SAFETY DATA SHEET CONBEXTRA EP10 BASE

Transcription

1 Revision Date: 8 May 2013 Revision: 3 SAFETY DATA SHEET CONBEXTRA EP10 BASE SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product Name Product No. CONBEXTRA EP10 BASE UK9, A UK Relevant identified uses of the substance or mixture and uses advised against Identified uses Base Component of Three-Part Epoxy System 1.3. Details of the supplier of the safety data sheet Supplier: 1.4. Emergency telephone number FOSROC Limited Drayton Manor Business Park Coleshill Road Tamworth Staffordshire B78 3TL Tel. +44 (0) Fax. +44 (0) enquiryuk@fosroc.com +44 (0) (08.30 to 17.00hrs Mon - Thu; to 16.00hrs Fri) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Xi;R36/38. R43. N;R51/ Label elements Contains: Labelling BISPHENOL A & F BLEND 1.4 BUTANE DIGLYCIDYL ETHER Risk Phrases Safety Phrases Irritant Dangerous for the environment R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S24/25 Avoid contact with skin and eyes. S26 S37 S57 S61 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. Use appropriate containment to avoid environmental contamination. Avoid release to the environment. Refer to special instructions/safety data sheets. 1 / 7

2 CONBEXTRA EP10 BASE 2.3. Other hazards SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures BISPHENOL A & F BLEND % CAS-No.: EC No.: Classification (EC 1272/2008) Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Aquatic Chronic 2 - H411 Classification (67/548/EEC) Xi;R36/38. N;R51/53. R BUTANE DIGLYCIDYL ETHER 10-30% CAS-No.: EC No.: Classification (EC 1272/2008) Acute Tox. 4 - H312 Acute Tox. 4 - H332 Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Skin Sens. 1 - H317 Aquatic Chronic 3 - H412 Classification (67/548/EEC) Not classified. The Full Text for all R-Phrases and Hazard Statements is Displayed in Section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation. Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues. Ingestion Remove victim immediately from source of exposure. Provide fresh air, warmth and rest, preferably in comfortable upright sitting position. Immediately rinse mouth and drink plenty of water. Keep person under observation. If person becomes uncomfortable seek hospital and bring these instructions. Skin Contact Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if irritation persists after washing. Eye Contact Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention Most important symptoms and effects, both acute and delayed General Information The severity of the symptoms described will vary dependant of the concentration and the length of exposure. Inhalation. May cause irritation to the respiratory system. Ingestion May cause discomfort if swallowed. Skin Contact Skin irritation. Eye Contact Irritation of eyes and mucous membranes Indication of any immediate medical attention and special treatment needed 2 / 7

3 No information available. CONBEXTRA EP10 BASE SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing Media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. Unsuitable Extinguishing Media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous Combustion Products Carbon monoxide (CO). Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted Advice for firefighters Special Fire Fighting Procedures No specific fire fighting procedure given. Keep run-off water out of sewers and water sources. Dike for water control. Protective Measures In Fire Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Avoid discharge into drains, water courses or onto the ground. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body Methods and material for containment and cleaning up Ventilate well. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Do not contaminate water sources or sewer Reference to other sections For waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Provide good ventilation. Avoid forming spray/aerosol mists Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Storage Class Chemical storage Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Ingredient Comments WEL = Workplace Exposure Limits 8.2. Exposure controls Protective Equipment 3 / 7

