1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product name: SAFE STEP HEAVY DUTY EPOXY REPAIR COMPOUND - BASE
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1 SAFE STEP HEAVY DUTY EPOXY REPAIR COMPOUND - BASE Page 1 Issued: 08/09/2003 Revision No: 1 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product name: SAFE STEP HEAVY DUTY EPOXY REPAIR COMPOUND - BASE Product code: Company name: 42036A ROCOL Site Safety Systems ROCOL House Swillington Leeds West Yorkshire LS26 8BS ENGLAND Tel: +44 (0) Fax: +44 (0) Emergency tel: +44 (0) COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients: BISPHENOL A-(EPICHLORHYDRIN) {REACTION PRODUCT} 50-70% EINECS: CAS: [Xi] R36/38; [Sens.] R43; [N] R51/53 BISPHENOL F - EPOXY RESIN 10-30% [Xi] R36/38; [N] R51/53 ALKYL GLYCIDYL ETHER 10-30% CAS: [Xi] R36/38; [Sens.] R43; [N] R51/53 3. HAZARDS IDENTIFICATION Main hazards: Irritating to eyes and skin. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic 4. FIRST AID MEASURES (SYMPTOMS) Skin contact: There may be irritation and redness at the site of contact. There may be irritation and redness. The eyes may water profusely. There may be soreness and redness of the mouth and throat. Exposure may cause coughing or wheezing. 4. FIRST AID MEASURES (ACTION) Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash immediately with plenty of soap and water. Obtain medical attention if soreness or redness persists. Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist examination. Do not induce vomiting. Wash out mouth with water. Seek medical attention if you feel unwell. Remove casualty from exposure ensuring one's own safety whilst doing so. Seek medical attention if you feel unwell. 5. FIRE-FIGHTING MEASURES Extinguishing media: Dry chemical powder. Carbon dioxide. Use water spray to cool containers. Exposure hazards: Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Refer to section 8 of SDS for personal protection details. Turn leaking containers leak-side up Environmental precautions: Clean-up procedures: to prevent the escape of liquid. Do not discharge into drains or rivers. Mix with sand or vermiculite. Transfer to a closable, labelled salvage container for disposal by an appropriate method.
2 SAFE STEP HEAVY DUTY EPOXY REPAIR COMPOUND - BASE Page 2 7. HANDLING AND STORAGE Handling requirements: Ensure there is sufficient ventilation of the area. Storage conditions: Suitable packaging: Store in cool, well ventilated area. Keep container tightly closed. Must only be kept in original packaging. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures: Ensure there is sufficient ventilation of the area. Respiratory protection: Hand protection: Eye protection: Skin protection: Self-contained breathing apparatus must be available in case of emergency. Protective gloves. Safety glasses with side-shields. Ensure eye bath is to hand. Protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES State: Liquid Colour: Odour: Solubility in water: Colourless Barely perceptible odour Insoluble Boiling point/range C: >200 Flash point C: >130 Relative density: STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to avoid: Materials to avoid: Haz. decomp. products: Direct sunlight. Heat. Strong oxidising agents. Strong acids. 11. TOXICOLOGICAL INFORMATION Hazardous ingredients: BISPHENOL A-(EPICHLORHYDRIN) {REACTION PRODUCT} ORL MUS LD mg/kg ORL RAT LD mg/kg SKN RBT LD50 >20 ml/kg 12. ECOLOGICAL INFORMATION Mobility: Insoluble in water. Persistence and degradability: Bioaccumulative potential: Other adverse effects: Not biodegradable. No data available. Toxic to aquatic organisms. 13. DISPOSAL CONSIDERATIONS NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. 14. TRANSPORT INFORMATION ADR / RID UN no: 3082 ADR Class: 9 Packing group: III Classification code: M6 Shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL A-(EPICHLORHYDRIN) {REACTION PRODUCT}) Labelling: 9 Hazard ID no: 90
3 SAFE STEP HEAVY DUTY EPOXY REPAIR COMPOUND - BASE Page 3 IMDG / IMO IATA / ICAO UN no: 3082 Class: 9 Packing group: III EmS: F-A,S-F Marine pollutant:. Labelling: 9 UN no: 3082 Class: 9 Packing group: III Packing instructions: 914 Labelling: REGULATORY INFORMATION Hazard symbols: Dangerous for the Irritant. Risk phrases: Safety phrases: R36/38: Irritating to eyes and skin. R43: May cause sensitisation by skin contact. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic S24/25: Avoid contact with skin and eyes. S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37: Wear suitable gloves. S57: Use appropriate container to avoid environmental contamination. S35: This material and its container must be disposed of in a safe way. Precautionary phrases: Contains epoxy constituents. See information supplied by the manufacturer. Note: The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. 16. OTHER INFORMATION Other information: EC Directive 1999/45/EC relating to the classification, packaging and labelling of dangerous Risk phrases used in s.2: Legal disclaimer: preparations. EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of specific information relating to dangerous preparations. R36/38: Irritating to eyes and skin. R43: May cause sensitisation by skin contact. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. [final page]
