SAFETY DATA SHEET according to regulation (EU) No. 453/2010

Transcription

1 KRAFFT, S.L. Unipersonal Carretera de Urnieta, s/n Apartado Andoain (Gipuzkoa) Phone: Fax: Emergency Telephone Number: (8:00-17:00 h.) (working hours) SAFETY DATA SHEET according to regulation (EU) No. 453/ IDENTIFICATION OFTHE PREPARATION Identification of the preparation: (RESIN) Recommended use: Epoxy resin Product code 35221, 35222, HAZARDS IDENTIFICATION Classification and labelling according to Directive 67/548/EEC Most Important Hazards: Highly flammable. Causes burns. May cause allergic skin reaction. Classification and labelling according to CLP (EC No.1272/2008) Classification: Flammable liquid, Category 2 Skin corrosion, Category 1A Eye irritation, Category 1 Skin sensitization, Category 1 Target Organ Systemic Toxicant - Single exposure, Category 3 Statements of hazard: Danger Highly flammable liquid and vapour Causes severe skin burns and eye damage May cause allergic skin reaction May cause respiratory irritation 1 of 5

2 (RESIN) Item No. VC0904C Precautions for safe handling: Keep out of the reach of children Keep away from heat/sparks/open flames/hot surface No smoking. Take precautionary measures against static discharge Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapours/spray Wear suitable gloves and eye/face protection Wash thoroughly after handling Contaminated work clothing should not be allowed out of the workplace 3. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight% EC Number EU Classification 67/548/EEC CHLOROSULFONATED POLYETHYLENE METHACRYLIC ACID FIRST-AID MEASURES General Information: Inhalation: CLP Classification EC No.1272/ F;R11 Flam. Liq. 2 R43 Skin Irrit. 2 Xi;R37/38 Skin Sens. 1 STOT SE 3: None None < C;R35 Xn;R21/22 Acute Tox. 4 Skin Corr. 1A Eye Dam. 1 STOT SE 3 If you feel unwell, seek medical advice (show the label where possible). Move to fresh air in case of accidental inhalation of vapours. Oxygen or artificial respiration if needed. Obtain medical attention. Skin Contact: Wash off with soap and water. Rinse immediately with plenty of water for at least 15 minutes. Obtain medical attention. Wash contaminated clothing before re-use. Eye Contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical attention is required. Ingestion: Protection of first-aiders: Notes to Physician: If swallowed, do not induce vomiting - seek medical advice. Use personal protective equipment. Avoid contact with skin, eyes and clothing. Treatment should be directed at preventing absorption, administering to symptoms (if they occur), and providing supportive therapy 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Extinguishing media which must not be used for safety reasons: Special instructions for protection and hygiene: Special protective equipment for firefighters: Carbon dioxide (CO2), Dry chemical, foam Flammable. Keep away from heat and sources of ignition. Use personal protective equipment Avoid contact with skin and eyes 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: For additional information on processing see sections 7, 8 and 11 of this safety data sheet. Environmental Precautions: Do not flush into surface water or sanitary sewer system. Cleanup: Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. 7. HANDLING AND STORAGE Handling precautions: Storage: Avoid breathing vapors or mists. Avoid contact with the skin and the eyes. Do not ingest. Wash thoroughly after handling. Wash contaminated clothing before reuse. Store in cool place. Keep away from heat and sources of ignition. 2 of 5

3 (RESIN) Item No. VC0904C 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Component ACGIH; TLV-TWA German MAK; TWA UK WEL; TWA Finnish OEL; HTP 50 ppm 50 ppm; 210 mg/m 3 50 ppm; 208 mg/m 3 10 ppm; 42 mg/m 3 CHLOROSULFONATED Not listed Not listed Not listed Not listed POLYETHYLENE METHACRYLIC ACID ppm 5 ppm; 18 mg/m 3 20 ppm; 72 mg/m 3 8h: 20 ppm; 71 mg/m 3 Ventilation: Respiratory Protection: Skin: Eyes: Hygiene Measures: Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. In case of insufficient ventilation, wear suitable respiratory equipment. Neoprene or nitrile gloves recommended. Wash contaminated clothing before re-use. Safety glasses with side-shields When using, do not eat, drink or smoke. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: White paste Odor: Resin odor ph: (5% solution) Boiling point/range: 100 C (212 F) Melting point: Flash point: 10 C. Risk of explosion: Flammable. Keep away from heat and sources of ignition. Vapor pressure: C Density: 1.03 Solubility in water: Partition coefficient (noctanol/water): Vapor density: >1 (Air = 1) Evaporation Rate: >1.0 (butyl acetate = 1) VOC Content(%): <50 g/l 10. STABILITY/REACTIVITY Stability: Conditions to Avoid: Materials to avoid: Hazardous decomposition products: Stable at normal conditions. Heat. Inert gas blanketing. Freezing. Strong oxidizing agents, Strong bases, Acids, Reducing agents Carbon oxides 11. TOXICOLOGICAL INFORMATION Component Weight% LD50/oral/rat LD50/dermal/rabbit LC50/inhalation/rat IARC Carcinogen mg/kg >5 g/kg 4632 ppm/4h; 400 ppm/1h Group 3: Monograph 60, 1994 METHACRYLIC ACID < mg/kg 500 mg/kg 7.1 mg/l/4h Local Effects Skin Irritation: Eye Irritation: Inhalation: Ingestion: Sensitization: Chronic toxicity: Specific Effects Causes burns. May cause allergic skin reaction. Severe eye irritation. Inhalation of vapours is irritating to the respiratory system, may cause throat pain and cough. Harmful if swallowed May cause sensitization of susceptible persons by skin contact. Possible risks of irreversible effects.. 3 of 5

