SAFETY DATA SHEET (SDS)

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1 SAFETY DATA SHEET (SDS) SECTION 1: IDENTIFICATION OF THE MIXTURE AND OF THE COMPANY BAHAGIAN 1: PENGENALAN CAMPURAN DAN SYARIKAT 1.1 PRODUCT IDENTIFIER PENGENALAN PRODUK PRODUCT NAME QUICKMIX QUICKRENDER (387) CAS NUMBER RELEVANT IDENTIFIED USES OF THE MIXTURE AND USES ADVISED AGAINST KEGUNAAN BAHAN CAMPURAN YANG RELEVAN DAN TELAK DIKENALPASTI SERTA NASIHAT PENYALAHGUNAAN BAHAN INI The mixture is to be used as plastering mortar. Campuran adalah untuk digunakan sebagai mortar melepa dinding. 1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET BUTIR-BUTIR SYARIKAT PEMBEKAL RISALAH DATA KESELAMATAN LAFARGE DRYMIX SDN BHD ( T) LEVEL 12, BANGUNAN TH UPTOWN 3, NO 3, JALAN SS21/39, PETALING JAYA, SELANGOR DARUL EHSAN, MALAYSIA 1.4 EMERGENCY TELEPHONE TELEFON KECEMASAN SECTION 2: HAZARD IDENTIFICATION BAHAGIAN 1: PENGENALAN BAHAYA 2.1 CLASSIFICATION OF THE MIXTURE KLASIFIKASI BAHAN ACCORDING TO OCCUPANTIONAL SAFETY AND HEALTH (CLASSIFICATION, LABELLING AND SAFETY DATA SHEET OF HAZARDOUS CHEMICALS) REGULATIONS 2013 MERUJUK KEPASA PERATURAN KESELAMATAN DAN KESIHATAN PEKERJAAN (CLASSIFICATION, LABELLING AND SAFETY DATA SHEET OF HAZARDOUS CHEMICALS) REGULATIONS 2013 Hazard Class Kelas Bahaya Skin Irritation Kerengsaan kulit Serious eye damage/eye irritation Kerosakan mata yang serius/kerengsaan mata Skin Sensitisation Sensitiviti kulit Specific target organ toxicity, single exposure Ketoksikan pada sasaran organ khusus, pendedahan tunggal pada saluran pernafasan Hazard Category Kategori Bahaya Hazard Statement Penyata Bahaya 2 H315 Causes skin irritation H315 Menyebabkan kerengsaan kulit 1 H318 Causes serious eye damage H318 Menyebabkan kerosakan mata yang teruk 1 H317 May cause an allergic skin reaction H317 Boleh menyebabkan tindak balas alergi pada kulit 3 H335 May cause respiratory irritation. H335 Boleh menyebabkan kerengsaan pernafasan SDS-QuickMix TM QuickRender (387) Page 1 of 16

2 2.1.2 LABEL ELEMENTS ELEMEN LABEL According to Occupational Safety and Health (Classification, Labelling and Safety Date Sheet of Hazardous Chemicals) Regulations 2013 Merujuk kepada peraturan Keselamatan Kesihatan Pekerja (Classification, Labelling and Safety Date Sheet of Hazardous Chemicals) Regulations 2013 HAZARD PICTOGRAMS PIKTOGRAM BAHAYA SIGNAL WORD ISYARAT PERKATAAN Danger Bahaya HAZARD STATEMENT PENYATA BAHAYA H315 H318 H317 H335 Causes skin irritation Menyebabkan kerengsaan kulit Causes serious eye damage Menyebabkan kerosakan mata yang teruk May cause an allergic skin reaction Boleh menyebabkan tindak balas alergi pada kulit May cause respiratory irritation. Boleh menyebabkan kerengsaan pernafasan PRECAUTIONARY STATEMENT PENYATAAN LANGKAH PERLINDUNGAN Keep out of children Jauhi dari kanak-kanak Wear protective gloves / protective clothing / eye protection / face protection Pakai sarung tangan perlindung / pelindung palaian / pelindung mata / pelindung muka P305+P351+P338+P310: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. If present and easy to do, continue rinsing. Immediately call a doctor / physician. P305+P351+P338+P310: JIKA PADA MATA: Bilas dengan berhati-hati dengan air selama beberapa minit. Tangkalkan kanta lekap. Jika ada dan mudah untuk dilakukan, teruskan membilas. Hubungi doctor / pakar perubatan dengan segera. P302+P352+P333+P313: IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs, get medical advice / attention. P302+P352+P333+P313: JIKA TERKENA KULIT: Basuh dengan sabun dan air. Jika kerengsaan kulit atau ruam terjadi, dapatkan nasihat / rawatan perubatan. P261+P304+P340+P312: Avoid breathing dust / fume / gas / mist / vapours / spray. IF INHALE: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a doctor / physician if you feel unwell. P261+P304+P340+P312: Elakkan dari menyedut debu / wasap / gas/ kabut / wap / semburan/ JIKA TERHIDU: Pindahkan mamgsa ke tempat udara segar dan biarkan rehat dalam kedudukan yang selesa untuk bernafas. Panggil doctor / pakar perubatan jika anda rasa tidak sihat. SDS-QuickMix TM QuickRender (387) Page 2 of 16

