SAFETY DATA SHEET Valspar Exterior Wood & Metal Gloss Base 1 According to Regulation (EC) No 1907/2006, Annex II, as amended.

Transcription

1 SAFETY DATA SHEET According to Regulation (EC) No 1907/2006, Annex II, as amended. SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product number , , , Relevant identified uses of the substance or mixture and uses advised against Identified uses Uses advised against Water-based paint. No specific uses advised against are identified Details of the supplier of the safety data sheet Supplier Valspar 220 Wharfedale Road, Winnersh, Wokingham, Berkshire, RG41 5TP Tel: Emergency telephone number Emergency telephone ( Monday - Sunday) SECTION 2: Hazards identification 2.1. of the substance or mixture (EC 1272/2008) Physical hazards Not Classified Health hazards Environmental hazards Not Classified Aquatic Chronic 3 - H Label elements Hazard statements Precautionary statements VOC Labelling H412 Harmful to aquatic life with long lasting effects. EUH208 Contains 2-octyl-2H-isothiazol-3-one, 1,2-Benzisothiazol-3(2H)-one. May produce an allergic reaction. P102 Keep out of reach of children. P273 Avoid release to the environment. P333+P313 If skin irritation or rash occurs: Get medical advice/ attention. P501 Dispose of contents/ container in accordance with national regulations. EU: (cat A/d): 130 g/l (2010). This product contains a maximum VOC content of 130 g/l. 1/15

2 Biocide Labelling Contains a biocidal product for the preservation of dry-film: 2-octyl-2H-isothiazol-3-one, 3- iodo-2-propynyl butylcarbamate, Diuron., Contains a biocidal product to control microbial deterioration: MIT. Supplementary precautionary statements P261 Avoid breathing vapour/ spray. P272 Contaminated work clothing should not be allowed out of the workplace Other hazards This product does not contain any substances classified as PBT or vpvb. SECTION 3: Composition/information on ingredients 3.2. Mixtures 10-30% CAS number: EC number: Substance with National workplace exposure limits. Not Classified 1-5% CAS number: EC number: Substance with National workplace exposure limits. Not Classified Amorphous silica <1% CAS number: Substance with National workplace exposure limits. Not Classified Aluminium hydroxide <1% CAS number: EC number: Substance with National workplace exposure limits. Not Classified 2/15

3 ammonia <1% CAS number: EC number: M factor (Acute) = 1 Acute Tox. 3 - H331 Skin Corr. 1B - H314 STOT SE 3 - H335 Aquatic Acute 1 - H400 Cellulose <1% CAS number: EC number: Not Classified diuron (ISO) <1% CAS number: EC number: M factor (Acute) = 10 M factor (Chronic) = 10 Acute Tox. 4 - H302 Carc. 2 - H351 STOT RE 2 - H373 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 3-iodo-2-propynyl butylcarbamate <1% CAS number: EC number: M factor (Acute) = 10 M factor (Chronic) = 1 Acute Tox. 4 - H302 Acute Tox. 3 - H331 Eye Dam. 1 - H318 Skin Sens. 1 - H317 STOT SE 3 - H335 STOT RE 1 - H372 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 3/15

4 2-octyl-2H-isothiazol-3-one <1% CAS number: EC number: M factor (Acute) = 10 M factor (Chronic) = 10 Acute Tox. 4 - H302 Acute Tox. 3 - H311 Acute Tox. 3 - H331 Skin Corr. 1B - H314 Skin Sens. 1 - H317 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 1,2-Benzisothiazol-3(2H)-one <1% CAS number: EC number: M factor (Acute) = 1 Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Aquatic Acute 1 - H400 Formaldehyde <1% CAS number: EC number: Acute Tox. 3 - H301 Acute Tox. 3 - H311 Acute Tox. 3 - H331 Skin Corr. 1B - H314 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Muta. 2 - H341 Carc. 1B - H350 STOT SE 3 - H335 The full text for all hazard statements is displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Ingestion Skin contact Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Get medical attention if any discomfort continues. Do not induce vomiting. Rinse mouth thoroughly with water. Get medical attention if any discomfort continues. Wash skin thoroughly with soap and water. Get medical attention if irritation persists after washing. 4/15

