Material Safety Data Sheet acc. to ISO/DIS 11014
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- Brittney Henry
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1 Page 1/8 1 Identification of substance Product details Application of the substance / the preparation Masking material Manufacturer/Supplier: Wieland Dental + Technik GmbH & Co.KG Schwenninger Str Pforzheim Telefon + 49 (07231)-37050, Telefax + 49 (07231) Information department: Abteilung Umweltschutz Marcus.Mueller@wieland-dental.de Emergency information: +49 (07231) ( Be kindly advised that this number can only be contacted at usual office hours.) 2 Composition/Data on components Chemical characterization Description: Solvent mixture with pigment additives Dangerous components: ethyl acetate 25-50% 10-25% acetone 10-25% n-butyl acetate 5-10% alkanes, C10-13, chloro 5-10% Additional information: For the wording of the listed risk phrases refer to section Hazards identification Hazard description: Harmful Highly flammable Dangerous for the environment Information pertaining to particular dangers for man and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Has a narcotizing effect. Highly flammable. Irritating to eyes and skin. Limited evidence of a carcinogenic effect. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Possible risk of harm to the unborn child Harmful: may cause lung damage if swallowed. Vapours may cause drowsiness and dizziness Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. NFPA ratings (scale 0-4) Health = 2 Fire = 3 Reactivity = 0 (Contd. on page 2)
2 Page 2/8 WHMIS-ratings (scale 0-4) (Contd. of page 1) HEALTH *2 FIRE 3 REACTIVITY 0 Health = *2 Fire = 3 Reactivity = 0 4 First aid measures General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; immediately call for medical help. Information for doctor: The following symptoms may occur: Headache Dizziness 5 Fire fighting measures Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water. For safety reasons unsuitable extinguishing agents: Water Water with full jet Special hazards caused by the material, its products of combustion or resulting gases: Formation of toxic gases is possible during heating or in case of fire. Protective equipment: Mount respiratory protective device. 6 Accidental release measures Person-related safety precautions: Wear protective equipment. Keep unprotected persons away. Measures for environmental protection: Do not allow to enter sewers/ surface or ground water. Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents 7 Handling and storage Handling: Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. (Contd. on page 3)
3 Page 3/8 Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Store away from oxidizing agents. Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. (Contd. of page 2) 8 Exposure controls and personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: ethyl acetate PEL REL TLV 1400 mg/m³, 400 ppm 1400 mg/m³, 400 ppm 1440 mg/m³, 400 ppm PEL Short-term value: C 300; 500* ppm Long-term value: 200 ppm *10-min peak per 8-hr shift REL Short-term value: 560 mg/m³, 150 ppm Long-term value: 375 mg/m³, 100 ppm TLV 75 mg/m³, 20 ppm acetone PEL 2400 mg/m³, 1000 ppm REL 590 mg/m³, 250 ppm TLV Short-term value: 1782 mg/m³, 750 ppm Long-term value: 1188 mg/m³, 500 ppm BEI n-butyl acetate PEL 710 mg/m³, 150 ppm REL Short-term value: 950 mg/m³, 200 ppm Long-term value: 710 mg/m³, 150 ppm TLV Short-term value: 950 mg/m³, 200 ppm Long-term value: 713 mg/m³, 150 ppm Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Breathing equipment: Use suitable respiratory protective device in case of insufficient ventilation. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Material of gloves Butyl rubber, BR Neoprene gloves Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 4)
