Risalah Data Keselamatan Safety data sheet

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1 Risalah Data Keselamatan Safety data sheet Mukasurat (Page): 1/21 1. Pengenalan bahan kimia dan pembekal Laromer LR 8863 M Nama bahan kimia: Trimethylolpropan, ethoxylated, acrylic acid ester Nombor CAS: Kegunaan: Reactive diluent Syarikat: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Nombor Telefon: Nombor Telefax: Maklumat kecemasan: Nombor Kecemasan Antarabangsa Nombor Telefon: Pengenalan Bahaya Pengelasan bahan dan campuran: Kerengsaan mata/ kerosakan mata yang serius: Kat. 2 Pemeka kulit: Kat. 1B Unsur label dan pernyataan berjaga-jaga: Piktogram:

2 Mukasurat (Page): 2/21 Kata Isyarat: Amaran Pernyataan Bahaya: Menyebabkan kerengsaan mata yang serius. Boleh menyebabkan tindak balas kulit alergi. Pernyataan Berjaga-jaga (Pencegahan): Pakai sarung tangan perlindungan dan pelindung mata/muka. Elakkan daripada tersedut debu/ wasap/gas/kabut/wap/semburan. Pakaian kerja yang tercemar tidak boleh dibawa keluar dari tempat kerja. Basuh bersih-bersih selepas mengendalikan bahan. Pernyataan Berjaga-jaga (Tindak Balas): JIKA TERKENA MATA: Bilas berhati-hati dengan air selama beberapa minit.tanggalkan kanta lekap, jika ada dan dapat dilakukan dengan mudah. Teruskan membilas. JIKA TERKENA KULIT (pada rambut): Basuh dengan sabun dan air yang banyak. Jika berlaku kerengsaan kulit atau ruam: Hubungi PUSAT RACUN atau doktor/pakar perubatan Tanggalkan pakaian yang tercemar dan basuh sebelum menggunakannya semula. Jika kerengsaan mata berterusan: Hubungi PUSAT RACUN atau doktor/pakar perubatan. Pernyataan Berjaga-jaga (Pelupusan): Lupuskan kandungan/ bekas ke tempat pengumpulan sisa berbahaya atau khusus. Bahaya lain yang tidak menyebabkan pengelasan: Tiada bahaya khusus yang diketahui jika peraturan/nota tentang penyimpanan dan pengendalian diberikan perhatian. Boleh menyebabkan tindakbalas alahan : Mengandungi TRIMETHYLOLPROPANE TRIACRYLATE 3. Komposisi dan Maklumat Mengenai Ramuan Bahan Kimia Keadaan kimia Ramuan berbahaya (OLIGOMER) Propylidynetrimethanol, ethoxylated, esters with acrylic acid (> 1 < 6.5 mol EO) Kandungan (berat/berat): >= 75 % Eye Dam./Irrit.: Kat. 2 - <= 100 % Skin Sens.: Kat. 1B Nombor CAS: ,2-bis(akriloiloksimetil)butil akrilat; trimetilolpropana triakrilat Kandungan (berat/berat): >= 0.3 % Skin Corr./Irrit.: Kat. 2 - < 1 % Eye Dam./Irrit.: Kat. 2 Nombor CAS: Skin Sens.: Kat. 1 Bagi pengelasan yang tidak ditulis dengan penuh dalam bahagian ini, teks lengkap boleh didapati di bahagian 16.

