SAFETY DATA SHEET Valspar Interior Varnish Stain - Gloss Base According to Regulation (EC) No 1907/2006, Annex II, as amended.

Transcription

1 SAFETY DATA SHEET According to Regulation (EC) No 1907/2006, Annex II, as amended. SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product number , Relevant identified uses of the substance or mixture and uses advised against Identified uses Uses advised against Water-based paint. No specific uses advised against are identified Details of the supplier of the safety data sheet Supplier Valspar 220 Wharfedale Road, Winnersh, Wokingham, Berkshire, RG41 5TP Tel: Emergency telephone number Emergency telephone ( Monday - Sunday) SECTION 2: Hazards identification 2.1. of the substance or mixture (EC 1272/2008) Physical hazards Not Classified Health hazards Environmental hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 STOT SE 3 - H335 Not Classified 2.2. Label elements Pictogram Signal word Hazard statements Warning H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. 1/11

2 Precautionary statements Contains VOC Labelling Supplementary precautionary statements P102 Keep out of reach of children. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves, eye and face protection. P312 Call a POISON CENTER/ doctor if you feel unwell. P302+P352 IF ON SKIN: Wash with plenty of water. P333+P313 If skin irritation or rash occurs: Get medical advice/ attention. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P501 Dispose of contents/ container in accordance with national regulations. Triethylamine, 2,4,7,9-tetramethyldec-5-yne-4,7-diol, reaction mass of: 5-chloro-2-methyl-4- isothiazolin-3-one [EC no ] and 2-methyl-2H -isothiazol-3-one [EC no ] (3:1) EU: (cat A/e): 130 g/l (2010). This product contains a maximum VOC content of 100 g/l. P261 Avoid breathing vapours. P264 Wash contaminated skin thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P362+P364 Take off contaminated clothing and wash it before reuse. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/ attention. P405 Store locked up Other hazards This product does not contain any substances classified as PBT or vpvb. SECTION 3: Composition/information on ingredients 3.2. Mixtures 1-methoxy-3-(3-methoxypropoxy)propane 5-10% CAS number: Eye Irrit. 2 - H319 Triethylamine 1-5% CAS number: EC number: Flam. Liq. 2 - H225 Acute Tox. 4 - H302 Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Corr. 1A - H314 STOT SE 3 - H335 2/11

3 propane-1,2-diol <1% CAS number: EC number: Substance with National workplace exposure limits. Not Classified Ethanediol <1% CAS number: EC number: Acute Tox. 4 - H302 STOT RE 2 - H373 2,4,7,9-tetramethyldec-5-yne-4,7-diol <1% CAS number: Eye Dam. 1 - H318 Skin Sens. 1B - H317 Aquatic Chronic 3 - H412 2-(2-butoxyethoxy)ethanol <1% CAS number: EC number: Eye Irrit. 2 - H319 dibutyltin dilaurate <1% CAS number: EC number: M factor (Acute) = 1 M factor (Chronic) = 1 Skin Corr. 1C - H314 Skin Sens. 1 - H317 Muta. 2 - H341 Repr. 1B - H360 STOT SE 1 - H370 STOT RE 1 - H372 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 3/11

4 Iron(1+), chloro[dimethyl 9,9-dihydroxy-3-methyl-2,4-di(2- pyridinyl-kn)-7-[(2-pyridinyl-kn)methyl]-3,7- diazabicyclo[3.3.1]nonane-1,5-dicarboxylate-kn3,kn7]-, chloride <1% CAS number: Acute Tox. 3 - H301 Skin Sens. 1 - H317 STOT RE 2 - H373 Aquatic Chronic 3 - H412 reaction mass of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no ] and 2-methyl-2H -isothiazol-3-one [EC no ] (3:1) <1% CAS number: M factor (Acute) = 10 M factor (Chronic) = 10 Acute Tox. 3 - H301 Acute Tox. 3 - H311 Acute Tox. 3 - H331 Skin Corr. 1B - H314 Skin Sens. 1 - H317 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 copper dinitrate <1% CAS number: EC number: M factor (Acute) = 10 Skin Corr. 1B - H314 Aquatic Acute 1 - H400 Aquatic Chronic 2 - H411 The full text for all hazard statements is displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Ingestion Skin contact Eye contact Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Get medical attention if any discomfort continues. Do not induce vomiting. Rinse mouth thoroughly with water. Get medical attention if any discomfort continues. Wash skin thoroughly with soap and water. Get medical attention if irritation persists after washing. Remove any contact lenses and open eyelids wide apart. Rinse with water. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. 4/11

