Material Safety Data Sheet Revision Number: 001.0 Issue date: 12/02/2009 1. PRODUCT AND COMPANY IDENTIFICATION Product type: Solder alloy Item number: M00685 Region: United States Company address: Contact information: Henkel Corporation Telephone: 626.968.6511 15051 East Don Julian Road Emergency telephone: 860.571.5100Emergency telephone: Irvine, CA 91746 860.571.5100 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Solid HEALTH: *2 Color: Gray, Metallic FLAMMABILITY: 1 Odor: PHYSICAL HAZARD: 0 Personal Protection: CAUTION:CAUTION: MAY BE HARMFUL IF SWALLOWED OR INHALED.MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. MAY BE HARMFUL IF SWALLOWED OR INHALED. MAY CAUSE ALLERGIC SKIN REACTION. Relevant routes of exposure: Relevant routes of exposure: Skin, Inhalation, Eyes Skin, Inhalation, Eyes Potential Health Effects Not a hazard under normal conditions of use. Excessive inhalation of fumes from many metals can produce an acute reaction known as "metal fume fever". Symptoms consist of chills and fever (very similar to and easily confused with flu symptoms) which come on a few hours after large exposures. Fumes may be irritating and may cause an allergic respiratory reaction. Fumes and/or dust produced by this product may be hazardous in case of ingestion or inhalation. Rosin thermal decomposition product (as formaldehyde) is classified by NIOSH as a potential occupational carcinogen. Excessive inhalation of fumes from many metals can produce an acute reaction known as "metal fume fever". Symptoms consist of chills and fever (very similar to and easily confused with flu symptoms) which come on a few hours after large exposures. Prolonged or repeated skin contact may cause irritation, skin sensitization and argyria (a nontoxic, cosmetic blue-gray discoloration of the skin and mucous membranes that is irreversible). Prolonged and/or repeated skin contact may result in mild irritation or redness. May cause sensitization by skin contact. This product may discolor the skin. Contact with eyes will cause irritation. Contact with eyes will cause irritation. May cause gastrointestinal tract irritation if swallowed. Not expected under normal conditions of use. May be harmful if swallowed. Page 1 of 5
Existing conditions aggravated by exposure: Existing conditions aggravated by exposure: Eye, skin, and respiratory disorders. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Tin 7440-31-5 60-100 7440-22-4 1-5 Copper 7440-50-8 0.1-1 4. FIRST AID MEASURES If exposed to excessive levels remove to fresh air. If symptoms develop and persist, get medical attention. Wash affected area immediately with soap and water. If symptoms develop and persist, get medical attention. Flush eye(s) immediately with plenty of water. If eye irritation persists, consult a specialist. DO NOT induce vomiting unless directed to do so by medical personnel. Seek medical advice. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: > 120.00 C (> 248 F) EstimatedDoes not flash. Carbon dioxide, foam, powder fine water spray Wear self-contained breathing apparatus. High temperatures may produce heavy metal dust, fumes or vapours. Oxides of Metals in Section 2. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Wear suitable respiratory protection. Collect spill using a vacuum cleaner with a HEPA filter. Do not sweep dry material. Store in a closed container until ready for disposal. Page 2 of 5
7. HANDLING AND STORAGE Handling: Storage: Use only in well-ventilated areas. Avoid skin and eye contact. When using do not eat, drink or smoke. Wash hands before breaks and immediately after handling the product. Store in original container until ready to use. For information on product shelf life contact Henkel Customer Service at (626) 968-6511 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Tin Copper 2 mg/m3 TWA 0.1 mg/m3 TWA Dust and fume. 1 mg/m3 TWA (as Cu) Dust and mist. 0.2 mg/m3 TWA Fume. 2 mg/m3 TWA (as Sn) 0.01 mg/m3 TWA (as Ag) 1 mg/m3 TWA (as Cu) Dust and mist. 0.1 mg/m3 TWA (as Cu) Fume. Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Use adequate ventilation to remove molten vapors or fumes. If ventilation is not sufficient to effectively prevent buildup of dust, appropriate NIOSH/MSHA respiratory protection must be provided. Safety goggles or safety glasses with side shields. Disposable rubber or plastic gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Solid Color: Gray, Metallic Odor: Odor threshold: ph: Vapor pressure: Negligible vapor pressure at ambient temperatures. Boiling point/range: Melting point/ range: 217 C (422.6 F) Specific gravity: 7.5 Vapor density: Flash point: > 120.00 C (> 248 F) EstimatedDoes not flash. Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Insoluble Partition coefficient (n-octanol/water): VOC content: Zero Page 3 of 5
10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable Will not occur. Heavy metal compounds. Strong acids and strong bases. Strong oxidizing agents. Solder alloy will react with concentrated nitric acid to produce toxic fumes of nitrogen oxides. 11. TOXICOLOGICAL INFORMATION Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Tin No No No No No No Copper No No No Hazardous components Tin Copper Health Effects/Target Organs Gastrointestinal, Irritant, Kidney, Liver, Lung, Nervous System Allergen, Eyes, Irritant, Respiratory, Skin Allergen, Blood, Central nervous system, Developmental, Gastrointestinal, Immune system, Irritant, Kidney, Liver, Mutagen, Sensory, Skin 12. ECOLOGICAL INFORMATION Ecological information: Do not empty into drains / surface water / ground water. 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Dispose of according to Federal, State and local governmental regulations. D011. 14. TRANSPORT INFORMATION U.S. Department of Transportation Ground (49 CFR) Environmentally hazardous substances, solid, n.o.s. DOT Reportable quantity: International Air Transportation (ICAO/IATA) Environmentally hazardous substance, solid, n.o.s. Water Transportation (IMO/IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. Page 4 of 5
15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: CERCLA Reportable quantity: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. above reporting de minimus above reporting de minimus Immediate Health, Delayed Health This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). (CAS# 7440-22-4). (CAS# 7440-22-4) 1,000 lbs. (454 kg) No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. D.2.A, D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format. Prepared by: Lou Fabrizio, Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 5 of 5