Revision Number: Issue date: 12/19/ PRODUCT AND COMPANY IDENTIFICATION. IDH number: HAZARDS IDENTIFICATION

Transcription

1 Safety Data Sheet Revision Number: Issue date: 12/19/ PRODUCT AND COMPANY IDENTIFICATION Product name: TEROSON PV 4600 BODY SHOP METAL SEALANT known as TEROSTAT 4600 MS- Product type: Sealant Item number: Restriction of Use: identified Region: United States Company address: Henkel Corporation One Henkel Way Rocky Hill, Connecticut Contact information: Telephone: +1 (860) MEDICAL EMERGENCY Phone: Poison Control Center (toll free) or TRANSPORT EMERGENCY Phone: CHEMTREC (toll free) or Internet: 2. HAZARDS IDENTIFICATION DANGER: EMERGENCY OVERVIEW CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED. MAY CAUSE CANCER. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2A RESPIRATORY SENSITIZATION 1 SKIN SENSITIZATION 1 CARCINOGENICITY 1A PICTOGRAM(S) Precautionary Statements Prevention: Response: Storage: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing vapors, mist, or spray. Wash affected area thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves, clothing, eye and face protection. In case of inadequate ventilation wear respiratory protection. IF ON SKIN: Wash with plenty of water. IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical attention. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Store locked up. Page 1 of 8

2 Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR ) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Phthalic acid esters Limestone Styrene butadiene divinylbenzene copolymer Polyvinyl chloride Epichlorohydrin-4,4'-isopropylidene diphenol resin Zinc oxide Titanium dioxide Quartz (SiO2) Disodium disulphite * Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: If mist or vapor of this product is inhaled, remove person immediately to fresh air. Seek medical attention if symptoms develop or persist. Immediately flush skin with plenty of water (using soap, if available). If symptoms develop and persist, get medical attention. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. DO NOT induce vomiting unless directed to do so by medical personnel. Symptoms: See Section FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Water spray (fog), foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus. Wear full protective clothing. identified. Page 2 of 8

3 Hazardous combustion products: Irritating and/or toxic fumes and gases may be emitted upon the product's decomposition. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Thermal decomposition products of polyvinyl chloride (PVC) may include vinyl chloride, hydrogen chloride, phosgene, ethylene, benzene, toluene, 1,3,5- trichlorobenzene, and naphthalene. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Prevent further leakage or spillage if safe to do so. Wear suitable protective clothing, gloves and eye/face protection. Do not allow product to enter sewer or waterways. Remove all sources of ignition. Absorb spill with inert material. Shovel material into appropriate container for disposal. Dispose of according to Federal, State and local governmental regulations. 7. HANDLING AND STORAGE Handling: Storage: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Avoid breathing fumes if this product is used at high temperatures. Provide adequate ventilation. Do not take internally. For industrial use only. For safe storage, store between 5 C (41 F) and 32 C (89.6 F) Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. For information on product shelf life contact Henkel Customer Service at (800) Page 3 of 8

4 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Phthalic acid esters 5 mg/m3 PEL 10 mg/m3 TWA Total Limestone 15 mg/m3 PEL Total Styrene butadiene divinylbenzene copolymer Polyvinyl chloride Epichlorohydrin-4,4'-isopropylidene diphenol resin Zinc oxide Titanium dioxide Quartz (SiO2) 1 mg/m3 TWA 1 ppm TWA (as vinyl chloride monomer) 5 ppm STEL (as vinyl chloride monomer) 0.5 ppm OSHA_ACT (as vinyl chloride monomer) (as vinyl chloride monomer) 15 MPPCF TWA 50 MPPCF TWA Total 5 mg/m3 TWA 15 mg/m3 TWA Total 5 mg/m3 PEL 15 mg/m3 PEL Total 2 mg/m3 TWA 10 mg/m3 STEL 10 mg/m3 TWA mg/m3 TWA 5 mg/m3 PEL Fume. 5 mg/m3 PEL 15 mg/m3 PEL Total 15 mg/m3 PEL Total 15 MPPCF TWA 15 mg/m3 TWA Total 50 MPPCF TWA Total 5 mg/m3 TWA 2.4 MPPCF TWA Respirable. 0.1 mg/m3 TWA Respirable mg/m3 PEL Disodium disulphite 5 mg/m3 TWA Engineering controls: Respiratory protection: Ventilation should effectively remove and prevent buildup of any vapor/mist/fume/dust generated from the handling of this product. When dusts or thermal processing fumes are generated and ventilation is not sufficient to effectively remove them, appropriate NIOSH/MSHA approved respiratory protection must be provided. Page 4 of 8

