Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet EU Regulation: 1907/2006 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 PRODUCT IDENTIFICATION PRODUCT NAME BIOLOGICAL DEFINITION INCI NAME EUCALYPTUS RADIATA, ESSENTIAL OIL ORGANIC EUCALYPTUS RADIATA FLOWER/LEAF/STEM OIL IS THE VOLATILE OIL OBTAINED FROM THE FLOWERS, LEAVES AND STEMS OF EUCALYPTUS, EUCALYPTUS RADIATA VAR. AUSTRALIANA, MYRTACEAE. EUCALYPTUS RADIATA FLOWER/LEAF/STEM SYNONYMS & TRADE NAMES EUCALYPTUS RADIATA OIL INTERNAL PRODUCT CODE K0180 CAS-NO EC NO EINECS NO DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET COMPANY ADDRESS O&3 Unit 2, Athelstan Business Park, Hanwell Lane, Hutton Conyers, Ripon, HG4 5BF, England DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET EMERGENCY CONTACTS MRS. ELEANOR WADE ( )

2 SECTION 2: HAZARDS IDENTIFICATION 2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE THE FULL TEXT FOR ALL HAZARD STATEMENTS IS DISPLAYED IN SECTION 16. CLASSIFICATION (67/548/EEC) NO ADDITIONAL DATA AVAILABLE. CLASSIFICATION (EU1272/2008) PHYSICAL: HEALTH: ENVIRONMENTAL: FLAM. LIQ. 3 H226 SKIN SENS. 1 H317; ASP. TOX. 1 H304 AQUATIC CHRONIC 2 H LABEL ELEMENTS LABEL IN ACCORDANCE WITH REGULATION (EC) NO 1272/2008. GHS LABEL GHS07 GHS08 GHS09 GHS02 SIGNAL WORD DANGER.. CONTAINS ALPHA-PINENE, BETA-PINENE, LIMONENE. HAZARDS STATEMENT H226 H304 H317 H411 FLAMMABLE LIQUID AND VAPOUR. MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. MAY CAUSE AN ALLERGIC SKIN REACTION. TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. PRECAUTIONARY STATEMENTS P273 P280 AVOID RELEASE TO THE ENVIRONMENT. WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION. P210 KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. NO SMOKING. P233 KEEP CONTAINER TIGHTLY CLOSED. P240 GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. P241 USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/ /EQUIPMENT. P242 USE ONLY NON-SPARKING TOOLS. P243 TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE. P261 AVOID BREATHING DUST/FUME/GAS/MIST/VAPOURS/SPRAY. P272 CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. P IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN. P IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER. SUPPLEMENTARY PRECAUTIONARY STATEMENTS P IF ON SKIN: (OR HAIR): REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/SHOWER. P321 SPECIFIC TREATMENT (SEE ON THIS LABEL). P331 DO NOT INDUCE VOMITING. P IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION. P363 WASH CONTAMINATED CLOTHING BEFORE REUSE. P IN CASE OF FIRE: USE FOR EXTINCTION. P391 COLLECT SPILLAGE. P STORE IN A WELL-VENTILATED PLACE. KEEP COOL. P405 STORE LOCKED UP. P501 DISPOSE OF CONTENTS/CONTAINER TO

