Risalah Data Keselamatan Safety data sheet

Transcription

1 Risalah Data Keselamatan Safety data sheet Mukasurat (Page): 1/22 1. Pengenalan bahan kimia dan pembekal Efka FA 4654 Kegunaan: wetting agent, Levelling Agent Syarikat: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Nombor Telefon: Nombor Telefax: Maklumat kecemasan: Nombor Kecemasan Antarabangsa Nombor Telefon: Pengenalan Bahaya Pengelasan bahan dan campuran: Cecair mudah terbakar: Kat. 3 Ketoksikan akut: Kat. 4 (oral) Kakisan/kerengsaan kulit: Kat. 2 Pemeka kulit: Kat. 1 Pendedahan tunggal STOT: Kat. 3 (Wap boleh menyebabkan rasa mengantuk dan pening.) Pendedahan tunggal STOT: Kat. 3 (kerengsaan pada sistem pernafasan) Pendedahan berulang STOT (Sistem imun, Hati, Saluran usus): Kat. 2 Bahaya kronik kepada persekitaran akuatik.: Kat. 2 Unsur label dan pernyataan berjaga-jaga:

2 Mukasurat (Page): 2/22 Piktogram: Kata Isyarat: Amaran Pernyataan Bahaya: Cecair dan wap mudah terbakar. Menyebabkan kerengsaan kulit. Memudaratkan jika tertelan. Boleh menyebabkan tindak balas kulit alergi. Boleh menyebabkan rasa mengantuk atau pening. Boleh menyebabkan kerengsaan saluran pernafasan. Boleh menyebabkan kerosakan pada organ (Sistem imun, Hati, Saluran usus) melalui pendedahan secara berpanjangan atau berulang. Toksik kepada hidupan akuatik dengan kesan yang berpanjangan. Pernyataan Berjaga-jaga (Pencegahan): Pakai sarung tangan perlindungan dan pelindung mata/muka. Jangan bernafaskan habuk/gas/kabut/wap. Elakkan pelepasan bahan ke persekitaran. Gunakan hanya di luar bangunan atau di dalam kawasan yang dialihudarakan dengan baik. Jauhkan daripada haba/percikan api/nyalaan terbuka/permukaan panas. Dilarang merokok. Ambil langkah berjaga-jaga terhadap nyahcas statik. Gunakan kelengkapan elektrik/pengalihudaraan/pencahayaan yang tahan letupan. Pakaian kerja yang tercemar tidak boleh dibawa keluar dari tempat kerja. Basuh dengan air yang banyak dan sabun sehingga bersih selepas mengendalikan bahan Jangan makan, minum atau merokok semasa menggunakan produk ini. Gunakan hanya alat yang tidak mengeluarkan percikan api. Bumikan/ikat bekas dan kelengkapan terimaan. Pernyataan Berjaga-jaga (Tindak Balas): Jika berlaku kerengsaan kulit atau ruam: Hubungi PUSAT RACUN atau doktor/pakar perubatan JIKA TERKENA KULIT (pada rambut): Basuh dengan sabun dan air yang banyak. JIKA TERKENA KULIT (atau rambut): Segera tanggalkan/buka semua pakaian yang tercemar. Basuh kulit dengan air/ pancuran air. JIKA TERSEDUT: Pindahkan mangsa ke kawasan berudara segar dan pastikan mangsa selesa bernafas. JIKA DITELAH: bilas mulut. Tanggalkan pakaian yang tercemar dan basuh sebelum menggunakannya semula. Jika berlaku kerengsaan kulit: Dapatkan nasihat/rawatan perubatan. Pungut tumpahan. Jika berlaku kebakaran: Gunakan busa atau serbuk kering untuk memadam kebakaran. Pernyataan Berjaga-jaga (Penyimpanan): Simpan di tempat yang dialihudarakan dengan baik. Simpan di tempat sejuk Pastikan bekas ditutup dengan ketat. Simpan di tempat berkunci. Pernyataan Berjaga-jaga (Pelupusan): Lupuskan kandungan/ bekas ke tempat pengumpulan sisa berbahaya atau khusus. Bahaya lain yang tidak menyebabkan pengelasan: Tiada bahaya khusus yang diketahui jika peraturan/nota tentang penyimpanan dan pengendalian diberikan perhatian. 3. Komposisi dan Maklumat Mengenai Ramuan Bahan Kimia Keadaan kimia Sediaan berdasarkan: minyak mineral, asid lemak

