Safety Data Sheet. according to Regulation (EC) No. 1907/2006. Nelkenöl (Eugenol) Print date: Page 1 of 6

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1 Print date: Page 1 of 6 SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Further trade names Eugenol - zinc oxide combined pack. Product group: CAS No.: EC No.: Zulieferprodukt Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture For temporary fillings. For dental use. Details of the supplier of the safety data sheet Company name: Street: Place: Im Heerfeld 7 D Eschenburg Telephone: + 49(0) 2774/705-0 Telefax:+49 (0)2774/ Internet: Responsible Department: Emergency telephone: SECTION 2: Hazards identification info@kettenbach.de QM Classification of the substance or mixture Indications of danger : Irritant R-phrases: Irritating to eyes. May cause sensitization by skin contact. +49 (0) (English/German) GHS classification Hazard categories: Serious eye damage/eye irritation: Eye Irrit. 2 Respiratory/skin sensitization: Skin Sens. 1 Hazard Statements: Causes serious eye irritation. May cause an allergic skin reaction. Label elements Signal word: Pictograms: Warning GHS07 Hazardous components which must be listed on the label Clove oil Hazard statements H319 Causes serious eye irritation.

2 Print date: Page 2 of 6 H317 May cause an allergic skin reaction. Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. Additional advice on labelling Product is classified and labelled in accordance with EC regulations or the corresponding national laws. SECTION 3: Composition/information on ingredients Substances Chemical characterization Essential oil. Hazardous components EC No. CAS No. Index No. REACH No Chemical name Classification GHS classification Clove oil Xi R36-43 Eye Irrit. 2, Skin Sens. 1; H319 H317 4-allyl-2-methoxy phenyl acetate Xn, Xi R22-36/37/38 Acute Tox. 4, Skin Irrit. 2, Eye Irrit. 2A, STOT SE 3; H302 H315 H319 H335 Quantity % 5-10 % Isoeugenol Xn, Xi R21/22-36/38-43 Full text of R- and H-phrases: see section 16. Acute Tox. 4, Acute Tox. 4, Skin Irrit. 2, Eye Irrit. 2, Skin Sens. 1; H302 H312 H315 H319 H317 < 1 % SECTION 4: First aid measures Description of first aid measures General information Change contaminated clothing. After inhalation Provide fresh air. Seek medical attention if problems persist. If victim is at risk of losing consciousness, position and transport on their side. After contact with skin After contact with skin, wash immediately with: Water and soap. After contact with eyes If product gets into the eye, keep eyelid open and rinse immediately with large quantities of water, for at least 5 minutes. Subsequently consult an ophthalmologist.

3 Print date: Page 3 of 6 After ingestion Seek medical attention if problems persist. SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media Carbon dioxide (CO2). Extinguishing powder. Water spray. alcohol resistant foam. Advice for firefighters No special measures are necessary. Additional information Extinguishing materials should be selected according to the surrounding area. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Provide adequate ventilation. Environmental precautions Do not empty into drains or the aquatic environment. Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Provide adequate ventilation. Reference to other sections See protective measures under point 7 and 8. SECTION 7: Handling and storage Precautions for safe handling Advice on safe handling Use only in well-ventilated areas. Avoid the formation of aerosol. Advice on protection against fire and explosion No special precautionary measures are necessary. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels No special requirements. Advice on storage compatibility Not required. Further information on storage conditions Always close containers tightly after the removal of product. SECTION 8: Exposure controls/personal protection Control parameters Exposure controls Occupational exposure controls Refer to chapter 7. No further action is necessary. Protective and hygiene measures Keep away from food, drink and animal feedingstuffs. Use only in well-ventilated areas. Avoid contact with skin, eye and clothing. Change contaminated clothing. Wash hands before breaks and at the end of work.

4 Print date: Page 4 of 6 Respiratory protection In case of inadequate ventilation wear respiratory protection. Hand protection Protective gloves. Type of chemical protective gloves to choose depends on the concentration and quantity of dangerous substances as well as on work place specifications. In the cases of special applications, it is recommended to check the chemical resistance with the manufacturer of the gloves. Eye protection Safety glasses. Tightly sealed safety glasses. Skin protection Lab apron. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Physical state: Colour: Odour: liquid colourless - yellow characteristic ph-value: Changes in the physical state Melting point: Boiling point: Flash point: Auto-ignition temperature Solid: Density (at 20 C): Water solubility: (at 20 C) Other information SECTION 10: Stability and reactivity 110 C 1,043 g/cm³ not miscible Test method Possibility of hazardous reactions No hazardous reactions known. Conditions to avoid None by intended use. Incompatible materials irrelevant Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects

5 Print date: Page 5 of 6 Acute toxicity CAS No. Chemical name Exposure routes Method Dose allyl-2-methoxy phenyl acetate Acute oral toxicity ATE 500 mg/kg Isoeugenol Acute oral toxicity ATE 500 mg/kg Acute dermal toxicity ATE 1100 mg/kg Species h Irritation and corrosivity Irritant effect on the eye: irritant. Sensitizing effects Sensitization trough skin contact possible. Carcinogenic/mutagenic/toxic effects for reproduction Not applicable. SECTION 12: Ecological information Toxicity Persistence and degradability Bioaccumulative potential Results of PBT and vpvb assessment not applicable Further information Doesn't get into the sewage water as long as the process is carried out according to regulations. Leakage into the environment must be prevented. 2,. SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Waste disposal according to official state regulations. Do not empty into drains. Do not remove with domestic waste. Do not empty into drains. Contaminated packaging Completely emptied packings can be re-cycled. SECTION 14: Transport information Land transport (ADR/RID) UN proper shipping name: Inland waterways transport UN proper shipping name: Not a hazardous material with respect to these transportation regulations. Not a hazardous material with respect to these transportation regulations.

6 Print date: Page 6 of 6 Other applicable information Not a hazardous material with respect to these transportation regulations. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulatory information Water contaminating class (D): 2 - water contaminating SECTION 16: Other information Full text of R-phrases referred to under sections 2 and 3 21/22 Harmful in contact with skin and if swallowed. 22 Harmful if swallowed. 36 Irritating to eyes. 36/37/38 Irritating to eyes, respiratory system and skin. 36/38 Irritating to eyes and skin. 43 May cause sensitization by skin contact. Full text of H-Statements referred to under sections 2 and 3 H302 Harmful if swallowed. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. Further Information The information is based on present level of our knowledge. It does not, however, give assurances of product properties and establishes no contract legal rights. The receiver of our product is singulary responsible for adhering to existing laws and regulations.