4 CONBEXTRA EP10 BASE Engineering Measures Provide adequate ventilation. Respiratory Equipment No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists. It is recommended to use respiratory equipment with combination filter, type A2/P2. Hand Protection Use suitable protective gloves if risk of skin contact. Use protective gloves made of: Butyl rubber. Nitrile. Eye Protection If risk of splashing, wear safety goggles or face shield. Other Protection Wear appropriate clothing to prevent any possibility of skin contact. Hygiene Measures Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. DO NOT SMOKE IN WORK AREA! Skin Protection Wear apron or protective clothing in case of contact. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Colour Odour Solubility Liquid Straw Mild Initial Boiling Point and Boiling >200 C Range: Relative Density 1.15 Insoluble in water Vapour Pressure 0.1 kpa 20 C Flash Point ( C) 9.2. Other information Not available. >150 C SECTION 10: STABILITY AND REACTIVITY Reactivity Reaction with: Acids. Alkalis. Amines Chemical stability Stable under normal temperature conditions Possibility of hazardous reactions Not relevant. Hazardous Polymerisation Will not polymerise Conditions to avoid Avoid excessive heat for prolonged periods of time Incompatible materials Materials To Avoid No specific, or groups of materials are likely to react to produce a hazardous situation Hazardous decomposition products When heated, vapours/gases hazardous to health may be formed. 4 / 7

5 SECTION 11: TOXICOLOGICAL INFORMATION CONBEXTRA EP10 BASE Information on toxicological effects Inhalation Gas or vapour may irritate respiratory system. Ingestion. May cause discomfort if swallowed. Skin Contact Irritating to skin. May cause sensitisation by skin contact. Eye Contact Irritating to eyes. Route of entry Skin and/or eye contact. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity: Dangerous for the environment: May cause long-term adverse effects in the aquatic environment Toxicity Acute Fish Toxicity Toxic to aquatic organisms Persistence and degradability Degradability: The product is not expected to be biodegradable Bioaccumulative potential Bioaccumulative Potential: No data available on bioaccumulation Mobility in soil Mobility: The product is insoluble in water Results of PBT and vpvb assessment This product does not contain any PBT or vpvb Substances Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS General Information Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION UN number UN No. (ADR/RID/ADN) 3082 UN No. (IMDG) 3082 UN No. (ICAO) UN Proper shipping name Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL A & F BLEND) 14.3 Transport hazard class(es) 5 / 7

6 CONBEXTRA EP10 BASE ADR/RID/ADN Class 9 ADR/RID/ADN Class Class 9: Miscellaneous dangerous substances and articles. ADR Label No. 9 IMDG Class 9 ICAO Class/Division 9 Transport Labels Packing group ADR/RID/ADN Packing group IMDG Packing group ICAO Packing group III III III Environmental hazards Environmentally Hazardous Substance/Marine Pollutant Special precautions for user EMS F-A, S-F Emergency Action Code 3Z Hazard No. (ADR) 90 Tunnel Restriction Code (E) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations. Guidance Notes Workplace Exposure Limits EH40. EU Legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION 6 / 7

7 CONBEXTRA EP10 BASE General Information The user must be instructed in the proper work procedure and be familiar with the contents of these instructions. Revision Comments NOTE: Lines within the margin indicate significant changes from the previous revision. Revision Date 8 May 2013 Revision 3 Risk Phrases In Full R20/21 Harmful by inhalation and in contact with skin. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Hazard Statements In Full H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Disclaimer The information on this data sheet represents our current data and is reliable provided that the product is used under the prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. 7 / 7

8 Revision Date: 8 May 2013 Revision: 3 SAFETY DATA SHEET CONBEXTRA EP10 HARDENER SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product Name Product No. CONBEXTRA EP10 HARDENER A UK9, UK Relevant identified uses of the substance or mixture and uses advised against Identified uses Hardener component of two part epoxy system 1.3. Details of the supplier of the safety data sheet Supplier: 1.4. Emergency telephone number FOSROC Limited Drayton Manor Business Park Coleshill Road Tamworth Staffordshire B78 3TL Tel. +44 (0) Fax. +44 (0) enquiryuk@fosroc.com +44 (0) (08.30 to 17.00hrs Mon - Thu; to 16.00hrs Fri) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Human Health Xn;R22. C;R34. R43. R52/53. Prolonged or repeated contact with skin may cause redness, itching, irritation and eczema/chapping. The product contains a small amount of sensitising substance which may provoke an allergic reaction among sensitive individuals in contact with skin. Environment The product contains a substance which is harmful to aquatic organisms and which may cause long term adverse effects in the aquatic environment Label elements Contains: Labelling TRIMETHYL HEXAMETHYLENEDIAMINE Risk Phrases Safety Phrases Corrosive R22 R34 R43 Harmful Harmful if swallowed. Causes burns. May cause sensitisation by skin contact. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S25 S26 Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 1 / 7

