LEHDER Environmental Services Limited has attempted to obtain an updated MSDS. No update is available for the following reason(s):

Transcription

1 LEHDER Environmental Services Limited has attempted to obtain an updated MSDS. No update is available for the following reason(s) Product has been discontinued. Obsolete (eg. product no longer manufactured under this name, manufactured or distributed by a different company and/or division). Company no longer exists (sold, merged, receivership, etc.). Contact information no longer valid. Consequently no further updates will be issued. This MSDS should be used until the product is removed from your facility. Please advise when product is no longer on site in order to remove it from your inventory. LEHDER Environmental Services Limited 704 Mara Street, Suite 210, Point Edward, Ontario, Canada N7V 1X4 Phone (519) Fax (519) th Avenue, Edmonton, Alberta, Canada T6E 0P5 Phone (780) Fax (780)

2 Material Safety Data Sheet Antifreeze & Coolant Section 1. Chemical Product and Company Identification Trade name Code Antifreeze & Coolant Material Uses Supplier Volvo Penta of the Americas, Inc Volvo Penta Drive Chesapeake, VA Telephone no. (757) Section 2. Composition, Information on Ingredients In Case of Emergency Name CAS # % by Weight Ethanediol Ethylhexanoic acid Section 3. Hazards Identification Physical state and Appearance Emergency Overview Routes of Entry Potential Acute Health Effects Potential Chronic Health Effects Eyes Skin Inhalation Ingestion Medical Conditions Aggravated by Overexposure Overexposure/Signs/Symptom Liquid WARNING! HARMFUL OR FATAL IF SWALLOWED. MAY CAUSE EYE AND SKIN IRRITATION. CONTAINS MATERIAL WHICH CAUSES DAMAGE TO THE FOLLOWING ORGANS KIDNEYS, RESPIRATORY TRACT, SKIN, CENTRAL NERVOUS SYSTEM, EYES. CONTAINS MATERIAL WHICH MAY CAUSE BIRTH DEFECTS BASED ON ANIMAL DATA. Do not ingest. Avoid contact with eyes, skin and clothing. Keep container closed. Use only with adequate ventilation. Avoid exposure during pregnancy. Wash thoroughly after handling. Ingestion Eye contact. Skin contact Inhalation Hazardous in case of eye contact (irritant). Sensitization of the product applicable. Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Hazardous in case of inhalation. Exposure can cause nausea, headache and vomiting. Harmful if swallowed. May be fatal if swallowed. Exposure can cause stomach pains, vomiting and diarrhoea. CARCINOGENIC EFFECTS Classified None. by NIOSH. MUTAGENIC EFFECTS TERATOGENIC EFFECTS Classified 3 by European Union [2Ethylhexanoic acid]. Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. Harmful if swallowed. Irritating to eyes and skin. See Toxicological Information (section 11) Section 4. First Aid Measures Eye Contact Skin contact Inhalation Ingestion es to physician Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Obtain medical attention. In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if irritation develops. If inhaled, remove to fresh air. Obtain medical attention if symptoms occur. INDUCE VOMITING by sticking finger in throat. Obtain medical attention immediately.

3 Antifreeze & Coolant Page 2/4 Section 5. Fire Fighting Measures Flammability of the Product Autoignition Temperature Flash points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances FireFighting Media and Instructions Protective Clothing (Fire) May be combustible at high temperature. >200 C (392 F) CLOSED CUP >100 C (212 F). LOWER 3% UPPER 15% carbon oxides (CO, CO2) nitrogen oxides (NO, NO2...). applicable. Risks of explosion of the product in presence of mechanical impact Risks of explosion of the product in presence of static discharge SMALL FIRE Use DRY chemical powder. Do not use water jet. LARGE FIRE Use water spray, fog or foam. Do not use water jet. Be sure to use an approved/certified respirator or equivalent. Special Remarks on Fire Hazards Special Remarks on Explosion Hazards Section 6. Accidental Release Measures Small Spill and Leak Large Spill and Leak Section 7. Handling and Storage Absorb with an inert material and place in an appropriate waste disposal container. Absorb with an inert material and put the spilled material in an appropriate waste disposal Handling Do not ingest. Avoid contact with eyes, skin and clothing. Avoid prolonged contact with eyes, skin and clothing. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Storage Keep container tightly closed. Keep container in a cool, wellventilated area. Section 8. Exposure Controls, Personal Protection Engineering Controls Personal Protection Eyes Body Respiratory Hands Personal Protection in Case of a Large Spill Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapours below their respective threshold limit value. Splash goggles. Protective Clothing Wear appropriate respirator when ventilation is inadequate. Be sure to use an approved/certified respirator or equivalent. Gloves. Splash goggles. Full suit. Vapour respirator. Boots. Gloves. A selfcontained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Product Name Exposure Limits Ethanediol 2Ethylhexanoic acid Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical state and Appearance Colour Odour Boiling/Condensation Point Melting/Freezing Point Vapour pressure Viscosity Solubility Physical Chemical Comments Liquid Green. Slight >155 C (311 F) <18 C (0.4 F) 0.2 kpa (1.4 mm of Hg) (at 20 C) Kinetic 20 to 30 cst Easily soluble in cold water, hot water.

4 Antifreeze & Coolant Page 3/4 Section 10. Stability and Reactivity Stability and Reactivity Conditions of Instability Incompatibility with Various Substances Hazardous decomposition products Hazardous Polymerization The product is stable. moisture oxidizing agents carbon oxides (CO, CO2) nitrogen oxides (NO, NO2...) Section 11. Toxicological Information Toxicity to Animals Chronic effects on humans Other Toxic Effects on Humans Section 12. Ecological Information Ecotoxicity Biodegradable/OECD Products of Degradation Toxicity of the Products of Biodegradation Section 13. Disposal Considerations Acute oral toxicity (LD50) 1650 mg/kg [Cat]. (Ethanediol). Acute dermal toxicity (LD50) 1260 mg/kg [Rabbit]. (2Ethylhexanoic acid). CARCINOGENIC EFFECTS Classified None. by NIOSH. TERATOGENIC EFFECTS Classified 3 by European Union [2Ethylhexanoic acid]. Contains material which causes damage to the following organs kidneys, upper respiratory tract, skin, central nervous system (CNS), eyes. Harmful if swallowed. Hazardous in case of skin contact (irritant), of eye contact (irritant). Ecotoxicity in water >100 mg/l [LC50], 96 hours [Fish]. >100 mg/l [EC50], 48 hours [Daphnia]. >100 mg/l [EC50], 72 hours [Algae]. Readily biodegradable. These products are carbon oxides (CO, CO2) and water. Some metallic oxides. The products of degradation are less toxic than the product itself. Waste information Waste stream Waste must be disposed of in accordance with federal, state and local environmental control regulations. Dispose of this material and its container at hazardous or special waste collection point. Consult your local or regional authorities. Section 14. Transport Information Regulatory Information UN number Proper shipping name Class Packing group Label Additional Information DOT Classification available. TDG Classification available. ADR/RID Class IMDG Class IATADGR Class

5 Antifreeze & Coolant Page 4/4 Section 15. Regulatory Information WHMIS (Canada) Class D2A Material causing other toxic effects (VERY TOXIC). All components in this product are included on the DSL list. Section 16. Other Information References Other Special Considerations Date of printing Date of issue Date of previous issue Version No Previous Validation. 1 ice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.