3 Mukasurat (Page): 3/22 terubah suai Ramuan berbahaya Hydrocarbons, C9, aromatics Kandungan (berat/berat): >= 30 % - <= 50 % Asp. Tox.: Kat. 1 Flam. Liq.: Kat. 3 STOT SE: Kat. 3 (drowsiness and dizziness) STOT SE: Kat. 3 (irr. to respiratory syst.) Aquatic Chronic: Kat. 2 Fatty acids, C18-unsatd., trimers, compds. with oleylamine Kandungan (berat/berat): >= 20 % Acute Tox.: Kat. 4 (oral) - <= 30 % Skin Corr./Irrit.: Kat. 2 Nombor CAS: Skin Sens.: Kat. 1A STOT RE (Saluran usus, Hati, Sistem imun): Kat. 2 (oral) Fatty acids, tall-oil, compds. with oleylamine Kandungan (berat/berat): >= 20 % - <= 30 % Nombor CAS: Acute Tox.: Kat. 4 (oral) Skin Corr./Irrit.: Kat. 2 Skin Sens.: Kat. 1A STOT RE (Hati, Sistem imun, Saluran usus): Kat. 2 (oral) Fatty acids, C18-unsatd., dimers, compds. with oleylamine Kandungan (berat/berat): >= 5 % - Acute Tox.: Kat. 4 (oral) <= 10 % Skin Corr./Irrit.: Kat. 2 Nombor CAS: Skin Sens.: Kat. 1A STOT RE (Hati, Saluran usus, Sistem imun): Kat. 2 (oral) 9-Octadecen-1-amine, (Z)- Kandungan (berat/berat): < 0.5 % Nombor CAS: Asp. Tox.: Kat. 1 Acute Tox.: Kat. 4 (oral) Skin Corr./Irrit.: Kat. 1A Eye Dam./Irrit.: Kat. 1 STOT SE: Kat. 3 (irr. to respiratory syst.) STOT RE (Hati, Sistem imun, Salur gastrousus): Kat. 2 Aquatic Acute: Kat. 1 Aquatic Chronic: Kat. 1 Faktor-M akut: 10 Faktor-M kronik: 10 Bagi pengelasan yang tidak ditulis dengan penuh dalam bahagian ini, teks lengkap boleh didapati di bahagian 16.

4 Mukasurat (Page): 4/22 4. Langkah-Langkah Pertolongan Cemas Nasihat am: Segera tanggalkan pakaian yang tercemar. Jika tersedut: Jika kesukaran berlaku selepas tersedut wap/aerosol, alihkan mangsa ke kawasan berudara bersih dan dapatkan rawatan perubatan. Apabila terkena kulit: Basuh bersih-bersih dengan sabun dan air. Apabila terkena mata: Segera basuh mata yang terkena produk selama sekurang-kurangnya 15 minit di bawah aliran air dengan membuka mata, rujuk pakar mata. Apabila tertelan: Segera basuh mulut dan kemudian minum air yang banyak, dapatkan rawatan perubatan. Nota kepada doktor: Gejala: Gejala dan kesan terpenting yang diketahui diterangkan didalam label (lihat bahagian 2) dan/atau bahagian 11., Gejala dan kesan penting selanjutnya tidak diketahui setakat ini. Nota kepada doktor: Rawatan: Rawat mengikut gejala (nyahcemar, fungsi utama), tiada penawar khusus diketahui. 5. Langkah-Langkah Pemadaman Kebakaran Bahan pemadam yang sesuai: serbuk kering, busa Bahaya tertentu: wap yang merbahaya Evolusi wasap/kabus. Bahan/kumpulan bahan yang dinyatakan boleh dibebaskan jika berlaku kebakaran. Peralatan perlindungan khusus: Gunakan alat pernafasan serba lengkap. Maklumat lanjut: Tahap risiko ditentukan oleh bahan yang terbakar dan keadaan kebakaran. Air pemadam api yang tercemar mestilah dilupuskan mengikut peraturan rasmi. 6. Langkah-Langkah Pelepasan Tidak Sengaja Langkah pencegahan diri: Gunakan pakaian pelindung diri. Perlindungan pernafasan diperlukan.

