Reactive & Non-Reactive Modified Silicone Fluid

Transcription

1 & Non- Modified Silicone Fluid With various organic s attached to some of the silicon atoms, our modified silicone fluids offer the features of dimethyl silicone fluid, plus an array of other functions. Silicone Fluids 2-6 Non- Silicone Fluids 7-9 Storage & Handling Precautions 9 The reactive and non-reactive silicone fluids in this catalog are arranged by molecular structure. If you have a product in mind that is not featured in this catalog, we may be able to offer trial production. Don't hesitate to consult with a Shin-Etsu representative for details.

2 Silicone Fluids Silicone Fluids Side chain type Si Si Si Si m rganic n Amino-modified [side chain type] Mono amino Diamino RNH2 RNR, NH2 H KF-868 KF-865 KF-864 KF-859 KF-393 KF-860 KF-880 KF-8004 KF-8002 KF-8005 KF-867 KF-8021 KF-869 KF , , 1,200 1,300 15,000 3, ,800 5,000 3,800 6, ,600 1,800 1,700 11,000 1,700 55,000 3,800 2,000 Water repellency Amino- Polyether RNH2 R(C2H4)a(C3H6)bR, X A 3, ,800 KF-877 5, ,200 Special amino KF ,000 : Please contact our Sales Department for further information. Low yellowing Epoxy-modified -1 [side chain type] Epoxy Epoxy (side-chain phenyl type) RCH CH2 X KF-101 KF-1 X , , Alicyclic epoxy R X KF-102 3,500 3,600 Epoxy - Polyether R CH CH2 R(C2H4)a(C3H6)bR, X ,500 KF-2 4, ,300 : Active ingredient 50% (toluene dilution) 2

3 Epoxy-modified -2 [side chain type] RCH CH2 Epoxy- Aralkyl CH2 CH KF-5 2, Carbinol-modified [side chain type] Carbinol RH X X Note: functional = 56,000/hydroxyl value [mgkh/g] Hydroxyl value [mgkh/g] Antifouling property Mercapto-modified [side chain type] Mercapto -- RSH KF-2001 KF ,900 30,000 Carboxyl-modified [side chain type] RCH Carboxyl X E 2, ,000 Methylhydrogen silicone fluid [side chain type] Hydrogen H KF-99 KF Water repellency 3

4 Silicone Fluids Dual-end type rganic Si Si n Si rganic Amino-modified [dual-end type] Amino Amino (side-chain phenyl type) RNH2 PAM-E KF-8010 X A X B KF-80 KF ,200 5,700 X B ,200 X Flexibility Epoxy-modified [dual-end type] Epoxy Alicyclic epoxy RCH CH2 R X KF-105 X A X B X C X AS X B ,000 1,800 2, ,700 Flexibility Carbinol-modified [dual-end type] Hydroxyl value [mgkh/g] Carbinol RH KF-6000 KF-6001 KF-6002 KF xygen permeability Note: functional = 56,000/hydroxyl value [mgkh/g] Methacryl-modified [dual-end type] Methacryl RCC =CH2 = X X AS X A X B X C X E ,600 2,400 3,900 xygen permeability 4

5 Polyether-modified [dual-end type] Hydroxyl value [mgkh/g] Polyether R(C2H4)a(C3H6)bH X X KF Note: functional = 56,000/hydroxyl value [mgkh/g] Mercapto-modified [dual-end type] Mercapto -- RSH X B X C ,700 2,300 Carboxyl-modified [dual-end type] Carboxyl -- RCH Phenol-modified [dual-end type] X C ,300 Flexibility Phenol R H KF Hydroxyl value [mgkh/g] Note: functional = 56,000/hydroxyl value [mgkh/g] Silanol end-capped [dual-end type] Silanol H X KF Acrylic-modified [dual-end type] Acrylic = R CCH=CH2 X ,600 Carboxylic acid anhydride-modified [dual-end type] Carboxylic acid anhydride Carboxylic acid anhydride (side-chain phenyl type) C R C = = X AS X A X B X P5-B ,000 1,600 1, , 5