3 Mukasurat (Page): 3/21 4. Langkah-Langkah Pertolongan Cemas Nasihat am: Segera tanggalkan pakaian yang tercemar. Jika tersedut: Jika kesukaran berlaku selepas tersedut wap/aerosol, alihkan mangsa ke kawasan berudara bersih dan dapatkan rawatan perubatan. Apabila terkena kulit: Basuh bersih-bersih dengan sabun dan air. Apabila terkena mata: Segera basuh mata yang terkena produk selama sekurang-kurangnya 15 minit di bawah aliran air dengan membuka mata, rujuk pakar mata. Apabila tertelan: Segera basuh mulut dan kemudian minum air yang banyak, dapatkan rawatan perubatan. Nota kepada doktor: Gejala: Gejala dan kesan terpenting yang diketahui diterangkan didalam label (lihat bahagian 2) dan/atau bahagian 11., Gejala dan kesan penting selanjutnya tidak diketahui setakat ini. Nota kepada doktor: Rawatan: Rawat mengikut gejala (nyahcemar, fungsi utama), tiada penawar khusus diketahui. 5. Langkah-Langkah Pemadaman Kebakaran Bahan pemadam yang sesuai: semburan air, serbuk kering, busa Alat memadam yang tidak sesuai untuk tujuan keselamatan: pancutan air Bahaya tertentu: wap yang merbahaya Evolusi wasap/kabus. Bahan/kumpulan bahan yang dinyatakan boleh dibebaskan jika berlaku kebakaran. Peralatan perlindungan khusus: Gunakan alat pernafasan serba lengkap. Maklumat lanjut: Tahap risiko ditentukan oleh bahan yang terbakar dan keadaan kebakaran. Air pemadam api yang tercemar mestilah dilupuskan mengikut peraturan rasmi.

4 Mukasurat (Page): 4/21 6. Langkah-Langkah Pelepasan Tidak Sengaja Langkah pencegahan diri: Gunakan pakaian pelindung diri. Perlindungan pernafasan diperlukan. Langkah berjaga-jaga untuk alam sekitar: Bendung air yang tercemar/air yang digunakan untuk memadam kebakaran. Jangan lepaskan ke dalam parit/air permukaan/air tanah. Kaedah pembersihan atau penyerapan: Bagi sejumlah besar: Pam produk. Bagi baki: Kutip dengan bahap penyerap yang sesuai. Lupuskan bahan yang diserap mengikut peraturan. 7. Pengendalian dan Penyimpanan; Pengendalian Tiada langkah khusus diperlukan dengan syarat produk digunakan dengan betul. Perlindungan terhadap kebakaran dan letupan: Bekas yang panas hendaklah disejukkan untuk mengelakkan pempolimeran. Ambil langkah berjagajaga terhadap luahan statik. Penyimpanan Maklumat lanjut tentang keadaan penyimpanan: Lindungi daripada kesan cahaya. Penstabil hanya berkesan dengan kehadiran oksigen Lindungi daripada suhu melebihi : 35 C 8. Kawalan pendedahan dan perlindungan diri Komponen dengan parameter kawalan tempat kerja Tiada had pendedahan pekerjaan yang diketahui. Peralatan perlindungan peribadi Perlindungan pernafasan: Perlindungan pernafasan yang sesuai bagi kepekatan yang tinggi atau kesan jangka panjang: Penapis gas bagi gas/wap sebatian organik (takat didih >65 C, cth EN Jenis A) Perlindungan tangan: Sarung tangan keselamatan kalis bahan kimia. Bahan yang sesuai untuk sentuhan jangka pendek (disyorkan: Sekurang-kurangnya indeks pelindung 2, bersamaan > 30 minit tempoh penelapan menurut EN 374) getah butil (butil) mm ketebalan salutan

5 Mukasurat (Page): 5/21 getah nitril (NBR) mm ketebalan salutan Nota tambahan : Spesifikasi adalah berdasarkan ujian ujian, data penerbitan dan maklumat dari pengeluar sarung tangan atau diambil yang serupa secara analogi. Oleh sebab banyak keadaan yang perlu dipertimbangkan (misalnya suhu), perlulah diambil kira, bahawa secara praktikalnya tempoh penggunaan sarung tangan pelindung kimia mungkin lebih pendek daripada tempoh penelapan yang ditentukan menurut ujian. Arahan penggunaan pengilang hendaklah dipatuhi kerana jenisnya yang pelbagai. Perlindungan mata: Kaca mata keselamatan dengan pelindung sisi (gogal berbingkai) (contohnya EN 166) Perlindungan badan: Perlindungan badan mesti dipilih bergantung kepada aktiviti dan pendedahan, contohnya apron, kasut perlindungan, pakaian perlindungan bahan kimia (Berdasarkan DIN-EN 465) Langkah kebersihan dan keselamatan am: Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik. Memakai pakaian kerja yang tertutup diperlukan sebagai tambahan kepada kelengkapan perlindungan diri yang dinyatakan. Asingkan daripada makanan. 9. Sifat Fizikal dan Kimia Bentuk: Warna: Bau: cecair kuning muda khusus nilai ph: (0.88 g/l, 20 C) takat lebur: < -20 C Bahan/produk tidak mengurai. takat didih: > 391 C (dianggarkan 1,013 hpa) Bahan/produk mengurai. (Garispanduan OECD 102) (Garispanduan OECD 103) Takat kilat: > 130 C Tahap penyejatan: tidak ditentukan Kemudahbakaran (pepejal/gas): tidak mencucuh Had letupan bawah: Untuk cecair tiada kaitan untuk pengelasan dan pelabelan., Had letupan bawah mungkin 5-15 C dibawah takat kilat. Had letupan atas: Untuk cecair tiada kaitan untuk pengelasan dan pelabelan. Suhu pencucuhan: Kajian secara saintifiknya tidak wajar.

