SAFETY DATA SHEET COLPOR 200PF BASE

Transcription

1 SAFETY DATA SHEET COLPOR 200PF BASE 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NO. SUPPLIER M113061UKTAM1 EMERGENCY TELEPHONE HAZARDS IDENTIFICATION Fosroc Ltd Drayton Manor Business Park Coleshill Road Tamworth Staffordshire B77 2JU +44 (0) (0) uk@fosroc.com Repeated exposure may cause skin dryness or cracking. Limited evidence of a carcinogenic effect. May cause harm to breastfed babies. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. CLASSIFICATION (1/45) Carc. Cat. 3;R40. N;R50/53. R64, R66. 3 COMPOSITION/INFORMATION ON INGREDIENTS Name EC No. CAS-No. Content % Classification (67/548/EEC) CHLORINATED PARAFFIN (C14-17) % N;R50/53. R64,R66. HYDROCARBON AND AROMATIC HYDROCARBON OILS BLEND ALKANES, C10-C13, CHLORO % < 1% Xn;R65. Carc. Cat. 3;R40. N;R51/53. Carc. Cat. 3;R40 R66 N;R50/53 The Full Text for all R-Phrases is Displayed in Section 16 4 FIRST-AID MEASURES INHALATION Move into fresh air and keep at rest. In case of persistent throat irritation or coughing: Seek medical attention and bring these instructions. INGESTION Immediately rinse mouth and drink plenty of water. Keep person under observation. If person becomes uncomfortable seek hospital and bring these instructions. SKIN CONTACT Remove contaminated clothes and rinse skin thoroughly with water. EYE CONTACT Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids widely. If irritation persists: Continue flushing during transport to hospital. Bring these instructions. 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Use fire-extinguishing media appropriate for surrounding materials. SPECIFIC HAZARDS If heated, vapours/gases hazardous to health (e.g. CO, NOx, HCl, isocyanates) may be formed. PROTECTIVE MEASURES IN FIRE Use air-supplied respirator during fire fighting. 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Avoid inhalation of vapours and contact with skin and eyes. 1 / 4

2 COLPOR 200PF BASE ENVIRONMENTAL PRECAUTIONS Do not discharge into drains, water courses or onto the ground. SPILL CLEAN UP METHODS Absorb spillage with suitable absorbent material. For waste disposal, see section HANDLING AND STORAGE USAGE PRECAUTIONS Observe good chemical hygiene practices. Avoid inhalation of vapours and contact with skin and eyes. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. STORAGE PRECAUTIONS Store in closed original container in a dry place. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Name STD TWA - 8 Hrs STEL - 15 Min Notes ALUMINOSILICATE ZEOLITE A CALCIUM CARBONATE (STEARATE COATED) QUARTZ (CRYSTALLINE SILICA) MEL WEL WEL 10 mg/m3 Inhal. Dust 10 mg/m3 Inhal. Dust 4 mg/m3 Resp. Dust 4 mg/m3 Resp. Dust 0,1 mg/m3 SILICA (HYDROPHOBIC) WEL 4 mg/m3 Inhal. Dust 10 mg/m3 Resp. Dust WEL = Workplace Exposure Limit. PROTECTIVE EQUIPMENT ENGINEERING MEASURES Provide adequate ventilation. Observe Occupational Exposure Limits and minimise the risk of inhalation of vapours. RESPIRATORY EQUIPMENT In case of inadequate ventilation use suitable respirator. It is recommended to use respiratory equipment with combination filter, type A2/P2. HAND PROTECTION The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. EYE PROTECTION Goggles/face shield are recommended. HYGIENE MEASURES Remove contaminated clothing and wash the skin thoroughly with soap and water after work. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE ODOUR SOLUBILITY BOILING POINT ( C) > 200 RELATIVE DENSITY 1.4 FLASH POINT ( C) > STABILITY AND REACTIVITY Dark coloured liquid Almost odourless Insoluble in water STABILITY Stable under normal temperature conditions. CONDITIONS TO AVOID Water, moisture. MATERIALS TO AVOID Strong oxidising substances. 2 / 4