4 SAFE STEP HEAVY DUTY EPOXY REPAIR COMPOUND - HARDENER Page 1 Issued: 08/09/2003 Revision No: 1 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product name: SAFE STEP HEAVY DUTY EPOXY REPAIR COMPOUND - HARDENER Product code: Company name: 42036B ROCOL Site Safety Systems ROCOL House Swillington Leeds West Yorkshire LS26 8BS ENGLAND Tel: +44 (0) Fax: +44 (0) Emergency tel: +44 (0) COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients: 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE 10-30% EINECS: CAS: [Xn] R21/22; [C] R34; [Sens.] R43; [-] R52/53 BENZYL ALCOHOL 10-30% EINECS: CAS: [Xn] R20/22 POLYETHERDIAMINE 1-10% CAS: Preparation [C] R34 PARATERTIARY BUTYL PHENOL 1-10% CAS: [Xi] R36/37/38; [Sens.] R43; [N] R51/53 NONYLPHENOL 1-10% EINECS: CAS: [Xn] R22; [C] R34; [N] R50/53 TRIMETHYL HEXAMETHYLENE DIAMINE 1-10% CAS: [Xn] R22; [Sens.] R43; [C] R34; [-] R52/53 BENZENE 1,3 - DIMETHANAMINE 1-10% CAS: [Xn] R20/22; [C] R35 2-PIPERAZIN-1-YLETHYLAMINE 1-10% EINECS: CAS: [Xn] R21/22; [C] R34; [Sens.] R43; [-] R52/53 3. HAZARDS IDENTIFICATION Main hazards: Harmful by inhalation, in contact with skin and if swallowed. Causes burns. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic 4. FIRST AID MEASURES (SYMPTOMS) Skin contact: There may be irritation and redness at the site of contact. There may be irritation and redness. The eyes may water profusely. There may be soreness and redness of the mouth and throat. Nausea and stomach pain may occur. There may be vomiting. There may be irritation of the throat with a feeling of tightness in the chest.
5 SAFE STEP HEAVY DUTY EPOXY REPAIR COMPOUND - HARDENER Page 2 4. FIRST AID MEASURES (ACTION) Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin. Obtain medical attention if soreness or redness persists. Bathe the eye with running water for 15 minutes. Consult a doctor. Wash out mouth with water. Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Consult a doctor. Remove casualty from exposure ensuring one's own safety whilst doing so. Seek medical attention if you feel unwell. 5. FIRE-FIGHTING MEASURES Extinguishing media: Dry chemical powder. Water spray. Water fog. Use water spray to cool containers. Exposure hazards: Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Refer to section 8 of SDS for personal protection details. Turn leaking containers leak-side up Environmental precautions: Clean-up procedures: to prevent the escape of liquid. Do not discharge into drains or rivers. Contain the spillage using bunding. Mix with sand or vermiculite. Transfer to a closable, labelled salvage container for disposal by an appropriate method. 7. HANDLING AND STORAGE Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do Storage conditions: Suitable packaging: not handle in a confined space. Store in cool, well ventilated area. Keep container tightly closed. Must only be kept in original packaging. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering measures: Ensure there is sufficient ventilation of the area. Respiratory protection: Hand protection: Eye protection: Skin protection: Self-contained breathing apparatus must be available in case of emergency. Protective gloves. Safety glasses with side-shields. Ensure eye bath is to hand. Protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES State: Liquid Colour: Odour: Solubility in water: Colourless Characteristic odour Insoluble Boiling point/range C: >200 Flash point C: >100 Autoflammability C: >350 Relative density: STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to avoid: Materials to avoid: Haz. decomp. products: Heat. Direct sunlight. Strong oxidising agents. Strong acids. 11. TOXICOLOGICAL INFORMATION Hazardous ingredients: BENZYL ALCOHOL IVN RAT LD50 53 mg/kg ORL MUS LD mg/kg ORL RAT LD mg/kg
6 SAFE STEP HEAVY DUTY EPOXY REPAIR COMPOUND - HARDENER Page 3 Chronic toxicity: Routes of exposure: NONYLPHENOL ORL MUS LD mg/kg ORL RAT LD mg/kg 2-PIPERAZIN-1-YLETHYLAMINE IPR MUS LD mg/kg ORL RAT LD µl/kg May cause sensitisation by skin contact. 12. ECOLOGICAL INFORMATION Mobility: Readily absorbed into soil. Persistence and degradability: Other adverse effects: Refer to section 4 of SDS for routes of exposure and corresponding symptoms. No data available. Toxic to aquatic organisms. 13. DISPOSAL CONSIDERATIONS NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. 14. TRANSPORT INFORMATION ADR / RID UN no: 2735 ADR Class: 8 Packing group: III Classification code: C7 Shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (Isophorone Diamine and p-tert butylphenol) Labelling: 8 Hazard ID no: 80 IMDG / IMO IATA / ICAO UN no: 2735 Class: 8 Packing group: III EmS: F-A,S-B Marine pollutant:. Labelling: 8 UN no: 2735 Class: 8 Packing group: III Packing instructions: 818(P&CA); 820(CAO) Labelling: REGULATORY INFORMATION Hazard symbols: Corrosive. Dangerous for the Risk phrases: Safety phrases: R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. R34: Causes burns. R43: May cause sensitisation by skin contact. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39: Wear suitable protective clothing, gloves and eye / face protection. S28: After contact with skin, wash immediately with plenty of soap and water.