5 4.2. Most important symptoms and effects, both acute and delayed Inhalation Ingestion Skin contact Eye contact May cause respiratory irritation. Headache. No specific symptoms known. May cause discomfort if swallowed. Causes skin irritation. Redness. May cause sensitisation by skin contact. Causes serious eye irritation. Redness Indication of any immediate medical attention and special treatment needed Notes for the doctor Specific treatments Treat symptomatically. The severity of the symptoms described will vary dependent on the concentration and the length of exposure. No specific chemical antidote is known to be required after exposure to this product. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire. Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Specific hazards Hazardous combustion products None known. Thermal decomposition or combustion products may include the following substances: Oxides of carbon. Toxic gases or vapours Advice for firefighters Protective actions during firefighting Special protective equipment for firefighters Avoid breathing fire gases or vapours. Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Provide adequate ventilation. Avoid contact with skin and eyes. Avoid inhalation of vapours. Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Environmental precautions The product is not expected to be hazardous to the environment. However, large or frequent spills may have hazardous effects on the environment. Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up Avoid contact with skin, eyes and clothing. Absorb spillage with non-combustible, absorbent material. Collect and place in suitable waste disposal containers and seal securely. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage Reference to other sections Reference to other sections For waste disposal, see Section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling 5/11

6 Usage precautions Advice on general occupational hygiene Avoid contact with skin, eyes and clothing. Avoid inhalation of vapours. Avoid spilling. Special precautions should be taken during surface preparation of pre-1960s paint surfaces over wood and metal as they may contain harmful lead Clean equipment and the work area every day. Wash contaminated skin thoroughly after handling Conditions for safe storage, including any incompatibilities Storage precautions Container must be kept tightly closed when not in use. Protect from freezing and direct sunlight Specific end use(s) Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Occupational exposure limits Triethylamine Long-term exposure limit (8-hour TWA): WEL 2 ppm 8 mg/m³ Short-term exposure limit (15-minute): WEL 4 ppm 17 mg/m³ Sk propane-1,2-diol Long-term exposure limit (8-hour TWA): WEL 150 ppm 474 mg/m³ total vapour and particulates Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ particulate Ethanediol Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ particulate Sk Long-term exposure limit (8-hour TWA): WEL 20 ppm 52 mg/m³ vapour Short-term exposure limit (15-minute): WEL 40 ppm 104 mg/m³ vapour Sk 2-(2-butoxyethoxy)ethanol Long-term exposure limit (8-hour TWA): WEL 10 ppm 67.5 mg/m³ Short-term exposure limit (15-minute): WEL 15 ppm mg/m³ dibutyltin dilaurate Long-term exposure limit (8-hour TWA): WEL 0.1 mg/m³ Short-term exposure limit (15-minute): WEL 0.2 mg/m³ as Sn Sk Iron(1+), chloro[dimethyl 9,9-dihydroxy-3-methyl-2,4-di(2-pyridinyl-kN)-7-[(2-pyridinyl-kN)methyl]-3,7- diazabicyclo[3.3.1]nonane-1,5-dicarboxylate-kn3,kn7]-, chloride Long-term exposure limit (8-hour TWA): WEL 1 mg/m³ Short-term exposure limit (15-minute): WEL 2 mg/m³ as Fe copper dinitrate Long-term exposure limit (8-hour TWA): WEL 1 mg/m³ Short-term exposure limit (15-minute): WEL 2 mg/m³ as Cu WEL = Workplace Exposure Limit Sk = Can be absorbed through the skin Exposure controls dust and mists dust and mists 6/11

7 Appropriate engineering controls Eye/face protection Hand protection Other skin and body protection Hygiene measures Respiratory protection Environmental exposure controls Provide adequate ventilation. Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. The following protection should be worn: Tight-fitting safety glasses. Personal protective equipment for eye and face protection should comply with European Standard EN166. It is recommended that chemical-resistant, impervious gloves are worn. To protect hands from chemicals, gloves should comply with European Standard EN374. The most suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can provide information about the breakthrough time of the glove material. Wear appropriate clothing to prevent skin contamination. Wash contaminated skin thoroughly after handling. Respiratory protection complying with an approved standard should be worn if a risk assessment indicates inhalation of contaminants is possible. Ensure all respiratory protective equipment is suitable for its intended use and is CE -marked. Keep container tightly sealed when not in use. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Appearance Colour Melting point Initial boiling point and range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Vapour pressure Vapour density Relative density Solubility(ies) Partition coefficient Auto-ignition temperature Decomposition Temperature Viscosity Explosive properties Oxidising properties Liquid. Various colours. Soluble in water. Not considered to be explosive. Does not meet the criteria for classification as oxidising Other information 7/11