6 Silicone Fluids Single-end type R Si Si n Si rganic Single-end, reactive, modified [Single-end type] Epoxy Carbinol Diol Methacryl RCH CH2 RH RCC =CH2 = Single-end carboxyl-modified Carboxyl RCH X BX X DX ,500 4,600 X BX X DX X DX X F X GX-A X ASX X BX ,300 KF ,600 X ,000 X : hydroxyl value [mgkh/g], functional = 56,000/hydroxyl value [mgkh/g] RH R, C R,, RH : Including non-reactive & dual-end type carboxyl-modified silicone fluid X ,450 Water repellency Antifouling property xygen permeability Silicone Fluids Side-chain, dual-end rganic Si Si m Si rganic n Si rganic Side-chain amino, dual-end methoxy RNH2, R, RCH CH2 : Active ingredient 50% (acetate IPA dillusion) KF-857 KF-8001 KF-862 KF ,900 1,900 Epoxy X ,

7 Non- Silicone Fluids Non- Silicone Fluids Side chain type Si Si Si Si m n rganic Polyether-modified Polyether Polyether (odorless) R(C2H4)a(C3H6)bR, R(C2H4)a(C3H6)bR, KF-351A KF-352A KF-353 KF-354L KF-355A KF-615A KF-945 KF-640 KF-642 KF-643 KF-644 KF-6020 KF-6204 X KF-6011 KF-60 KF-6015 KF , , HLB Water soluble Water dispersible Easily emulsifiable Low surface tension Good permeability Anti-fogging property R(C2H4a(C3H6)bR, Polyether, long-chain alkyl, aralkyl CaH2a+1 CH2 CH X Aralkyl-modified Aralkyl CH2 CH KF

8 Fluoroalkyl-modified Fluoroalkyl CH2CH2CF3 FL-5 X X FL--cs FL--450cs FL--1,000cs FL--10,000cs ,000 10, Chemical resistance il & solvent resistance High specific Poor solubility Long-chain alkyl-modified Long-chain alkyl CaH2a+1 KF-4 KF-413 KF-414 KF-415 KF-4003 KF-4701 KF-4917 KF-7235B X Paintable Water repellency Long-chain alkyl, aralkyl CaH2a+1 CH2 CH X Higher fatty acid ester-modified CR Higher fatty acid ester X , Contains higher fatty acids Higher fatty acid amide RNHCR, KF-3935 Paste consistency (melt point: 49 ) High melt point Water repellency 8

9 Phenyl-modified Phenyl Si Si C6H5 Si C6H5 m n Si KF-50-cs KF cs KF-50-1,000cs KF-50-3,000cs KF-53 KF-54 X KF-54SS 300 1,000 3, Heat resistance High refractive Low-temperature resistance Non- Silicone Fluids Dual-end type rganic Si Si n Si rganic Polyether-modified Polyether R(C2H4)a(C3H6)bR, melt point KF HLB Storage & Handling Precautions Quality, Storage and Handling Many modified silicone fluids contain organic functional s or hydrolyzable s, and their reactivity varies. Before using these products, carefully consider their respective characteristics. Heat, light, acids and bases may cause deterioration of modified silicone fluids. Take care to prevent contamination, and seal tightly and store in a cool, dark place. ur modified silicone fluids are not produced specifically for medical use. Accordingly, they should not be used as is for orthopedic or cosmetic surgery or other medical applications. If amino-modified silicone fluid is being used as an aerosol and the particles are inhaled, there is a possibility of acute inhalation toxicity. Average consumers should not use amino-modified silicone fluid in spray applications. Some silicone products described herein are classified as hazardous materials under the laws of certain countries. In such cases, the laws must be followed regarding storage, labeling, and handling. Safety & Hygiene Some modified silicone fluids may cause skin irritation. If contact occurs, they are difficult to remove from the skin, so always wear rubber gloves (etc.) and avoid contact with the skin and mucous membranes. In case of contact, wipe with a rag or waste (etc.), then wash with soap and water or flush thoroughly with water. In case of accidental eye contact, immediately flush with water for at least 15 minutes and then seek medical attention. Be sure there is adequate ventilation when handling these products. If you feel ill after breathing the vapors, move immediately to an area with fresh air. Keep out reach of children. Please read the Safety Data Sheet (SDS) before use. SDS can be obtained from our Sales Department. ther Some of the products (product name starting with X) featured in this catalog are preproduction prototypes. Please contact Shin-Etsu to confirm the availability of all products. For cosmetics, "A Grade" products are available, but in some cases a separate application is required if modified silicone fluids are to be used as a cosmetic ingredient. Please contact Shin-Etsu regarding required documents. 9

