Page ( 9 Issue date: 4/07/205 (4/07/205 FREESIA FRAGRANCE OIL (FRE23 Section. Identification of the substance or the mixture and of the supplier. Product Identifier Product identifier: Other identifiers: FREESIA FRAGRANCE (FRE23(Contains:citronellol, geraniol, hexyl cinnamic aldehyde, linalool None.2 Relevant identified uses of the substance of mixture and uses advised against Product uses: Fragrances.3 Details of the supplier of the safety data sheet Company name: Company address: Just a Soap 0 Bunting Road Bury St Edmunds IP32 7BX E-Mail address: enquiry@justasoap.co.uk Company phone: +44 284 848730.4 Emergency telephone number Emergency phone: +44 284 848730 2. Classification of the substance or mixture Section 2. Hazards identification Classification under Regulation (EC No 272/2008 Class and category of danger: Skin Corrosion / Irritation Category 2 Eye Damage / Irritation Category 2 Sensitization - Skin Category Hazardous to the Aquatic Environment - Acute Hazard Category Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H35, Causes skin irritation. H37, May cause an allergic skin reaction. H39, Causes serious eye irritation. H400, Very toxic to aquatic life. H4, Toxic to aquatic life with long lasting effects. Classification under Directive 999/45/EC Hazard symbols: Xi, Irritant. N, Dangerous for the environment.
Page 2 ( 9 Issue date: 4/07/205 (4/07/205 Risk phrases: FREESIA FRAGRANCE (FRE23 R38, Irritating to the skin. R43, May cause sensitisation by skin contact. R50/53, Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 2.2 Label elements Signal word: Hazard statements: Supplemental Information: Precautionary statements: Warning H35, Causes skin irritation. H37, May cause an allergic skin reaction. H39, Causes serious eye irritation. H400, Very toxic to aquatic life. H4, Toxic to aquatic life with long lasting effects. EUH208, Contains benzyl cinnamate, limonene, PARA TERTIARY BUTYL CYCLO HEXYL ACETATE, eugenol, NEROLEX (SRS NEROL 900 (BBA, p-tert-butyl-alphamethylhydrocinnamic aldehyde. May produce an allergic reaction. P26, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/35/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333/33, If skin irritation or rash occurs: Get medical advice/attention. P337/33, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P39, Collect spillage. P50, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: Other hazards: None
Page 3 ( 9 Issue date: 4/07/205 (4/07/205 FREESIA FRAGRANCE (FRE23 Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name CAS EC REACH Registration No. % hexyl cinnamic aldehyde 0-86-0 202-983-3 34.90% linalool Classification for (DSD 67/548/EEC Xi-N ; R38-R43-R50/53 Classification for (CLP 272/2008 SS B-EH A-EH C2;H37- H400-H4,- 78-70-6 20-34-4 2.65% Xi ; R38 SCI 2-EDI 2;H35-H39,- BETA IONONE 490-07-6 238-969-9.2% N ; R5/53 EH C2;H4,- TERPINEOL 8000-4-7 232-268- 0.03% Xi ; R36/38 SCI 2-EDI 2;H35-H39,- citronellol 06-22-9 203-375-0 5.78% Xi-N ; R38-R43-R5/53 SCI 2-EDI 2-SS B;H35- H37-H39,- BENZYL ACETATE 40--4 205-399-7 5.34% - ; - EH C3;H42,- PHENYL ETHYL PHENYL ACETATE benzyl cinnamate SCI 2-EDI 2-EH C2;H35- H39-H4,- ATO 4-SCI 2-SS B-REP 2-EH C2;H302-H35-H37- H36-H4,- FL 3-SCI 2-SS B-AH -EH A-EH C;H226-H304- H35-H37-H40,- SCI 2-EDI 2-EH C2;H35- H39-H4,- SCI 2-EDI -SS ;H35- H37-H38,- SCI 2-EDI 2-SS B;H35- H37-H39,- EDI 2-EH A-EH C;H39- H40,- YSAMBER K b/n A2396 TETRA HYDRO GERANIOL p-tert-butyl-alphamethylhydrocinnamic aldehyde limonene NEROLIN BROMELIA geraniol NEROLEX (SRS NEROL 900 (BBA bangalol eugenol 02-20-5 203-03- 2.73% N ; R5/53 EH C2;H4,- 03-4-3 203-09-3.64% Xi-N ; R43-R5/53 SS B-EH C2;H37-H4,- 547-77- 4 45-460-.53% N ; R5/53 EH C2;H4,- 06-2-8 203-374-5.3% 80-54-6 20-289-8 0.98% 5989-27-5 227-83-5 0.73% 93-8-5 202-226-7 0.65% 06-24- 203-377- 0.55% 06-25-2 203-378-7 0.55% 2829-6-6 248-908-8 0.22% Xi-N ; R38-R5/53 Xn-N ; R22-R38-R43-R62- R5/53 Xn-N ; R0-R38-R43-R65- R50/53 Xi-N ; R38-R5/53 Xi ; R38-R4-R43 Xi ; R43-R36/38 Xi-N ; R36-R50/53 97-53-0 202-589- 0.% Xi ; R36-R43 EDI 2-SS B;H37-H39,- PARA TERTIARY BUTYL CYCLO HEXYL ACETATE 3220-23-4 250-954-9 0.% Xi-N ; R43-R5/53 SS B;H37,- Substances with Community workplace exposure limits, not listed above: Name CAS EC % DEP 84-66-2 20-550-6 0.65% Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.%: Not Applicable 4. Description of first aid measures IF ON SKIN: Wash with plenty of soap and water. Section 4. First-aid measures