3 P501: Disposal of contents / container to harden by application of water and dispose of as concrete waste. P501: Pelupusan bahan / bekas dengan cara mengeraskannya dengan menggunakan air dan melupuskannya dengan menggunakan air dan melupuskannya sebagai sisa konkrit. SUPPLEMENT INFORMATION MAKLUMAT TAMBAHAN Skin contact with wet cement, fresh concrete or mortar may cause irritation dermatitis or burns. Sentuhan kulit dengan mortar boleh menyebabkan dermatitis atau kelecuran kulit. OTHER HAZARDS BAHAYA LAIN None known Tidak ketahui SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS BAHAGIAN 3: KOMPOSISI / MAKLUMAT BAHAN 3.1 SUBSTANCES BAHAN Not applicable Tidak berkenaan 3.2 MIXTURES CAMPURAN BAHAN INFORMATION ON INGREDIENTS INFORMASI BAHAN CHEMICAL NAME CAS NUMBER weight % Silica sand Portland cement Limestone powder Additives Trade secret <5% SECTION 4: FIST-AID MEASURES BAHAGIAN 4: LANGKAH-LANGKAH KESELAMATAN 4.1 DESCRIPTION OF FIST AID MEASURES PENERANGAN LANGKAH-LANGKAH PERTOLONGAN CEMAS GENERAL NOTES NOTA AM No personal protective equipment is needed for first aid responders. First aid workers should avoid contact with wet mortar or mixture containing wet wet mortar. Pemberi pertolongan kecemasan tidak memerlukan peralatan perlindung diri. Mereka harus mengelakkan daripada terkena campuran simen basah. FOLLOWING CONTACT WITH EYES TINDAKAN JIKA TERKENA MATA Do not rub eyes. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately. Jangan menggosok mata. Siram dan bilas air pada mata selama 15 minit. Tanggalkan kanta lekap, jika ada. Teruskan bilas.hubungi pakar perubatan segera. SDS-QuickMix TM QuickRender (387) Page 3 of 16

4 FOLLOWING CONTACT WITH SKIN TINDAKAN JIKA TERKENA KULIT Wash off with soap and plenty of water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Basuh dengan sabun and bilas dengan air yang banyak. Dapatkan rawatan perubatan sekiranya terdapat kerengsaan kulit. Tanggalkan pakaian yang tercemar, basuh sebulem digunakan lagi. FOLLOWING INHALATION TINDAKAN JIKA TERSEDUT/TERHIDU Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist. Alihkan mangsa ke kawasan udara segar and biarkan rehat dalam kedudukan yang selesa untuk bernafas Hubungi doctor jika kerengsaan berterusan atau tanda-tanda lain berterusan. FOLLOWING CONTACT INJESTION TINDAKAN JIKA TERTELAN Rinse mouth. Get medical attention if symptoms occur. Bilas mulut. Dapatkan rawatan perubatan sekiranya tanda-tanda berterusan. MOST IMPORTANT SYMPTOMS/EFFECTS. BOTH ACUTE AND DELAYED GEJALA DAN KESA PENTING, AKUT DAN KELEWATAN TINDAKAN EYES: Eye contact with cement (wet or dry) may cause serious and potentially irreversible injuries MATA: Mata yang terkena dengan simen (kering atau basah) boleh menyebabkan kecederaan serius dan berpotensi tidak dapat dipulihkan. SKIN: Cement may have an irritating effect on moist skin (due to sweat or humidity) after prolonged contact or may cause dermatitis after repeated contact. KULIT: Simen boleh menyebabkan kerengsaan pada kulit yang lembap (disebabkan oleh peluh atau kelembapan) terutama jika berterusa mengendalikannya serta boleh menyebabkan dermatitis jika bersentuhan berulang-ulangan. Prolonged skim contact with wet cement may cause serious burn because they develop without pain being felt. Sentuhan simen pada kulit yang berterusan boleh menyebabkan kelecuran yang serius, ini kerana kelecuran terjadi tanpa dirasai. For more details, see Reference (1) Untuk maklumat kelanjutan, rujuk pada Rujukan (1) INHALATION: May cause respiratory irritation. Repeated inhalation of dust over a long period of time increases the risk of developing lung diseases. MENYEDUT/MENGHIDU:Boleh menyebabkan kerengsaan pernafasan. Jika aktiviti ini dilakukan berulang kali dalam tempoh masa yang panjang akan meningkatkan risiko penyakit paru-paru. Medical condition aggravated by exposure: Inhaling cement dust may aggravate existing respiratory system disease(s) and/or medical conditions such as emphysema or asthma and/or existing skin/eye conditions. Keadaan kesihatan bertambah teruk akibat pendedahan berpanjangan: Menyedut/menghidu debu simen boleh memburukan lagi penyakit system pernafasan sedia ada dan/atau emfisema atau asma dan/atau sakit kulit dan/atau mata yang sedia ada. 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED RAWATAN PERUBATAN SEGERA DAN RAWATAN KHAS YANG DIPERLUKAN When contacting a doctor/physician, take the SDS or the product label with you. Apabila menghubungi doctor / pakar perubatan, sila bawa SDS atau label produk bersama anda. IF IN EYES: Contact a specialist of occupational medicine or eye specialist, preferably an ophthalmologist. JIKA PADA MATA: Hubungi paka perubatan atau pakar mata, sebaik-baiknya pakar ophthalmology. SDS-QuickMix TM QuickRender (387) Page 4 of 16