4 (RESIN) Item No. VC0904C Carcinogenic effects: Mutagenic effects: Reproductive toxicity: Target Organ Effects:. Eyes, Skin, Respiratory System, Gastrointestinal Tract 12. ECOLOGICAL INFORMATION Ecotoxicity: No information available 13. DISPOSAL CONSIDERATIONS Waste from Residues: According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user based on the application for which the product was used. 14. TRANSPORT INFORMATION IATA (Air) Proper Shipping Name: Consumer Commodity Hazard Class: Class 9 UN/ID No: ID 8000 IMDG (Vessel) Proper shipping name: Adhesives, containing flammable liquid, Limited Quantity Hazard Class: Class 3, PG II UN/ID No: UN 1133 Marine Pollutant: None ADR/RID Proper Shipping Name: Adhesives, containing flammable liquid Hazard Class: Class 3, PG II UN/ID No: UN 1133 ADR/RID: Limited Quantity; LQ6 15. REGULATORY INFORMATION This product is classified in accordance with Annex VI to Directive 67/548/EEC Contains epoxy constituents: See information supplied by the manufacturer. Indication of Danger: F - Highly flammable, C - Corrosive Names of the ingredients given on the warning label: Methacrylic acid, Methyl methacrylate R -phrase(s): R11 - Highly flammable R34 - Causes burns R43 - May cause sensitization by skin contact S -phrase(s): S 2 - Keep out of the reach of children S16 - Keep away from sources of ignition - No smoking S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S36/39 - Wear suitable protective clothing and eye/face protection S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) 16. OTHER INFORMATION Risk Phrases mentioned in Section 3: R11 - Highly flammable. R35 - Causes severe burns. R43 - May cause sensitization by skin contact. R21/22 - Harmful in contact with skin and if swallowed. R37/38 - Irritating to respiratory system and skin. 4 of 5

5 (RESIN) Item No. VC0904C 16. OTHER INFORMATION Prepared By: Denise Boyd, Manager- Environmental, Health & Safety Company: ITW Permatex 10 Columbus Blvd. Hartford, CT USA Telephone: Revision Date: March 30, 2012 Revision Number: 7 5 of 5

6 KRAFFT, S.L. Unipersonal Carretera de Urnieta, s/n Apartado Andoain (Gipuzkoa) Phone: Fax: Emergency Telephone Number: (8:00-17:00 h.) (working hours) SAFETY DATA SHEET according to regulation (EU) No. 453/ IDENTIFICATION OFTHE PREPARATION Identification of the preparation: (HARDENER) Recommended use: Curing chemical Product code 35221, 35222, HAZARDS IDENTIFICATION Classification and labelling according to Directive 67/548/EEC Most Important Hazards: Highly flammable. Irritating to respiratory system and skin. May cause allergic skin reaction. Classification and labelling according to CLP (EC No.1272/2008) Classification: Flammable liquid, Category 2 Skin irritation, Category 2 Skin sensitization, Category 1 Target Organ Systemic Toxicant - Single exposure, Category 3 Statements of hazard: Highly flammable liquid and vapour Causes skin irritation May cause allergic skin reaction May cause respiratory irritation 1 of 4

7 (HARDENER) Item No. VC0905C Precautions for safe handling: Keep out of the reach of children Keep away from heat/sparks/open flames/hot surface No smoking. Take precautionary measures against static discharge Use only outdoors or in a well-ventilated area Avoid breathing vapors or mists Wash thoroughly after handling Wear protective gloves/clothing and eye/face protection Contaminated work clothing should not be allowed out of the workplace 3. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight% EC Number EU Classification 67/548/EEC 3,5-DIETHYL-1,2-DIHYDRO-1- PHENYL-2-PROPYLPYRIDINE CLP Classification EC No.1272/2008 > F;R11 Flam. Liq. 2 R43 Skin Irrit. 2 Xi;R37/38 Skin Sens. 1 STOT SE 3: < None None 4. FIRST-AID MEASURES General Information: Inhalation: Skin Contact: Eye Contact: Ingestion: Protection of first-aiders: If you feel unwell, seek medical advice (show the label where possible). Move to fresh air in case of accidental inhalation of vapours. Obtain medical attention. Wash off with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before re-use. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If swallowed, do not induce vomiting - seek medical advice. Use personal protective equipment. Avoid contact with skin, eyes and clothing. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media: Extinguishing media which must not be used for safety reasons: Special instructions for protection and hygiene: Special protective equipment for firefighters: Carbon dioxide (CO2), Dry chemical, foam Flammable. Keep away from heat and sources of ignition. Use personal protective equipment Avoid contact with skin and eyes 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: For additional information on processing see sections 7, 8 and 11 of this safety data sheet. Environmental Precautions: Do not flush into surface water or sanitary sewer system. Cleanup: Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. 7. HANDLING AND STORAGE Handling precautions: Storage: Keep away from sources of ignition - No smoking. Avoid breathing vapors or mists. Avoid contact with the skin and the eyes. Wash thoroughly after handling. Wash contaminated clothing before reuse. Store in cool place. Keep away from heat and sources of ignition. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Component ACGIH; TLV-TWA German MAK; TWA UK WEL; TWA Finnish OEL; HTP 50 ppm 50 ppm; 210 mg/m 3 50 ppm; 208 mg/m 3 10 ppm; 42 mg/m 3 2 of 4