6 Mukasurat (Page): 6/21 Penguraian terma: pencucuhan sendiri: > 160 C, 500 kj/kg Risiko penguraian swapecut eksoterma apabila melebihi suhu yang dinyatakan. Berdasarkan ciri strukturnya produk tidak dikelaskan sebagai mencucuhsendiri. (DTA) Jenis ujian: Swanyalaan spontan pada suhu bilik. Kebolehan swapemanasan sendiri: tidak berkenaan, produk ialah cecair Bahaya letupan: Berdasarkan struktur kimia tiada petunjuk ciri-ciri mudah meletup. Sifat yang menggalakkan kebakaran: Berdasarkan sifat strukturnya produk ini tidak dikelasifikasikan sebagai pengoksida. Tekanan Wap: Pa (20 C) (OECD Guideline 104) Kepekatan: 1.12 g/cm3 (25 C) Ketumpatan relatif: (20 C) Ketumpatan wap relatif (udara): tidak ditentukan Keterlarutan dalam air: 0.88 g/l (20 C) Pekali petakan n-oktanol/air (log Pow): 2.89 (23 C; nilai ph: 8.1) Penjerapan/air-tanah: log KOC: 2.2 Tegangan permukaan: 47.3 mn/m (22 C; 0.1 g/l) (DIN 51757) (Garispanduan OECD 109) (Garispanduan OECD 107) (, Kaedah 'Ring') Kelikatan, dinamik: Kelikatan, kinematik: mpa*s (25 C) 72.3 mm2/s (20 C) (DIN EN ISO 2555) (OECD 114) 10. Kestabilan dan Kereaktifan Keadaan yang perlu dielakkan: Jauhkan dari haba yang terlalu panas. Lihat MSDS bahagian 7 - Pengendalian dan Penyimpanan. Penguraian terma: > 160 C, 500 kj/kg (DTA) Risiko penguraian swapecut eksoterma apabila melebihi suhu yang dinyatakan.

7 Mukasurat (Page): 7/21 Bahan yang perlu dielakkan: peroksida, pemula radikal bebas, alkali Tindak balas berbahaya: Produk boleh terpolimer jika hayat simpan atau suhu penyimpanan jauh melebihi had ditentukan. Haba terbentuk semasa pempolimeran. Bertindak balas dengan peroksida dan komponen radikal lain. Produk distabilkan terhadap pempolimeran spontan sebelum dihantar. Bahan penguraian berbahaya: Tiada produk penguraian yang berbahaya jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan. 11. Maklumat Toksikologi Ketoksikan akut Penilaian ketoksikan akut: Tidak toksik selepas sekali ditelan. Tidak toksik selepas sekali terkena kulit Data eksperimen/dikira: LD50 tikus (melalui mulut): > 2,000 mg/kg (Garispanduan OECD 401) LD50 arnab (dermal): > 13,200 mg/kg Kerengsaan Penilaian kesan merengsa: Tidak merengsakan kulit. Sentuhan dengan mata boleh menyebabkan kerengsaan. Data eksperimen/dikira: Kakisan/Kerengsaan kulit arnab: tidak merengsa (Garispanduan OECD 404) Kerosakkan/kerengsaan mata yang serius arnab: Merengsa (Garispanduan OECD 405) Pemekaan pernafasan/kulit Penilaian pemekaan: Pemekaan selepas sentuhan kulit yang berulang mungkin berlaku. Data eksperimen/dikira: Ujian Buehler marmut: pemekaan kulit (Garispanduan OECD 406) Cerakin Nodus Limfa Setempat Mencit (LLNA) mencit: pemekaan kulit (Garispanduan OECD 429) Kemutagenan sel germa Penilaian kemutagenan: Bahan tidak mutagen dalam bakteria. Bahan adalah mutagen dalam pelbagai sistem ujian kultur sel; walau Kekarsinogenan