5 SECTION 5: FIRE-FIGHTING MEASURES BAHAGIAN 5: LANGKAH MEMADAM KEBAKARAN 5.1 EXTINGUISHING MEDIA ALAT PEMADAM API Common cement is not flammable. Simen tidak mudah terbakar. 5.2 SPECIAL HAZARD ARISING FROM THE SUBSTANCE OR MIXTURE BAHAYA KHUSUS YANG TIMBUL DARIPADA BAHAN ATAU PENCAMPURAN Common cements are non-combustible and non-explosive and will not facilitate or sustain the combustion of other materials. Simen adalah bahan tidak mudah terbakar dan bukan bahan letupan dan tidak akan menyebabkan atau mengekalkan pembakaran bahan-bahan lain. 5.3 ADVICE FOR FIRE-FIGHTERS NASIHAT UNTUK AHLII PEMADAM PEMBAKARAN Common cement poses no fire-related hazards. General measures for a fire are applicable. Fire fighters should wear complete protective clothing including self-contained breathing apparatus. Do not breathe fumes. Keep containers cool by spraying with water. If exposes to fire. Avoid run off to waterways and sewers. Simen tidak menimbulkan bahaya berkaitan kebakaran. Langkah-langkah umum untuk memadam api mesti digumakan. Ahli pemadam pembakaran harus memakai pakaian pelindung yang termasuk peralatan pernafasan serba lengkap. Jangan menyedut wasap. Pastikan bekas disejuk dengan menyembur air. Jangan terdedah kepada api. Elakkan lari ke laluan air dan pembentung. SECTION 6: ACCIDENTAL RELEASE MEASURES BAHAGIAN 6: LANGKAH-LANGKAH MENYELAMAT KEMALANGAN 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES LANGKAH PERLINDUNGAN DIRI, KELENGKAPAN PERLINDUNG DIRI DAN PROSEDUR KECEMASAN FOR NON-EMERGENCY PERSONNEL UNTUK KAKITANGAN BUKAN KECEMASAN Wear protective equipment as described under Section 8 and follow the advice for safe handling and use given under Section 7 Pakai peralatan perlindungan seperti yang dinyatakan di bawah Seksyen 8 dan ikut nasihat untuk pengendalian yang selamat dan penggunaan diberi di bawah Seksyen FOR EMERGENCY RESPONDERS UNTUK KAKITANGAN KECEMASAN Emergency procedures are not required. However, respiratory protection is needed in situation with high dust levels. Prosedur kecemasan tidak diperlukan. Walau bagaimanapun, perlindungan pernafasan yang diperlukan dalam keadaan yang terdedah pada paras habuk tang tinggi. 6.2 ENVIRONMENTAL PRECAUTIONS LANGKAH PERLINDUNGAN ALAM SEKITAR Do not wash cement down sewage and drainage systems or into bodies of water (e.g. streams). Jangan menyalurkan simen di kumbahan dan system saliran atau ke dalam saliran air (contohnya: sungai) 6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANNING UP KAEDAH DAN BAHAN UNTUK PEMBENTUNGAN DAN PEMBERSIHAN Collect the spillage in a dry state if possible. Kumpul tumpahan dalam keadaan kering jika boleh. SDS-QuickMix TM QuickRender (387) Page 5 of 16

6 Dry cement Use cleanup methods such as vacuum extraction (Industrial portable units equipped with high efficiency air filter or equivalent technique) which do not cause airborne dispersion. Never use compressed air. Simen kering Gunakan kaedah pembersihan seperti pengekstrakan vakum (unit mudah alih yang dilengkapi dengan penapis udara atau teknik yang setarafnya) yang tidakmenyebabkan serakan udara. Jangan menggunakan udara termampat. Alternately, wipe-up the dust by mopping, wet brushing or by using water sprays or hoses (fine mist to avoid that the dust becomes airborne) and remove slurry. Sebagai alternatif, lap debu/habuk dengan mengemop, memberus atau dengan menggunakan semburan air (semburan halus untuk mengelakkan debu menjadi bawaan udara). If not possible, remove by slurrying with water (see wet cement) Jika tidak boleh, keluarkan pancutan air (lihat simen basah) When wet cleaning or vacuum cleaning is not possible and only dry cleaning with brush can be done, ensure that the workers wear the appropriate personal protective equipment and prevent dust from spreading. Jika pembersihan basah atau pembersihan vakum tidak bolah dilakukan, sila lakukan pembersihan dengan hanya menyapu, pastikan pekerja memakai peralatanperlindungan diri yang sesuai dan elakkan habuk daripada merebak. Avoid inhalation of cement and contact with skin. Place spilled materials into a container. Solidify before disposal as described under Section 13. Elak menyedut / menghidu simen dan terkena pada kulit. Letakkan tumpahan ke dalam bekas. Mengeraskkannya sebelum pelupusan seperti yang dinyatakan di Bahagian 13. Wet cement Clean up wet cement and placed in a container. Allow material to dry and solidify before disposal as described under Section 13. Simen basah Bersihkan simen basah dan diletakkan di dalam sebuah bekas. Biarkannya mengering dan mengeras sebelum dilupuskan seperti yang dinyatakan di Bahagian REFERENCE TO OTHER SECTIONS RUJUKAN KE BAHAGIAN LAIN See Section 8 and 13 for more details. Lihat Bahagian 8 dan 13 untuk maklumat lanjut SECTION 7: HANDLING AND STORAGE BAHAGIAN 7: PENGENDALIAN DAN PENYIMPANAN Do not handle or store near food beverages or smoking materials. Jangan memegang atau menyimpan berhampiran minuman, makanan atau bahan-bahan asapan. 7.1 PRECAUTIONS FOR SAFE HANDLING LANGKAH PERLINDUNGAN UNTU PENGENDALIAN SELAMAT PROTECTIVE MEASURES Follow the recommendations as given under Section 8. To clean up dry cement, see Subsection 6.3. Langkah-langkah perlindungan Mengikut cadangan seperti yang diberikan di Bahagian 8. Untuk membersihkan simen kering, lihat Sub Bahagian 6.3. Measures to prevent fire Not applicable. Langkah-langkah untuk mencegah kebakaran Tidak berkenaan. Measures to prevent aerosol and dust generation. Do not sweep. Use dry cleanup methods such as vacuum clean-up or vacuum extraction, which do not cause airborne dispersion. Langkah-langkah untuk mencegah penghasilan habuk. Jangan menyapu. Gunakan kaedah pembersihan kering seperti pengekstrakan vakum, yang tidak menyebabkan SDS-QuickMix TM QuickRender (387) Page 6 of 16

