SAFETY DATA SHEET SALINOFIX

Transcription

1 Revision Date 27/01/12 Revision 1 Supersedes date No previous SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No Relevant identified uses of the substance or mixture and uses advised against Identified uses Damping system additive 1.3. Details of the supplier of the safety data sheet Supplier 1.4. Emergency telephone number SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture STEHLIN HOSTAG INK UK LTD UNIT D4 LINKMEL CLOSE QUEENS DRIVE INDUSTRIAL ESTATE NOTTINGHAM NG2 1NA Tel : Fax : sds@stehlin.co.uk Classification (EC 1272/2008) Physical and Chemical Hazards Human health Environment Classification (1999/45/EEC) Xi;R36/38. R43. Not classified. Skin Irrit. 2 - H315;Eye Irrit. 2 - H319;Skin Sens. 1 - H317 Not classified. Human health Irritating to eyes and skin. May cause sensitisation by skin contact 2.2. Label elements Contains Label In Accordance With (EC) No. 1272/2008 A mixture of: 5-chloro-2-methyl-2H -isothiazol-3-one (EC ) and 2-methyl-2H-isothiazol-3-0 BRONOPOL (INN) Signal Word Hazard Statements Precautionary Statements Warning H315 H317 H319 P280 Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Wear protective gloves/protective clothing/eye protection/face protection. 1 / 6

2 Supplementary Precautionary Statements 2.3. Other hazards P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P IF ON SKIN: Wash with plenty of soap and water. P IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P313 Get medical advice/attention. P321 Specific treatment (see on this label). P If skin irritation occurs: Get medical advice/attention. P If skin irritation or rash occurs: Get medical advice/attention. P337 If eye irritation persists: P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P501 Dispose of contents/container to SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures BRONOPOL (INN) <1.5% CAS-No.: EC No.: Classification (EC 1272/2008) Acute Tox. 4 - H302 Acute Tox. 4 - H312 Skin Irrit. 2 - H315 Eye Dam. 1 - H318 STOT Single 3 - H335 Aquatic Acute 1 - H400 Classification (67/548/EEC) Xn;R21/22 Xi;R37/38,R41 N;R50 A mixture of: 5-chloro-2-methyl-2H -isothiazol-3-one (EC ) and 2-methyl-2H-isothiazol-3-0 <1.5% CAS-No.: EC No.: Classification (EC 1272/2008) Acute Tox. 3 - H301 Acute Tox. 3 - H311 Acute Tox. 2 - H330 Skin Corr. 1B - H314 Skin Sens. 1 - H317 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Classification (67/548/EEC) T;R23/24/25. C;R34. N;R50/53. R43. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor Ingestion Wash out mouth with water Consult a doctor. Skin contact Remove all contaminated clothes and footwear immediately, unless stuck to skin. Wash immediately with plenty of water and soap and rinse thoroughly. Eye contact Bathe the eye with running water for 15 minutes Consult a doctor. 2 / 6

3 4.2. Most important symptoms and effects, both acute and delayed General information Immediate effects can be expected after short-term exposure. Eye bathing equipment should be available on the premises. Inhalation. There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing. Ingestion There may be soreness and redness of the mouth and throat. Skin contact There may be irritation and redness at the site of contact. Eye contact There may be irritation and redness. The eyes may water profusely Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Suitable extinguishing media for the surrounding fire should be used. Use water spray to cool containers Special hazards arising from the substance or mixture Hazardous combustion products In combustion emits toxic fumes Advice for firefighters Special Fire Fighting Procedures Wear self-contained breathing aparatus and protective clothing. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Refer to section 8 of SDS for personal protection details. If outside do not approach from downwind. Notify the police and fire brigade immediately. If outside, keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid Environmental precautions Do not discharge into drains or rivers. Contain the spillage using bunding Methods and material for containment and cleaning up Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method Reference to other sections See section 7 for information on safe Handling. See section 8 for information on personal protective equipment. See section 13 for disposal information. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air Conditions for safe storage, including any incompatibilities Store in cool, well ventilated area. Keep container tightly closed. It is recommended to store in original packaging Specific end use(s) Dampening solution additive for the printing industry. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes A mixture of: 5-chloro-2-methyl-2H -isothiazol-3-one (EC ) and 2-methyl-2H-isothiazol-3-0 WEL 0.05 mg/m3 3 / 6

4 WEL = Workplace Exposure Limit Exposure controls Engineering measures Ensure thers is sufficient ventilation of the area. Respiratory equipment Self contained breathing apparatus must be available in case of emergency Hand protection Wear Nitrile gloves of minimum thickness 0.5mm. Gloves should be replaced regularly or if any change in appearance is noticed. Ensure gloves are manufactured in accordance with BS EN 374. Penetration times carried out according to EN 34 part III are not always practicable, therefore maximum wearing time of 50% of penetration time is recommended. Eye protection Safety glasses with side-shields. Ensure eye bath is to hand. Skin protection Impermeable protective clothing Environmental Exposure Controls An environmental assessment must be made to ensure compliance with local environmental legislation. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Colour Odour Solubility Viscosity Flash point ( C) Not applicable Other information Liquid Colourless. Barely peceptible odour Soluble in water. non viscous SECTION 10: STABILITY AND REACTIVITY Reactivity Stable under recommended transport or storage conditions Chemical stability Stable under normal conditions Possibility of hazardous reactions Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below Conditions to avoid Avoid heat Incompatible materials Materials To Avoid Strong oxidising agents, strong acids Hazardous decomposition products In combustions emits toxic fumes SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects General information Immediate effects can be expected after short-term exposure. Inhalation There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing. Ingestion There may be soreness and redness of the mouth and throat. Skin contact There may be irritation and redness at the site of contact 4 / 6

5 Eye contact There may be irritation and redness The eyes may water profusely. Route of entry Skin and/or eye contact. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Negligible ecotoxicity Toxicity Persistence and degradability Degradability Biodegradable Bioaccumulative potential Bioaccumulative potential No bioaccumulation potential Mobility in soil Mobility: Readily absorbed into soil The product is soluble in water Results of PBT and vpvb assessment This substance is not identified at a PBT substance Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Transfer to a suitable container and arrange for collection by specialised disposal company. NB: The user's attention is drawn to the possible existence of regional and antional regulations regarding disposal. SECTION 14: TRANSPORT INFORMATION General UN number This product is not classified for transport UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments Chemical Safety Assessment A chemical safety assessment has not been carried out for the substance or the mixure by the supplier 5 / 6

6 SECTION 16: OTHER INFORMATION Revision Comments This is first issue. Issued By Revision Date 27/01/12 Revision 1 Supersedes date B.A Hayden HSQE Manager No previous SDS No Safety Data Sheet Status Approved. Date of issue: 16/02/12 Risk Phrases In Full R34 R21/22 R37/38 R43 R41 R23/24/25 R50/53 R50 Hazard Statements In Full H318 H314 H315 H330 H302 H312 H317 H335 H301 H311 H410 H400 Causes burns. Harmful in contact with skin and if swallowed. Irritating to respiratory system and skin. May cause sensitisation by skin contact. Risk of serious damage to eyes. Toxic by inhalation, in contact with skin and if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Very toxic to aquatic organisms. Causes serious eye damage. Causes severe skin burns and eye damage. Causes skin irritation. Fatal if inhaled. Harmful if swallowed. Harmful in contact with skin. May cause an allergic skin reaction. May cause respiratory irritation. Toxic if swallowed. Toxic in contact with skin. Very toxic to aquatic life with long lasting effects. Very toxic to aquatic life. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6 / 6