10 Shin-Etsu Chemical Co., Ltd. Silicone Division, Sales and Marketing Department 6-1 htemachi 2-chome, Chiyoda-ku, Tokyo, Japan. Phone: +81-(0) Fax: +81-(0) Shin-Etsu Silicones Europe B.V. Bolderweg 32, 1332 AV, Almere, The Netherlands Phone : +31-(0) Fax : +31-(0) (Products & Services: Fluid products) Germany Branch Rheingaustrasse , Wiesbaden, Germany Phone : +49-(0) Fax : +49-(0) (Products & Services: Elastomer products) Shin-Etsu Silicone Taiwan Co., Ltd. Hung Kuo Bldg. 11F-D, No. 167, Tun Hua N. Rd., Taipei, Taiwan, R..C. Phone : +886-(0) Fax : +886-(0) Shin-Etsu Silicone Korea Co., Ltd. GT Tower 15F, 411, Seocho-daero, Seocho-gu, Seoul 06615, Korea Phone : +82-(0) Fax : +82-(0) Shin-Etsu Singapore Pte. Ltd. 4 Shenton Way, #10-03/06, SGX Centre II, Singapore Phone : Fax : Shin-Etsu Silicones India Pvt. Ltd. Flat No.7, 7th Floor, 24 Ashoka Estate, Barakhamba Road, New Delhi - 101, India Phone : Fax : Shin-Etsu Silicones (Thailand) Ltd. 7th Floor, Harindhorn Tower, 54 North Sathorn Road, Bangkok 10500, Thailand Phone : +66-(0) Fax : +66-(0) Shin-Etsu Silicone International Trading (Shanghai) Co., Ltd. 29F Junyao International Plaza, No.789, Zhao Jia Bang Road, Shanghai , China Phone : +86-(0) Fax : +86-(0) Guangzhou Branch B-2409, 2410, Shine Plaza, 9 Linhexi Road, Tianhe, Guangzhou, Guangdong , China Phone : +86-(0) Fax : +86-(0) The data and information presented in this catalog may not be relied upon to represent standard values, Shin-Etsu reserves the right to change such data and information, in whole or in part, in this catalog, including product performance standards and specifications without notice. Users are solely responsible for making preliminary tests to determine the suitabillity of products for their intended use. Statements concerning possible or suggested user made herein may not be relied upon, or be construed, as a guaranty of no patent infringement. Users are solely responsible for exporting or importing the silicone products described herein, and complying with all applicable laws, regulations, and rules relating to the use of such products. Shin-Etsu recommends checking each pertinent country's laws, regulations, and rules in advance, when exporting or importing, and before using, the products. Please contact Shin-Etsu before reproducing any part of this catalog. Copyright belongs to Shin-Etsu Chemical Co., Ltd. The silicone products described herein have been designed, manufactured and developed solely for general industrial use only; such silicone products are not designed for, intended for use as, or suitable for, medical, surgical or other particular purposes. Users have the sole responsibility and obligation to determine the suitability of the silicone products described herein for any application, to make preliminary tests, and to confirm the safety of such products for their use. Users must never use the silicone products described herein for the purpose of implantation into the human body and/or injection into humans. Shin-Etsu Silicone is a registered trademark of Shin-Etsu Chemical Co., Ltd. C Shin-Etsu / P.A. Printed in Japan.