Safety Data Sheet. according to Regulation (EU) No. 1907/2006. SYMPROfluid Nicoclean

Transcription

1 Page 1 of 6 1. Identification of the substance/preparation and of the company/undertaking Identification of the substance or preparation Use of the substance/preparation Special denture cleaner for removing stubborn nicotine stains. Company/undertaking identification Company name: Street: Place: Untere Giesswiesen 2 D Hilzingen Telephone: Telefax: andris@renfert.com Contact person: Frau Andris Telephone: Internet: Emergency telephone: 2. Hazards identification Vergiftungs-Zentrale Freiburg Classification Indications of danger : Irritant R-phrases: Irritating to eyes, respiratory system and skin. 3. Composition/information on ingredients Chemical characterization ( Mixture ) Alkaline cleaning agent Hazardous components EC-No. CAS-No. Chemical name Quantity Classification aminoethanol, ethanolamine < 10 % Xn, C R20/21/ Dowanol DPM < 10 % caustic potash, potassium hydroxide < 2 % Xn, C R22-35 Full text of each relevant R phrase can be found in heading First aid measures General information Take off immediately all contaminated clothing. After inhalation Provide fresh air. After contact with skin After contact with skin, wash immediately with plenty of water and soap. In case of skin irritation, seek medical treatment. After contact with eyes In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart. Subsequently consult an ophthalmologist. After ingestion Rinse mouth immediately and drink large quantities of water. Do not induce vomiting. Immediately get

2 Page 2 of 6 medical attention. 5. Fire-fighting measures Suitable extinguishing media The product itself is not combustible. Extinguishing materials should be selected according to the surrounding area. Special exposure hazards arising from substance or preparation itself, combustion products, resulting gases Thermal decomposition can lead to the escape of irritating gases and vapors. 6. Accidental release measures Personal precautions Wear personal protection equipment. Provide adequate ventilation. Environmental precautions Do not empty into drains or the aquatic environment. Methods for cleaning up/taking up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). 7. Handling and storage Handling Advice on safe handling Handle and open container with care. Wear personal protection equipment. Avoid contact with skin and eyes. Avoid contact with skin and eyes. Avoid contact with skin and eyes. Avoid contact with skin and eyes. Avoid contact with skin and eyes. Avoid contact with skin and eyes. Avoid contact with skin and eyes. Avoid contact with skin and eyes. Avoid contact with skin and eyes. Avoid contact with skin and eyes. Advice on protection against fire and explosion No special precautionary measures are necessary. Storage Requirements for storage rooms and vessels Keep only in the original container in a cool, well-ventilated place. Keep container tightly closed. Advice on storage compatibility Do not store together with: Acid. Further information on storage conditions Keep away from food, drink and animal feedingstuffs. 8. Exposure controls/personal protection Exposure limit values

3 Page 3 of 6 Exposure limits (EH40) CAS-No. Chemical name ml/m³ mg/m³ F/ml Category Origin (2-methoxymethylethoxy) propanol TWA (8 h) WEL - - STEL (15 min) WEL Aminoethanol TWA (8 h) WEL STEL (15 min) WEL Potassium hydroxide - - TWA (8 h) WEL Exposure controls Occupational exposure controls See chapter 7. No further action is necessary. Protective and hygiene measures Take off immediately all contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with skin and eyes. Respiratory protection Provide adequate ventilation. Respiratory protection required in case of: aerosol or mist generation. - 2 STEL (15 min) WEL Hand protection Tested protective gloves are to be worn: Suitable material: NR (Natural rubber (Caoutchouc), Natural latex). CR (polychloroprenes, Chloroprene rubber). In the cases of special applications, it is recommended to check the chemical resistance with the manufacturer of the gloves. Eye protection Tightly sealed safety glasses. Environmental exposure controls Do not empty into drains or the aquatic environment. 9. Physical and chemical properties General information Physical state: Colour: Odour: liquid blue earthy Important health, safety and environmental information ph-value (at 20 C): 12 Changes in the physical state Boiling point: Flash point: Density (at 20 C): Water solubility: Viscosity / dynamic: > 100 C not applicable 1,01-1,03 g/cm³ complete miscible product has not been tested. Test method 10. Stability and reactivity

4 Page 4 of 6 Conditions to avoid Thermal decomposition can lead to the escape of irritating gases and vapors. Materials to avoid Reacts with : acid. Oxidizing agents, strong. Hazardous decomposition products Reacts with : Light metals. Formation of: Hydrogen. 11. Toxicological information Corrosive and irritant effects Irritant effect on the skin: irritant. Irritant effect on the eye: irritant. Sensitising effects no danger of sensitization. Additional information on tests The classification was undertaken in accordance with the calculation method governed by the Preparations Directive (1999/45/EC). Empirical data on effects on humans Irritating to eyes, respiratory system and skin. 12. Ecological information Persistence and degradability The surfactants contained in the product are biodegradable according to the requirements of the Detergent Directive 648/2004/EC. Other adverse effects due to the alkaline character of the product, usually, it has to be neutralized before contaminated effluents are introduced into the waste water treatment system. Further information 1 Do not empty into drains or the aquatic environment. 13. Disposal considerations Advice on disposal Remove according to the regulations. due to the alkaline character of the product, usually, it has to be neutralized before contaminated effluents are introduced into the waste water treatment system. Waste disposal number of waste from residues/unused products MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND INSTITUTIONAL WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS; separately collected fractions (except 15 01); detergents containing dangerous substances Classified as hazardous waste. Contaminated packaging Handle contaminated packaging in the same way as the substance itself. 14. Transport information Land transport (ADR/RID) UN number: ADR/RID class: Warning plate

5 Page 5 of 6 ADR/RID packing group: III Description of the goods ÄTZENDER BASISCHER ANORGANISCHER FLÜSSIGER STOFF, N.A.G. Marine transport UN number: IMDG code: IMDG packing group: III Description of the goods CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (2-Amino-ethanol and potassiumhydroxide mixture) Air transport UN/ID number: ICAO/IATA-DGR: ICAO packing group: III Description of the goods CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (2-Amino-ethanol and potassiumhydroxide mixture) 15. Regulatory information Labelling Danger symbols: Xi - Irritant R phrases 36/37/38 Irritating to eyes, respiratory system and skin. S phrases 24/25 Avoid contact with skin and eyes. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. EU regulatory information 1999/13/EC (VOC): ca. 4 % (40,8 g/l) Additional information Labelling for contents according to regulation (EC) No 648/2004, annex 7: < 5% non-ionic surfactants, perfumes National regulatory information Water contaminating class (D): 1 - slightly water contaminating Additional information M 004 Reizende Stoffe / Ätzende Stoffe (BGI 595) 16. Other information Full text of R-phrases referred to under sections 2 and 3 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. 22 Harmful if swallowed. 34 Causes burns. 35 Causes severe burns. 36/37/38 Irritating to eyes, respiratory system and skin. Further Information The information is based on present level of our knowledge. It does not, however, give assurances of product properties and establishes no contract legal rights. The receiver of our product is singulary responsible for adhering to existing laws and regulations.

6 Page 6 of 6 Reserved for industrial and professional use. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)