SAFETY DATA SHEET In conformity with Article 31 of 1907/2006/CE

Transcription

1 SAFETY DATA SHEET In conformity with Article 31 of 1907/2006/CE 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY Commercial name: ESSICLEAN 2 Use: Cleaning agent Name, address, telephone number of the manufacturer/distributor: ESSILOR INTERNATIONAL 147, rue de Paris Charenton-le-Pont Cedex (FRANCE) Tel.: (33)(0) ramesh2@essilor.fr Emergency telephone number: N ORFILA Tel.: (33) (0) HAZARDS IDENTIFICATION Harmful : May cause lung defect if swallowed Static electricity : This product can accumulate electrical charges that could cause electric shocks generated fires. 3. COMPOSITION / INFORMATION ON INGREDIENTS Aliphatic hydrocarbons or cycloparaffinic Synonyms Kerdane HFC 365 Forane 365HX Chemical name Kerosene HFC Acetate Chemical family light distillate (petroleum) hydrotreated 1,1,1,3,3-pentafluorobutane 1,1,1,2,2,3,4,5,5,5- decafluoropentane 2-methoxy-1- methylethyl acetate PGME ; PGMEA ; Methoxypropanol acetate Concentration 50% 10% 10% CAS no et Hazard Symbols Xn Xn Xi R Phrases R65-66 R R10-36 S Phrases S S16 S25 Notes note H + note 4 ESSICLEAN 2 xxx 1/6

2 4. FIRST AID MEASURES Ingestion: In case of swallowing, do not induce vomiting. Seek medical advice Inhalation: Quickly remove the patient away from the area. Seek medical advice Eyes: Wash eyes thoroughly until irritation disappears. If irritation persists, call a doctor Skin contact: In case of skin contact, wash thoroughly the infected area with soap and water. Remove infected clothing. Use clothing again only until after cleaning. 5. FIRE-FIGHTING MEASURES Extinguishing media Suitable Forbidden Powder, foam, water with additive Sprayed water without additive Recommendations: Toxic fumes are released if temperature exceeds 200 C. 6. ACCIDENTAL RELEASE MEASURES Recover the fluid and absorb the spilled liquid using proper absorbent. Eliminate this material according to current waste regulation. Prevent any spread into sewer systems or groundwater. 7. HANDLING AND STORAGE Handling : Storage : Handle only in well ventilated areas. Prevent from static electricity build-up Avoid eye and skin contact Avoid inhalation of vapours Store at room temperature in tightly closed original containers Keep away from heat Keep away from oxidizing agents, alkaline, strong acids Compatible materials : polyethylene, polypropylene, Teflon, polyester, steel Incompatible materials : natural rubber, polystyrene ESSICLEAN 2 xxx 2/6

3 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering measures : Room ventilation must comply with current regulations (specific pollution workshop). It is recommended to use a ventilation system, such as a hood or a suction system closer to the source, to maintain the exposure at a threshold level as low as possible. Occupational exposure limits : This product is a complex mixture of substances whose toxicity values known are as follows : Hydrocarbon vapours C6 C12 : VLE mg/m 3 VME mg/m 3 1-méthoxy-2-propanol acetate : VLE 550 mg/m 3 VME 275 mg/m 3 HFC 365HX : LD50 > 2000 mg/kg (rat) LC50 > mg/m 3 Individual protection : Respiratory protection : Use in a well ventilated area Use filtering mask using suitable cartridge for organic fumes (A type) when recommended exposure limits are exceeded. Hand protection : use nitrile or Viton gloves (do not use either natural rubber or latex gloves). Eye protection : Safety glasses Skin protection : Protective clothing Collective protection : Safety shower, eyewash facility 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : none Odour : hydrocarbon smell ph : NA Flash point : 63 C Explosive limits in air : LEL : 0,6% UEL : 7% Relative density : 0,816 Solubility : - in water : weak (0,10% weight) - in solvents : unknown Other data : - Vapour pressure (20 C) : 0,1 kpa - Vapour pressure (38 C) : 0,2 kpa - Vapour pressure (50 C) : 0,4 kpa - Boiling point : between 180 and 217 C ASTM - Vapour density : > 1,00 - Molecular weight : 155 (calculated) ESSICLEAN 2 xxx 3/6

4 10. STABILITY AND REACTIVITY Stable under normal temperature and normal pressure conditions 11. TOXICOLOGICAL INFORMATION Respiratory track: Fumes concentration exceeding those indicated in exposure limits can be irritating for the eyes and respiratory system, may cause severe headaches and dizziness, may induce drowsiness or have other negative effects on the central nervous system. Skin contact: Repeated or prolonged skin contacts can cause discomfort (skin irritation) and dermatitis. Eye contact: Discomfort, without eye tissue damage; Digestive track : Accidental inhalation of very small quantities of liquid in the lung when swallowing or vomiting may cause bronchopneumonia or oedema. 12. ECOTOXICOLOGICAL INFORMATION Mobility : Density of this preparation is below one (1) so it is highly volatile. Taking into consideration its physical and chemical properties, this product could sink slightly into the soil. Persistence/Degradability : based on his biodegradation speed, this product is classified as biodegradable according to OCDE regulations. Bioaccumulation : This product is not considered as potentially harmful for aquatic environment. 13. DISPOSAL CONSIDERATIONS Empty containers remain dangerous. Apply safety measures. Do not reuse empty containers. Do not release the product in the sewer system. Respect waste local appropriate regulations. ESSICLEAN 2 xxx 4/6

5 14. TRANSPORT INFORMATION UN no. Class Name and description Packing group Labels Classification code Packing instruction Polluant marin BY ROAD ADR BY SEA IMDG BY AIR IATA 15. REGULATORY INFORMATION Labelling (as indicated in EC directives 2004/73/EC; 2006/8/EC) : The note H is applicable + note 4 Product identification : Essiclean 2 R phrases : R : Harmful if swallowed. Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking. S-phrases : S (2) : Keep out of the reach of children. Do not breathe vapour. Avoid contact with skin. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Identification of the dangers : Harmful Other information : Toxic Substances Control Act (TSCA) : All ingredients are listed on the TSCA inventory. Tables of occupational diseases (French regulation): N 84 : Disease caused by liquid organic solvents for professional use: aliphatic hydrocarbons liquids ESSICLEAN 2 xxx 5/6

6 16. OTHER INFORMATION Since we have no way of knowing the user's working conditions, the information contained herein is based on the best of our current knowledge and on the French and European regulations applicable on the date of the publication of this data sheet. This product may not be used for any other purposes than those specified in our documentation and featured on our packaging. As always, the user remains solely responsible to take any necessary measures to fulfill local and current regulations requirements. The information provided in this data sheet should be taken into account as a description of the safety requirements which are applicable to our product, and not as a guarantee of its properties o O o ---- ESSICLEAN 2 xxx 6/6