8 Mukasurat (Page): 8/21 Penilaian kekarsinogenan: Kajian tidak perlu dijalankan. Ketoksikan pembiakan Penilaian ketoksikan pembiakan: Keputusan kajian haiwan tidak menunjukkan kesan gangguan kesuburan. Keputusan telah ditentukan dalam Ujian Saringan (OECD 421/422). Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Ketoksikan perkembangan Penilaian keteratogenan: Tiada petunjuk kesan ketoksikan/teratogen diperhatikan dalam kajian haiwan. Ketoksikan khusus organ sasaran (sekali pendedahan): Penilaian sekali STOT: Berdasarkan maklumat yang ada, ketoksikan organ sasaran yang khusus adalah tidak dijangka selepas sekali pendedahan. Ketoksikan dos berulang dan Ketoksikan organ sasaran tertentu (pendedahan berulang) Penilaian ketoksikan dos berulang: Selepas pemberian yang berulang, kesan yang nyata ialah kerengsaan Produk belum diuji. Penyataan diambil daripada bahan/produk yang mempunyai struktur dan komposisi yang sama. Bahaya penyedutan Tidak boleh digunakan 12. Maklumat Ekologi Keekotoksikan Penilaian ketoksikan akuatik: Toksik secara akut kepada organisma akuatik. Perencatan aktiviti degradasi di dalam enap cemar yang diaktifkan tidak dijangka akan berlaku semasa bahan berkepekatan rendah dimasukkan kedalam loji rawatan biologi. Ketoksikan kepada ikan: LC50 (96 h) 1.95 mg/l, Brachydanio rerio (Garispanduan OECD 203, statik) Nilai nominal (disahkan melalui kawalan kepekatan secara analitik). Invertebrat air: EC50 (48 h) 70.7 mg/l, Daphnia magna (Garispanduan OECD 202, Bahagian 1, statik) Nilai nominal (disahkan melalui kawalan kepekatan secara analitik).

9 Mukasurat (Page): 9/21 Tumbuhan akuatik: EC50 (72 h) 2.2 mg/l, Desmodesmus subspicatus (Garispanduan OECD 201, statik) Nilai nominal (disahkan melalui kawalan kepekatan secara analitik). Mikroorganisma/Kesan ke atas enap cemar diaktifkan: EC20 (3 h) 292 mg/l, Enap cemar diaktifkan (Garispanduan OECD 209, statik) Kepekatan nominal Ketoksikan kronik kepada ikan: Kajian secara saintifiknya tidak wajar. Ketoksikan kronik kepada invertebrata akuatik: Kajian secara saintifiknya tidak wajar. Penilaian ketoksikan daratan: Kajian secara saintifiknya tidak wajar. Mobiliti Penilaian pengangkutan di antara bahagian di persekitaran: Bahan tidak akan menyejat ke atmosfera daripada permukaan air Penjerapan kepada fasa tanah pejal tidak dijangka Keterusan dan boleh keterdegradasikan Maklumat penyingkiran: % Pembentukan CO2 relatif kepada nilai teori (28 hari) (OECD 301B; ISO 9439; 92/69/EEC, C.4-C) (aerobik, enap cemar diaktifkan, domestik, tidak disesuaikan) Penilaian kestabilan dalam air: Jika terkena air bahan akan menghidrolisis dengan lambat. Maklumat tentang Kestabilan dalam Air (Hidrolisis): t 1/2 453 hari (12 C, nilai ph 7), (Garispanduan OECD 111, ph 7) Potensi Biotumpukan Penilaian potensi bioakumilasi: Tiada akumulasi yang ketara dalam organisma dijangka hasil daripada pekali pengagihan n- oktanol/air (log Pow). 13. Maklumat Pelupusan Bahan ini dan/atau bekasnya hendaklah dilupus sebagai sisa berbahaya. Pembungkusan tercemar: Bungkusan yang tidak tercemar boleh diguna semula. Bungkusan yang tidak boleh dibersihkan hendaklah dilupuskan dengan cara yang sama dengan kandungannya.