7 serakan udara. Measures to protect the environment Avoid release to the environment. Spillages or uncontrolled discharges into watercourses must be alerted to the appropriate regulatory body. Langkah untuk melindungi alam sekitar Elakkan daripada melepaskan bahan ke persekitaran. Tumpahan atau pelepasan tidak terkawal ke dalam alur air hendaklah dimaklumkan kepada badan kawal selia INFORMATION ON GENERAL OCCUPATIONAL HYGIENE Do not handle or store near food and beverage or smoking materials. In dusty environment, wear dust mask and protective goggles. Use protective gloves to avoid skin contact. Maklumat umum mengenai kebersihan pekerjaan Jangan memegang atau menyimpan berdekatan dengan makanan dan minuman atau bahan asapan. Dalam persekitaran berdebu, pakai topeng habuk dan cermin mata pelindung. Gunakan sarung tangan pelindung untuk mengelakkan sentuhan kulit. 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES KEADAAN UNTUK PENYIMPANAN SELAMAT, TERMASUK APA-APA KETAKSERASIAN Packed products should be stored in unopened bags, clear of the ground in cool dry condition and protected from excessive draught in order to avoid degradation of quality. Beg simen mesti di simpan di kawasan khas, kering, tidak secara langsung di permukaan tanah dan dilindungi dari udara panas yang berlebihan untuk mengekalkan kualitinya. Bag should be stacked in a stable manner. Beg perlu disusun dengan cara yang stabil. 7.3 SPECIFIC END USE(S) KEGUNAAN AKHIR YANG KHUSUS No additional information for the specific end uses (see Section 12). Tiada maklumat tambahan untuk kegunaan akhir tertentu (lihat Bahagian 12). SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION BAHAGIAN 8: KAWALAN PENDEDAHAN / PELINDUNG DIRI 8.1 CONTROL PARAMETERS PARAMETER KAWALAN WEL 8 hr Time Weighted Average (TWA) Total inhaled dust XX mg/m3 Respirable dust x mg/m 8.2 EXPOSURE CONTROLS KAWALAN PENDEDAHAN APPROPRIATE ENGINEERING CONTROLS KAWALAN KEJURUTERAAN YANG SESUAI Measures to reduce generation of dust and to avoid dust propagating in the environment such as de-dusting, exhaust, ventilation and dry clean-up methods which do not cause airborne dispersion. Langkah-langkah untuk mengurangkan penghasilan habuk dan serakkan debu di alam sekitar seperti penggunaa penyedut debu, ekzos, pengudaraan dan kaedah pembersihan kering Individual protection measures such as personal protection equipment Langkah-langkah perlindungan seperti peralatan perlindungan diri General During work avoid kneeling in fresh mortar whenever possible. If kneeling is absolutely necessary then appropriate SDS-QuickMix TM QuickRender (387) Page 7 of 16

8 waterproof personal protective equipment must be worn. Umum Jika boleh, elakkan melutut semasa melakukan kerja di mortar atau konkrit. Jika melutut,maka peralatan perlindungan diri kalis air yang sesuai mesti dipakai. Do not eat, drink or smoke when working with cement to avoid contact with skin or mouth. Immediately after working with cement or cement-containing materials, workers should wash or shower or use skin moisturisers. Jangan makan, minum atau merokok semasa bekerja dengan simen untuk mengelakkan dari terkena kulit atau mulut. Sejurus selepas bekerja dengan simen atau bahan yang mengandungi simen, perlu mencuci atau mandi atau menggunakan pelembap kulit. Remove contaminated clothing, footwear, watches etc. and clean thoroughly before re-using them. Tanggalkan pakaian yang tercemar, kasut, jam tangan dan lain-lain dan bersih dengan teliti sebelum menggunakan semula mereka. Eye/face protection: Wear DOSH approved glasses or safety goggles according national standards when handling dry or wet cement to prevent contact with eyes. Perlindungan mata / muka: Pakai cermin mata atau gogal keselamatan yang diiktiraf oleh JKKP atau mengikut standard kebangsaan apabila mengendalikan simen kering atau basah untuk mengelakkan terkena mata. Skin protection: Use suitable protective gloves, booth, closed long-sleeved protective clothing as well as skin care products (e.g. barrier creams) to protect the skin from prolonged contact with wet cement. Particular care should be taken to ensure that wet cement does not enter the boots. For the gloves respect the maximum wearing time to avoid skin problems. Perlindungan kulit: Gunakan sarung tangan yang sesuai, pakaian lengan panjang dan juga produk penjagaan kulit (contohnya krim penghalang) untuk melindungi kulit daripada sentuhan berpanjangan dengan simen basah. Perhatian khusus perlu diambil untuk memastikan bahawa simen basah tidak memasuki but. Pakai sarung tangan sepanjang masa kerja untuk mengelakkan masalah kulit. In some circumstances, such as when laying concrete or screed, waterproof trousers or kneepads as necessary Dalam sesetengah keadaan, seperti kerja-kerja konkrit, seluar kalis air atau kneepads adalah diperlukan Respiratory protection: Wear DOSH approved respiratory protection. Fitted well and good condition. Perlindungan pernafasan: Pakai perlindungan pernafasan diiktiraf oleh JKKP. Dipasang dengan baik dan berkeadaan baik 8.3 ENVIRONMENTAL EXPOSURE CONTROLS KAWALAN PENDEDAHAN ALAM SEKITAR Environmental exposure controls for the emission of cement particles into air has to be in accordance with the available technology and regulations for the emission of general dust particles. Kawalan alam sekitar untuk pelepasan habuk simen ke udara perlu mengikut peraturan-peraturan bagi pelepasan habuk umum dan menggunakkan teknologi sedia ada. Air: Environmental exposure controls for the emission of cement particles into air has to be in accordance with the available technology and regulations for the emission of general dust particles. Udara: Kawalan alam sekitar bagi pelepasan habuk simen ke udara perlu mengikut peraturan-peraturan bagi pelepasan habuk umum dan menggunakkan teknologi sedia ada Water: Do not wash cement into sewage systems or into bodies of water to avoid high ph. Above ph 9 negative ecotoxicological impacts are possible. Air: Jangan mencuci simen ke dalam sistem kumbahan atau ke dalam saliran air untuk mengelakkan penghasilan ph yang tinggi. Kealkalian ph 9 dan ke atas memberi impak ekotoksikologikal yang negatif. Soil and terrestrial environment: No special emission control measures are necessary for the exposure to the terrestrial environment. Tanah dan persekitaran daratan: Tiada langkah kawalan pelepasan khas yang perlu bagi pendedahan kepada persekitaran daratan. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES BAHAGIAN 9: FIZIKAL DAN KIMIA 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES MAKLUMAT TENTANG CII FIZIK AND KIMIA This information applies to the whole mixture Maklumat ini terpakai kepada seluruh campuran SDS-QuickMix TM QuickRender (387) Page 8 of 16