5 Mukasurat (Page): 5/22 Langkah berjaga-jaga untuk alam sekitar: Bendung air yang tercemar/air yang digunakan untuk memadam kebakaran. Jangan lepaskan ke dalam parit/air permukaan/air tanah. Kaedah pembersihan atau penyerapan: Bagi sejumlah besar: Pam produk. Bagi baki: Kutip dengan bahap penyerap yang sesuai. Lupuskan bahan yang diserap mengikut peraturan. 7. Pengendalian dan Penyimpanan; Pengendalian Pastikan pengalihudaraan menyeluruh di kawasan simpanan dan di tempat kerja. Perlindungan terhadap kebakaran dan letupan: Jauhkan dari sumber pencucuhan. Ambil langkah berjaga-jaga terhadap luahan statik. Jika dihantar di dalam bungkusan plastik, suhu tertinggi yang dibenarkan semasa mengosongkannya ialah 5 Kelvin di bawah takat kilat. Penyimpanan Maklumat lanjut tentang keadaan penyimpanan: Simpan di tempat dingin. Pastikan bekas sentiasa bertutup rapat. Lindungi daripada suhu di bawah : 5 C Lindungi daripada suhu melebihi : 35 C 8. Kawalan pendedahan dan perlindungan diri Peralatan perlindungan peribadi Perlindungan pernafasan: Perlindungan pernafasan yang sesuai bagi kepekatan yang tinggi atau kesan jangka panjang: Penapis gas bagi gas/wap sebatian organik (takat didih >65 C, cth EN Jenis A) Perlindungan tangan: Sarung tangan keselamatan kalis bahan kimia. Bahan yang sesuai juga sekiranya terkena produk secara berpanjangan dan langsung. (Syor: Indeks perlindungan 6, bersamaan > 480 minit tempoh penelapan menurut EN 374): fluoroelastomer (FKM) mm ketebalan salutan Lamina Polietilena (lamina PE ) - kira-kira 0.1 mm ketebalan salutan Bahan yang sesuai untuk sentuhan jangka pendek (disyorkan: Sekurang-kurangnya indeks pelindung 2, bersamaan > 30 minit tempoh penelapan menurut EN 374) getah nitril (NBR) mm ketebalan salutan Nota tambahan : Spesifikasi adalah berdasarkan ujian ujian, data penerbitan dan maklumat dari pengeluar sarung tangan atau diambil yang serupa secara analogi. Oleh sebab banyak keadaan yang perlu dipertimbangkan (misalnya suhu), perlulah diambil kira, bahawa secara praktikalnya

6 Mukasurat (Page): 6/22 tempoh penggunaan sarung tangan pelindung kimia mungkin lebih pendek daripada tempoh penelapan yang ditentukan menurut ujian. Arahan penggunaan pengilang hendaklah dipatuhi kerana jenisnya yang pelbagai. Perlindungan mata: Kaca mata keselamatan dengan pelindung sisi (gogal berbingkai) (contohnya EN 166) Perlindungan badan: Perlindungan badan mesti dipilih bergantung kepada aktiviti dan pendedahan, contohnya apron, kasut perlindungan, pakaian perlindungan bahan kimia (Berdasarkan DIN-EN 465) Langkah kebersihan dan keselamatan am: Kendalikan mengikut amalan kesihatan dan keselamatan industri yang baik. Memakai pakaian kerja yang tertutup diperlukan sebagai tambahan kepada kelengkapan perlindungan diri yang dinyatakan. 9. Sifat Fizikal dan Kimia Bentuk: Warna: Bau: Ambang bau: nilai ph: cecair perang muda khusus Tidak ditentukan disebabkan oleh bahaya kesihatan yang mungkin melalui penyedutan. tidak terlarut takat didih: dianggarkan > 160 C Penyataan adalah berdasarkan ciri setiap komponen. Takat kilat: 45 C (DIN EN 22719; ISO 2719) Tahap penyejatan: tidak ditentukan Kemudahbakaran (pepejal/gas): Mudah terbakar. Had letupan bawah: Untuk cecair tiada kaitan untuk pengelasan dan pelabelan., Had letupan bawah mungkin 5-15 C dibawah takat kilat. Had letupan atas: Untuk cecair tiada kaitan untuk pengelasan dan pelabelan. Suhu pencucuhan: 450 C Maklumat terpakai kepada pelarut. Penguraian terma: Tiada penguraian jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan.

