: Ferrous Ammonium Sulfate Hexahydrate

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1 SECTION 1: Identification 1.1. Identification Product form Substance name Chemical name Ferrous Ammonium Sulfate Hexahydrate Date of issue: 08/31/2006 Revision date: 06/27/2017 Supersedes: 06/27/2013 Version: 1.1 : Substance CAS-No. : Product code Formula : Ferrous Ammonium Sulfate Hexahydrate : Iron (II) Ammonium Sulfate Hexahydrate : LC Recommended use and restrictions on use Use of the substance/mixture Recommended use Restrictions on use 1.3. Supplier : FeH8N2O8S2 6H2O : For laboratory and manufacturing use only. : Laboratory chemicals : Not for food, drug or household use LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA USA T F Emergency telephone number Emergency number : CHEMTREC: or SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Specific target organ toxicity (single exposure) Category 3 H315 H319 H335 Full text of H statements : see section 16 Causes skin irritation Causes serious eye irritation May cause respiratory irritation 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation : P261 - Avoid breathing dust P264 - Wash exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves, eye protection P302+P352 - IF ON SKIN: Wash with plenty of soap and water P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 - Call a POISON CENTER or doctor/physician if you feel unwell P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing and wash it before reuse P403+P233 - Store in a well-ventilated place. Keep container tightly closed 06/27/2017 EN (English US) Page 1

2 2.3. Other hazards which do not result in classification Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS US) Not applicable P405 - Store locked up P501 - Dispose of contents/container to comply with local, state and federal regulations If inhaled: Remove person to fresh air and keep comfortable for breathing : None. SECTION 3: Composition/Information on ingredients 3.1. Substances Substance type : Mono-constituent Name Product identifier % GHS-US classification Ferrous Ammonium Sulfate Hexahydrate (Main constituent) Full text of hazard classes and H-statements : see section Mixtures Not applicable SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion Chronic symptoms (CAS-No.) Skin Irrit. 2, H315 Eye Irrit. 2A, H319 STOT SE 3, H335 : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. : May cause respiratory irritation. : Causes skin irritation. : Causes serious eye irritation. : Nausea. Vomiting. Diarrhoea. Cardiac and blood circulation effects. : Enlargement/affection of the liver Immediate medical attention and special treatment, if necessary Obtain medical assistance. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Specific hazards arising from the chemical Fire hazard Explosion hazard : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. : Not flammable. : Not applicable Special protective equipment and precautions for fire-fighters Firefighting instructions Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection For non-emergency personnel Protective equipment : Gloves. Safety glasses. 06/27/2017 EN (English US) 2/6

3 Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Avoid breathing dust. Use only outdoors or in a well-ventilated area. : Wash exposed skin thoroughly after handling Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials : Keep only in the original container in a cool, well ventilated place away from : Direct sunlight, incompatible materials, Protect from moisture. Keep container tightly closed. : Strong oxidizers. Strong acids. : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters ACGIH ACGIH TWA (mg/m³) 1 mg/m³ Iron salts, soluble, as Fe NIOSH NIOSH REL (TWA) (mg/m³) 1 mg/m³ Iron salts, soluble, as Fe 8.2. Appropriate engineering controls Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure Individual protection measures/personal protective equipment Personal protective equipment: Gas mask. Gloves. Safety glasses. Hand protection: Wear protective gloves Eye protection: Chemical goggles or safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: Gas mask 06/27/2017 EN (English US) 3/6

4 Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Crystalline powder. Color : Green Colorless Odor : Odorless characteristic Odor threshold ph : 3-5 5% solution Melting point : 100 C Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) : Non flammable. Vapor pressure Relative vapor density at 20 C Relative density : Specific gravity / density : g/cm³ Molecular mass : g/mol Solubility : Water: 269 g/l Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties : Not applicable. Oxidizing properties Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Hygroscopic Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Do not allow contact with air. Moisture. Incompatible materials Incompatible materials Strong acids. Strong bases Hazardous decomposition products Gaseous ammonia. Sulfur compounds. SECTION 11: Toxicological information Information on toxicological effects 06/27/2017 EN (English US) 4/6

5 Likely routes of exposure Acute toxicity : Inhalation; Skin and eye contact LD50 oral rat 3250 mg/kg ATE US (oral) 3250 mg/kg body weight Skin corrosion/irritation : Causes skin irritation. ph: 3-5 5% solution Serious eye damage/irritation : Causes serious eye irritation. ph: 3-5 5% solution Respiratory or skin sensitization Germ cell mutagenicity Based on available data, the classification criteria are not met Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact Symptoms/effects after ingestion Chronic symptoms Based on available data, the classification criteria are not met : May cause respiratory irritation. : Based on available data, the classification criteria are not met. : May cause respiratory irritation. : Causes skin irritation. : Causes serious eye irritation. : Nausea. Vomiting. Diarrhoea. Cardiac and blood circulation effects. : Enlargement/affection of the liver. SECTION 12: Ecological information Toxicity Persistence and degradability Persistence and degradability Not established Bioaccumulative potential Bioaccumulative potential Not established Mobility in soil Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations Disposal methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated 06/27/2017 EN (English US) 5/6

6 SECTION 15: Regulatory information US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory RQ (Reportable quantity, section 304 of EPA's List of Lists) SARA Section 311/312 Hazard Classes 1000 lb Immediate (acute) health hazard All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory International regulations CANADA Not listed on the Canadian DSL (Domestic Substances List) EU-Regulations National regulations Not listed on the Canadian IDL (Ingredient Disclosure List) US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm SECTION 16: Other information Revision date : 06/27/2017 Other information Full text of H-phrases: see section 16: --- H H H NFPA health hazard NFPA fire hazard NFPA reactivity : None. Causes skin irritation Causes serious eye irritation May cause respiratory irritation : 2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury. : 0 - Materials that will not burn under typical dire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. : 0 - Material that in themselves are normally stable, even under fire conditions. Hazard Rating Health Flammability Physical Personal protection : 2 Moderate Hazard - Temporary or minor injury may occur : 0 Minimal Hazard - Materials that will not burn : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. : B B - Safety glasses, Gloves SDS US LabChem Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. 06/27/2017 EN (English US) 6/6

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