5 Eye contact Remove any contact lenses and open eyelids wide apart. Rinse with water. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues Most important symptoms and effects, both acute and delayed Inhalation Ingestion Skin contact Eye contact No specific symptoms known. However, this product contains VOCs which may cause a headache. No specific symptoms known. May cause discomfort if swallowed. May be slightly irritating to skin. May cause skin sensitisation or allergic reactions in sensitive individuals. May be slightly irritating to eyes Indication of any immediate medical attention and special treatment needed Notes for the doctor Specific treatments Treat symptomatically. The severity of the symptoms described will vary dependent on the concentration and the length of exposure. No specific chemical antidote is known to be required after exposure to this product. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire. Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Specific hazards Hazardous combustion products None known. Thermal decomposition or combustion products may include the following substances: Oxides of carbon. Toxic gases or vapours Advice for firefighters Protective actions during firefighting Special protective equipment for firefighters Avoid breathing fire gases or vapours. Control run-off water by containing and keeping it out of sewers and watercourses. Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Avoid contact with eyes and prolonged skin contact Environmental precautions Environmental precautions The product contains a substance which may cause long-term adverse effects in the aquatic environment. The product contains substances which are water-soluble and may spread in water systems. The product contains volatile substances which may spread in the atmosphere. Avoid release to the environment. Contain spillage with sand, earth or other suitable non-combustible material Methods and material for containment and cleaning up Methods for cleaning up Avoid contact with skin, eyes and clothing. Absorb spillage with non-combustible, absorbent material. Collect and place in suitable waste disposal containers and seal securely. Flush contaminated area with plenty of water. Wash thoroughly after dealing with a spillage Reference to other sections 5/15

6 Reference to other sections For waste disposal, see Section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Advice on general occupational hygiene Avoid contact with skin, eyes and clothing. Avoid spilling. Special precautions should be taken during surface preparation of pre-1960s paint surfaces over wood and metal as they may contain harmful lead Clean equipment and the work area every day. Wash contaminated skin thoroughly after handling Conditions for safe storage, including any incompatibilities Storage precautions Container must be kept tightly closed when not in use. Protect from freezing and direct sunlight Specific end use(s) Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Occupational exposure limits Long-term exposure limit (8-hour TWA): WEL 4 mg/m³ Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ respirable dust inhalable dust Long-term exposure limit (8-hour TWA): WEL 150 ppm 474 mg/m³ total vapour and particulates Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ particulate Amorphous silica Long-term exposure limit (8-hour TWA): WEL 6 mg/m³ inhalable dust Long-term exposure limit (8-hour TWA): WEL 2.4 mg/m³ respirable dust Aluminium hydroxide Long-term exposure limit (8-hour TWA): WEL 2 mg/m³ Cellulose Long-term exposure limit (8-hour TWA): WEL 4 mg/m³ Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ Short-term exposure limit (15-minute): WEL 20 mg/m³ diuron (ISO) Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ Formaldehyde Long-term exposure limit (8-hour TWA): WEL 2 ppm 2.5 mg/m³ Short-term exposure limit (15-minute): WEL 2 ppm 2.5 mg/m³ WEL = Workplace Exposure Limit 8.2. Exposure controls respirable dust inhalable dust inhalable dust Appropriate engineering controls Eye/face protection Hand protection Provide adequate ventilation. Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. No specific hand protection recommended. 6/15

7 Other skin and body protection Hygiene measures Respiratory protection Environmental exposure controls Wear appropriate clothing to prevent skin contamination. Wash contaminated skin thoroughly after handling. Respiratory protection not required. Respiratory protection complying with an approved standard should be worn if a risk assessment indicates inhalation of contaminants is possible. Keep container tightly sealed when not in use. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Appearance Colour Melting point Initial boiling point and range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Vapour pressure Vapour density Relative density Solubility(ies) Partition coefficient Auto-ignition temperature Decomposition Temperature Viscosity Explosive properties Oxidising properties Liquid. Various colours. Soluble in water. Not considered to be explosive. Does not meet the criteria for classification as oxidising Other information Other information None. SECTION 10: Stability and reactivity Reactivity Reactivity There are no known reactivity hazards associated with this product Chemical stability Stability Stable at normal ambient temperatures and when used as recommended Possibility of hazardous reactions 7/15