7 Mukasurat (Page): 7/22 pencucuhan sendiri: Tidak swacucuh. Jenis ujian: Swanyalaan spontan pada suhu bilik. Bahaya letupan: tidak mudah meletup Sifat yang menggalakkan kebakaran: tidak merebakkan api Tekanan Wap: tidak ditentukan Kepekatan: dianggarkan g/cm3 (20 C) Ketumpatan relatif: (20 C) (20 C) Ketumpatan wap relatif (udara): tidak ditentukan (ISO ) (Garispanduan OECD 109) Keterlarutan dalam air: tidak terlarut (20 C) 4 mg/l (20 C) Higroskopi: Tidak higroskopik Keterlarutan (kualitatif) pelarut: pelarut organik terlarut Pekali petakan n-oktanol/air (log Pow): tidak berkenaan untuk campuran Tegangan permukaan: Kajian secara saintifiknya tidak wajar. Kelikatan, dinamik: mpa*s (25.0 C) 10. Kestabilan dan Kereaktifan Keadaan yang perlu dielakkan: Lihat MSDS bahagian 7 - Pengendalian dan Penyimpanan. Penguraian terma: Tiada penguraian jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan. Bahan yang perlu dielakkan: agen pengoksida yang kuat Tindak balas berbahaya: Tiada tindakbalas berbahaya jika disimpan dan dikendalikan seperti yang dinyatakan. Bahan penguraian berbahaya: Tiada produk penguraian yang berbahaya jika disimpan dan dikendalikan seperti yang ditetapkan/dinyatakan.

8 Mukasurat (Page): 8/ Maklumat Toksikologi Ketoksikan akut Data eksperimen/dikira: LD50 tikus (melalui mulut): 300-2,000 mg/kg Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. LC50 tikus (melalui penyedutan): 4 h tidak ditentukan LD50 tikus (dermal): tidak ditentukan Kerengsaan Data eksperimen/dikira: Kakisan/Kerengsaan kulit arnab: Merengsa Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Kerosakkan/kerengsaan mata yang serius arnab: kerosakan tak berbalik Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Pemekaan pernafasan/kulit Data eksperimen/dikira: Cerakin Nodus Limfa Setempat Mencit (LLNA) mencit: pemekaan kulit Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Kemutagenan sel germa Penilaian kemutagenan: Tiada data diperoleh tentang kesan mutagen. Kekarsinogenan Penilaian kekarsinogenan: Tiada data diperoleh. Ketoksikan pembiakan Penilaian ketoksikan pembiakan: Tiada data diperoleh. Ketoksikan perkembangan Penilaian keteratogenan: Tiada data diperoleh. Ketoksikan khusus organ sasaran (sekali pendedahan):

9 Mukasurat (Page): 9/22 Penilaian sekali STOT: Menyebabkan kerengsaan sementara pada saluran pernafasan. Kemungkinan berlaku kesan narkotik (rasa mengantuk atau pening) Ketoksikan dos berulang dan Ketoksikan organ sasaran tertentu (pendedahan berulang) Penilaian ketoksikan dos berulang: Produk ini boleh menyebabkan kerosakan sistem imun setelah pengambilan berulang melalui oral/derma/penyedutan. Bahan boleh menyebabkan kerosakan kepada hati selepas tertelan secara Merosakkan salur gastrousus Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Bahaya penyedutan Tiada bahaya penyedutan dijangka. 12. Maklumat Ekologi Keekotoksikan Ketoksikan kepada ikan: LC50 (96 h) > mg/l, Ikan Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Invertebrat air: LC50 (48 h), daphnia tidak ditentukan Tumbuhan akuatik: EC50 (72 h) > 1-10 mg/l, alga Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Mikroorganisma/Kesan ke atas enap cemar diaktifkan: EC0 > mg/l, bakteria Produk belum diuji. Penyataan diambil daripada ciri setiap komponen. Ketoksikan kronik kepada ikan: Tiada data diperoleh. Ketoksikan kronik kepada invertebrata akuatik: Tiada data diperoleh. Penilaian ketoksikan daratan: Tiada data didapati berkenaan dengan ketoksikan daratan. Mobiliti Penilaian pengangkutan di antara bahagian di persekitaran: Tiada data diperoleh.