10 Mukasurat (Page): 10/ Maklumat Pengangkutan Pengangkutan domestik: Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan laut IMDG Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan udara IATA/ICAO Tidak dikelaskan sebagai berbahaya di bawah peraturan pengangkutan Pengangkutan secara pukal menurut Lampiran II MARPOL dan IBC Peraturan: Tidak dinilai Penghantaran yang Tidak dinilai diluluskan: Nama pencemaran: Tidak dinilai Kategori pencemaran: Tidak dinilai Jenis Kapal: Tidak dinilai 15. Maklumat Pengawalseliaan Peraturan lain Jika maklumat peraturan lain yang berkenaan tidak dinyatakan dibahagian lain didalam risalah data keselamatan ini, ianya akan dinyatakan bahagian ini. 16. Maklumat lain Teks penuh pengelasan, simbol bahaya dan pernyataan bahaya, jika dinyatakan dalam seksyen 2 atau 3: Eye Dam./Irrit. Skin Sens. Skin Corr./Irrit. Kerengsaan mata/ kerosakan mata yang serius Pemeka kulit Kakisan/kerengsaan kulit

11 Mukasurat (Page): 11/21 Garis menegak pada margin sebelah kiri tangan menunjukkan pindaan dari versi sebelumnya. Data yang terdapat dalam risalah data keselamatan ini adalah berdasarkan pengetahuan dan pengalaman kami, dan menerangkan tentang produk yang berkaitan dengan keperluan keselamatan sahaja. Data tidak menyatakan ciri produk (spesifikasi produk). Data dalam risalah data keselamatan ini juga tidak menyatakan apa-apa ciri khusus atau kesesuaian produk yang dipersetujui untuk apa-apa tujuan tertentu. Penerima produk bertanggungjawab untuk memastikan bahawa apa-apa hak pemilikan serta undang-undang dan perundangan sedia ada dipatuhi.

12 Mukasurat (Page): 12/21 1. Identification of the chemical and of the supplier Laromer LR 8863 M Chemical name: Trimethylolpropan, ethoxylated, acrylic acid ester CAS Number: Use: Reactive diluent Company: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Telephone: Telefax number: Emergency information: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: Serious eye damage/eye irritation: Cat. 2 Skin sensitization: Cat. 1B Label elements and precautionary statement: Pictogram: Signal Word: Warning Hazard Statement: Causes serious eye irritation. May cause an allergic skin reaction. Precautionary Statements (Prevention): Wear protective gloves and eye/face protection. Avoid breathing dust/fume/gas/mist/vapours/spray. Contaminated work clothing should not be allowed out of the workplace. Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response):

13 Mukasurat (Page): 13/21 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Wash with plenty of soap and water. If skin irritation or rash occurs: Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash it before reuse. If eye irritation persists: Call a POISON CENTER or doctor/physician. Precautionary Statements (Disposal): Dispose of contents/container to hazardous or special waste collection point. Other hazards which do not result in classification: No specific dangers known, if the regulations/notes for storage and handling are considered. May produce an allergic reaction. Contains: TRIMETHYLOLPROPANE TRIACRYLATE 3. Composition/information on ingredients Chemical nature Hazardous ingredients Propylidynetrimethanol, ethoxylated, esters with acrylic acid Content (W/W): >= 75 % - <= 100 Eye Dam./Irrit.: Cat. 2 % Skin Sens.: Cat. 1B CAS Number: Trimethylolpropane triacrylate Content (W/W): >= 0.3 % - < 1 % CAS Number: Skin Corr./Irrit.: Cat. 2 Eye Dam./Irrit.: Cat. 2 Skin Sens.: Cat. 1 For the classifications not written out in full in this section the full text can be found in section First-Aid Measures General advice: Immediately remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