4 Page 4/8 Not suitable are gloves made of the following materials: Strong gloves Leather gloves Eye protection: Safety glasses Body protection: Protective work clothing (Contd. of page 3) 9 Physical and chemical properties General Information Form: Color: Odor: Fluid Yellow Product specific Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 55 C (131 F) Flash point: -7 C (19 F) Ignition temperature: 370 C (698 F) Auto igniting: Product is not selfigniting. Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible. Explosion limits: Lower: 2.6 Vol % Upper: 13.0 Vol % Density at 20 C (68 F): 1 g/cm³ Solubility in / Miscibility with Water: Solvent content: Organic solvents: > 75 % Not miscible or difficult to mix. 10 Stability and reactivity Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Dangerous reactions Reacts with acids, alkalis and oxidizing agents. Dangerous products of decomposition: Carbon monoxide and carbon dioxide Nitrogen oxides (NOx) 11 Toxicological information Acute toxicity: LD/LC50 values that are relevant for classification: ethyl acetate Oral LD mg/kg (rbt) Inhalative LC50/4 h 1600 mg/l (Ratte) Oral LD mg/kg (Ratte) Dermal LD mg/kg (rab) (Contd. on page 5)
5 Page 5/8 (Contd. of page 4) Inhalative LC50/4 h 5320 mg/l (mus) Primary irritant effect: on the skin: Irritant to skin and mucous membranes. on the eye: Irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: Inhalation of concentrated vapors as well as oral intake will lead to anaesthesia-like conditions and headache, dizziness, etc. The product shows the following dangers according to internally approved calculation methods for preparations: Irritant 12 Ecological information Ecotoxical effects: Remark: Toxic for fish General notes: Toxic for aquatic organisms Water danger class 3 (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. 13 Disposal considerations Product: Recommendation: Must be specially treated adhering to official regulations. Uncleaned packagings: Recommendation: Packagings that cannot be cleansed are to be disposed of in the same manner as the product. 14 Transport information DOT regulations: Hazard class: 3 Identification number: UN1263 Packing group: II Proper shipping name (technical name): PAINT Label 3 Remarks: Special marking with the symbol (fish and tree). Land transport ADR/RID (cross-border): ADR/RID class: 3 (F1) Flammable liquids Danger code (Kemler): 33 UN-Number: 1263 Packaging group: II (Contd. on page 6)
6 Page 6/8 Special marking: Symbol (fish and tree) Description of goods: 1263 PAINT Maritime transport IMDG: (Contd. of page 5) IMDG Class: 3 UN Number: 1263 Label 3 Packaging group: II EMS Number: F-E,S-E Marine pollutant: Yes Symbol (fish and tree) Propper shipping name: PAINT Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 3 UN/ID Number: 1263 Label 3 Packaging group: II Propper shipping name: PAINT Environmental hazards: Product contains environmentally hazardous substances: alkanes, C10-13, chloro 15 Regulations Sara Section 355 (extremely hazardous substances): None of the ingredient is listed. Section 313 (Specific toxic chemical listings): TSCA (Toxic Substances Control Act): ethyl acetate acetone n-butyl acetate Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: (Contd. on page 7)
7 Page 7/8 (Contd. of page 6) Cancerogenity categories EPA (Environmental Protection Agency) II acetone I IARC (International Agency for Research on Cancer) 3 NTP (National Toxicology Program) TLV (Threshold Limit Value established by ACGIH) A acetone A4 MAK (German Maximum Workplace Concentration) NIOSH-Ca (National Institute for Occupational Safety and Health) OSHA-Ca (Occupational Safety & Health Administration) Product related hazard informations: The product has been classified and marked in accordance with directives on hazardous materials. Hazard symbols: Harmful Highly flammable Dangerous for the environment Hazard-determining components of labelling: toluene alkanes, C10-13, chloro Risk phrases: Highly flammable. Irritating to eyes and skin. Limited evidence of a carcinogenic effect. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Possible risk of harm to the unborn child Harmful: may cause lung damage if swallowed. Vapours may cause drowsiness and dizziness Safety phrases: Keep container in a well-ventilated place. Keep away from sources of ignition - No smoking. Do not breathe gas/fumes/vapour/spray. Avoid contact with eyes. Wear suitable protective clothing and gloves. Use appropriate container to avoid environmental contamination. National regulations: Water hazard class: Water danger class 3 (Self-assessment): extremely hazardous for water. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. (Contd. on page 8)
8 Page 8/8 Department issuing MSDS: Abteilung Umweltschutz Contact: Herr Marcus Müller (Contd. of page 7)
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