3 COLPOR 200PF BASE HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. 11 TOXICOLOGICAL INFORMATION INHALATION Unlikely to be hazardous by inhalation because of the low vapour pressure of the substance at ambient temperature. INGESTION Irritating. May cause nausea, stomach pain and vomiting. SKIN CONTACT Skin irritation is not anticipated when used normally. EYE CONTACT May cause temporary eye irritation. 12 ECOLOGICAL INFORMATION ECOTOXICITY Not determined. MOBILITY The product is insoluble in water. BIOACCUMULATION Not determined. DEGRADABILITY The product is not expected to be biodegradable. 13 DISPOSAL CONSIDERATIONS DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements. WASTE CLASS TRANSPORT INFORMATION PROPER SHIPPING NAME UN NO. ROAD ADR CLASS NO. ADR CLASS ADR PACK GROUP TUNNEL RESTRICTION CODE HAZARD No. (ADR) ADR LABEL NO. HAZCHEM CODE UN NO. SEA IMDG CLASS IMDG PACK GR. EMS UN NO. AIR AIR CLASS AIR PACK GR. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CHLORINATED PARAFFIN (C14-17), HYDROCARBON AND AROMATIC HYDROCARBON OILS BLEND) 3082 Class : Miscellaneous dangerous substances and articles. (E) 0 3Z 3082 F-A, S-F REGULATORY INFORMATION LABELLING 3 / 4

4 COLPOR 200PF BASE CONTAINS Harmful Dangerous for the environment HYDROCARBON AND AROMATIC HYDROCARBON OILS BLEND RISK PHRASES SAFETY PHRASES R40 Limited evidence of a carcinogenic effect. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R64 R66 May cause harm to breastfed babies. Repeated exposure may cause skin dryness or cracking. S36/37 Wear suitable protective clothing and gloves. S57 S60 S61 Use appropriate containment to avoid environmental contamination. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. 16 OTHER INFORMATION GENERAL INFORMATION Only trained personnel should use this material. DATE 30/11/2010 RISK PHRASES IN FULL R65 R40 R64 R66 R51/53 R50/53 Harmful: may cause lung damage if swallowed. Limited evidence of a carcinogenic effect. May cause harm to breastfed babies. Repeated exposure may cause skin dryness or cracking. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 4 / 4

5 REVISION DATE 25/07/2010 SAFETY DATA SHEET COLPOR 200PF CURING AGENT 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING SUPPLIER EMERGENCY TELEPHONE HAZARDS IDENTIFICATION FOSROC Limited Drayton Manor Business Park Coleshill Road Tamworth Staffordshire B78 3TL Tel. +44 (0) Fax. +44 (0) uk@fosroc.com Repeated exposure may cause skin dryness or cracking. May cause sensitisation by inhalation and skin contact. Limited evidence of a carcinogenic effect. May cause harm to breastfed babies. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. CLASSIFICATION (1/45) Xn;R48/20. Carc. Cat. 3;R40. R42/43. N;R50/53. R64, R66. ENVIRONMENT The product contains a substance which is harmful to aquatic organisms and which may cause long term adverse effects in the aquatic environment. 3 COMPOSITION/INFORMATION ON INGREDIENTS Name EC No. CAS-No. Content % Classification (67/548/EEC) CHLORINATED PARAFFIN (C14-17) % N;R50/53. R64,R66. DIPHENYLMETHANE DIISOCYANATE % Xn;R20,R48/20. Carc. Cat. 3;R40. Xi;R36/37/38. R42/43. The Full Text for all R-Phrases is Displayed in Section 16 4 FIRST-AID MEASURES INHALATION Move the exposed person to fresh air at once. Get medical attention. Provide rest, warmth and fresh air. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. INGESTION DO NOT INDUCE VOMITING! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Remove victim immediately from source of exposure. Get medical attention immediately! Provide rest, warmth and fresh air. SKIN CONTACT Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention promptly if symptoms occur after washing. EYE CONTACT Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Use fire-extinguishing media appropriate for surrounding materials. 6 ACCIDENTAL RELEASE MEASURES 1 / 4