10 Mukasurat (Page): 10/22 Keterusan dan boleh keterdegradasikan Penilaian biodegradasi dan penyingkiran (H2O): Tidak mudah terbiodegradasikan (oleh kriteria OECD). Potensi Biotumpukan Penilaian potensi bioakumilasi: Produk belum diuji. Maklumat tambahan Perhatian tambahan bagi nasib pada alam sekitar & laluan: Rawatan didalam loji rawatan air sisa biologi mestilah dijalankan menurut peraturan dan pentadbiran setempat. 13. Maklumat Pelupusan Mestilah dibuang atau dibakar mengikut peraturan tempatan. Pembungkusan tercemar: Bungkusan yang tidak tercemar boleh diguna semula. Bungkusan yang tidak boleh dibersihkan hendaklah dilupuskan dengan cara yang sama dengan kandungannya. 14. Maklumat Pengangkutan Pengangkutan domestik: Kelas bahaya: 3 Kumpulan pembungkusan: III Nombor-ID: UN 1268 Label Bahaya: 3, EHSM Nama penghantaran yang betul: SULINGAN PETROLEUM, N.O.S. (mengandungi ALKYL-C3/C4- BENZENE) Maklumat lanjut Kod Hazchem:3Y Nombor IERG:14 Pengangkutan laut IMDG Kelas bahaya: 3 Kumpulan pembungkusan: III Nombor-ID: UN 1268 Label Bahaya: 3, EHSM Bahan pencemar laut: YA Nama penghantaran yang SULINGAN PETROLEUM, N.O.S. (mengandungi ALKYL-C3/C4-

11 Mukasurat (Page): 11/22 betul: BENZENE) Pengangkutan udara IATA/ICAO Kelas bahaya: 3 Kumpulan pembungkusan: III Nombor-ID: UN 1268 Label Bahaya: 3 Nama penghantaran yang betul: SULINGAN PETROLEUM, N.O.S. (mengandungi ALKYL-C3/C4- BENZENE) Pengangkutan secara pukal menurut Lampiran II MARPOL dan IBC Peraturan: Tidak dinilai Penghantaran yang Tidak dinilai diluluskan: Nama pencemaran: Tidak dinilai Kategori pencemaran: Tidak dinilai Jenis Kapal: Tidak dinilai 15. Maklumat Pengawalseliaan 16. Maklumat lain Teks penuh pengelasan, simbol bahaya dan pernyataan bahaya, jika dinyatakan dalam seksyen 2 atau 3: Asp. Tox. Flam. Liq. STOT SE Aquatic Chronic Acute Tox. Skin Corr./Irrit. Skin Sens. STOT RE Eye Dam./Irrit. Aquatic Acute Bahaya aspirasi Cecair mudah terbakar Pendedahan tunggal STOT Bahaya kronik kepada persekitaran akuatik. Ketoksikan akut Kakisan/kerengsaan kulit Pemeka kulit Pendedahan berulang STOT Kerengsaan mata/ kerosakan mata yang serius Bahaya akut kepada persekitaran akuatik Garis menegak pada margin sebelah kiri tangan menunjukkan pindaan dari versi sebelumnya. Data yang terdapat dalam risalah data keselamatan ini adalah berdasarkan pengetahuan dan pengalaman kami, dan menerangkan tentang produk yang berkaitan dengan keperluan keselamatan sahaja. Data tidak menyatakan ciri produk (spesifikasi produk). Data dalam risalah data keselamatan ini juga tidak menyatakan apa-apa ciri khusus atau kesesuaian produk yang dipersetujui untuk apa-apa tujuan tertentu. Penerima produk bertanggungjawab untuk memastikan bahawa apa-apa hak pemilikan serta undang-undang dan perundangan sedia ada dipatuhi.