Page 4 ( 9 Issue date: 4/07/205 (4/07/205 FREESIA FRAGRANCE (FRE23 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 4.2 Most important symptoms and effects, both acute and delayed Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4. for further information. 5. Extinguishing media SECTION 5: Firefighting measures Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6. Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil. 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 3. 7. Precautions for safe handling: Section 7. Handling and storage Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product.
Page 5 ( 9 Issue date: 4/07/205 (4/07/205 FREESIA FRAGRANCE (FRE23 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s: Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. 8. Control parameters Workplace exposure limits: Section 8. Exposure controls/personal protection Ingredient CAS EC Description Reference DEP 84-66-2 20-550- 6 Long-term exposure limit (8-hour TWA reference period Short-term exposure limit (5- minute reference period - 5-0 UK EH40 Oct 2007 UK EH40 Oct 2007 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and to ensure occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use, the following engineering controls may be required as additional protective measures: a Isolate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the rest of the plant. b Employ the use of Personal protective equipment - an approved, properly fitted respirator with organic vapour cartridges or canisters and particulate filters. c Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is openly weighed or measured. In addition, use general dilution ventilation of the work area to eliminate or reduce possible worker exposures. d Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. 9. Information on basic physical and chemical properties Appearance: Odour: ph: Initial boiling point / range: Flash point: > 65 C Vapour pressure: Section 9. Physical and chemical properties
Page 6 ( 9 Issue date: 4/07/205 (4/07/205 FREESIA FRAGRANCE (FRE23 Relative density: Solubility(ies: 9.2 Other information: None available Section 0. Stability and reactivity 0. Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 0.2 Chemical stability: Good stability under normal storage conditions. 0.3 Possibility of hazardous reactions: Not expected under normal conditions of use. 0.4 Conditions to avoid: Avoid extreme heat. 0.5 Incompatible materials: Avoid contact with strong acids, alkalis or oxidising agents. 0.6 Hazardous decomposition products: Not expected.. Information on toxicological effects Section. Toxicological information This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in Regulation (EC No 272/2008 (CLP. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Assumed Toxicity Value (LD50 or ATE for Acute Oral Toxicity: 4456 Assumed Toxicity Value (LD50 or ATE for Acute Dermal Toxicity: >5000 Assumed Toxicity Value (LC50 or ATE for Acute Inhalation Toxicity: Inhalation Route: Information about hazardous ingredients in the mixture Not Applicable Refer to Sections 2 and 3 for additional information. Not Available Not Available