6 REVISION DATE 25/07/2010 SPILL CLEAN UP METHODS COLPOR 200PF CURING AGENT Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers. Do not contaminate water sources or sewer. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. STORAGE PRECAUTIONS Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Name STD TWA - 8 Hrs STEL - 15 Min Notes DIPHENYLMETHANE DIISOCYANATE WEL 0.02 mg/m mg/m3 WEL = Workplace Exposure Limit. PROTECTIVE EQUIPMENT ENGINEERING MEASURES Provide adequate general and local exhaust ventilation. RESPIRATORY EQUIPMENT No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. HAND PROTECTION Use protective gloves. EYE PROTECTION Wear approved safety goggles. OTHER PROTECTION Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. HYGIENE MEASURES DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. Wash promptly with soap & water if skin becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE COLOUR ODOUR SOLUBILITY Viscous liquid Brown Musty (mouldy). Insoluble in water BOILING POINT ( C) > 200 RELATIVE DENSITY 1.25 FLASH POINT ( C) > STABILITY AND REACTIVITY STABILITY Stable under normal temperature conditions. CONDITIONS TO AVOID Avoid contact with acids and oxidising substances. HAZARDOUS DECOMPOSITION PRODUCTS Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). 2 / 4

7 REVISION DATE 25/07/2010 COLPOR 200PF CURING AGENT 11 TOXICOLOGICAL INFORMATION INHALATION Harmful by inhalation. May cause irritation to the respiratory system. INGESTION Harmful if swallowed. SKIN CONTACT Harmful in contact with skin. Irritating to skin. May cause sensitisation by skin contact. EYE CONTACT Irritating to eyes. TARGET ORGANS Skin Eyes Respiratory system, lungs 12 ECOLOGICAL INFORMATION ECOTOXICITY Harmful to aquatic organisms, may cause long term adverse effects in the aquatic environment 13 DISPOSAL CONSIDERATIONS DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements. WASTE CLASS * HCODE H14 14 TRANSPORT INFORMATION PROPER SHIPPING NAME UN NO. ROAD ADR CLASS NO. ADR PACK GROUP IMDG CLASS IMDG PACK GR. AIR CLASS AIR PACK GR. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CHLORINATED PARAFFIN) REGULATORY INFORMATION LABELLING CONTAINS Harmful Dangerous for the environment DIPHENYLMETHANE DIISOCYANATE RISK PHRASES R40 Limited evidence of a carcinogenic effect. R42/43 May cause sensitisation by inhalation and skin contact. SAFETY PHRASES R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R64 R66 S23 May cause harm to breastfed babies. Repeated exposure may cause skin dryness or cracking. Do not breathe vapour/spray. S36/37 Wear suitable protective clothing and gloves. 3 / 4

8 REVISION DATE 25/07/2010 STATUTORY INSTRUMENTS S38 S45 S57 S60 S61 COLPOR 200PF CURING AGENT The Chemicals (Hazard Information and Packaging for Supply) Regulations 200 (S.I 200 No. 716). APPROVED CODE OF PRACTICE Classification and Labelling of Substances and Preparations Dangerous for Supply. GUIDANCE NOTES Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. CHIP for everyone HSG(108). 16 OTHER INFORMATION In case of insufficient ventilation, wear suitable respiratory equipment. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). Use appropriate containment to avoid environmental contamination. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. GENERAL INFORMATION The user must be instructed in the proper work procedure and be familiar with the contents of these instructions. REVISION DATE 25/07/2010 REV. NO./REPL. SDS GENERATED RISK PHRASES IN FULL R20 R48/20 R36/37/38 R40 R64 R42/43 R66 R50/53 1 Harmful by inhalation. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. May cause harm to breastfed babies. May cause sensitisation by inhalation and skin contact. Repeated exposure may cause skin dryness or cracking. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. DISCLAIMER The information on this data sheet represents our current data and is reliable provided that the product is used under the prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. 4 / 4