8 Possibility of hazardous reactions Will not polymerise Conditions to avoid Conditions to avoid Avoid freezing. Avoid heat Incompatible materials Materials to avoid Water-reactive materials. Organic peroxides/hydroperoxides Hazardous decomposition products Hazardous decomposition products Does not decompose when used and stored as recommended. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity - oral Notes (oral LD₅₀) Acute toxicity - dermal Notes (dermal LD₅₀) Acute toxicity - inhalation Notes (inhalation LC₅₀) ATE inhalation (gases ppm) 593, Skin corrosion/irritation Animal data Serious eye damage/irritation Serious eye damage/irritation Respiratory sensitisation Respiratory sensitisation Skin sensitisation Skin sensitisation Germ cell mutagenicity Genotoxicity - in vitro Genotoxicity - in vivo Carcinogenicity Carcinogenicity Reproductive toxicity Reproductive toxicity - fertility Reproductive toxicity - development Specific target organ toxicity - single exposure STOT - single exposure Not classified as a specific target organ toxicant after a single exposure. Specific target organ toxicity - repeated exposure STOT - repeated exposure Not classified as a specific target organ toxicant after repeated exposure. 8/15

9 Aspiration hazard Aspiration hazard Toxicological information on ingredients. Acute toxicity - oral Notes (oral LD₅₀) Acute toxicity - dermal Notes (dermal LD₅₀) No information available. Scientifically unjustified. Acute toxicity - inhalation Acute toxicity inhalation (LC₅₀ dust/mist mg/l) Species Notes (inhalation LC₅₀) ATE inhalation (dusts/mists mg/l) 6.82 Rat 6.82 Skin corrosion/irritation Animal data Dose: 0.5 g, 4 hours, Rabbit Erythema/eschar score: No erythema (0). Oedema score: No oedema (0). Serious eye damage/irritation Serious eye damage/irritation Respiratory sensitisation Respiratory sensitisation No information available. Skin sensitisation Skin sensitisation Local Lymph Node Assay (LLNA) - Mouse: Not sensitising. Germ cell mutagenicity Genotoxicity - in vitro Genotoxicity - in vivo Bacterial reverse mutation test: Negative. Chromosome aberration: Negative. Carcinogenicity Carcinogenicity NOAEL 50 mg/m³, Inhalation, Rat Reproductive toxicity 9/15

10 Reproductive toxicity - fertility Reproductive toxicity - development No information available. No information available. Specific target organ toxicity - single exposure STOT - single exposure Not classified as a specific target organ toxicant after a single exposure. Specific target organ toxicity - repeated exposure STOT - repeated exposure NOAEC 10 mg/m³, Inhalation, Rat Not classified as a specific target organ toxicant after repeated exposure. Aspiration hazard Aspiration hazard Not anticipated to present an aspiration hazard, based on chemical structure. Acute toxicity - oral Acute toxicity oral (LD₅₀ mg/kg) Species Notes (oral LD₅₀) 22,000.0 Rat ATE oral (mg/kg) 22,000.0 Acute toxicity - dermal Notes (dermal LD₅₀) LD₅₀ > 2000 mg/kg, Rabbit Acute toxicity - inhalation Notes (inhalation LC₅₀) No information available. Skin corrosion/irritation Animal data Dose: 0.5 ml, 4 hours, Rabbit Primary dermal irritation index: 0 Serious eye damage/irritation Serious eye damage/irritation Dose: 0.1 ml, 96 days, Rabbit Respiratory sensitisation Respiratory sensitisation No information available. Skin sensitisation Skin sensitisation Guinea pig maximization test (GPMT) - Guinea pig: Not sensitising. Germ cell mutagenicity 10/15