3 2.3 OTHER HAZARDS ADVERSE PHYSIO-CHEMICAL PROPERTIES ADVERSE EFFECTS ON HUMAN HEALTH PBT OR VPVB ACCORDING TO ANNEX XIII SECTION 16 (OTHER INFORMATION): RISK & SAFETY PHRASES IN FULL. SECTION 3: COMPOSITION OF INGREDIENTS % CINEOL CAS-NO.: EC NO.: CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3 H226, 10-30% ALPHA-TERPINEOL CAS-NO.: EC NO.: CLASSIFICATION (EC 1272/2008) SKIN IRRIT 2 H % ALPHA-PINENE CAS-NO.: EC NO.: CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3 - H226, SKIN IRRIT. 2 - H315, SKIN SENS. 1 - H317, ASP. TOX. 1 - H MIXTURES 5-10% LIMONENE CAS-NO.: EC NO.: CLASSIFICATION (EC 1272/2008) FLAM. LIQ. 3 H226, SKIN IRRIT 2 H315 ASP TOX. 1 H304, SKIN SENS. 1 H317 AQUATIC ACUTE 1 H400, AQUATIC CHRONIC 1 H % BETA-PINENE CAS. NO: EC NO: CLASSIFICATION (EC 1272/2008); DANGER, FLAM. LIQ. 3 H226, SKIN SENS. 1 H317, ASP TOX. 1 H304, AQUATIC CHRONIC 1 H % 4-TERPINEOL CAS-NO.: EC NO.: CLASSIFICATION (EC 1272/2008) ACUTE TOX. 4 H302, SKIN IRRIT. 2 H % PARA-CYMENE CAS-NO.: EC NO.: CLASSIFICATION (EC 1272/2008); FLAM. LIQ. 3 H226, ASP. TOX. 1 H304, AQUATIC CHRONIC 2 H411 <1% GERANIOL CAS-NO.: EC NO.: CLASSIFICATION (EC 1272/2008) SKIN IRRIT. 2 H315, EYE DAM. 1 H318, SKIN SENS. 1 H317 SECTION 4: FIRST AID MEASURES 4.1 DESCRIPTION OF FIRST AID MEASURES GENERAL INFORMATION INHALATION INGESTION SKIN CONTACT EYE CONTACT ALWAYS REMOVE CONTAMINATED CLOTHING IMMEDIATELY. GET MEDICAL ATTENTION IMMEDIATELY. REMOVE FROM EXPOSURE SITE TO FRESH AIR, KEEP AT REST, AND OBTAIN MEDICAL ATTENTION. GET MEDICAL ATTENTION IMMEDIATELY. IMMEDIATELY CALL THE DOCTOR. RINSE MOUTH WITH WATER AND OBTAIN MEDICAL ATTENTION. REMOVE CONTAMINATED CLOTHES. WASH THOROUGHLY WITH SOAP AND WATER. CONTACT PHYSICIAN IF IRRITATION PERSISTS. FLUSH IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES. CONTACT PHYSICIAN IF SYMPTOMS PERSIST. 4.2 MOST IMPORTANT SYMPTOMS & EFFECTS (ACUTE & DELAYED) 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION OR SPECIAL TREATMENT REQUIRED OBSERVE RISK OF ASPIRATION IF VOMITING OCCURS. TREAT SYMPOMATICALLY.

4 SECTION 5: FIRE FIGHTING MEASURES 5.1 EXTINGUISHING MATERIAL 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE 5.3 ADVICE FOR FIRE-FIGHTERS FOAM, CO2, DRY CHEMICAL POWDER. BURNING PRODUCES IRRITATING, TOXIC AND OBNOXIOUS FUMES SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS: WEAR POSITIVE-PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA) AND APPROPRIATE PROTECTIVE CLOTHING. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 PERSONAL PRECAUTIONS 6.2 ENVIRONMENTAL PRECAUTIONS 6.3 METHODS & MATERIAL FOR CONTAINMENT AND CLEANING UP 6.4 REFERENCES TO OTHER SECTIONS ENSURE ADEQUATE VENTILATION OF THE WORKING AREA, EVACUATE PERSONNEL TO SAFE AREA, WEAR SUITABLE PROTECTIVE EQUIPMENT. NO SMOKING, SPARKS, FLAMES OR OTHER SOURCES OF IGNITION NEAR SPILLAGE. AVOID CONTACT WITH SKIN, EYES AND CLOTHING. AVOID INHALATION. DO NOT DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND. DISPOSE OF IN LINE WITH LOCAL AUTHORITY GUIDELINES. REMOVE IGNITION SOURCES. PROVIDE ADEQUATE VENTILATION. AVOID EXCESSIVE INHALATION OF VAPOURS. CONTAIN SPILLAGE IMMEDIATELY BY USE OF SAND OR INERT POWDER. DISPOSE OF ACCORDING TO LOCAL REGULATIONS. COVER WITH AN INERT, INORGANIC, NON-COMBUSTIBLE ABSORBENT MATERIAL (E.G DRY-LIME, SAND, SODA ASH). REFER & CONSIDER SECTION 12. SECTION 7: HANDLING & STORAGE 7.1 PRECAUTIONS FOR SAFE-HANDLING 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES 7.3 SPECIFIC END USE(S) SECTION 8: EXPOSURE CONTROLS & PERSONAL PROTECTION 8.1 CONTROL PARAMETERS 8.2 EXPOSURE CONTROLS HANDLE IN ACCORDANCE WITH GOOD HYGIENE AND SAFETY PRACTICE. KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND HOT SURFACES. - NO SMOKING. USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. USE IN ACCORDANCE WITH GOOD MANUFACTURING AND INDUSTRIAL HYGIENE PRACTICES. USE IN AREAS WITH ADEQUATE VENTILATION DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. STORAGE CLASS: FLAMMABLE LIQUID STORAGE. STORE ONLY IN THE ORIGINAL RECEPTACLE. KEEP CONTAINER TIGHTLY SEALED. KEEP IN COOL, DRY, VENTILATED STORAGE AND CLOSED CONTAINERS. KEEP AWAY FROM HEAT. THE INFORMATION REQUIRED IS CONTAINED IN THIS MATERIAL SAFETY DATA P-CYMENE (CAS: ) INGREDIENT COMMENTS CONTAINS NO SUBSTANCES WITH OCCUPATIONAL EXPOSURE LIMIT VALUES. EYE PROTECTION HAND PROTECTION RESPIRATORY EQUIPMENT HYGIENE MEASURES WEAR PROTECTIVE GLOVES/EYE PROTECTION/FACE PROTECTION. AVOID CONTACT WITH EYES. WEAR APPROVED SAFETY GOGGLES. (EN166) AVOID CONTACT WITH SKIN. WASH HANDS BEFORE BREAKS AND AT END OF WORK. WEAR PROTECTIVE GLOVES. DIN/EN 374. THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/ THE SUBSTANCE/ THE PREPARATION. PENETRATION TIME OF GLOVE MATERIAL: THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED. DO NOT INHALE GASES / FUMES / AEROSOLS. CERTIFIED RESPIRATORY PROTECTIVE DEVICE RECOMMENDED. GOOD PERSONAL HYGIENE PRACTICES ARE ALWAYS ADVISABLE, ESPECIALLY WHEN WORKING WITH CHEMICALS / OILS.