14 Mukasurat (Page): 14/21 On ingestion: Rinse mouth immediately and then drink plenty of water, seek medical attention. Note to physician: Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Note to physician: Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Suitable extinguishing media: water spray, dry powder, foam Unsuitable extinguishing media for safety reasons: water jet Specific hazards: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental Release Measures Personal precautions: Use personal protective clothing. Breathing protection required. Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods for cleaning up or taking up: For large amounts: Pump off product. For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations. 7. Handling and Storage Handling No special measures necessary provided product is used correctly.

15 Mukasurat (Page): 15/21 Protection against fire and explosion: Heated containers should be cooled to prevent polymerization. Take precautionary measures against static discharges. Storage Further information on storage conditions: Protect from the effects of light. The stabilizer is only effective in the presence of oxygen. Protect from temperatures above: 35 C 8. Exposure controls and personal protection Components with occupational exposure limits No occupational exposure limits known. Personal protective equipment Respiratory protection: Suitable respiratory protection for higher concentrations or long-term effect: Gas filter for gases/vapours of organic compounds (boiling point >65 C, e. g. EN Type A) Hand protection: Chemical resistant protective gloves Suitable materials for short-term contact (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374) butyl rubber (butyl) mm coating thickness nitrile rubber (NBR) mm coating thickness Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust). General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Segregate from foodstuffs.

16 Mukasurat (Page): 16/21 9. Physical and Chemical Properties Form: Colour: Odour: liquid light yellow characteristic ph value: (0.88 g/l, 20 C) Melting point: < -20 C The substance / product does not decompose. Boiling point: > 391 C (approx. 1,013 hpa) The substance / product decomposes. (Directive 92/69/EEC, A.6) (OECD Guideline 102) (OECD Guideline 103) Flash point: > 130 C Evaporation rate: not determined Flammability (solid/gas): not flammable Lower explosion limit: For liquids not relevant for classification and labelling., The lower explosion point may be 5-15 C below the flash point. Upper explosion limit: For liquids not relevant for classification and labelling. Ignition temperature: Study scientifically not justified. Thermal decomposition: > 160 C, 500 kj/kg Risk of exothermic self-accelerating decomposition above the indicated temperature. Self ignition: Based on its structural properties the product is not classified as selfigniting. (DTA) Test type: Spontaneous selfignition at room-temperature. Self heating ability: not applicable, the product is a liquid Explosion hazard: Based on the chemical structure there is no indicating of explosive properties. Fire promoting properties: Based on its structural properties the product is not classified as oxidizing. Vapour pressure: Pa (20 C) (OECD Guideline 104)

17 Mukasurat (Page): 17/21 Density: 1.12 g/cm3 (25 C) Relative density: (20 C) Relative vapour density (air): not determined (DIN 51757) (OECD Guideline 109) Solubility in water: 0.88 g/l (20 C) Partitioning coefficient n-octanol/water (log Pow): 2.89 (OECD Guideline 107) (23 C; ph value: 8.1) Adsorption/water - soil: log KOC: 2.2 (OECD Guideline 121) Surface tension: 47.3 mn/m (22 C; 0.1 g/l) (Regulation 440/2008/EC, A.5, Ring method) Viscosity, dynamic: Viscosity, kinematic: mpa*s (25 C) 72.3 mm2/s (20 C) (DIN EN ISO 2555) (OECD 114) 10. Stability and Reactivity Conditions to avoid: Avoid extreme heat. See MSDS section 7 - Handling and storage. Thermal decomposition: > 160 C, 500 kj/kg (DTA) Risk of exothermic self-accelerating decomposition above the indicated temperature. Substances to avoid: peroxides, free radical initiators, alkalies Hazardous reactions: The product can polymerize if the shelf life or storage temperature are greatly exceeded. Heat develops during polymerization. Reacts with peroxides and other radical components. The product is stabilized against spontaneous polymerization prior to despatch. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. Experimental/calculated data: LD50 rat (oral): > 2,000 mg/kg (OECD Guideline 401)

