Safety data sheet according to 1907/2006/EC, Article 31

Transcription

1 Page 1/10 * SECTION 1: Identification of the substance/mixture and of the company/ undertaking 1.1 Product identifier Trade name Mycoflex 4100 TS - Komponente A Article number: Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Primer/ Subcoating 1.3 Details of the supplier of the safety data sheet Manufacturer/Supplier: MC-Bauchemie Müller GmbH & Co. KG Am Kruppwald 1-8 D Bottrop Tel.: +49(0) Fax.: +49(0) info@mc-bauchemie.de MC-Bauchemie AG Hagackerstr. 10 CH-8953 Dietikon Tel.: Fax : Informing department: Technische Abteilung msds@mc-bauchemie.de 1.4 Emergency telephone number: Tel.: +49 / (0) (MCR) Tel.: * SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flam. Liq. 3 H226 Flammable liquid and vapour. Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2 H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335-H336 May cause respiratory irritation. May cause drowsiness or dizziness. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. Asp. Tox. 1 H304 May be fatal if swallowed and enters airways. Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. (Contd. on page 2)

2 Page 2/10 Hazard pictograms d~ GHS02 Signal word Danger Hazard-determining components of labelling: d~ GHS07 d~ GHS08 (Contd. of page 1) xylene Propyl -2,2-diphenyl-4,4 dipropyloxirane polymers and homologues 1-methoxypropan-2-ol Hazard statements H226 Flammable liquid and vapour. H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H335-H336 May cause respiratory irritation. May cause drowsiness or dizziness. H373 May cause damage to organs through prolonged or repeated exposure. H304 May be fatal if swallowed and enters airways. H412 Harmful to aquatic life with long lasting effects. Precautionary statements P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. P321 Specific treatment (see on this label). P331 Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P362+P364 Take off contaminated clothing and wash it before reuse. Additional information: Contains epoxy constituents. May produce an allergic reaction. 2.3 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. * SECTION 3: Composition/information on ingredients 3.2 Chemical characterisation: Mixtures Description: Mixture consisting of the following components. Dangerous components: CAS: EINECS: xylene STOT RE 2, H373; Asp. Tox. 1, H304; Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H % (Contd. on page 3)

3 Page 3/10 CAS: EINECS: Reg.nr.: xxxx CAS: NLP: Reg.nr.: CAS: EINECS: methoxypropan-2-ol Flam. Liq. 3, H226; STOT SE 3, H336 Propyl -2,2-diphenyl-4,4 dipropyloxirane polymers and homologues Aquatic Chronic 2, H411; Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 [3-(2,3-epoxypropoxy)propyl]trimethoxysilane Skin Irrit. 2, H315; Eye Irrit. 2, H319; STOT SE 3, H335 (Contd. of page 2) 25-50% 5-<25% <1.5% Additional information For the wording of the listed hazard phrases refer to section 16. * SECTION 4: First aid measures 4.1 Description of first aid measures General information Instantly remove any clothing soiled by the product. Take affected persons into the open air. After inhalation Supply fresh air and call for doctor for safety reasons. After skin contact Instantly wash with water and soap and rinse thoroughly. After eye contact Rinse opened eye for several minutes under running water. Seek medical treatment. After swallowing Do not induce vomiting; instantly call for medical help. 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed If swallowed or in case of vomiting, danger of entering the lungs SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam. For safety reasons unsuitable extinguishing agents Water with a full water jet. 5.2 Special hazards arising from the substance or mixture No further relevant information available. 5.3 Advice for firefighters Protective equipment: Put on breathing apparatus. (Contd. on page 4)

4 Page 4/10 (Contd. of page 3) SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures 6.2 Environmental Wear protective equipment. Keep unprotected persons away. precautions: Prevent material from reaching sewage system, holes and cellars. 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose of contaminated material as waste according to item 13. Ensure adequate ventilation. 6.4 Reference to other sections See Section 7 for information on safe handling See Section 8 for information on personal protection equipment. See Section 13 for information on disposal. * SECTION 7: Handling and storage 7.1 Precautions for safe handling Store in cool, dry place in tightly closed containers. Open and handle container with care. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. 7.2 Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and containers: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep container tightly sealed. 7.3 Specific end use(s) No further relevant information available. * SECTION 8: Exposure controls/personal protection Additional information about design of technical systems: No further data; see item Control parameters Components with critical values that require monitoring at the workplace: methoxypropan-2-ol WEL Short-term value: 560 mg/m³, 150 ppm Long-term value: 375 mg/m³, 100 ppm Sk (Contd. on page 5)

5 Page 5/10 (Contd. of page 4) DNELs Propyl -2,2-diphenyl-4,4 dipropyloxirane polymers and homologues Oral DNEL 0.75 mg/kg bw/tag (General) (Kurzfristig und Langfristig Systemisch) Dermal DNEL 3.6 mg/kg bw/day (General) (Kurzfristig und Langfristig Systemisch) 8.3 mg/kg bw/day (Workers) (Kurzfristig und Langfristig Systemisch) Inhalative DNEL 0.75 mg/m³ (General) (Kurzfristig und Langfristig Systemisch) 12.3 mg/m³ (Workers) (Kurzfristig und Langfristig Systemisch) PNECs Propyl -2,2-diphenyl-4,4 dipropyloxirane polymers and homologues PNEC 3 μg/l (Fresh water) 0.3 μg/l (Marine) PNEC 10 mg/l (Sewage Treatment Plant) PNEC 0.5 mg/kg dwt (Marine water sediment) 0.05 mg/kg dwt (Sediment) 0.5 mg/kg dwt (Fresh water sediment) Additional information: The lists that were valid during the compilation were used as basis. 8.2 Exposure controls Personal protective equipment General protective and hygienic measures Keep away from foodstuffs, beverages and food. Instantly remove any soiled and impregnated garments. Wash hands during breaks and at the end of the work. Avoid contact with the eyes and skin. Protection of hands: Protective gloves. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation After use of gloves apply skin-cleaning agents and skin cosmetics. Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material Eye protection: Safety glasses Tightly sealed safety glasses. Body protection: Protective work clothing. The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 6)