Page 7 ( 9 Issue date: 4/07/205 (4/07/205 FREESIA FRAGRANCE (FRE23 Section 2. Ecological information 2. Toxicity: Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. 2.2 Persistence and degradability: Not available 2.3 Bioaccumulative potential: Not available 2.4 Mobility in soil: Not available 2.5 Results of PBT and vpvb assessment: This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. 2.6 Other adverse effects: Not available 3. Waste treatment methods: Section 3. Disposal considerations Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken to an approved waste handling site for recycling or disposal. 4. UN number: UN3082 Section 4. Transport information 4.2 UN Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (hexyl cinnamic aldehyde, BETA IONONE 4.3 Transport hazard class(es: 9 Sub Risk: - 4.4. Packing Group: III 4.5 Environmental hazards: This is an environmentally hazardous substance. 4.6 Special precautions for user: None additional 4.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable Section 5. Regulatory information 5. Safety, health and environmental regulations/legislation specific for the substance or mixture None additional 5.2 Chemical Safety Assessment A Chemical Safety Assessment has not been carried out for this product. Section 6. Other information
Page 8 ( 9 Issue date: 4/07/205 (4/07/205 FREESIA FRAGRANCE (FRE23 Concentration % Limits: EH A=69.76% EH C2=39.90% EH C3=3.96% EH C4=42.0% SCI 2=33. 59% EDI 2=28.39% SS =2.87% Total Fractional Values: EH A=.43 EH C2=2.5 EH C3=25.27 EH C4=2.38 SCI 2=2.98 EDI 2=3. 52 SS =34.90 Key to revisions: Not applicable Key to abbreviations: Abbreviation Meaning AH Aspiration Hazard Category ATO 4 Acute Toxicity - Oral Category 4 EDI Eye Damage / Irritation Category EDI 2 Eye Damage / Irritation Category 2 EH A Hazardous to the Aquatic Environment - Acute Hazard Category EH C Hazardous to the Aquatic Environment - Long-term Hazard Category EH C2 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 EH C3 Hazardous to the Aquatic Environment - Long-term Hazard Category 3 FL 3 Flammable Liquid, Hazard Category 3 H226 H302 H304 H35 H37 H38 H39 H36 H400 H40 H4 H42 P202 P20 P233 P240 P24 P242 P243 P26 P264 P270 P272 P273 Flammable liquid and vapour. Harmful if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Causes serious eye irritation. Suspected of damaging fertility or the unborn child (exposure route. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects. Harmful to aquatic life with long lasting effects. Do not handle until all safety precautions have been read and understood. Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing vapour or dust. Wash hands and other contacted skin thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment.
Page 9 ( 9 Issue date: 4/07/205 (4/07/205 FREESIA FRAGRANCE (FRE23 P280 Wear protective gloves/eye protection/face protection. P30/30 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P30/32 IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell. P302/352 IF ON SKIN: Wash with plenty of soap and water. P303/36/353 P305/35/338 IF ON SKIN (or hair: Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308/33 IF exposed or concerned: Get medical advice/attention. P30 P330 P33 Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do not induce vomiting. P332/33 If skin irritation occurs: Get medical advice/attention. P333/33 If skin irritation or rash occurs: Get medical advice/attention. P337/33 If eye irritation persists: Get medical advice/attention. P362 P363 Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. P370/378 In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P39 Collect spillage. P403/235 Store in a well-ventilated place. Keep cool. P405 P50 Store locked up. REP 2 Toxic to Reproduction Category 2 SCI 2 Skin Corrosion / Irritation Category 2 SS Sensitization - Skin Category SS B Dispose of contents/container to approved disposal site, in accordance with local regulations. Sensitization - Skin Category B The information in this safety data sheet is to the best of our knowledge true and accurate but all data, instructions, recommendations and/or suggestions are made without guarantee.