18 Mukasurat (Page): 18/21 LD50 rabbit (dermal): > 13,200 mg/kg (similar to OECD guideline 402) Irritation Assessment of irritating effects: Not irritating to the skin. Eye contact causes irritation. Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404) Serious eye damage/irritation rabbit: Irritant. (OECD Guideline 405) Respiratory/Skin sensitization Assessment of sensitization: Sensitization after skin contact possible. Experimental/calculated data: Buehler test guinea pig: skin sensitizing (OECD Guideline 406) Mouse Local Lymph Node Assay (LLNA) mouse: skin sensitizing (OECD Guideline 429) Germ cell mutagenicity Assessment of mutagenicity: The substance was not mutagenic in bacteria. The substance was mutagenic in various cell culture test systems; however, these results could not be confirmed in tests with mammals. Carcinogenicity Assessment of carcinogenicity: Study does not need to be conducted. Reproductive toxicity Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility impairing effect. The results were determined in a Screening test (OECD 421/422). The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Developmental toxicity Assessment of teratogenicity: No indications of a developmental toxic / teratogenic effect were seen in animal studies. Specific target organ toxicity (single exposure): Assessment of STOT single: Based on the available information there is no specific target organ toxicity to be expected after a single exposure.

19 Mukasurat (Page): 19/21 Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: After repeated exposure the prominent effect is local irritation. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Aspiration hazard not applicable 12. Ecological Information Ecotoxicity Assessment of aquatic toxicity: Acutely toxic for aquatic organisms. The inhibition of the degradation activity of activated sludge is not anticipated when introduced to biological treatment plants in appropriate low concentrations. Toxicity to fish: LC50 (96 h) 1.95 mg/l, Brachydanio rerio (OECD Guideline 203, static) Nominal values (confirmed by concentration control analytics) Aquatic invertebrates: EC50 (48 h) 70.7 mg/l, Daphnia magna (OECD Guideline 202, part 1, static) Nominal values (confirmed by concentration control analytics) Aquatic plants: EC50 (72 h) 2.2 mg/l, Desmodesmus subspicatus (OECD Guideline 201, static) Nominal values (confirmed by concentration control analytics) Microorganisms/Effect on activated sludge: EC20 (3 h) 292 mg/l, activated sludge (OECD Guideline 209, static) Nominal concentration. Chronic toxicity to fish: Study scientifically not justified. Chronic toxicity to aquatic invertebrates: Study scientifically not justified. Assessment of terrestrial toxicity: Study scientifically not justified. Mobility Assessment transport between environmental compartments: The substance will not evaporate into the atmosphere from the water surface. Adsorption to solid soil phase is not expected. Persistence and degradability

20 Mukasurat (Page): 20/21 Elimination information: % CO2 formation relative to the theoretical value (28 d) (OECD 301B; ISO 9439; 92/69/EEC, C.4-C) (aerobic, activated sludge, domestic, non-adapted) Assessment of stability in water: In contact with water the substance will hydrolyse slowly. Information on Stability in Water (Hydrolysis): t 1/2 453 d (12 C, ph value 7), (OECD Guideline 111, ph 7) Bioaccumulation potential Assessment bioaccumulation potential: No significant accumulation in organisms is expected as a result of the distribution coefficient of n- octanol/water (log Pow). 13. Disposal Considerations This material and its container must be disposed of as hazardous waste. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport Information Domestic transport: Not classified as a dangerous good under transport regulations Sea transport IMDG Not classified as a dangerous good under transport regulations Air transport IATA/ICAO Not classified as a dangerous good under transport regulations Transport in bulk according to Annex II of MARPOL and the IBC Code Regulation: Not evaluated Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated Ship Type: Not evaluated

21 Mukasurat (Page): 21/ Regulatory Information Other regulations If other regulatory information applies that is not already provided elsewhere in this safety data sheet, then it is described in this subsection. 16. Other Information Full text of classifications, hazard symbols and hazard statements, if mentioned in section 2 or 3: Eye Dam./Irrit. Skin Sens. Skin Corr./Irrit. Serious eye damage/eye irritation Skin sensitization Skin corrosion/irritation Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

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