11 Genotoxicity - in vitro Genotoxicity - in vivo Chromosome aberration: Negative. Chromosome aberration: Negative. Carcinogenicity Carcinogenicity NOAEL 1700 mg/kg/day, Oral, Rat Reproductive toxicity Reproductive toxicity - fertility Reproductive toxicity - development Multi-generation study - NOAEL mg/kg/day, Oral, Mouse P, F1 Developmental toxicity: - NOAEL: mg/kg/day, Oral, Mouse This substance has no evidence of toxicity to reproduction. Specific target organ toxicity - single exposure STOT - single exposure Not classified as a specific target organ toxicant after a single exposure. Specific target organ toxicity - repeated exposure STOT - repeated exposure NOAEL 1700 mg/m³, Oral, Rat Not classified as a specific target organ toxicant after repeated exposure. Aspiration hazard Aspiration hazard Not anticipated to present an aspiration hazard, based on chemical structure. SECTION 12: Ecological Information Toxicity Toxicity Aquatic Chronic 3 - H412 Harmful to aquatic life with long lasting effects. Ecological information on ingredients. Acute aquatic toxicity Acute toxicity - fish Acute toxicity - aquatic invertebrates Acute toxicity - aquatic plants LC₅₀, 96 hours: 1000 mg/l, Pimephales promelas (Fat-head Minnow) EC₅₀, 48 hours: 100 mg/l, Daphnia magna EC₅₀, 72 hours: 61 mg/l, Pseudokirchneriella subcapitata Acute aquatic toxicity Acute toxicity - fish LC₅₀, 96 hours: mg/l, Oncorhynchus mykiss (Rainbow trout) 11/15

12 Acute toxicity - aquatic invertebrates Acute toxicity - aquatic plants Acute toxicity - microorganisms LC₅₀, 96 hours: mg/l, Mysidopsis bahia EC₅₀, 48 hours: mg/l, Pseudokirchneriella subcapitata NOEC, 18 hours: > mg/l, Pseudomonas putida Chronic aquatic toxicity Chronic toxicity - aquatic invertebrates NOEC, 7 days: mg/l, Ceriodaphnia sp Persistence and degradability Persistence and degradability Ecological information on ingredients. Phototransformation Stability (hydrolysis) Biodegradation No information available. No significant reaction in water. Not applicable. Substance is inorganic. Phototransformation Biodegradation Water - DT₅₀ : 2.3 years Water - (>81.7%): 28 days The substance is readily biodegradable Bioaccumulative potential Bioaccumulative potential Partition coefficient No data available on bioaccumulation. Ecological information on ingredients. Bioaccumulative potential Partition coefficient The product is not bioaccumulating. Not applicable. Substance is inorganic. Bioaccumulative potential Partition coefficient BCF: 0.09, Pow: Mobility in soil Mobility The product is water-soluble and may spread in water systems. Ecological information on ingredients. 12/15

13 Mobility The product is insoluble in water and will sediment in water systems. Surface tension C Results of PBT and vpvb assessment Results of PBT and vpvb assessment This product does not contain any substances classified as PBT or vpvb. Ecological information on ingredients. Results of PBT and vpvb assessment This substance is not classified as PBT or vpvb according to current EU criteria. Results of PBT and vpvb assessment This substance is not classified as PBT or vpvb according to current EU criteria Other adverse effects Other adverse effects None known. Ecological information on ingredients. Other adverse effects None known. Other adverse effects None known. SECTION 13: Disposal considerations Waste treatment methods General information Disposal methods Reuse or recycle products wherever possible. Dispose of contents/container in accordance with national regulations. SECTION 14: Transport information General The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number Not applicable UN proper shipping name Not applicable Transport hazard class(es) No transport warning sign required. 13/15

14 14.4. Packing group Not applicable Environmental hazards Environmentally hazardous substance/marine pollutant No Special precautions for user Not applicable Transport in bulk according to Annex II of MARPOL and the IBC Code Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations The Volatile Organic Compounds in Paints, Varnishes and Vehicle Refinishing Products Regulations 2012, SI 2012/1715 EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended) Chemical safety assessment No chemical safety assessment has been carried out. SECTION 16: Other information procedures according to Regulation (EC) 1272/2008 Revision comments EUH208, Aquatic Chronic 3 - H412: Calculation method. Product name change. Revised formulation. Revision date 25/09/2017 Revision 2 Supersedes date 09/10/2015 SDS number /15

15 Hazard statements in full H301 Toxic if swallowed. H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H331 Toxic if inhaled. H335 May cause respiratory irritation. H341 Suspected of causing genetic defects. H350 May cause cancer. H351 Suspected of causing cancer. H372 Causes damage to organs (Larynx) through prolonged or repeated exposure. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. EUH208 Contains 2-octyl-2H-isothiazol-3-one, 1,2-Benzisothiazol-3(2H)-one. May produce an allergic reaction. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 15/15