6 Page 6/10 (Contd. of page 5) * SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties General Information Appearance: Form: Fluid Colour: Yellow Smell: Characteristic Change in condition Melting point/freezing point: Not determined Initial boiling point and boiling range: 120 C Flash point: 30 C Ignition temperature: 184 C Self-inflammability: Product is not selfigniting. Explosive properties: Product is not explosive. However, formation of explosive air/steam mixtures is possible. Critical values for explosion: Lower: 1.1 Vol % Upper: 13.7 Vol % Steam pressure at 20 C: 13 hpa Density at 20 C 0.95 g/cm³ Solubility in / Miscibility with Water: Not miscible or difficult to mix 9.2 Other information No further relevant information available. * SECTION 10: Stability and reactivity 10.1 Reactivity No further relevant information available Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications Possibility of hazardous reactions No dangerous reactions known 10.4 Conditions to avoid No further relevant information available Incompatible materials: No further relevant information available Hazardous decomposition products: No dangerous decomposition products known * SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met. (Contd. on page 7)

7 Page 7/10 (Contd. of page 6) LD/LC50 values that are relevant for classification: Propyl -2,2-diphenyl-4,4 dipropyloxirane polymers and homologues Oral LD50 30,000 mg/kg (Ratte) Dermal LD50 >2,000 mg/kg (kan) Primary irritant effect: Skin corrosion/irritation Causes skin irritation. Serious eye damage/irritation Causes serious eye irritation. Respiratory or skin sensitisation May cause an allergic skin reaction. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Based on available data, the classification criteria are not met. Reproductive toxicity Based on available data, the classification criteria are not met. STOT-single exposure May cause respiratory irritation. May cause drowsiness or dizziness. STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure. Aspiration hazard May be fatal if swallowed and enters airways. * SECTION 12: Ecological information 12.1 Toxicity Aquatic toxicity: No further relevant information available Persistence and degradability No further relevant information available Bioaccumulative potential No further relevant information available Mobility in soil No further relevant information available. Additional ecological information: General notes: Do not allow product to reach ground water, water bodies or sewage system. Danger to drinking water if even small quantities leak into soil Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable Other adverse effects No further relevant information available. * SECTION 13: Disposal considerations 13.1 Waste treatment methods Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system. European waste catalogue WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVES, SEALANTS AND PRINTING INKS (Contd. on page 8)

8 Page 8/10 (Contd. of page 7) wastes from MFSU and removal of paint and varnish waste paint and varnish containing organic solvents or other dangerous substances Uncleaned packagings: Recommendation: Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning. * SECTION 14: Transport information 14.1 UN-Number ADR, IMDG, IATA UN UN proper shipping name ADR 1866 RESIN SOLUTION IMDG, IATA RESIN SOLUTION 14.3 Transport hazard class(es) ADR Class 3 (F1) Flammable liquids. Label 3 IMDG, IATA Class 3 Flammable liquids. Label Packing group ADR, IMDG, IATA III 14.5 Environmental hazards: Marine pollutant: No 14.6 Special precautions for user Warning: Flammable liquids. Kemler Number: 30 EMS Number: F-E,S-E Stowage Category A 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code Transport/Additional information: Not applicable. ADR Limited quantities (LQ) 5L Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml Transport category 3 Tunnel restriction code D/E Remarks: Beförderung nach RN 2301a (Contd. on page 9)

9 Page 9/10 (Contd. of page 8) IMDG Limited quantities (LQ) 5L Excepted quantities (EQ) Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml UN "Model Regulation": UN 1866 RESIN SOLUTION, 3, III * SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture t Directive 2012/18/EU Qualifying quantity (tonnes) for the application of lowertier requirements Qualifying quantity (tonnes) for the application of uppertier requirements t REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: Chemical safety assessment: A Chemical Safety Assessment has not been carried out. * SECTION 16: Other information These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. Department issuing data specification sheet: Environment protection department. Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) (Contd. on page 10)

10 Page 10/10 * Data compared to the previous version altered. (Contd. of page 9) ICAO: International Civil Aviation Organisation ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) DNEL: Derived No-Effect Level (REACH) PNEC: Predicted No-Effect Concentration (REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vpvb: very Persistent and very Bioaccumulative Flam. Liq. 3: Flammable liquids Category 3 Acute Tox. 4: Acute toxicity Category 4 Skin Irrit. 2: Skin corrosion/irritation Category 2 Eye Irrit. 2: Serious eye damage/eye irritation Category 2 Skin Sens. 1: Skin sensitisation Category 1 STOT SE 3: Specific target organ toxicity (single exposure) Category 3 STOT RE 2: Specific target organ toxicity (repeated exposure) Category 2 Asp. Tox. 1: Aspiration hazard Category 1 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2 Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard Category 3