Material Safety Data Sheet

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Company: Chemtura Corporation 199 Benson Road Middlebury, CT United States of America Telephone: (US) Emergency telephone number: CHEMTREC: (24 hours) : Chemtura Corporation Emergency Response: CHEMTURA : For additional emergency telephone numbers see section 16 of the Safety Data Sheet. Prepared by: 02/14/2013 Product Safety Department (US) MSDSRequest@chemtura.com SECTION 2. HAZARDS IDENTIFICATION Emergency Overview CAUTION! Colour: light pink Odour: mild sweet Hazard Summary : May cause eye and skin irritation. Consumption of alcoholic beverages increases the toxic effects of this chemical (Thiram). Consumption of alcohol should be avoided before and after exposure. OSHA Hazards : TOXIC BY INHALATION. MODERATE SKIN IRRITANT MODERATE EYE IRRITANT Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. SAP / 11 SDS Number:

2 OSHA NTP ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Component / CAS-No Ethylene glycol Ingredients not precisely identified are non-hazardous and/or proprietary. Weight percent % % % SECTION 4. FIRST AID MEASURES First aid procedures Inhalation Skin contact : Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth, if possible. Call a POISON CENTER or doctor/ physician. : Remove contaminated clothing and shoes. Rinse immediately with plenty of water for at least 15 minutes. Call a POISON CENTER or doctor/ physician. Eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 30 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a POISON CENTER or doctor/ physician. Ingestion : Call a physician or poison control centre immediately. Have person sip a glass of water if able to swallow. If swallowed, DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. SECTION 5. FIREFIGHTING MEASURES Flammable properties Flash point : Remarks: no data available Ignition temperature : Remarks: not determined SAP / 11 SDS Number:

3 Lower explosion limit Upper explosion limit : Remarks: no data available : Remarks: no data available Fire fighting Suitable extinguishing media Unsuitable extinguishing media Further information : Extinguishing media - large fires Alcohol-resistant foam (on small fires) Carbon dioxide (CO2) Dry chemical Water spray : Water spray jet : Do not discharge extinguishing waters into streams, rivers and lakes. Protective equipment and precautions for firefighters Special protective equipment for firefighters : Body covering protective clothing, full "turn-out" gear. Self-contained breathing apparatus (EN 133) SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for containment / Methods for cleaning up : Wear suitable protective equipment. Avoid contact with skin and eyes. : Prevent leaks and prevent soil / water pollution caused by leaks. : Absorb on inert material such as sand, earth, vermiculite. Collect for disposal. Dam up. Large spills should be collected mechanically (remove by pumping) for disposal. Pump excess material into suitable container (metal drums, metal tank, or such). In accordance with local and national regulations. SECTION 7. HANDLING AND STORAGE Handling Handling procedures : Do not eat, drink or smoke when using this product. Avoid contact with skin, eyes and clothing. Avoid inhalation of vapour or mist. Use with adequate ventilation. Wash thoroughly after handling. Wash thoroughly after handling. Storage Requirements for storage : Keep in a dry, cool place. SAP / 11 SDS Number:

4 areas and containers SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Components with workplace control parameters Components / CAS-No. Value / Basis / Update TWA ACGIH TWA OSHA P TWA OSHA P Control parameters 0.05 mg/m3 5 mg/m3 5 mg/m3 Further information Ethylene glycol C OSHA P C ACGIH ppm 125 mg/m3 100 mg/m3 Ingredients not precisely identified are non-hazardous and/or proprietary. Engineering measures Personal protective equipment Eye protection : Safety glasses with side-shields Hand protection : Impervious gloves Skin and body protection Respiratory protection Hygiene measures : Preventive skin protection : In the absence of engineering controls sufficient to maintain airborne concentrations below recommended occupational exposure limit values, appropriate respiratory protection should be utilized. A respiratory protection program that meets OSHA and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. : Do not store near food, feed or fertilizers. SAP / 11 SDS Number:

5 Do not contaminate ponds, lakes, streams, or any source of water. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical state Colour Odour : liquid : light pink : mild sweet Safety data Flash point Ignition temperature Lower explosion limit Upper explosion limit : Remarks: not determined ph : ca. 7.8 Melting point/range : -4 F (-20 C) Vapour pressure Density : no data available : ca g/cm3 Specific Gravity : at 25 C Water solubility Partition coefficient: n- octanol/water Viscosity, kinematic SECTION 10. STABILITY AND REACTIVITY Materials to avoid Hazardous decomposition products Hazardous reactions : Remarks: Oxidizing agents Strong acids and strong bases : Note: Carbon oxides Other hazardous decomposition products may be formed. : Hazardous polymerisation does not occur. SAP / 11 SDS Number:

6 SECTION 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50: 4,587 mg/kg Species: rat Remarks: The following toxicological data shown are those obtained from tests on products of similar composition. Acute inhalation toxicity : LC50: > 1.0 mg/l Exposure time: 4 h Species: rat Acute dermal toxicity : LD50: > 2,000 mg/kg Species: rat Remarks: The following toxicological data shown are those obtained from tests on products of similar composition. Skin irritation : Species: rabbit Result: Moderate skin irritation Remarks: Information given is based on data obtained from similar substances. : Species: rabbit Result: Skin irritation Eye irritation : Species: rabbit Result: Moderate eye irritation Remarks: Information given is based on data obtained from similar substances. : Species: rabbit Classification: No eye irritation Sensitisation : Species: guinea pig Classification: Non sensitizing. Remarks: Information given is based on data obtained from similar substances. CMR effects : Carcinogenicity: Animal testing did not show any carcinogenic effects. Mutagenicity: Animal testing did not show any mutagenic effects. Teratogenicity: No effects on or via lactation Reproductive toxicity: No toxicity to reproduction : Carcinogenicity: Animal testing did not show any carcinogenic effects. Mutagenicity: In vitro tests showed mutagenic effects Reproductive toxicity: No effects on or via lactation SAP / 11 SDS Number:

7 12. ECOLOGICAL INFORMATION Toxicity to fish : LC50: 2.3 mg/l Species: Oncorhynchus mykiss (rainbow trout) flow-through test LC50: 3.6 mg/l Species: Lepomis macrochirus (Bluegill sunfish) flow-through test : LC50: 0.13 mg/l Species: Oncorhynchus mykiss (rainbow trout) Toxicity to daphnia and other aquatic invertebrates : EC50: > 57 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) flow-through test : EC50: 0.21 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) Toxicity to algae : EC50: 1.9 mg/l Species: Chlorella vulgaris (Fresh water algae) Growth inhibition : mg/l Species: Chlorella vulgaris (Fresh water algae) 0.14 mg/l Species: Scenedesmus capricornutum (fresh water algae) Toxicity to fish (Chronic toxicity) : NOEC: 0.32 mg/l Exposure time: 21 d Species: Cyprinus carpio (Carp) Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC: 0.32 mg/l Exposure time: 17 d Species: Daphnia magna (Water flea) : mg/l SAP / 11 SDS Number:

8 Exposure time: 21 d Species: Daphnia magna (Water flea) Biodegradability : Result: According to the results of tests of biodegradability this product is not readily biodegradable. Further information on ecology SECTION 13. DISPOSAL CONSIDERATIONS Further information : Dispose of waste material in compliance with all federal, state, and local regulations. The product should not be allowed to enter drains, water courses or the soil. SECTION 14. TRANSPORT INFORMATION DOT UN number : 3082 Description of the goods : Environmentally hazardous substances, liquid, n.o.s. : (, ) Class : 9 Packing group : III ERG Code : 171 TDG Not dangerous goods IATA UN number : 3082 Description of the goods : Environmentally hazardous substance, liquid, n.o.s. (, ) Class : 9 Packing group : III Labels : 9 Environmentally hazardous : no IMDG UN number : 3082 Description of the goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (, ) Class : 9 Packing group : III EmS Number 1 : F-A EmS Number 2 : S-F Marine pollutant Environmentally hazardous : yes : yes SAP / 11 SDS Number:

9 SECTION 15. REGULATORY INFORMATION OSHA Hazards : Toxic by inhalation., Moderate skin irritant, Moderate eye irritant CERCLA Reportable Quantity SARA 302 Reportable Quantity SARA 311/312 Hazards : 72 lbs : : Acute Health Hazard 10 lbs EPCRA - EMERGENCY PLANNING COMMUNITY RIGHT - TO - KNOW SARA 302 Reportable : Quantity ethylene oxide lbs SARA 313 Components : Ethylene glycol California Prop. 65 Components : WARNING! This product contains a chemical known to the State of California to cause cancer. quartz (SiO2) (Fr = 100%) quartz (SiO2) (Fr = 100%) acetaldehyde Oxirane acetaldehyde ethylene oxide 1,4-Dioxane ,4- dioxane WARNING! This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Oxirane ethylene oxide The components of this product are reported in the following inventories: US.TSCA Not On TSCA Inventory SAP / 11 SDS Number:

10 DSL This product contains the following components that are not on the Canadian DSL nor NDSL lists. AICS NZIoC ENCS KECI PICCS IECSC SECTION 16. OTHER INFORMATION Further information HMIS Classification : Health hazard: 2 Flammability: 1 Physical hazards: 0 SAP / 11 SDS Number:

11 NFPA Classification : Health hazard: 2 Fire Hazard: 1 Reactivity Hazard: Other Emergency Phone Number Latin America: Brazil All other countries +44 (0) Mexico: The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. SAP / 11 SDS Number: