Material Safety Data Sheet acc. to ISO/DIS 11014

Transcription

1 Page 1/8 1 Identification of substance Product use: Reagent for water analysis Catalogue number: L Manufacturer/Supplier: Orbeco-Hellige Inc Parkland Dr. Sarasota, FL phone: (941) fax: (941) Made in Germany Emergency information: Chemtrec: Hazards identification Hazard description: Xn Harmful?@G?@E O Oxidizing Canadian Hazard Symbols: ;= WHMIS classification: C Oxidizing materials D2A Very toxic material causing other toxic effects Information pertaining to particular dangers for man and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. R 8 Contact with combustible material may cause fire. R 22 Harmful if swallowed. R 36/37/38 Irritating to eyes, respiratory system and skin. R 42/43 May cause sensitization by inhalation and skin contact. Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. NFPA ratings (scale 0-4) OX Health = 2 Fire = 0 Reactivity = 1 (Contd. on page 2)

2 Page 2/8 The substance possesses oxidizing properties. (Contd. of page 1) 3 Composition / Data on components Description: Mixture of the substances listed below: Composition and Information on Ingredients: CAS: EINECS: EU Number: RTECS: SE potassium persulphate?@g Xn,?@G Xi,?@E O; R /37/38-42/ % CAS: sodium carbonate?@g Xi; R % EINECS: EU Number: Additional information: For the wording of the listed risk phrases refer to section 16. * 4 First aid measures General information: Immediately remove any clothing soiled by the product. After inhalation: Supply fresh air or oxygen; call for doctor. After skin contact: Immediately wash with water and soap and rinse thoroughly. Seek medical treatment. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: Drink copious amounts of water, induce vomiting. Immediately call a doctor. The following symptoms may occur: after inhalation: breathing difficulty coughing mucous membrane irritation after swallowing: cramps gastric or intestinal disorders vomiting diarrhoea Danger: risk of airways sensitization risk of skin sensitization 5 Fire fighting measures Suitable extinguishing agents: Fire-extinguishing powder CO2. Do not use water. For safety reasons unsuitable extinguishing agents: Water Foam Special hazards caused by the material, its products of combustion or resulting gases: Formation of toxic gases is possible during heating or in case of fire. Sulfur oxides (SOx) Protective equipment: Wear fully protective suit. Wear self-contained respiratory protective device. (Contd. on page 3)

3 Page 3/8 Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. Collect contaminated fire fighting water separately. It must not enter the sewage system. (Contd. of page 2) 6 Accidental release measures Person-related safety precautions: Wear protective equipment. Keep unprotected persons away. Avoid formation of dust. Use respiratory protective device against the effects of fumes/dust/aerosol. Measures for environmental protection: Do not allow product to reach sewage system or any water course. Measures for cleaning/collecting: Dispose contaminated material as waste according to item 13. Pick up mechanically. Ensure adequate ventilation. 7 Handling and storage Handling: Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Prevent formation of dust. Work only in fume cabinet. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect from heat. Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Store away from flammable substances. Further information about storage conditions: Keep receptacle tightly sealed. Store in dry conditions. Protect from heat and direct sunlight. Protect from humidity and water. 8 Exposure controls and personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: potassium persulphate (60-70%) TLV () 0.1 mg/m³ Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Breathing equipment: Use respiratory protective device against the effects of fumes/dust/aerosol. Recommended filter device for short term use: Filter P2 Protection of hands: Only use chemical-protective gloves with CE-labelling of category III. After use of gloves apply skin-cleaning agents and skin cosmetics. (Contd. on page 4)

4 Page 4/8 (Contd. of page 3) Material of gloves Nitrile rubber, NBR Recommended thickness of the material: 0.11 mm Penetration time of glove material Value for the permeation: Level 6 (480 min) The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles Body protection: Protective work clothing 9 Physical and chemical properties Odor Threshold: Not applicable. Form: Powder Color: White Odor: Odorless Melting point/melting range: Undetermined. Boiling point/boiling range: 1600 C (2912 F) Freezing Point: Not applicable. Flash point: Not applicable. Flammability (solid, gaseous): Contact with combustible material may cause fire. Upper Flammable Limit: Not applicable. Lower Flammable Limit: Not applicable. Ignition temperature: Undetermined. Sensitivity to Mechanical Impact: None Sensitivity to Static Discharge: None Auto igniting: Product is not selfigniting. Vapor Density: Not applicable. Specific Gravity: Not applicable. Density at 20 C (68 F): g/cm³ Solubility in / Miscibility with Water: Soluble. Coefficient of Water / Oil Distribution: Not applicable. ph-value (10 g/l) at 20 C (68 F): 11.3 Solvent content: Organic solvents: 0.0 % Solids content: % 10 Stability and reactivity Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat. Materials to be avoided: alkalis acids metals combustible materials reducing agents store away from solvents Dangerous reactions Reacts with heavy metals. Dangerous products of decomposition: oxygen (Contd. on page 5)

5 Page 5/8 see chapter 5 (Contd. of page 4) * 11 Toxicological information Acute toxicity: Quantitative data on the toxicity of the preparation are not available. LD/LC50 values that are relevant for classification: potassium persulphate Oral LD mg/kg (rat) Oral LD mg/kg (rat) LDLo 714 mg/kg (human) Primary irritant effect: on the skin: Irritant to skin and mucous membranes. on the eye: Irritating effect. Sensitization: Sensitization possible through inhalation. Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Irritant repeated skin exposure can produce local skin destruction or dermatitis Carcinogenicity: NTP? IARC Monographs? OSHA Regulated? see chapter 8 / 15 Teratogenicity: Not found. Mutagenicity: Not found. Reproductive Toxicity: Not found. Synergistic Products: None * 12 Ecological information Information about elimination (persistence and degradability): Other information: Quantitative data on the ecological effect of this preparation are not available. Does not cause biolocigal oxygen deficit. The following statements refer to the individual components. Ecotoxical effects: Aquatic toxicity: potassium persulphate Daphnia EC mg/l/24h (Daphnia magna) LC mg/l/96h (Poecilia reticulata) EC mg/l/48h (Daphnia magna) LC mg/l/96h (Lepomis macrochirus) Remark: Reacts with water to form toxic decomposition products. General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or unneutralized. (Contd. on page 6)

6 Page 6/8 (Contd. of page 5) Rinse off of bigger amounts into drains or the aquatic environment may lead to increased ph-values. A high ph-value harms aquatic organisms. * 13 Disposal considerations Product: Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Hand over to hazardous waste disposers. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. * 14 Transport information DOT regulations: dcz j Hazard class: 5.1 Identification number: UN1492 Packing group: III Proper shipping name (technical name): POTASSIUM PERSULPHATE Label 5.1 Land transport ADR/RID (cross-border): dczj ADR/RID class: 5.1 (O2) Oxidizing substances Danger code (Kemler): 50 UN-Number: 1492 Packaging group: III Description of goods: 1492 POTASSIUM PERSULPHATE Maritime transport IMDG: dczj IMDG Class: 5.1 UN Number: 1492 Label 5.1 Packaging group: III Marine pollutant: No Propper shipping name: POTASSIUM PERSULPHATE Air transport ICAO-TI and IATA-DGR: dczj ICAO/IATA Class: 5.1 UN/ID Number: 1492 Label 5.1 (Contd. on page 7)

7 Page 7/8 Packaging group: III Propper shipping name: POTASSIUM PERSULPHATE Canadian TDG Class: 5.1 (Contd. of page 6) * 15 Regulations Sara Section 355 (Extremely hazardous substances): Section 313 (Specific toxic chemical listings): TSCA (Toxic Substances Control Act): potassium persulphate Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: Canadian Ingredient Disclosure List Limit 0,1% Limit 1% Canadian Domestic Substances List (DSL) potassium persulphate EPA (Environmental Protection Agency) IARC (International Agency for Research on Cancer) NTP (National Toxicology Program) NIOSH-Ca (National Institute for Occupational Safety and Health) OSHA-Ca (Occupational Safety & Health Administration) Product related hazard informations: The product has been classified and marked in accordance with directives on hazardous materials. (Contd. on page 8)

8 Page 8/8 Hazard symbols: Xn Harmful O Oxidizing Hazard-determining components of labelling: potassium persulphate Risk phrases: 8 Contact with combustible material may cause fire. 22 Harmful if swallowed. 36/37/38 Irritating to eyes, respiratory system and skin. 42/43 May cause sensitization by inhalation and skin contact. Safety phrases: 17 Keep away from combustible material. 22 Do not breathe dust. 24 Avoid contact with skin. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 37 Wear suitable gloves. 45 In case of accident or if you feel unwell, seek medical advice immediately. 60 This material and its container must be disposed of as hazardous waste. Information about limitation of use: Employment restrictions concerning young persons must be observed. Employment restrictions concerning pregnant and lactating women must be observed. Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water. CPR Classification: Class C Class D, Division 2A MSDS discloses information elements required by the CPR. (Contd. of page 7) * 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant R-phrases 22 Harmful if swallowed. 36 Irritating to eyes. 36/37/38 Irritating to eyes, respiratory system and skin. 42/43 May cause sensitization by inhalation and skin contact. 8 Contact with combustible material may cause fire. Recommended restriction of use professional/industrial use only Contact: Orbeco-Hellige, Inc., Quality Assurance Dept., Phone: Sources International Chemical Safety Cards (ICSCs) Data arise from manufacturers' data sheets, reference works and literature. * Data compared to the previous version altered.