100-mL boiling water within the optimum cooking time. After that, filtering water with 16-mesh colander and leave it for 30 seconds. Then weigh again (W 2 ) and calculate expansion ratio using the equation. 2.4 Production of canned red jasmine brown rice gruel: calculate the sterilized time (F 0 ) Canned gruel production was carried out by following Figure 1. Prepare by rinse the raw rice for 2 minutes and leaved it until dry for 15 minutes. Then, put 20-gram red jasmine brown rice in to lacquer cans (307x 113) with thermocouple on its side. Then, filled with 150 gm of water with contained 0.20 salt concentrations (w/w) prior to exhaust at 85 degree Celsius and sealed it immediately. Then, fill canned gruel to complete the basket and sterilize it with water spray overpressure retort by connecting with thermometer and set it at 120 degree Celsius for 20 minutes at 2-bar pressure. Record the temperature every one minute until done. Then, the data is sent to the computer with E-VAL TM software and calculate the time with general method [10] by calculate Lethal rate value (L) using the equation (1). When T is at the slowest heating (Cold spot) of food in the containers provide heat during. The sum of the L in each temperature range is the F 0 of the sterilization process, which is calculated using Equation (2). When t is time in the heating process [11]. Fig. 1. Canned gruel production. 2.5 Effect of soaking duration on the quality of canned rice gruel Canned rice gruel production was carried out by following Figure 1. Additionally, the cleaned raw rice was soaked in the can for 20 50 and 80 minutes before subjected to sterilize. Also, the water absorption of the rice during soaking in the can was determined. The test was done by check the increasing weight of the red jasmine brown rice by poured out using a 16-mesh colander. Leave it for 30 seconds before weighting. The percentage of water absorption was calculated. All canned rice gruel prepared from red jasmine brown rice that absorbed different amount of water were subjected to analysis their physical properties and sensory evaluation. Physical properties, namely, color appearance and texture were determined following method by 2.2. Turbidity of liquid in the can was analysis by using Turbidimeter (Lovibond, TurbiCheck, Germany), filtering gruel with 16-mesh colander and leave it for 30 seconds and then put the water 1-mL and diluted with distilled water 9-mL into the sample tube. And 26

water absorption of rice gruel measured by weight of cleaned rice before sterilization (A 1 ). After sterilization, filtering water out of gruel by 16-mesh colander and leaved it for 2 minutes. Then weigh again (A 2 ) and calculate water absorption using the equation. Sensory evaluation A thirty panel comprising of students from the Food Science Department evaluated the samples using 9-point hedonic scale method: 9(excellent) to 1 (very poor. Evaluation in terms of appearance, texture, flavor and overall liking was done. 2.6 Statistical analysis Data were analyzed with SPSS version 16.0 using Completely Randomized Design (CRD). Test for three times for chemical quality analysis and five times for physical quality analysis. And using Randomized Complete Block Design (RCBD) for sensory evaluation. Significance difference were tested using the Duncan's Multiple. Range Test (DMRT). III. RESULTS AND DISCUSSION 3.1 Physicochemical properties and cooking quality of cooked red jasmine brown rice qthe analysis of chemical characteristics before can processing found that the red jasmine brown rice had the moisture content and amylose of 10.77± 0.20 percent and 20.44 ± 0.61, respectively. The rice is soft and slightly sticky [12] by the hardness and stickiness value equal 2628.88 ± 291.78 and 57.70 ± 9.79 respectively. The grain expansion is 1.10 ± 0.01. The rice expansion ratio affects rice texture. The more rice expansion, the softer the rice texture. In term of cooking quality, the comparison between red jasmine brown rice and white jasmine rice is shown in Table 1. It is found that red rice uses longer cooking time due to their aril property of water absorption and water transmission to the internal seed. Moreover, it contains proteins, fats and minerals. Proteins can block water absorption so long cooking time is needed [2]. When consider the expansion ratio and water absorption ratio, it is found that the values are not different. 3.2 Calculate the Sterilized Time (F 0 ) for canned red jasmine brown rice gruel production The process time of sterilize impacted on the texture of the gruel. The preliminary experiment found that 20 minutes of sterilization time was enough to boil rice to become gruel. From the study of heat level for the optimal sterilization on canned gruel quality, it is found that, at the temperature of 120 degree Celsius, process time 20 minutes and the pressure of two bars, calculating F 0 was equals to 11.2. The recommendation F 0 for non-acid food is 6.[10]. This means if we sterilize at 120 degree Celsius for 20 minutes, microorganisms leading to expired food and contaminated food are killed at commercial sterilization. Therefore, in this experiments, 20 minutes was the minimal time for canned rice gruel sterilization The cleaned raw rice was soaked in the can for 0 20 50 and 80 minutes before subjected to sterilize. The water absorption of the rice during soaking in the can was determined. It was found that the percentage of raw rice water absorption were 0, 75, 90 and 100 of their full saturation, respectively. All canned rice gruel prepared from red jasmine brown rice that absorbed different amount of water were subjected to analysis their physical properties and sensory evaluation. Table 2 showed the textural qualities of the rice gruel and turbidity of liquid in the can. 3.3 Effect of soaking duration on the quality of canned rice gruel 27