7 SAFE STEP HEAVY DUTY EPOXY REPAIR COMPOUND - HARDENER Page 4 Note: S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S57: Use appropriate container to avoid environmental contamination. S35: This material and its container must be disposed of in a safe way. The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. 16. OTHER INFORMATION Other information: Product label needs to specify: Contains Isophorone Diamine and Benzyl Alcohol. EC Directive Risk phrases used in s.2: Legal disclaimer: 1999/45/EC relating to the classification, packaging and labelling of dangerous preparations. EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of specific information relating to dangerous preparations. R21/22: Harmful in contact with skin and if swallowed. R34: Causes burns. R43: May cause sensitisation by skin contact. R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic R20/22: Harmful by inhalation and if swallowed. R36/37/38: Irritating to eyes, respiratory system and skin. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic R22: Harmful if swallowed. R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic R35: Causes severe burns. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. [final page]
8 SAFE STEP HEAVY DUTY EPOXY REPAIR COMPOUND - FILLER Page 1 Issued: 10/09/2003 Revision No: 1 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product name: SAFE STEP HEAVY DUTY EPOXY REPAIR COMPOUND - FILLER Product code: Company name: 42036C ROCOL Site Safety Systems ROCOL House Swillington Leeds West Yorkshire LS26 8BS ENGLAND Tel: +44 (0) Fax: +44 (0) Emergency tel: +44 (0) COMPOSITION / INFORMATION ON INGREDIENTS Contains: NON-HAZARDOUS SUBSTANCE 1-100% 3. HAZARDS IDENTIFICATION Main hazards: No significant hazard. 4. FIRST AID MEASURES (SYMPTOMS) Skin contact: There may be mild irritation at the site of contact. There may be irritation and redness. There may be irritation of the throat. There may be irritation of the throat with a feeling of tightness in the chest. 4. FIRST AID MEASURES (ACTION) Skin contact: Wash immediately with plenty of soap and water. Bathe the eye with running water for 15 minutes. Wash out mouth with water. Remove casualty from exposure ensuring one's own safety whilst doing so. Seek medical attention if you feel unwell. 5. FIRE-FIGHTING MEASURES Extinguishing media: Dry chemical powder. Water spray. Water fog. Exposure hazards: Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Refer to section 8 of SDS for personal protection details. Environmental precautions: Clean-up procedures: Do not discharge into drains or rivers. Wash the spillage site with large amounts of water. 7. HANDLING AND STORAGE Handling requirements: Avoid the formation or spread of dust in the air. Storage conditions: Store in cool, well ventilated area. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Respiratory protection: Self-contained breathing apparatus must be available in case of emergency. Hand protection: Eye protection: Skin protection: Protective gloves. Safety glasses with side-shields. Ensure eye bath is to hand. Protective clothing.
9 Issued: 10/09/2003 SAFE STEP HEAVY DUTY EPOXY REPAIR COMPOUND - FILLER Page 2 9. PHYSICAL AND CHEMICAL PROPERTIES State: Powder Colour: Odour: Solubility in water: Beige Odourless Insoluble Flash point C: >130 Autoflammability C: > STABILITY AND REACTIVITY Stability: Stable under normal conditions. Conditions to avoid: Materials to avoid: Haz. decomp. products: Heat. Strong oxidising agents. Strong acids. 11. TOXICOLOGICAL INFORMATION Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding symptoms. 12. ECOLOGICAL INFORMATION Persistence and degradability: Biodegradable. Bioaccumulative potential: Other adverse effects: No bioaccumulation potential. Negligible ecotoxicity. 13. DISPOSAL CONSIDERATIONS NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. 14. TRANSPORT INFORMATION ADR / RID IMDG / IMO IATA / ICAO UN no: Shipping name: Class: Class: Not Classed Not Classed Not Classed Not Classed 15. REGULATORY INFORMATION Hazard symbols: No significant hazard. Note: The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. 16. OTHER INFORMATION Other information: EC Directive 1999/45/EC relating to the classification, packaging and labelling of dangerous Legal disclaimer: preparations. EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of specific information relating to dangerous preparations. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product. [final page]
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