Dixie Chemical Company, Inc. SAFETY DATA SHEET According to 2001/58/EC 1. Identification of the substance/preparation and of the company/undertaking Trade Name: Octadecenylsuccinic anhydride Date of Issue: July 7, 2005 Formula: Revised Date: May 15, 2012 Chemical Family: Anhydrides Telephone Number: Information (281) 474-3271 Emergency Number: Chemtrec (800) 424-9300 HMIS Hazard Rating 4 = Extreme Health: Fire: Reactivity: 2 1 1 3 = High 2 = Moderate 1 = Slight 0 = Least PPE rating to be supplied by user depending on use conditions. 2. Hazard Identification EMERGENCY OVERVIEW: This product is a amber colored liquid with a mild odor. Health Hazard: This product may cause irritation to skin and respiratory system. Eye contact may cause severe irritation and possible corneal injury. Ingestion may cause irritation of the mouth, throat and gastrointestinal tract. Flammability Hazards: This product is Non-Flammable. Reactivity Hazards: No known hazards. Environmental Hazards: Environmental effects of this product are not known. Emergency Considerations: Emergency responders must wear the proper personal protective equipment (and have appropriate fire suppression equipment) suitable for the situation to which they are responding. US DOT SYMBOLS CANADA (WHMIS) SYMBOLS EUROPEAN and (GHS) Hazard Symbols Non-Regulated Not Controlled EU LABELING AND CLASSIFICATION: Classification of the substance or mixture according to Regulation (EC) No1272/2008 These substances are not classified in the Annex I of Directive 67/548/EEC Signal Word: Warning! Hazard Statement(s): H316: Causes mild skin irritation H317: May use an allergic skin reaction H318: Causes serious eye damage H319: Causes serious eye irritation H335: May cause respiratory irritation H413: May cause long lasting harmful effects to aquatic life. 10601 Bay Area Blvd. Pasadena, Texas 77507 Page 1
Precautionary Statement(s): P261: Avoid breathing dust/vapors P271: Use only in well ventilated area. P281: Use personal protective equipment as required. P314: Get medical advice/attention if you feel unwell Hazard Classification: [Xi] Irritant Risk Phrases: R36/37/38: Irritating to eyes, respiratory system and skin R43: May cause sensitization by skin contact. Safety Phrases: S24: Avoid contact with skin S26: In case of contact with eyes S36/37/39: Wear suitable protective clothing 3. Composition/ information on ingredients Component Percentage EC No. CAS # Octadecenylsuccinic anhydride >90% 249-210-6 28777-98-2 Hexadecenylsuccinic anhydride <5% 250-911-4 32072-96-1 Mixed C16-18 olefins <3% 271-651-8 68603-32-7 Chemical Family: Anhydride Molecular Weight: Mixture Formula: C 22 H 38 O 3 C 20 H 34 O 3 R-Phrases: R36/37/38 4. First aid measures. Inhalation: Skin Contact: Eye Contact: Ingestion: Remove victim to fresh air. If breathing is difficult, give oxygen. If not breathing, administer artificial respiration. Get medical attention. Immediately remove contaminated clothing and shoes. Wipe excess material from skin and flush with water for at least 15 minutes. Use soap if available or follow by washing with soap and water. Do not reuse contaminated clothing without laundering. Get medical attention. Immediately flush with plenty of water for at least 15 minutes. Get medical attention. Get medical attention immediately. 5. Fire-fighting measures Suitable extinguishing media: Use water, foam, dry chemical, or carbon dioxide (CO 2 ). 10601 Bay Area Blvd. Pasadena, Texas 77507 Page 2
Special protective equipment: Firefighters should wear NIOSH approved self-contained breathing apparatus. Responders should wear protective clothing to prevent skin contact. Move containers from fire area. If unable to move, cool sealed containers with water. Special risks: Other information: This material reacts with water or steam to form octadecenylsuccinic acid and hexadecenylsuccinic acid. This reaction is slightly exothermic. It should not present any problems if large quantities of water are used. Collect separately contaminated extinguishing water. Do not allow extinguishing water to enter surface water or ground water. 6. Accidental release measures Personal Precautions: Clean-up personnel should wear protective equipment to prevent contact with skin and eyes. Environmental precautions: Do not allow material to enter surface water or ground water. Procedures for cleaning / adsorption: Contain and recover. Flush away residues with water, but do not allow material to enter surface or ground water. 7. Handling and storage Handling: Containers do not have to be grounded and bonded when material is transferred, but is recommended as a good practice. Storage: Store in a cool, dry place. Keep away from heat, sparks, and flames. 8. Exposure controls and personal protection Exposure limit values: None Occupation exposure controls: Depending on the temperature and quantity of the material being handled, protective clothing should be specifically selected. Respiratory Protection: Required when high vapor concentrations are generated. 10601 Bay Area Blvd. Pasadena, Texas 77507 Page 3