0.41 percent of liquid, 0.27 percent of ash, and 8.66 percent of carbohydrate. CONCLUSION The result was that gruel which prepared from raw rice with 100 percent water absorption had less hardness and stickiness than others. Therefore, soaking rice for long time until fully absorb water might significantly affect to a rice texture. Because the starch inside will absorb water. When the fully absorbed rice is heated at a high temperature, the rice will be easily broken. Moreover, regarding the turbidity and water absorption, when rice was soaked in hot water for a long time, rice would absorb water and was expanded. Then, the group of molecules would be loosened which made a starch spread out more with made the liquid in the can become turbid. When considering the color of rice gruel prepared from the red jasmine brown rice that absorbed different amount of water by using Hunter Lab system as shown in table 3. The a* value or red color had tendency to increase as the soaking time increase. However, it was found that there was no statistical significance different of Hunter value for all treatments. The result of sensory evaluation was shown in table 4. The rice gruel prepared from all experimental treatments had the score of flavor and texture not significantly different (p < 0.05). However, the score of the overall acceptance of the sample with prepared from raw rice that was not soaked was greater than that was fully absorbed water. It may indicate that the panelist prefer the gruel that had more hardness. 3.3 The chemical composition of canned rice gruel. Regarding chemical composition of red jasmine brown rice gruel as shown in table 5. There was 89.73 percent of moisture content, 0.93 percent of protein, In addition, concerning cooking, red jasmine brown rice needed more time to be cooked than white rice. Even though, an elongation rate and a volume of both rice were similar. It was because the skin of red rice against water absorption. The result from calculating the time of sterilizing canned rice gruel had F 0 of 11.21. Therefore, the process time of 20 minutes at 120 degree Celsius was safety to be used. Finally, when soaking raw rice in saline at 0.2 (w/w) percent intensity in order to encourage the different absorb rate in rice. The result shown that fully water absorbed raw rice lead the rice gruel had the least hardness and stickiness. Moreover, the turbidity of the liquid in the can was increased as the soaking time increased. And when measuring their color, the result was that there were no significant impacts from soaking duration to gruel color. Sensory evaluation found that all attributes which were range of like slightly to like moderated. The score of the overall acceptance of the sample with prepared from raw rice that was not soaked was greater than that was fully absorbed water. ACKNOWLEDGEMENTS The author are thankful to the staff of teachers, King Mongkut's Institute of Technology Ladkrabang and the author are thankful to the Thailand Research Fund, Thailand for research funding supports. REFERENCES [1] FAO. 2014. World Food Situation: Large cereal supplies and record trade in 2013/14; wheat production to decline and rice to increase slightly in 2014. <http://www.fao.org/worldfoodsituation/csdb/en/, Accessed date, Sep 2015 [2] Zhang X, Wang L, Cheng M, Wang R, Luo X, Li Y & Chen Z, Influence of ultrasonic enzyme treatment on the cooking and eating quality of brown rice, Journal of Cereal Science, vol. 63, pp.140-146, May 2015. [3] Ohtsubo, K., Suzuki, K., Yasui, Y. and Kasumi, T, Bio-functional components in the processed pregerminated brown rice by a twin-screw extruder, 28

Journal of Food Composition and Analysis, vol. 18(4), pp. 303-316, June 2005. [4] Boluda-Aguilar M, Taboada-RodrÃguez A, López-Gómez A, MarÃn-Iniesta F & Barbosa-Cà novas GV, Quick cooking rice by high hydrostatic pressure processing, LWT - Food Science and Technology, vol. 51(1), pp. 196-204, April 2013. [5] Thai Agricultural Standard, Thai Agricultural Standard TAS 4004-2012-Rice, Office of Thai Agricultural Standard and food. Ministry of Agriculture and Cooperatives, Bangkok, November 2012. [6] Official Methods of Analysis of AOAC International. 18th ed. Gaithersburg, Maryland: AOAC International, 2005 [7] Leelayuthsoontorn, P. & Thipayarat, A, Textural and morphological changes of Jasmine rice under various elevated cooking conditions, Food Chemistry, vol. 96, pp. 606-613, June 2006. [8] Juliano, B.O. and C.M. Perez, Result of a collaborative test on the measurement of grain elongation of milled rice during cooking, J. Cereal Sci., vol. 2, pp. 281 92, 1984 [9] Mohapatra D & Bal S, Cooking quality and instrumental textural attributes of cooked rice for different milling fractions, Journal of Food Engineering, vol. 73(3), pp. 253-259, April 2006. [10] Holdsworth, S.D, Thermal processing of packed foods, Blackie Academic and Professional Co. Inc, New York, 283 p, 1997. [11] Herson, A.C. and Hulland, E.D, Canned food, Thermal Processing and Microbiology, Edinburgh, Churchill Livingstone, New York, 1980 [12] Juliano, B.O. & Goddard, M.S, Cause of varietal difference in insulin and glucose responses to ingested rice, Plant Foods for Human. Nutrition, vol. 36, pp. 35-41, March 1986. [13] Naraporn Dalai, Storage and hydrothermal treatments on physical and chemical properties of milled rice and flour, A Thesis Submitted in Partial Fulfillment of the Requrements for the degree of Master of Science in food technology, Suranaree University of Technology, 96 pages, 2010. 29