Safety Data Sheet in Accordance with regulation 453/2010 Page 1 of 6

Transcription

1 Safety Data Sheet in Accordance with regulation 453/2010 Page 1 of 6 Date of issue : Replaces Data Sheet of : --- "*" alterations as compared to previous version; n.ap. = not applicable; = not available SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade Name : J-B Weld Epoxy Adhesive Resin Article No. : Preparation No. : Registration No. : 1.2 Relevant identified uses of the substance or mixture and uses advised against Use: adhesives 1.3 Details of the supplier of the safety data sheet Address of the Company / Supplier : J-B Weld; Unit 30, Bidavon Industrial Estate, Bidford-Upon-Avon, Warwickshire, B50 4JN, UK Telephone : (UK) , sales@jb-weld.co.uk Responsible for the data sheet : CoSiChem AG, Ernst-Lemmer-Straße 27, D Marburg, info@cosichem.de 1.4 Emergency telephone number Emergency - Telephone of Company / Supplier Telephone : (8:30 16:30) SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification and labelling according to Directive 1272/2008/EC: Classification and labelling according to Directive 67/548/EEC / 1999/45/EC: Irritant / Sensitizing / N - Dangerous for the environment 2.2 Label elements Classification according to EEC - Regulations : Yes. Applicable Exemptions : No. Hazard Identification : Irritant & Dangerous for the environment Hazard Symbol(s) : Component(s) : contains 4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane (Resin, Bisphenol-A-Epichlorhydrin) R - Phrases : R 36/38: Irritating to eyes and skin. R 43: May cause sensitization by skin contact. R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S - Phrases : S 2: Keep out of reach of children. S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 29/35 - Do not empty into drains; dispose of this material and its container in a safe way. S 37 / 39: Wear suitable gloves and eye / face protection. S 46: If swallowed, seek medical advice immediately and show this container or label. S 51: Use only in well-ventilated areas. S 61: Avoid release to the environment. refer to special instructions / Safety data sheets. Additional Markings : The above mentioned labelling is valid for distribution to private consumer. 2.3 Other hazards May cause irritation of respiratory tract. May be harmful if swallowed. Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product. Contains epoxy resin, which might cause skin problems with people who earlier had obtained epoxy allergy.

2 Safety Data Sheet in Accordance with regulation 453/2010 Page 2 of 6, SECTION 3: Composition/information on ingredients 3.1 Substances Dangerous Ingredients : 3.2 Mixtures Chemical Characterisation : Polymer suspension Dangerous Ingredients : CAS - No. Index - No. EEC - No. Material m% - range Symbol R / H - phrases ,4'-Isopropylidenediphenol, 10-30% Xi, N R 36/ /53 oligomeric reaction products with 1-chloro-2,3-epoxypropane GHS07 GHS09 H319 H315 H317 H411 SECTION 4: First aid measures 4.1 Description of first aid measures Inhalation : Move to fresh air in case of accidental inhalation of fumes from overheating or combustion Skin Contact : Wash off with warm water and soap. If skin irritation persists, call a physician Eye Contact : In case of eye contact, remove contact lens and rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists, consult a specialist. Show this safety data sheet to the doctor in attendance Ingestion : Clean mouth with water and afterwards drink plenty of water. Do not induce vomiting. Consult a physician. Show this safety data sheet to the doctor in attendance. 4.2 Most important symptoms and effects, both acute and delayed Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. Effects of skin contacts may include: redness, irritation. Eye contact: redness, lachrymation. 4.3 Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable Extinguishing Media : Use dry chemical, CO 2, water spray or "alcohol" foam Extinguishing Media to Avoid : High volume water jet. 5.2 Special hazards arising from the substance or mixture In the event of fire the following can be released: Carbon oxides, halogenated hydrocarbon 5.3 Advice for firefighters Special Protective Equipment : Wear positive pressure self-contained breathing apparatus. Wear full protective clothing Additional Information : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire, cool tanks with water spray. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures See chapter Contaminated surfaces will be extremely slippery. 6.2 Environmental precautions Do not contaminate water. Do not let product enter drains. Local authorities should be advised if significant spillages cannot be contained. 6.3 Methods and material for containment and cleaning up Pick up and transfer to properly labelled containers. Use approved industrial vacuum cleaner for removal. Dispose of wastes in an approved waste disposal facility. 6.4 Reference to other sections

3 Safety Data Sheet in Accordance with regulation 453/2010 Page 3 of 6 SECTION 7: Handling and storage 7.1 Precautions for safe handling Precautions for Safe Handling : Avoid contact with skin and eyes. Remove and wash contaminated clothing before re-use. When using, do not eat, drink or smoke. Wash hands before breaks and at the end of workday. Contains high molecular weight epoxy resin, which might cause skin problems with people who earlier had obtained epoxy allergy Precautions in Case of Fire and Explosion : Normal measures for preventive fire protection. Do not smoke. 7.2 Conditions for safe storage, including any incompatibilities Storage Instructions : Keep container tightly closed in a dry and well-ventilated place. Store in original container. Keep at temperatures below 35 C. Handle and open container with care. Do not re-use empty containers Store away from : Do not store together with oxidizing agents Further Information on Storage Conditions : 7.3 Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1 Control parameters Material Limit Value 8.2 Exposure controls Appropriate engineering controls Provide appropriate exhaust ventilation at machinery Individual protection measures 8.2.2a Respiratory Not required under normal use Protection : 8.2.2b Hand Protection : Protective gloves complying with EN 374. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time c Eye Protection : Safety glasses 8.2.2d Skin Protection : Long sleeved clothing Environmental exposure controls : Do not contaminate water.

