SAFETY DATA SHEET WESSCO UV SATIN LACQUER

Transcription

1 Revision Date 24/02/12 Revision 1 Supersedes date No previous SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No Relevant identified uses of the substance or mixture and uses advised against Identified uses UV Curing Varnish 1.3. Details of the supplier of the safety data sheet Supplier 1.4. Emergency telephone number SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture STEHLIN HOSTAG INK UK LTD UNIT D4 LINKMEL CLOSE QUEENS DRIVE INDUSTRIAL ESTATE NOTTINGHAM NG2 1NA Tel : Fax : sds@stehlin.co.uk Classification (1999/45/EEC) Physical and Chemical Hazards Human health Environment Xi;R38, R41. R43. R52/53. Not classified. Skin Irrit. 2 - H315;Eye Dam. 1 - H318;Skin Sens. 1 - H317 Aquatic Chronic 3 - H412 Human health Irritating to Skin. Risk of serious damage to eyes May cause sensitisation by skin contact Environment The product contains a substance which is harmful to aquatic organisms and which may cause long term adverse effects in the aquatic environment Label elements Label In Accordance With (EC) No. 1272/2008 Signal Word Hazard Statements Danger H315 H317 H318 H412 Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Harmful to aquatic life with long lasting effects. 1 / 6

2 Precautionary Statements P280 Supplementary Precautionary Statements 2.3. Other hazards Wear protective gloves/protective clothing/eye protection/face protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P IF ON SKIN: Wash with plenty of soap and water. P IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P321 Specific treatment (see on this label). P If skin irritation occurs: Get medical advice/attention. P If skin irritation or rash occurs: Get medical advice/attention. P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P501 Dispose of contents/container to SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures Glycerol Propoxy Triacrylate 50-60% CAS-No.: EC No.: Eye Irrit. 2 - H319 Classification (67/548/EEC) Xi;R36. TRIPROPYLENE GLYCOL DIACRYLATE 10-15% CAS-No.: EC No.: Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 STOT Single 3 - H335 Aquatic Chronic 2 - H411 Classification (67/548/EEC) Xi;R36/37/38. N;R51/53. R43. DPGDA (Dipropylene Glycol Diacrylate) 10-15% CAS-No.: EC No.: Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Classification (67/548/EEC) Xi;R38,R41. R43. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a doctor Ingestion Wash out mouth with water Consult a doctor. 2 / 6

3 Skin contact Remove all contaminated clothes and footwear immediately, unless stuck to skin. Wash immediately with plenty of water and soap and rinse thoroughly. Eye contact Bathe the eye with running water for 15 minutes Consult a physician for specific advice Most important symptoms and effects, both acute and delayed General information Immediate effects can be expected after short-term exposure. Eye bathing equipment should be available on the premises. Inhalation. There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing. Ingestion There may be soreness and redness of the mouth and throat. Skin contact There may be irritation and redness at the site of contact. Eye contact There may be irritation and redness. The eyes may water profusely Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Use fire-extinguishing media appropriate for surrounding materials. Use water spray to cool containers Special hazards arising from the substance or mixture Unusual Fire & Explosion Hazards In combustion emits toxic fumes 5.3. Advice for firefighters Protective equipment for fire-figthers Wear self contained breathing apparatus. Wear Protective clothing to prevent contact with skin and eyes. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Refer to protective measures listed in sections 7 and 8. Turn leaking containers leak side up to prevent the escape of liquid. If outside do not approach from downwind. If outside keep bystanders upwind and away from danger point. Mark out the contaminated area with signs and prevent access to unauthorised peronnel Environmental precautions Do not discharge into drains or rivers. Contain the spillage using bunding Methods and material for containment and cleaning up Absorb with sand or other inert absorbent. Transfer to a closeable, labelled salvage container for disposal by an appropriate methods Reference to other sections See section 7 for information on safe Handling. See section 8 for information on personal protective equipment. See section 13 for disposal information. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not use in confined spaces without adequate ventilation and/or respirator. Avoid forming spray/aerosol mists Conditions for safe storage, including any incompatibilities Store in cool, well ventilated area. Keep container tightly closed. The floor of the storage room must be impermeable to prevent the escape of liquids. It is recommended to store in original packaging Specific end use(s) UV light curing varnish for professional use in pressrooms only. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 3 / 6

4 8.1. Control parameters 8.2. Exposure controls Engineering measures Ensure thers is sufficient ventilation of the area. The floor of the storage area must be impermeable to prevent the escape of liquids. Respiratory equipment Self contained breathing apparatus must be available in case of emergency Hand protection Wear Nitrile gloves of minimum thickness 0.5mm. Gloves should be replaced regularly or if any change in appearance is noticed. Ensure gloves are manufactured in accordance with BS EN 374. Penetration times carried out according to EN 34 part III are not always practicable, therefore maximum wearing time of 50% of penetration time is recommended. Eye protection Wear tight-fitting goggles or face shield. Ensure eye bath is to hand. Skin protection Impermeable protective clothing Environmental Exposure Controls An environmental assessment must be made to ensure compliance with local environmental legislation. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Colour Odour Solubility Flash point ( C) 9.2. Other information Liquid Off White Typical Acrylate Insoluble in water Non-viscous >100 degrees C Not applicable SECTION 10: STABILITY AND REACTIVITY Reactivity Stable under recommended transport or storage conditions Chemical stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Hazardous reactions will not occur under normal transport or storage conditions. Decomposition may occur on exposure to conditions or materials listed below Conditions to avoid Avoid heat. Direct sunlight Incompatible materials Materials To Avoid Strong acids. Strong oxidising substances Hazardous decomposition products In combustions emits toxic fumes SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects General information Immediate effects can be expected after short-term exposure. Inhalation There may be irritation of the throat with a feeling of tightness in the chest. Exposure may cause coughing or wheezing. Ingestion There may be soreness and redness of the mouth and throat. 4 / 6

5 Skin contact There may be irritation and redness at the site of contact Eye contact There may be irritation and redness The eyes may water profusely. Route of entry Skin and/or eye contact. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Not applicable Toxicity Persistence and degradability Degradability No data available Bioaccumulative potential Bioaccumulative potential Theorectical low bioaccumulation potential Mobility in soil Mobility: Heavier than water Results of PBT and vpvb assessment This substance is not identified at a PBT substance Other adverse effects Toxic to aquatic and soil organisms. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Transfer to a suitable container and arrange for collection by specialised disposal company. NB: The user's attention is drawn to the possible existence of regional and antional regulations regarding disposal. SECTION 14: TRANSPORT INFORMATION General UN number Not classed as hazardous for transport UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. 5 / 6

6 15.2. Chemical Safety Assessment A chemical safety assessment has not been carried out for the substance or the mixure by the supplier SECTION 16: OTHER INFORMATION Revision Comments This is first issue. Issued By Revision Date 24/02/12 Revision 1 Supersedes date B.A Hayden HSQE Manager No previous SDS No Safety Data Sheet Status Approved. Date issued: 28/02/12 Risk Phrases In Full R36/37/38 R36 R38 R43 R41 R51/53 Hazard Statements In Full H318 H319 H315 H317 H335 H411 Irritating to eyes, respiratory system and skin. Irritating to eyes. Irritating to skin. May cause sensitisation by skin contact. Risk of serious damage to eyes. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Causes serious eye damage. Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction. May cause respiratory irritation. Toxic to aquatic life with long lasting effects. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6 / 6