5 ENGINEERING MEASURES SKIN PROTECTION PERSONAL PROTECTION OTHER PROTECTION PROCESS CONDITIONS ENVIROMENTAL EXPOSURE CONTROLS NONE. WEAR PROTECTIVE CLOTHING TO REDUCE THE RISK OF SKIN AND EYE CONTACT. AVOID INHALATION OF THE PRODUCT. AVOID CONTACT WITH SKIN AND EYES. AVOID CONTACT WITH SKIN AND EYES. USE PERSONAL PROTECTION ACCORDING TO DIRECTIVE 89/686/EEC. WEAR SUITABLE PROTECTION TO AVOID CONTACT WITH SKIN AND EYES. DO NOT INHALE VAPOURS. ENSURE AREA IS WELL VENTILATED. AVOID VAPOUR INHALATION. SAFETY SHOWER & EYE BATH. AVOID DISCHARGING INTO DRAINAGE WATER. SECTION 9: PHYSICAL & CHEMICAL PROPERTIES 9.1 PHYSICAL & CHEMICAL PROPERTIES 9.2 OTHER INFORMATION APPEARANCE COLOUR ODOUR LIQUID COLOURLESS - PALE YELLOW CHARACTERISTIC RELATIVE 20 C FLASH POINT ( C) 42 C. REFRACTIVE 20 C SOLUBILITY IN 20 C SECTION 10: STABILITY & REACTIVITY INSOLUBLE IN WATER REACTIVITY 10.2 CHEMICAL STABILITY 10.3 POSSIBILITY OF HAZARDOUS REACTIONS 10.4 CONDITIONS TO AVOID 10.5 INCOMPATIBLE MATERIALS 10.6 HAZARDOUS DECOMPOSITION PRODUCTS NOT APPLICABLE. STABLE UNDER SUGGESTED STORAGE CONDITIONS (<15 C). STABLE UNDER NORMAL CONDITIONS. NONE UNDER NORMAL PROCESSING. STORAGE AT HIGH TEMPERATURES. DO NOT STORE ABOVE 15 C. AVOID HEAT, FLAMES AND OTHER SOURCES OF IGNITION. AVOID OXIDISING AGENTS & ACIDS, ALKALIS. THIS PRODUCT DOES NOT DECOMPOSE UNDER NORMAL CONDITIONS. UNDER FIRE CONDITIONS THE PRODUCT WILL PRODUCE A MIXTURE OF IRRITATING FUMES & SMOKE & CARBON MONOXIDE. SECTION 11: TOXICOLOGICAL INFORMATION 11.1 TOXICOLOGICAL EFFECTS

6 ACUTE TOXICITY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG TERM ADVERSE EFFECTS IN THE AQUATIC ENVIRONMENT. SKIN IRRITATION EYE DAMAGE OR IRRITATION RESPIRATORY OR SKIN SENSITIVITY GERM CELL MUTAGENICITY CARCINOGENICITY REPRODUCTIVE TOXICITY STOT SINGLE EXPOSURE STOT REPEATED EXPOSURE ASPIRATION HAZARD OTHER INFORMATION MAY CAUSE ALLERGIC REACTION. MAY HAVE REVERSIBLE EFFECTS ON THE EYES, SUCH AS EYE IRRITATION WHICH IS TOTALLY REVERSIBLE BY THE END OF OBSERVATION AT 21 DAYS. TREAT IMMEDIATELY IN HIGH CONCENTRATIONS, VAPOURS MAY IRRITATE THROAT AND RESPIRATORY SYSTEM AND CAUSE COUGHING. NO DATA NO DATA SECTION 12: ECOLOGICAL INFORMATION 12.1 TOXICITY 12.2 PERSISTENCE & DEGRADABILITY 12.3 BIO- ACCUMULATIVE POTENTIAL 12.4 MOBILITY IN SOIL 12.5 RESULTS OF PBT & VPVB ASSESSMENT 12.6 OTHER ADVERSE EFFECTS NO DATA SECTION 13: DISPOSAL INFORMATION 13.1 WASTE TREATMENT METHODS ALWAYS RECOVER SPILLED PRODUCT. DISCARD WASTE MATERIAL WITH AUTHORIZED WASTE MANAGEMENT SERVICES. ACT IN ACCORDANCE WITH LOCAL & NATIONAL WASTE REGULATIONS. SECTION 14: TRANSPORT INFORMATION 14.1 TRANSPORT INFORMATION 14.2 UN SHIPPING NAME 14.3 TRANSPORT HAZARD CLASS(ES) UN NUMBER ROAD: 1169 SEA: 1169 AIR: 1169 EXTRACTS, AROMATIC, LIQUID. ADR/RID/ADN CLASS: 3 IMDG CLASS: 3 ICAO CLASS/DIVISION: 3 TRANSPORT LABELS