4 Safety Data Sheet in Accordance with regulation 453/2010 Page 4 of 6 SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Form : paste Colour : Odour : sweet ph-value, undiluted :, ph-value, 1% aqueous solution : Boiling point / Boiling - range ( C) :, Melting point / Melting range ( C) : Flash point ( C, c.c.) : > 93, Flammability (EEC A10/A13) : No Ignition temperature ( C) : Autoflammability (EEC A16) : No Oxidising properties : No Explosion hazard : No Explosion limits (Vol.%) lower :, upper : Vapour pressure : Density (g/ml) : 1, Solubility (in Water) : immiscible Partition coefficient, n-octanol/water : Viscosity : Solvent content (m %) : 9.2 Other information Thermal decomposition ( C) : > Vapour density (Air = 1) : SECTION 10: Stability and reactivity 10.1 Reactivity 10.2 Chemical stability Stable under recommended storage conditions Possibility of hazardous reactions No hazards to be specially mentioned Conditions to avoid Keep away from heat and sources of ignition Incompatible materials Incompatible with oxidizing agents. Incompatible with strong acids and bases Hazardous decomposition products No decomposition if stored and applied as directed. To avoid thermal decomposition, do not overheat. SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute Health Effects : Inhalation, LC50 rat, (mg/l/4h) : Ingestion, LD50 rat, (mg/kg) : Skin - contact, LD50 rat, (mg/kg) : Irritation (to skin / eye) : Irritating to eyes and skin. Sensitisation : May cause sensitisation by skin contact Subacute / Chronic Toxicity : Carcinogenicity : Mutagenicity : Teratogenicity : Narcotic Effects : No Practical Experience Observations relevant for classification : Further Observations : Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in non-allergic contact dermatitis and absorption through the skin General Remarks : Classification of the preparation has been done by calculation in accordance with EEC directives.

5 Safety Data Sheet in Accordance with regulation 453/2010 Page 5 of 6 SECTION 12: Ecological information 12.1 Toxicity Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. We have no quantitative data concerning the ecological effects of this product Persistence and degradability No data is available on the product itself Bioaccumulative potential: n.v Mobility in soil: n.v Results of PBT and vpvb assessment: n.v Other adverse effects COD-Value, mg/g : BOD5-Value, mg/g : AOX-Remarks : The product contains organic halogens Significant Components : 4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane Other adverse effects : Not applicable. SECTION 13: Disposal considerations 13.1 Waste treatment methods Recommendation : Waste - Code - No. : The Waste code should be assigned in discussion between the user, the producer and the waste disposal company. In addition comply with the regional authorities Contaminated Packaging Recommendation : Wash with suitable cleaner. Otherwise as described under Residues Safe Handling : As described under Residues. SECTION 14: Transport information ADR IMDG IATA 14.1 UN number UN proper shipping name UN 3082 Environmentally hazardous substance, liquid, n.o.s. (Contains: Resin, Bisphenol A-Epichlorhydrin) 14.3 Transport hazard class(es) Environmentally hazardous substance, liquid, n.o.s. (Contains: Resin, Bisphenol A- Epichlorhydrin) Miscellaneous Environmentally hazardous substance, liquid, n.o.s. (Contains: Resin, Bisphenol A-Epichlorhydrin) Miscellaneous 14.4 Packing group III III III 14.5 Environmental hazards 14.6 Special precautions for user Transport-category : 3 Classification Code : M6 Hazard - No.: 90 LQ: 5 L No. F-A, S-F 14.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Packing Instructions (Passenger): 964 Packing Instructions (Cargo): 964

6 Safety Data Sheet in Accordance with regulation 453/2010 Page 6 of 6 SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture No data available Chemical safety assessment : SECTION 16: Other information Text of R / H phrases mentioned in Section 3 R 36/38: Irritating to eyes and skin. R 43: May cause sensitization by skin contact. R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. H 315: Causes skin irritation. H 317: May cause an allergic skin reaction. H 319: Causes serious eye irritation. H 411: Toxic to aquatic life with long lasting effects. The statements in this Material Safety Data Sheet were made to the best of our knowledge and are as accurate as possible. They are given for information only. They do not constitute a contractual guarantee of a product s properties. They must neither be altered nor transferred to other products. Prepared by : CoSiChem AG, Ernst-Lemmer-Straße 27, D Marburg, ( Receipt of Data : , unl_0012_a