8 (HARDENER) Item No. VC0905C 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Component ACGIH; TLV-TWA German MAK; TWA UK WEL; TWA Finnish OEL; HTP 3,5-DIETHYL-1,2-DIHYDRO-1- PHENYL-2-PROPYLPYRIDINE Not listed Not listed Not listed Not listed Ventilation: Respiratory Protection: Skin: Eyes: Hygiene Measures: Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. In case of insufficient ventilation, wear suitable respiratory equipment. Neoprene or nitrile gloves recommended. Safety glasses When using, do not eat, drink or smoke. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: White paste Odor: Methacrylate ph: (5% solution) Boiling point/range: 100 C (212 F) Melting point: Flash point: 7 C. Risk of explosion: Flammable. Keep away from heat and sources of ignition. Vapors are heavier than air and may spread along floors. Vapor pressure: C Density: 0.96 Solubility in water: Partition coefficient (noctanol/water): Vapor density: >1 (Air = 1) Evaporation Rate: >1.0 (butyl acetate = 1) VOC Content(%): <50 g/l 10. STABILITY/REACTIVITY Stability: Conditions to Avoid: Materials to avoid: Hazardous decomposition products: Stable at normal conditions. Heat. Inert gas blanketing. Freezing. Strong oxidizing agents, Strong bases, Reducing agents, Acids Carbon oxides, Nitrogen oxides (NOx) 11. TOXICOLOGICAL INFORMATION Component Weight% LD50/oral/rat LD50/dermal/rabbit LC50/inhalation/rat IARC Carcinogen > mg/kg >5 g/kg 4632 ppm/4h; 400 Group 3: Monograph ppm/1h 60, 1994 Local Effects Skin Irritation: Eye Irritation: Inhalation: Ingestion: Sensitization: Chronic toxicity: Specific Effects Carcinogenic effects: Mutagenic effects: Reproductive toxicity: Target Organ Effects: May cause skin irritation and/or dermatitis. May cause allergic skin reaction. Irritating, but will not permanently injure eye tissue. May cause irritation of respiratory tract. Irritating to mouth, throat and stomach. May cause sensitization of susceptible persons by skin contact... Eyes, Skin, Respiratory System 3 of 4

9 (HARDENER) Item No. VC0905C 12. ECOLOGICAL INFORMATION Ecotoxicity: No information available 13. DISPOSAL CONSIDERATIONS Waste from Residues: According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user based on the application for which the product was used. 14. TRANSPORT INFORMATION IATA (Air) Proper Shipping Name: Consumer Commodity Hazard Class: Class 9 UN/ID No: ID 8000 IMDG (Vessel) Proper shipping name: Adhesives, containing flammable liquid, Limited Quantity Hazard Class: Class 3, PG II UN/ID No: UN 1133 Marine Pollutant: None ADR/RID Proper Shipping Name: Adhesives, containing flammable liquid Hazard Class: Class 3, PG II UN/ID No: UN 1133 ADR/RID: Limited Quantity; LQ6 15. REGULATORY INFORMATION This product is classified in accordance with Annex VI to Directive 67/548/EEC Indication of Danger: F - Highly flammable, Xi - Irritant R -phrase(s): R11 - Highly flammable R37/38 - Irritating to respiratory system and skin R43 - May cause sensitization by skin contact S -phrase(s): S 2 - Keep out of the reach of children S16 - Keep away from sources of ignition - No smoking S24 - Avoid contact with skin S36/37 - Wear suitable protective clothing and gloves 16. OTHER INFORMATION Risk Phrases mentioned in Section 3: R11 - Highly flammable. R43 - May cause sensitization by skin contact. R37/38 - Irritating to respiratory system and skin. Prepared By: Denise Boyd, Manager- Environmental, Health & Safety Company: ITW Permatex 10 Columbus Blvd. Hartford, CT USA Telephone: Revision Date: March 30, 2012 Revision Number: 7 4 of 4