7 TUNNEL RESTRICTION CODE (D/E) HAZCHEM CODE 3YE EMS F-E, S-D HIN PACKING GROUP ADR/RID/ADN PACKING GROUP: III IMDG PACKING GROUP: III ICAO PACKING GROUP: III ENVIRONMENTALLY HAZARDOUS SUBSTANCE/MARINE POLLUTANT 14.5 ENVIROMENTAL HAZARDS 14.6 SPECIAL PRECAUTIONS FOR USER 14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 & THE IBC CODE. EMS F-A-S-F NONE. SECTION 15: REGULATORY INFORMATION 15.1 PRODUCT SPECIFIC SAFETY, HEALTH & ENVIRONMENTAL REGULATIONS & LEGISLATION 15.2 CHEMICAL SAFETY ASSESSMENT REGULATION (EC) NO 1907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL OF 18 TH DECEMBER CONCERNING THE REGISTRATION, EVALUATION, AUTHORIZATION & RESTRICTION OF CHEMICALS (REACH), ESTABLISHING A EUROPEAN CHEMICALS AGENCY, AMENDING DIRECTIVE EU DIRECTIVES 1999/45/EC AND REPEALING COUNCIL REGULATION (EEC) NO793/93 & COMMISSION REGULATION (EC) NO1488/94 AS WELL AS COUNCIL DIRECTIVE 76/769/EEC & COMMISSION DIRECTIVE 91/155/ECC, 93/67/ECC, 93/105/EEC & 2000/21/EC (INCLUDING AMENDMENTS). THE CHEMICALS (HAZARD INFORMATION & PACKAGING FOR SUPPLY REGULATIONS 2009 (S.I.2009 STATUTORY INSTRUMENTS NO 716). CLASSIFICATION & LABELLING OF SUBSTANCES & PREPARATIONS DANGEROUS FOR SUPPLY. SAFETY DATA APPROVED CODE OF PRACTICE SHEETS FOR SUBSTANCES & PREPARATIONS. GUIDANCE NOTES WORKPLACE EXPOSURE LIMITS EH40. CHIP FOR EVERYONE HSG 108. AN ASSESSMENT HAS NOT BEEN EXECUTED AS THIS IS NOT A HAZARDOUS MATERIAL ACCORDING TO ARTICLE 31 OF REACH 1907/2006. SECTION 16: OTHER INFORMATION H318 CAUSES SERIOUS EYE DAMAGE. H315 CAUSES SKIN IRRITATION. H226 FLAMMABLE LIQUID AND VAPOUR. H302 HARMFUL IF SWALLOWED. HAZARD AND/ OR PRECAUTIONARY STATEMENTS IN FULL H304 MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. H317 MAY CAUSE AN ALLERGIC SKIN REACTION. H411 TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. H410 VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS. H400 VERY TOXIC TO AQUATIC LIFE..

8 TRAINING INSTRUCTIONS: REFER TO POSSIBLE HAZARD BEFORE USE OF THIS PRODUCT. ABBREVIATIONS & ACRONYMS: MSDS INCI CAS IMDG ADR RID ICAO ADN GHS TREM CARD STOT MATERIAL SAFETY DATA SHEET. INTERNATIONAL NOMENCLATURE OF COSMETIC INGREDIENTS. CHEMICAL ABSTRACT SERVICE. INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS. ACCORD EUROPEAN SUR LE TRANSPORT DES MERCHANDISES DANGEREUSES PAR ROUTE (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD). INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY RAIL. INTERNATIONAL CIVIL AVIATION ORGANIZATION. INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY INLAND WATERWAYS. GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION & LABELLING OF CHEMICALS. TRANSPORT EMERGENCY CARD. SPECIFIC TARGET ORGAN TOXICITY. DOCUMENTATION REVISION DATE CHANGE DESCRIPTION 10 TH APRIL 2018 DATA LAUNCH