Hand protection: Data is based on Hexadecenylsuccinic anhydride, CAS 32072-96-1, using test method ASTM F739-99a: Glove Material: PVC Nitrile Rubber Neoprene Rubber Butyl Rubber Layer Thickness: 1.1 mm 0.48 mm 0.96 mm 0.66 mm Breakthrough time: >480 Min. >480 Min. >480 Min. >480 Min. Eye Protection: Chemical goggles and possibly a face shield. Skin Protection: Required when liquid contact is possible. General safety and hygiene measures: Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower after work using plenty of soap and water. 9. Physical and chemical properties Form: Liquid Color: Amber Odor: Mild ph: Boiling Point: 212 o C (414 o F) @ 0.5 mm Hg (initial boiling point) Flash Point: 185 o C (365 o F) PMCC, ASTM D93 Melting Point: Lower Explosive Limit: Upper Explosive Limit: Auto ignition Temperature: Oxidizing properties: Vapor Pressure (mm Hg): <1.0 @ 20 o C (68 o F) ASTM D5191 Relative Density (Air = 1): >1 Partition coefficient: n-octanol / water: Volatility/Vol (%): Solubility in H 2 O: Solubility in Fat: Specific Gravity (H 2 O = 1): 0.95 @ 25 o C (77 o F) Evaporation Rate: Evaporation Rate: 10. Stability and reactivity Chemical Stability: Conditions to Avoid: Stable. Incompatible materials. 10601 Bay Area Blvd. Pasadena, Texas 77507 Page 4
Incompatible Materials: Decomposition Products: Hazardous Polymerization: Alkaline substances. Water will affect product quality. Oxides of carbon. Occurs at temperatures above 220 o C (428 o F). Will not occur. 11. Toxicological information Octadecenylsuccinic anhydride Dermal LD50: >5000 mg/kg (rabbit) Ingestion: LD50: >5000 mg/kg (mouse) TDLo: 60 g/kg (rat) 30D-I Intraperitoneal: LD50: 2150 mg/kg (rat) Carcinogenicity listed by: IARC: No 12. Ecological information No data available. 13. Disposal considerations Product: Material must be disposed of in compliance with respective national regulations. Packaging: Product packaging must be disposed of in compliance with respective national regulations. 14. Transport information Not classified as hazardous under transport regulations. 15. Regulatory Information European Regulations: EINECS Number: Octadecenylsuccinic Anhydride: 249-210-6 Hexadecenylsuccinic Anhydride: 250-911-4 Mixed C16-18 Olefins: 271-651-8 Labeling according to EC directives. Symbol: Xi Irritant 10601 Bay Area Blvd. Pasadena, Texas 77507 Page 5
R-Phrases: R36/37/38 R43 S-Phrases: S36/37/39 S26 S24 Irritating to eyes, respiratory system and skin. May cause sensitization by skin contact Wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Avoid contact with skin German Water Hazard Classification (WGK) Number: 1. Listed Name(s): Dihydro-3-(octadecenyl)furan-2,5-dion. Kenn-Number: 4644. Classification according to Annex 3 of VwVwS. U.S. Regulations: TSCA: All substances are listed on, or are exempt from reporting. SARA Hazard Notification: Hazard Categories Under Title III: Section 302 Extremely Hazardous Substances: Section 313 Toxic Chemicals: CERCLA RQ: Acute. Not Listed. Not Listed. Not Listed. TSCA 12(b) Export Notification: Not Listed California Proposition 65: Not Listed HMIS Hazard Rating Health: 2 Fire: 1 Reactivity: 1 PPE rating to be supplied by user depending on use conditions. 4 = Extreme 3 = High 2 = Moderate 1 = Slight 0 = Least Canadian Regulations: All substances are listed on the DSL, or are exempt from reporting. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and MSDS contains all the information required by the Controlled Products Regulations. Japanese Regulations: 10601 Bay Area Blvd. Pasadena, Texas 77507 Page 6
Mixed C16-18 Olefins is not listed on the ENCS. All other components are listed. ENCS Number: Octadecenylsuccinic Anhydride: 2-852X (unlisted chemical name) Hexadecenylsuccinic Anhydride: 2-852X (unlisted chemical name) Mixed C16-18 Olefins: Not Listed Australian Regulations: All components are listed on the AICS. Korean Regulations: All components are listed on the ECL. ECL Number: Octadecenylsuccinic Anhydride: KE-10724 ECL Number: Hexadecenylsuccinic Anhydride: KE-18485 Mixed C16-18 Olefins: KE-00651 SECTION 16 OTHER INFORMATION PPE Codes (NPCA-HMIS) A Glasses B Glasses, Gloves C Glasses, Gloves, Apron D Faceshield, Gloves, Apron E Glasses, Gloves, Dustmask F Glasses, Gloves, Apron, Dust Respirator G Glasses, Gloves, Vapor Respirator H Goggles, Gloves, Apron, Vapor Respirator I Glasses, Gloves, Dust/Vapor Respirator J Goggles, Gloves, Apron, Dust/Vapor Respirator K Supplied Air, Gloves, Full Protective Suit, Boots Disclaimer The information contained in the Safety Data Sheet is based on technical data that Dixie Chemical Company believes to be reliable and is provided to our customers at no cost. It is intended for use by persons having technical skill and at their own discretion and risk. Dixie Chemical Company will assume no liability in connection with any uses of this information and no warranties, expressed or implied, are made with regards to this information since conditions of use are outside Dixie Chemical Company s control. 10601 Bay Area Blvd. Pasadena, Texas 77507 Page 7