12 Mukasurat (Page): 12/22 1. Identification of the chemical and of the supplier Efka FA 4654 Use: wetting agent, Levelling Agent Company: BASF (Malaysia) Sdn Bhd No 2, Jalan Astaka U8/87 Bukit Jelutong, Seksyen U Shah Alam, Selangor, MALAYSIA Telephone: Telefax number: Emergency information: International emergency number: Telephone: Hazard identification Classification of the substance and mixture: Flammable liquids: Cat. 3 Acute toxicity: Cat. 4 (oral) Skin corrosion/irritation: Cat. 2 Skin sensitization: Cat. 1 Specific target organ toxicity single exposure: Cat. 3 (Vapours may cause drowsiness and dizziness.) Specific target organ toxicity single exposure: Cat. 3 (irritating to respiratory system) Specific target organ toxicity repeated exposure (Immune system, Liver, Intestinal tract): Cat. 2 Hazardous to the aquatic environment - chronic: Cat. 2 Label elements and precautionary statement: Pictogram: Signal Word: Warning Hazard Statement: Flammable liquid and vapour. Causes skin irritation. Harmful if swallowed. May cause an allergic skin reaction. May cause drowsiness or dizziness. May cause respiratory irritation. May cause damage to organs (Immune system, Liver, Intestinal tract) through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects.

13 Mukasurat (Page): 13/22 Precautionary Statements (Prevention): Wear protective gloves and eye/face protection. Do not breathe dust/gas/mist/vapours. Avoid release to the environment. Use only outdoors or in a well-ventilated area. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Take precautionary measures against static discharge. Use explosion-proof electrical/ventilating/lighting/equipment. Contaminated work clothing should not be allowed out of the workplace. Wash with plenty of water and soap thoroughly after handling. Do not eat, drink or smoke when using this product. Use only non-sparking tools. Ground/bond container and receiving equipment. Precautionary Statements (Response): If skin irritation or rash occurs: Call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Wash with plenty of soap and water. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF SWALLOWED: rinse mouth. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. Collect spillage. In case of fire: Use foam or dry powder for extinction. Precautionary Statements (Storage): Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. Precautionary Statements (Disposal): Dispose of contents/container to hazardous or special waste collection point. Other hazards which do not result in classification: No specific dangers known, if the regulations/notes for storage and handling are considered. 3. Composition/information on ingredients Chemical nature Preparation based on: mineral oil, fatty acids, modified Hazardous ingredients Hydrocarbons, C9, aromatics Content (W/W): >= 30 % - <= 50 % Asp. Tox.: Cat. 1 Flam. Liq.: Cat. 3 STOT SE: Cat. 3 (drowsiness and dizziness) STOT SE: Cat. 3 (irr. to respiratory syst.) Aquatic Chronic: Cat. 2 Fatty acids, C18-unsatd., trimers, compds. with oleylamine Content (W/W): >= 20 % - <= 30 % Acute Tox.: Cat. 4 (oral) CAS Number: Skin Corr./Irrit.: Cat. 2 Skin Sens.: Cat. 1A STOT RE (Intestinal tract, Liver, Immune system): Cat. 2 (oral) Fatty acids, tall-oil, compds. with oleylamine

14 Mukasurat (Page): 14/22 Content (W/W): >= 20 % - <= 30 % CAS Number: Acute Tox.: Cat. 4 (oral) Skin Corr./Irrit.: Cat. 2 Skin Sens.: Cat. 1A STOT RE (Liver, Immune system, Intestinal tract): Cat. 2 (oral) Fatty acids, C18-unsatd., dimers, compds. with oleylamine Content (W/W): >= 5 % - <= 10 % Acute Tox.: Cat. 4 (oral) CAS Number: Skin Corr./Irrit.: Cat. 2 Skin Sens.: Cat. 1A STOT RE (Liver, Intestinal tract, Immune system): Cat. 2 (oral) 9-Octadecen-1-amine, (Z)- Content (W/W): < 0.5 % CAS Number: Asp. Tox.: Cat. 1 Acute Tox.: Cat. 4 (oral) Skin Corr./Irrit.: Cat. 1A Eye Dam./Irrit.: Cat. 1 STOT SE: Cat. 3 (irr. to respiratory syst.) STOT RE (Liver, Immune system, Gastrointestinal tract): Cat. 2 Aquatic Acute: Cat. 1 Aquatic Chronic: Cat. 1 M-factor acute: 10 M-factor chronic: 10 For the classifications not written out in full in this section the full text can be found in section First-Aid Measures General advice: Immediately remove contaminated clothing. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. On skin contact: Wash thoroughly with soap and water. On contact with eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. On ingestion: Rinse mouth immediately and then drink plenty of water, seek medical attention. Note to physician:

15 Mukasurat (Page): 15/22 Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further important symptoms and effects are so far not known. Note to physician: Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Suitable extinguishing media: dry powder, foam Specific hazards: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Special protective equipment: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental Release Measures Personal precautions: Use personal protective clothing. Breathing protection required. Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods for cleaning up or taking up: For large amounts: Pump off product. For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance with regulations. 7. Handling and Storage Handling Ensure thorough ventilation of stores and work areas. Protection against fire and explosion: Sources of ignition should be kept well clear. Take precautionary measures against static discharges. If delivered in plastic packing, highest permissable emptying temperature is 5 Kelvin below the flash point.

16 Mukasurat (Page): 16/22 Storage Further information on storage conditions: Keep container tightly closed and in a cool place. Protect from temperatures below: 5 C Protect from temperatures above: 35 C 8. Exposure controls and personal protection Personal protective equipment Respiratory protection: Suitable respiratory protection for higher concentrations or long-term effect: Gas filter for gases/vapours of organic compounds (boiling point >65 C, e. g. EN Type A) Hand protection: Chemical resistant protective gloves Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): fluoroelastomer (FKM) mm coating thickness Polyethylene-Laminate (PE laminate) - ca. 0.1 mm coating thickness Suitable materials for short-term contact (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374) nitrile rubber (NBR) mm coating thickness Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing. Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166) Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN in case of splashes or EN ISO in case of dust). General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. 9. Physical and Chemical Properties Form: Colour: Odour: Odour threshold: liquid light brown product specific Not determined due to potential health hazard by inhalation.

17 Mukasurat (Page): 17/22 ph value: insoluble Boiling point: approx. > 160 C The statements are based on the properties of the individual components. Flash point: 45 C (DIN EN 22719; ISO 2719) Evaporation rate: not determined Flammability (solid/gas): Flammable. Lower explosion limit: For liquids not relevant for classification and labelling., The lower explosion point may be 5-15 C below the flash point. Upper explosion limit: For liquids not relevant for classification and labelling. Ignition temperature: 450 C Information applies to the solvent. Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Self ignition: not self-igniting Test type: Spontaneous selfignition at room-temperature. Explosion hazard: not explosive Fire promoting properties: not fire-propagating Vapour pressure: not determined Density: approx g/cm3 (20 C) Relative density: (20 C) (20 C) Relative vapour density (air): not determined (ISO ) (OECD Guideline 109) Solubility in water: insoluble (20 C) 4 mg/l (20 C) Hygroscopy: Non-hygroscopic Solubility (qualitative) solvent(s): organic solvents soluble

18 Mukasurat (Page): 18/22 Partitioning coefficient n-octanol/water (log Pow): not applicable for mixtures Surface tension: Study scientifically not justified. Viscosity, dynamic: mpa*s (25.0 C) 10. Stability and Reactivity Conditions to avoid: See MSDS section 7 - Handling and storage. Thermal decomposition: No decomposition if stored and handled as prescribed/indicated. Substances to avoid: strong oxidizing agents Hazardous reactions: No hazardous reactions when stored and handled according to instructions. Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. 11. Toxicological Information Acute toxicity Experimental/calculated data: LD50 rat (oral): 300-2,000 mg/kg The product has not been tested. The statement has been derived from the properties of the individual components. LC50 rat (by inhalation): 4 h not determined LD50 rat (dermal): not determined Irritation Experimental/calculated data: Skin corrosion/irritation rabbit: Irritant. The product has not been tested. The statement has been derived from the properties of the individual components. Serious eye damage/irritation rabbit: irreversible damage