5 Eye/face protection: Skin protection: Wear safety glasses; chemical goggles (if splashing is possible). Chemical resistant, impermeable gloves. Gloves should be tested to determine suitability for prolonged contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Color: Odor: Odor threshold: ph: Vapor pressure: Boiling point/range: Melting point/ range: Specific gravity: Vapor density: Flash point: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Flammability: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Viscosity: Decomposition temperature: paste Tan mild Not determined 220 F (104.4 C) 1.20 at 25 C (77 F) Not determined 104 C (219.2 F) Not applicable Not applicable Not applicable emulsifiable 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Reactivity: Conditions to avoid: Stable at normal conditions. Will not occur. Irritating and/or toxic fumes and gases may be emitted upon the product's decomposition. Upon decomposition, this product emits carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. Oxides of sulfur. This product may react with strong acids or oxidizing agents. Heat, flames, sparks and other sources of ignition. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes Page 5 of 8

6 Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: Inhalation of vapors or mists of the product may be irritating to the respiratory system. This product may cause irritation to the skin. Prolonged or repeated skin contact may cause skin irritation or allergic skin sensitization reaction. Contact can cause moderate to severe irritation and possible injury to the eyes. Ingestion of this product may cause nausea, vomiting and diarrhea. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Phthalic acid esters Developmental, Kidney, Liver, Reproductive Limestone Nuisance dust Styrene butadiene divinylbenzene No Records copolymer Polyvinyl chloride Respiratory Epichlorohydrin-4,4'-isopropylidene diphenol resin Allergen, Irritant Zinc oxide Titanium dioxide Quartz (SiO2) Disodium disulphite Oral LD50 (Mouse) = 7,950 mg/kg Oral LD50 (Rat) = > 5 g/kg Inhalation LC50 (Mouse, 4 h) = > 5.7 mg/l Hazardous Component(s) NTP Carcinogen IARC Carcinogen Blood, Gastrointestinal, Immune system, Irritant, Kidney, Metabolic, Nervous System, Pancreas, Respiratory, Skin Irritant, Respiratory, Some evidence of carcinogenicity Immune system, Lung, Some evidence of carcinogenicity Allergen, Blood, Cardiac, Central nervous system, Corrosive, Irritant, Kidney, Liver, Metabolic, Respiratory OSHA Carcinogen (Specifically Regulated) Phthalic acid esters No No No Limestone No No No Styrene butadiene divinylbenzene copolymer No No No Polyvinyl chloride No No Yes Epichlorohydrin-4,4'-isopropylidene diphenol resin No No No Zinc oxide No No No Titanium dioxide No Group 2B No Quartz (SiO2) Known To Be Human Carcinogen. Group 1 No Disodium disulphite No No No 12. ECOLOGICAL INFORMATION Ecological information: No data available. Page 6 of 8

7 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Dispose of according to Federal, State and local governmental regulations. Material, if discarded, is not expected to be a characteristic hazardous waste under RCRA. Wastes must be tested using methods described in 40 CFR Part 261 to determine if it meets applicable definitions of hazardous wastes. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: Identification number: Packing group: International Air Transportation (ICAO/IATA) Proper shipping name: Hazard class or division: Identification number: Packing group: Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: Not regulated Not regulated 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. above reporting de minimis above reporting de minimis. Immediate Health, Delayed Health This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Aluminium oxide (CAS# ). Zinc oxide (CAS# ). This product contains a chemical known in the State of California to cause cancer. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: 3 Prepared by: Cheryl Neason, Regulatory Affairs Specialist Issue date: 12/19/2016 Page 7 of 8

8 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 8 of 8