9 (a) Appearance : Grey powder (b) Odour : Ordourless (c) Odour threshold : Not available (d) ph (in water) : (e) Melting/Freezing point : >1250 o C (f) Initial boiling point/range : Not available (g) Flash point : Not flammable (h) Evaporation rate : NA (i) Flammability : Non-flammable (j) Upper/Lower flammability or exposure limit : Not available (k) Vapour pressure : Not available (l) Vapour density : Not available (m) Specific Gravity : (n) Solubility : Not soluble (o) Partition coefficient (in octanol/water) : Not available (p) Auto-ignition temperature : Not available (q) Decomposition temperature : Not available (r) Viscousity : None, solid (s) Exposure properties : Not applicable (t) Oxidizing properties : Not applicable (u) Other information VOC : 0% (weight %) (a) Rupa : Serbuk kelabu (b) Bau : Tidak berbau (c) Bau ambang : Tiada (d) ph (dalam air) : (e) Takat lebur : >1250 o C (f) Takat didih awal dan jarak takat didih : Tidak berkenaan (g) Takat flash : Tidak berkenaan (h) Kadar evaporasi : Tidak berkenaan (i) Kebolehan Mudah Terbakar (pepejal, gas) : Tidak mudah terbakar (j) Tahap pembakaran : Tidak berkenaan (k) Tekaan wap : Tidak berkenaan (l) Ketumpatan wap : Tidak berkenaan (m) Ketumpatan relatif : (n) Kelarutan di dalam air : Sedikit (0,1-1,5g/l) (o) Pekali sekatan (n- oktanol/air) : Tidak berkenaan (p) Suhu auto-pembakaran : Tidak berkenaan (q) Suhu penguraian : Tidak berkenaan (r) Kelikatan : Tidak berkenaan (s) Sifat letupan : Tidak berkenaan (t) Sifat pengoksidaan : Tidak berkenaan (u) Informasi lain Sebatian Organik Meruap: 0% (berat %) SECTION 10: STABILILITY AND REACTIVITY BAHAGIAN 10: KESTABILAN DAN KEREAKTIFAN 10.1 REACTIVITY KEREAKTIFAN The product is stable and non-reactive under normal conditions of use, storage and transport. Produk ini stabil dan bukan reaktif di bawah keadaan biasa penggunaan, penyimpanan dan pengangkutan CHEMICAL STABILITY KESTABILAN KIMIA Material is stable under normal conditions. Bahan ini stabil dalam keadaan biasa. Contact with incompatible materials should be avoided. Tindakbalas dengan bahan-bahan yang tidak serasi harus dielakkan. Wet cement is alkaline and incompatible with acids, with ammonium salts, with aluminum or other non-noble metals. Cement dissolves in hydrofluoric acid to produce corrosive silicon tetrafluoride gas. Cement reacts with water to form silicates and calcium hydroxide. Silicates in cement react with powerful oxidizers such as fluorine, boron trifluoride, chorine trifluoride, managanese triflouride and oxygen difluoride. SDS-QuickMix TM QuickRender (387) Page 9 of 16

10 Simen basah adalah beralkali dan tidak serasi dengan asid, garam ammonium,aluminium atau logam non-noble. Simen larut dalam asid hidrofluorik untukmenghasilkan gas silikon tetrafluoride yang menghakis. Simen bertindak balas dengan air untuk membentuk silikat dan kalsium hidroksida. Silikat dalam simen bertindak balas dengan agen pengoksidaan yang kuat seperti fluorin, boron trifluoride,klorin, trifluoride, triflouride managanese dan difluoride oksigen POSSIBILITY OF HAZARDOUS REACTIONS KEMUNGKINAN TINDAK BALAS BERBAHAYA No dangerous reaction known under conditions of normal use. Tiada tindakbalas bahaya yang diketahui di bawah keadaan-keadaan penggunaan normal CONDITIONS TO AVOID KEADAAN YANG PERLU DIELAK Contact with incompatible materials. Sentuhan dengan bahan-bahan yang tidak serasi IMCOMPATIBLE MATERIALS BAHAN TIDAK SERASI Strong oxidizing agents. Agen pengoksidaan keras HAZARDOUS DECOMPOSITION PRODUCTS PRODUK PENGHURAIAN YANG BERBHAYA No hazardous decomposition products are known. Tiada produk penguraian berbahaya yang diketahui. SECTION 11: TOXICOLOGICAL INFORMATION BAHAGIAN 11: KEMUNGKINAN TINDAK BALAS BERBAHAYA 11.1 INFORMATION ON TOXICOLOGICAL EFFECTS MAKLUMAT TENTANG KESAN TOKSIKOLOGI Apart from skin sensitization, Portland cement and common cement have the same toxicological and eco-toxicological properties. Selain pemekaan kulit, simen Portland dan simen biasa mempunyai sifat toksikologi dan eko-toksikologi yang sama. Information on toxicological effects Maklumat tentang kesan toksikologi HAZARD CLASS CATEGORY EFFECT REFERENCE Acute toxicity dermal Ketoksikan akut dermis - Limit test, rabbit, 24 hours contact, 2,000 mg/kg body weight no lethality. Based on available data, the classification criteria are not met Ujian had, arnab, dedahan 24 jam, 2,000 mg/kg berat badan - tidak bahaya. Berdasarkan data yang ada, kriteria pengelasan tidak dipenuhi (2) Acute toxicity inhalation Ketoksikan akut penyedutan - No acute toxicity.by inhalation observed Based on available data, the classification criteria are not met. Tiada ketoksikan akut melalui penyedutan diperhatikan Berdasarkan data yang ada, kriteria pengelasan tidak dipenuhi. (5) SDS-QuickMix TM QuickRender (387) Page 10 of 16

11 Acute toxicity oral Ketoksikan akut oral Skin corrosion / irritation Kakisan kulit / kerengsaan Serious eye damage / irritation Kerosakan mata yang serius / kerengsaan No indication of oral toxicity from studies with cement kiln dust Based on available data, the classification criteria are not met Tiada petunjuk ketoksikan lisan daripada kajian dengan debu simen Berdasarkan data yang ada, kriteria pengelasan tidak dipenuhi 2 Cement in contact with wet skin may cause thickening, cracking or fissuring of the skin. Prolonged contact in combination with abrasion may cause severe burns Simen bersentuhan dengan kulit yang basah boleh menyebabkan penebalan, retak atau kulit merekah. Sentuhan berpanjangan dan bergeser boleh menyebabkan luka melecur yang teruk 1 Portland cement clinker caused a mixed picture of corneal effects and the calculated irritation index was 128. Common cements contain varying quantities of Portland cement clinker, fly ash, blast furnace slag, gypsum, natural pozzolans, burnt shale, silica fume and limestone. Direct contact with cement may cause corneal damage by mechanical stress, immediate or delayed irritation or inflammation. Direct contact by larger amounts of dry cement orsplashes of wet cement may cause effects ranging from moderate eye irritation (e.g. conjunctivitis or blepharitis)to chemical burns and blindness Simen klinker Portland memberi kesan pada kornea dan indeks kerengsaan yang dihasilkan adalah 128. Kebiasaan, simen mengandungi kuantiti berbeza-beza untuk Portland simen klinker, flyash, blast furnace slag, gipsum, pozzolans semula jadi, burnt shale, debu silika dan batu kapur. Terdedah secara langsung dengan simen boleh menyebabkan kerosakan kornea disebabkan oleh tekanan mekanikal, kegatalan serta-merta atau keradangan. Terdedah secara langsung dengan jumlah yang lebih besar simen kering atau serakkan simen basah boleh menyebabkan kesan terdiri daripad kerengsaan mata yang sederhana (seperti konjunktivitis atau blepharitis) sehingga kebakaran kimia dan juga buta. Literature survey kajian ilmiah (2) Human experience (2) Pengalaman Manusia (6), (7) Skin sensitization Sensitiviti kulit 1B Some individual may develop eczema upon exposure to wet cement dust, cause either by the high ph which induces irritant contact dermatitis after prolonged contact, or by an immunological reaction to soluble Cr (Vl) which elicits allergic contact dermatitis. Sesetengah individu mungkin mengalami ekzema apabila terdedah kepada habuk simen basah, ini didebabkan oleh ph yang tinggi yang mendorong dermatitis merengsa selepas terdedah berpanjangan, atau dengan reaksi imunologi untuk larut Cr (VI) yang boleh menimbulkan alergi dermatitis. (3), (4), (12) Respiratory sensitization Sensitiviti pernafasan - There is no indication of sensitization of respiratory system Based on available data, the classification criteria are not met Tidak ada petunjuk sensitivity pada system pernafasan Berdasarkan data yang ada, kriteria pengelasan tidak dipenuhi (1) SDS-QuickMix TM QuickRender (387) Page 11 of 16

12 Germ cell mutagenicity Kemutagenan sel kuman Carcinogenicity Kekarsinogenan Reproductive toxicity Ketoksikan reproduktif STOT single exposure STOT Pendedahan Tunggal - No indication Based on available data, then classification criteria are not met Tiada petunjuk Berdasarkan data yang ada, maka kriteria pengelasan tidak dipenuhi - No casual association has been established between Portland cement exposure and cancer Tiada hubung kait antara pendedahan simen Portland dan kanser The epidemiological literature does not support the designation of Portland cement as suspected human carcinogen Rujukan ilmiah bidang epidemiologi tidak menyatakan hubung kait simen Portland sebagai sebagai punca karsinogen manusia Portland cement is not classified as a human carcinogen (According to ACGIH A4: Agents that cause concern that they could be carcinogenic or humans but which cannot be assessed conclusively because of a lack of data. In vitro or animal studies do not provide indications of carcinogenicity that are sufficient to classify the agent with one of the other notations) Simen Portland tidak diklasifikasi sebagai karsinogen manusia (Menurut ACGIH A4: Agen yang menyebabkan kebimbanganbahawa ia boleh menjadi karsinogenik pada manusia tetapi ia tidak dapat dinilai dengan pasti kerana kekurangan data. Kajian in vitro atau pada haiwan juga tidak memberikan tanda-tanda kekarsinogenan yang mencukupi untuk engklasifikasikan simen sebagai ejen) Based on available data, the classification criteria are not met. Berdasarkan data yang ada, kriteria pengelasan tidak dipenuhi. - Based on available data, the classification criteria are not met Berdasarkan data yang ada, kriteria pengelasan tidak dipenuhi. 3 Cement dust may irritate the throat and respiratory tract. Coughing, sneezing and shortness of breath may occur following exposure in excess of occupational exposure limits Debu simen boleh mengganggu tekak dan saluran pernafasan. Batuk, bersin dan sesak nafas mungkin berlaku berikutan pendedahanyang melebihi had pendedahan pekerjaan Overall, the pattern of evidence clearlyindicates that occupational exposure to cement dust has produced deficits in respiratory function. However, evidence available at the present time is insufficient to establish with any confidence the close-response relationship forthese effects. Secara keseluruhan, corak bukti jelas menunjukkan bahawa pendedahan kepada habuk simen telah menghasilkan defisit dalam fungsi pernafasan. Walau bagaimanapun, bukti yang ada pada masa ini tidak mencukupi untuk menghubungkan kesan ini (1) (1), (10) No evidence from human experience Tiada bukti dari pengalaman manusia (1) STOT repeated - There is an indication of COPD. The effects are acute (1) SDS-QuickMix TM QuickRender (387) Page 12 of 16

13 exposure STOT - Pendedahan Berulang and due to high exposures. No chronic effects or effects at low concentration have been observed. Terdapat tanda-tanda COPD. Kesan adalah akut dan kerana pendedahan yang tinggi. Tiada kesan kronik atau kesan pada kepekatan rendah diperhatikan. Aspiration hazard Bahaya pernafasan Based on available data, the classification criteria are not met. Berdasarkan data yang ada, kriteria pengelasan tidak dipenuhi. - Not applicable as cement are not used as an aerosol Tidak berkenaan kerana simen tidak digunakan sebagai aerosol (11) SECTION 12: ECOLOGICAL INFORMATION BAHAGIAN 12: MAKLUMAT EKOLOGI Apart from skin sensitation, Portland cement clinker and common cements have the same toxicological and eco-toxicological properties. Selain sensitiviti kulit, klinker simen Portland dan simen biasa mempunyai sifat toksikologi dan ekotoksikologikal yang sama TOXICITY KETOKSIKAN The product is not hazardous to the environment. Eco-toxicological tests with Portland cement on Daphnia megna (Reference (5)) and Selenastrum coli [Reference (6)] have shown little toxicological impact. Therefore LC50 and EC50 values could not be determined [Reference (7)]. There is no indication of sediment phase toxicity [Reference (8)]. The addition of large amounts of cement to water may however cause a rise in ph and may therefore, be toxic to aquatic life under certain circumstances. Produk ini tidak berbahaya kepada alam sekitar. Ujian eko-toksikologi dengan simen Portland pada Daphnia megna (Rujukan (5)) dan Selenastrum coli [Rujukan (6)] telah menunjukkan kesan toksikologi yang sedikit. Oleh itu nilai LC50 dan EC50 tidak dapat ditentukan [Rujukan (7)]. Tidak ada petunjuk ketoksikan pada fasa sedimen [Rujukan (8)]. Bagaimanapun, penambahan jumlah yang besar simen kepada air, boleh menyebabkan kenaikan ph dan mungkin kerana itu, menjadi toksik kepadahidupan akuatik pada keadaan tertentu PERSISTENCE AND DEGRADABILITY PENINGKATAN BERTERUSAN DAN PEMEROSOTAN No data is available on the degradability of this product. Tiada data boleh didapati untuk produk ini BIO-ACCUMULATIVE POTENTIAL POTENSI BIO-KUMULATIF No data available for this product. Tiada data boleh didapati untuk produk ini MOBILITY IN SOIL MOBILITY DALAM TANAH Not relevant. After hardening, cement presents no toxicity risks. Tidak relevan. Selepas pengerasan, simen tidak mempunyai risiko ketoksikan. SDS-QuickMix TM QuickRender (387) Page 13 of 16

14 SECTION 13: DISPOSAL CONSIDERATIONS BAHAGIAN 13: CARA-CARA PELUPUSAN 13.1 DISPOSAL INSTRUCTIONS ARAHAN PELUPUSAN Dispose of contents/container in accordance with local/ regional/ national/ international regulations. Do not contaminate ponds, waterways or ditches with chemical or used container. Menguruskan bahan / bekal menurut peraturan antarabangsa / tempatan / kawasan / negara. Jangan cemarkan kolam, jalan air atau parit dengan bekas kimia atau digunakan HAZARDOUS WASTE CODE KOD SISA BERBAHAYA The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Kod sisa perlu diberikan dalam perbincangan antara pengguna, pengeluar dan syarikat pelupusan sisa WASTE FROM RESIDUES/ UNUSED PRODUCTS SISA DARIPADA SISA-SIA / PRODUK YANG TIDAK DIGUNAKAN Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see:disposal instructions). Lupuskan mengikut peraturan-peraturan tempatan. Bekas kosong atau pelapik boleh menyimpan beberapa sisa produk. Bahan ini dan bekasnya hendaklah dilupuskan dengan cara yang selamat (lihat : Arahan Pelupusan) CONTAMINATED PACKAGING BUNGKUSAN TERCEMAR Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied Bekas kosong hendaklah dibawa ke tapak pengendalian bahan buangan yang diluluskan untuk dikitar semula atau pembuangan. Kerana bekas yang kosong boleh mengekalkan saki-baki produk, ikuti amaran label walaupun setelah bekas dikosongkan SECTION 14: TRANSPORT INFORMATION BAHAGIAN 14: MAKLUMAT PENGANGKUTAN DOT IATA IMDG Not regulated as dangerous goods Tidak dikawal selia sebagai barang-barang berbahaya Not regulated as dangerous goods Tidak dikawal selia sebagai barang-barang berbahaya Not regulated as dangerous goods Tidak dikawal selia sebagai barang-barang berbahaya Transport in bulk according to This substance/mixture is not intended to be transported in bulk. Annex II of MARPOL 73/78 and the IBC Code Pengangkutan dalam pukal menurut Bahan / campuran ini tidak bertujuan untuk diangkut secara pukal. Lampiran II MARPOL 73/78 dankod IBC SDS-QuickMix TM QuickRender (387) Page 14 of 16