19 Mukasurat (Page): 19/22 The product has not been tested. The statement has been derived from the properties of the individual components. Respiratory/Skin sensitization Experimental/calculated data: Mouse Local Lymph Node Assay (LLNA) mouse: skin sensitizing The product has not been tested. The statement has been derived from the properties of the individual components. Germ cell mutagenicity Assessment of mutagenicity: No data available concerning mutagenic effects. Carcinogenicity Assessment of carcinogenicity: No data available. Reproductive toxicity Assessment of reproduction toxicity: No data available. Developmental toxicity Assessment of teratogenicity: No data available. Specific target organ toxicity (single exposure): Assessment of STOT single: Causes temporary irritation of the respiratory tract. Possible narcotic effects (drowsiness or dizziness). Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: The product may cause damage to the immune system after repeated oral/dermal/inhalative uptake. The substance may cause damage to the liver after repeated ingestion. Damages the gastrointestinal tract. The product has not been tested. The statement has been derived from the properties of the individual components. Aspiration hazard No aspiration hazard expected.

20 Mukasurat (Page): 20/ Ecological Information Ecotoxicity Toxicity to fish: LC50 (96 h) > mg/l, Fish The product has not been tested. The statement has been derived from the properties of the individual components. Aquatic invertebrates: LC50 (48 h), daphnia not determined Aquatic plants: EC50 (72 h) > 1-10 mg/l, algae The product has not been tested. The statement has been derived from the properties of the individual components. Microorganisms/Effect on activated sludge: EC0 > mg/l, bacteria The product has not been tested. The statement has been derived from the properties of the individual components. Chronic toxicity to fish: No data available. Chronic toxicity to aquatic invertebrates: No data available. Assessment of terrestrial toxicity: No data available concerning terrestrial toxicity. Mobility Assessment transport between environmental compartments: No data available. Persistence and degradability Assessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria). Bioaccumulation potential Assessment bioaccumulation potential: The product has not been tested. Additional information Add. remarks environm. fate & pathway:

21 Mukasurat (Page): 21/22 Treatment in biological waste water treatment plants has to be performed according to local and administrative regulations. 13. Disposal Considerations Must be disposed of or incinerated in accordance with local regulations. Contaminated packaging: Uncontaminated packaging can be re-used. Packs that cannot be cleaned should be disposed of in the same manner as the contents. 14. Transport Information Domestic transport: Hazard class: 3 Packing group: III ID number: UN 1268 Hazard label: 3, EHSM Proper shipping name: PETROLEUM DISTILLATES, N.O.S. (contains ALKYL-C3/C4- BENZENE) Further information Hazchem Code:3Y IERG Number:14 Sea transport IMDG Hazard class: 3 Packing group: III ID number: UN 1268 Hazard label: 3, EHSM Marine pollutant: YES Proper shipping name: PETROLEUM DISTILLATES, N.O.S. (contains ALKYL-C3/C4- BENZENE) Air transport IATA/ICAO Hazard class: 3 Packing group: III ID number: UN 1268 Hazard label: 3 Proper shipping name: PETROLEUM DISTILLATES, N.O.S. (contains ALKYL-C3/C4- BENZENE)

22 Mukasurat (Page): 22/22 Transport in bulk according to Annex II of MARPOL and the IBC Code Regulation: Not evaluated Shipment approved: Not evaluated Pollution name: Not evaluated Pollution category: Not evaluated Ship Type: Not evaluated 15. Regulatory Information 16. Other Information Full text of classifications, hazard symbols and hazard statements, if mentioned in section 2 or 3: Asp. Tox. Flam. Liq. STOT SE Aquatic Chronic Acute Tox. Skin Corr./Irrit. Skin Sens. STOT RE Eye Dam./Irrit. Aquatic Acute Aspiration hazard Flammable liquids Specific target organ toxicity single exposure Hazardous to the aquatic environment - chronic Acute toxicity Skin corrosion/irritation Skin sensitization Specific target organ toxicity repeated exposure Serious eye damage/eye irritation Hazardous to the aquatic environment - acute Vertical lines in the left hand margin indicate an amendment from the previous version. The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. This safety data sheet is neither a Certificate of Analysis (CoA) nor technical data sheet and shall not be mistaken for a specification agreement. Identified uses in this safety data sheet do neither represent an agreement on the corresponding contractual quality of the substance/mixture nor a contractually designated use. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.