8 Other information None. SECTION 10: Stability and reactivity Reactivity Reactivity There are no known reactivity hazards associated with this product Chemical stability Stability Stable at normal ambient temperatures and when used as recommended Possibility of hazardous reactions Possibility of hazardous reactions Will not polymerise Conditions to avoid Conditions to avoid Avoid freezing. Avoid heat Incompatible materials Materials to avoid Water-reactive materials. Organic peroxides/hydroperoxides Hazardous decomposition products Hazardous decomposition products Does not decompose when used and stored as recommended. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity - oral Notes (oral LD₅₀) ATE oral (mg/kg) 63, Acute toxicity - dermal Notes (dermal LD₅₀) ATE dermal (mg/kg) 95, Acute toxicity - inhalation Notes (inhalation LC₅₀) ATE inhalation (vapours mg/l) Skin corrosion/irritation Skin corrosion/irritation Serious eye damage/irritation Serious eye damage/irritation Respiratory sensitisation Respiratory sensitisation Skin sensitisation Skin sensitisation Germ cell mutagenicity Genotoxicity - in vitro Genotoxicity - in vivo Skin Irrit. 2 - H315, Causes skin irritation. Eye Irrit. 2 - H319 Causes serious eye irritation. Skin Sens. 1 - H317 May cause an allergic skin reaction. 8/11

9 Carcinogenicity Carcinogenicity Reproductive toxicity Reproductive toxicity - fertility Reproductive toxicity - development Specific target organ toxicity - single exposure STOT - single exposure STOT SE 3 - H335 May cause respiratory irritation. Target organs Respiratory system, lungs Specific target organ toxicity - repeated exposure STOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure. Aspiration hazard Aspiration hazard Inhalation Ingestion Skin contact Eye contact May cause respiratory irritation. Headache. No specific symptoms known. May cause discomfort if swallowed. Causes skin irritation. Redness. May cause sensitisation by skin contact. Causes serious eye irritation. Redness. Toxicological information on ingredients. Triethylamine Acute toxicity - oral Acute toxicity oral (LD₅₀ mg/kg) Species Rat ATE oral (mg/kg) Acute toxicity - dermal ATE dermal (mg/kg) 1,100.0 Acute toxicity - inhalation ATE inhalation (vapours mg/l) 11.0 Skin corrosion/irritation Animal data Rabbit Corrosive to skin. SECTION 12: Ecological Information Toxicity Toxicity The product is not expected to be hazardous to the environment. However, large or frequent spills may have hazardous effects on the environment Persistence and degradability Persistence and degradability 9/11

10 12.3. Bioaccumulative potential Bioaccumulative potential Partition coefficient No data available on bioaccumulation Mobility in soil Mobility The product is water-soluble and may spread in water systems Results of PBT and vpvb assessment Results of PBT and vpvb assessment This product does not contain any substances classified as PBT or vpvb Other adverse effects Other adverse effects None known. SECTION 13: Disposal considerations Waste treatment methods General information Disposal methods Reuse or recycle products wherever possible. Empty containers or liners may retain some product residues and hence be potentially hazardous. Care should be taken when handling emptied containers that have not been thoroughly cleaned or rinsed out. Dispose of contents/container in accordance with national regulations. SECTION 14: Transport information General The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number Not applicable UN proper shipping name Not applicable Transport hazard class(es) No transport warning sign required Packing group Not applicable Environmental hazards Environmentally hazardous substance/marine pollutant No Special precautions for user Not applicable Transport in bulk according to Annex II of MARPOL and the IBC Code Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture 10/11

11 National regulations The Volatile Organic Compounds in Paints, Varnishes and Vehicle Refinishing Products Regulations 2012, SI 2012/1715 EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended). Commission Regulation (EU) No 2015/830 of 28 May Chemical safety assessment No chemical safety assessment has been carried out. SECTION 16: Other information procedures according to Regulation (EC) 1272/2008 Revision comments Skin Irrit. 2 - H315, Skin Sens. 1 - H317, Eye Irrit. 2 - H319, STOT SE 3 - H335: Calculation method. This is first issue. Revision date 15/06/2017 SDS number 1601 Hazard statements in full H225 Highly flammable liquid and vapour. H301 Toxic if swallowed. H302 Harmful if swallowed. H311 Toxic in contact with skin. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H331 Toxic if inhaled. H332 Harmful if inhaled. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H360 May damage fertility or the unborn child. H370 Causes damage to organs (Thymus). H372 Causes damage to organs (Thymus) through prolonged or repeated exposure. H373 May cause damage to organs through prolonged or repeated exposure. H373 May cause damage to organs (Gastro-intestinal tract) through prolonged or repeated exposure if swallowed. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 11/11