Glycolic Acid. Section 1: Chemical Product and Company Identification. Section 2: Composition and Information on Ingredients Substances

Transcription

1 Material Safety Data Sheet Glycolic Acid Section 1: Chemical Product and Company Identification Product Name : GLYCOLIC ACID CAS# : RTECS : MC TSCA : TSCA 8(b) inventory: Glycolic acid CI# : Not available. Synonym : Hydroxyacetic Acid Chemical Name : Glycolic Acid Chemical Formula : C2H4O3 Contact Information : AVID ORGANICS PVT. LTD. B-5, IInd floor, Madhu Vihar, I.P. Extension, Delhi Section 2: Composition and Information on Ingredients Substances Name : GLYCOLIC ACID CAS# : % by Weight : 100 Toxicological Data on Ingredients : Glycolic acid: ORAL (LD50): Acute: 1950 mg/kg [Rat] mg/kg [Guinea pig]. VAPOR (LC50): Acute: 7.1 mg/m 4 hours [Rat]. Section 3: Hazards Identification Potential Acute Health Effects: Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (corrosive), of eye contact (corrosive). Slightly hazardous in case of skin contact (permeator). The amount of tissue damage depends on length of contact. Eye contact can result in corneal damage or blindness. Skin contact can produce inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking, unconsciousness or death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

2 Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Classified Development toxin [POSSIBLE]. The substance is toxic to lungs. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. Section 4: FIRST-AID MEASURES Eye Contact : Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately. Skin Contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Serious Skin Contact : Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention. Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Serious Inhalation : Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention. Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Serious Ingestion : Not available.

3 Section 5: Fire and Explosion Data Flammability of the Product : May be combustible at high temperature. Auto-Ignition Temperature : Not available. Flash Points : Not available. Flammable Limits : Not available. Products of Combustion : These products are carbon oxides (CO, CO2). Fire Hazards in Presence of : Slightly flammable to flammable in presence of heat. Various Substances Explosion Hazards in Presence of Various Substances Fire Fighting Media and Instructions Special Remarks on Fire Hazards Special Remarks on Explosion Hazards : Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. : SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. : Not available. : Not available. Section 6: Accidental Release Measures Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate. Large Spill: Corrosive solid. Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Neutralize the residue with a dilute solution of sodium carbonate. Section 7: Handling and Storage Precautions: Keep locked up... Keep container dry. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, alkalis, moisture.

4 Storage: Hygroscopic. Deliquescent. Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 23 C (73.4 F). Section 8: Exposure Controls/Personal Protection Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Personal Protection: Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self-contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits: Not available. Section 9: Physical and Chemical Properties Physical state and appearance : Solid. (Crystalline solid.) Odor : Odorless. Taste : Not available. Molecular Weight : g/mole Color : White to yellowish. ph (1% soln/water) : 2.33 [Acidic.] Boiling Point : Not available. Melting Point : 79 C (174.2 F) Critical Temperature : Not available. Specific Gravity : 1.49 (Water = 1) Vapor Pressure : Not available. Vapor Density : Not available. Volatility : Not available. Odor Threshold : Not available. Water/Oil Dist. Coeff. : The product is more soluble in water; log(oil/water) = -1.1 Ionicity (in Water) : Not available. Dispersion Properties : See solubility in water, methanol, diethyl ether, acetone.

5 Solubility : Easily soluble in cold water. Soluble in methanol, diethyl ether, acetone. Section 10: Stability and Reactivity Data Stability : The product is stable. Instability Temperature : Not available. Conditions of Instability : Excess heat, dust generation, incompatible materials, moist air or water Incompatibility with various substances : Reactive with oxidizing agents, alkalis, moisture. Corrosivity : Non-corrosive in presence of glass. Special Remarks on Reactivity : Hygroscopic; Deliquescent. Aliphatic amines, isocyanates, alkylene oxides, epichlorohydrin, caustics, ammonia, sulfuric acid Special Remarks on Corrosivity : This material has little tendency to cause corrision to metals. Polymerization : Will not occur. Section 11: Toxicological Information Routes of Entry : Absorbed through skin. Inhalation. Ingestion. Toxicity to Animals : WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 1920 mg/kg [Guinea pig]. Acute toxicity of the vapor (LC50): 7.1 mg/m3 4 hours [Rat]. Chronic Effects on Humans : DEVELOPMENTAL TOXICITY: Classified Development toxin [POSSIBLE]. Causes damage to the following organs: lungs. Other Toxic Effects on Humans : Very hazardous in case of skin contact (irritant), of ingestion, Hazardous in case of skin contact (corrosive), of eye contact (corrosive), of inhalation Special Remarks on Chronic Effects on Humans Special Remarks on other Toxic Effects on Humans (lung corrosive). Slightly hazardous in case of skin contact (permeator). : May cause adverse reproductive effects (fetotoxicity and developmental abnormalities) according to animal studies. No human studies information for humans was found. : Acute Potential Health Effects: Skin: Causes severe irritation. May cause skin burns. May be harmful if absorbed through skin. Eyes: Causes severe eye irritation. May cause eye burns. Inhalation: May be harmful if inhaled. Causes severe irritation of the respiratory tract and mucous membranes. May cause chemical burns to the respiratory tract. May affect sense organs, and metabolism. Ingestion: May be harmful if swallowed. Causes irritation of the digestive tract. May cause digestive (gastrointestinal) tract burns. May affect behavior (somnolence or general depressed activity), urinary system, and blood. Chronic Potential Health Effects: No information found

6 Section 12: Ecological Information Ecotoxicity : Not available. BOD5 and COD : Not available. Products of Biodegradation : Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of : Biodegradation The products of degradation are less toxic than the product itself. Special Remarks on the Products of Biodegradation : Not available. Section 13: Disposal Considerations Waste Disposal : Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14: Transport Information DOT Classification : Class 8: Corrosive material Identification : Corrosive solid, acidic, organic, n.o.s. (Glycolic acid) UNNA: 3261 PG: II Special Provisions for Transport : Not available. Section 15: Regulatory Information Federal and State Regulations: TSCA 8(b) inventory : Glycolic Acid HMIS (U.S.A.): Health Hazard : 3 Fire Hazard : 1 Reactivity : 0 Personal Protection : J

7 National Fire Protection Association (U.S.A.): Health : 3 Flammability : 1 Reactivity : 0 Specific hazard: Protective Equipment : Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles. Section 16: Other Information References : Manufacturer's Material Safety Data Sheet Other Special Considerations : Not available. The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Avid Organics be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Avid Organics has been advised of the possibility of such damages.