9 2.3. Other hazards S36/37/39 S45 CONBEXTRA EP10 HARDENER Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). Not Classified as PBT/vPvB by current EU criteria. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures TRIMETHYL HEXAMETHYLENEDIAMINE % CAS-No.: EC No.: Classification (EC 1272/2008) Acute Tox. 4 - H302 Skin Corr. 1B - H314 Skin Sens. 1 - H317 Aquatic Chronic 3 - H412 Classification (67/548/EEC) Xn;R22. C;R34. R43,R52/53. PARA TOLUENE SULPHONIC ACID MONO HYDRATE 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 STOT Single 3 - H335 Classification (67/548/EEC) Xi;R36/37/38. The Full Text for all R-Phrases and Hazard Statements is Displayed in Section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation. Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort continues. Ingestion NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Get medical attention immediately! Skin Contact Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention promptly if symptoms occur after washing. Eye Contact Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Get medical attention immediately. Continue to rinse Most important symptoms and effects, both acute and delayed General Information The severity of the symptoms described will vary dependant of the concentration and the length of exposure. Inhalation. Difficulty in breathing. Coughing, chest tightness, feeling of chest pressure. Severe irritation in nose and throat. May cause an asthma-like shortness of breath. Headache. Nausea, vomiting. Ingestion May cause chemical burns in mouth and throat. Skin Contact May cause serious chemical burns to the skin. Eye Contact Eye contact may cause serious and potentially irreversible injuries. 2 / 7

10 CONBEXTRA EP10 HARDENER 4.3. Indication of any immediate medical attention and special treatment needed No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY! SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing Media This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials. Unsuitable Extinguishing Media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous Combustion Products In case of fire, toxic gases (CO, CO2, NOx) may be formed. Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted. Specific Hazards In case of fire, toxic gases may be formed Advice for firefighters Special Fire Fighting Procedures No specific fire fighting procedure given. Protective Measures In Fire Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Do not allow ANY environmental contamination Methods and material for containment and cleaning up DO NOT TOUCH SPILLED MATERIAL! Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area Reference to other sections For personal protection, see section 8. For waste disposal, see section 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Provide good ventilation. Avoid inhalation of vapours/spray and contact with skin and eyes Conditions for safe storage, including any incompatibilities Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Storage Class Corrosive storage Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Ingredient Comments No exposure limits noted for ingredient(s) Exposure controls 3 / 7

11 Protective Equipment CONBEXTRA EP10 HARDENER Process Conditions Provide eyewash, quick drench. Engineering Measures Provide adequate ventilation. Respiratory Equipment No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists. It is recommended to use respiratory equipment with combination filter, type A2/P2. Hand Protection Use suitable protective gloves if risk of skin contact. Polyvinyl chloride (PVC). Nitrile. Viton rubber (fluor rubber). Eye Protection If risk of splashing, wear safety goggles or face shield. Other Protection Wear appropriate clothing to prevent any possibility of skin contact. Use barrier creams to prevent skin contact. Hygiene Measures DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. Wash promptly with soap & water if skin becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke. Skin Protection Wear apron or protective clothing in case of splashes. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Colour Odour Solubility Liquid Colourless Amine. Ammonia Initial Boiling Point and Boiling >230 C Range: Relative Density C Vapour Pressure ph-value, Conc. Solution 11 Miscible with water Immiscible with water kpa Flash Point ( C) 110 C Auto Ignition Temperature ( C) 350 C Flammability Limit - Lower(%) 1.2 vol % 9.2. Other information Not available. SECTION 10: STABILITY AND REACTIVITY Reactivity Reaction with: Acids Chemical stability Stable under normal temperature conditions Possibility of hazardous reactions Reacts with Acids, Alkalis and Oxidising Agents Hazardous Polymerisation Will not polymerise Conditions to avoid 4 / 7