15 SECTION 15: REGULATORY INFORMATION BAHAGIAN 15: MAKLUMAT PERATURAN 15.1 Safety, health and environmental regulations / legislation specific for the substance or mixture Peraturan / undang-undang khusus berkenaan keselamatan, kesihatan dan alam sekitar untuk bahan atau campuran (a) Occupational Safety and Health Act 1994 and relevant regulations (b) Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations (c) Environmental Quality Act 1974 (a) Akta Keselamatan dan Kesihatan Pekerjaan 1994 dan peraturan-peraturan yang berkaitan (b) Keselamatan dan Kesihatan Pekerjaan (Pengelasan, Pelabelan dan Helaian Data Keselamatan Bahan Kimia Berbahaya) 2013 Peraturan-Peraturan Pekerjaan. (c) Akta Kualiti Alam Sekeliling 1974 SECTION 16: OTHER INFORMATION BAHAGIAN 16: MAKLUMAT LAIN 16.1 ABBRIEVIATION AND ACRONYMS SINGAKATAN DAN AKRONIM ACGIH ADR / RID CAS CLP COPD DOT ECHA IATA IMDG RPE SDS STOT American Conference of Industrial Hygienist European Agreements on the transport of dangerous goods by road / railway Chemical Abstracts Service Classification, labelling and packaging (Regulation EC) Chronic Obstructive Pulmonary Disease Department of Transportation (USA) European Chemicals Agency International Air Transport Association International agreement on the maritime transport of dangerous goods LC 50 median lethal close Respiratory protective equipment Safety Data sheet Specific target organ toxicity 16.2 KEY LITERATURE REFERENCES AND SOURCE OF DATA RUJUKAN ILMIAH UTAMA DAN SUMBER DATA 1) Portland Cement Dust Hazard assessment document EH 75/7. UK Health and Safety Executive, Available from cement.pdf 2) Observation on the effects of skin irritation caused by cement, Kietzman.et.al,Dermatosen, 47,5, (1999) 3) European Commission s Scientific Committee on Toxicity. Ecotoxicology and the Environment (SCTEE) opinion of the risks to health from Cr(vl)in cement (European Commission 2002) 4) Epidemiological assessment of the occurrence of allergic dermatitis in workers in the construction industry related to the content of Cr(vl) in cement, NIOH, Page 11,2003 5) TNO report V An acute (4 hour) inhalation toxicity study with Portland Cement Clinker CLP/GHS fine in rats, August ) TNO report V8815/09. Evaluation of eye irritation potential of cement clinker W invitro using the isolation chicken eye test. April ) TNO report V8815/10. Evaluation of eye irritation potential of cement clinker W in vitro using the isolation chicken eye test. April ) Investigation of the cytotoxic and prainflammatory effect of cement dusts in rat alveolar marcrophages. Van Berlo et.al Chem. Res. Toxicol spet:22(9) ) Cytotoxicity and genotoxicity of cement dust in A549 human epithelial lung cells in vitro: Gminski et.al, Abstract DGPT conference Mainz ) Comments on a recommendation from the American Conference of governmental industrial hygienist to change the threshold limit value for Portland cement, Patrick A. Hessel and John F. Gamble. EpiLung Consulting. June ) Prospective monitoring of exposure and lung function among cement workers. Interim report of the study after the data collection of Phase I-II Hilde Noto. Helge Kjuus. Maritskogstad and Karl-Christian Nordby, National Institute of Occupational Health, Oslo, Norway, March ) Occurance of allergic contact dermatitis caused by chromium in cement. A review of epidemiological investigations, KareLenvik, Helge Kjuus, NIOH, Oslo December 2011 SDS-QuickMix TM QuickRender (387) Page 15 of 16

16 16.3 TRANING ADVICE NASIHAT LATIHAN In addition to health, safety and environmental training programmes for their workers, companies must ensure that workers read, understand and apply the requirements of this SDS Tambahan kepada program latihan perkerjaan berkenaan kesihatan, keselamatan dan alam sekitar, pihak syarikat perlu memastikan bahawa pekerja membaca, memahami dan melaksanakan keperluan SDS ini FURHTER INFORMATION MAKLUMAT LANJUT The data and test methods used for the purposes of classification of common cements are given or referred to in Section 11.1 Data dan kaedah ujian yang digunakan bagi maksud klasifikasi simen yang diberikan adalah seperti Bahagian DISCLAIMER PENAFIAN The information in this (M)SDS was obtained from sources which we believe are reliable but cannot guarantee. Additionally, your use of this information is beyond our control and may be beyond our knowledge. Therefore, the information is provided without any representation orwarranty express or implied. Maklumat dalam ini (M) SDS yang diperolehi daripada sumber-sumber yang kami percaya boleh dipercayai tetapi tidak boleh menjamin. Selain itu, penggunaan maklumat ini adalah di luar kawalan kami dan mungkin di luar pengetahuan kita. Oleh itu, maklumat yang disediakan tanpa apa-apa representasi orwarranty nyata atau tersirat. Issue Date Tarikh Dikeluarkan 1 February 2016 SDS-QuickMix TM QuickRender (387) Page 16 of 16

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