12 Avoid excessive heat for prolonged periods of time Incompatible materials Materials To Avoid Acids Strong oxidising substances Hazardous decomposition products In case of fire, toxic gases (CO, CO2, NOx) may be formed. SECTION 11: TOXICOLOGICAL INFORMATION CONBEXTRA EP10 HARDENER Information on toxicological effects Inhalation Harmful by inhalation. May cause damage to mucous membranes in nose, throat, lungs and bronchial system. Ingestion. Harmful if swallowed. May cause burns in mucous membranes, throat, oesophagus and stomach. Skin Contact Causes burns. Harmful in contact with skin. May cause sensitisation by skin contact. Eye Contact Causes burns. Health Warnings This substance is corrosive. Route of entry Inhalation. Ingestion. Skin and/or eye contact. Target Organs No specific target organs noted. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity: Harmful to aquatic organisms, may cause long term adverse effects in the aquatic environment Toxicity Acute Fish Toxicity Ecotoxic to fish/daphnia/algae Persistence and degradability Degradability: The product is not readily biodegradable Bioaccumulative potential Bioaccumulative Potential: No data available on bioaccumulation Mobility in soil Mobility: The product is insoluble in water Results of PBT and vpvb assessment This product does not contain any PBT or vpvb Substances Other adverse effects Not relevant. SECTION 13: DISPOSAL CONSIDERATIONS General Information When handling waste, consideration should be made to the safety precautions applying to handling of the product Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. Note that fully cured material is not considered as hazardous waste. 5 / 7

13 SECTION 14: TRANSPORT INFORMATION CONBEXTRA EP10 HARDENER UN number UN No. (ADR/RID/ADN) 2327 UN No. (IMDG) 2327 UN No. (ICAO) UN Proper shipping name Proper Shipping Name TRIMETHYLHEXAMETHYLENEDIAMINES 14.3 Transport hazard class(es) ADR/RID/ADN Class 8 ADR/RID/ADN Class Class 8: Corrosive substances. ADR Label No. 8 IMDG Class 8 ICAO Class/Division 8 Transport Labels Packing group ADR/RID/ADN Packing group IMDG Packing group ICAO Packing group III III III Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user EMS F-A, S-B Emergency Action Code 2X Hazard No. (ADR) 80 Tunnel Restriction Code (E) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not relevant. SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References The Control of Substances Hazardous to Health Regulations 2002 (S.I 2002 No. 2677) with amendments. Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations. Guidance Notes Workplace Exposure Limits EH40. 6 / 7

14 EU Legislation CONBEXTRA EP10 HARDENER Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. Water Hazard Classification WGK 2 Do not allow product to reach ground water, water course or sewage system Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION General Information The user must be instructed in the proper work procedure and be familiar with the contents of these instructions. Revision Comments NOTE: Lines within the margin indicate significant changes from the previous revision. Revision Date 8 May 2013 Revision 3 Risk Phrases In Full R34 R22 R52/53 R36/37/38 R43 Hazard Statements In Full H302 H314 H315 H317 H319 H335 H412 Causes burns. Harmful if swallowed. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Irritating to eyes, respiratory system and skin. May cause sensitisation by skin contact. Harmful if swallowed. Causes severe skin burns and eye damage. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. Harmful to aquatic life with long lasting effects. Disclaimer The information on this data sheet represents our current data and is reliable provided that the product is used under the prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. 7 / 7