MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET Sichuan Tianyu Oleochemical Co., Ltd. Product name: LUTAMIDE S Revision Page: 1 of 5 Section 1. Chemical Product and Company Identification Product name LUTAMIDE S Material Uses Supplier/ Manufacturer Surfactant. Sichuan Tianyu Oleochemical Co. Ltd. Naxi District Luzhou City, Sichuan, Province, P.R. China In Case of Emergency Sichuan Tianyu Oleochemical Co. Ltd. Emergency Response (24 hours) Customer Service Section 2. Composition, Information on Ingredients Name CAS # % by Weight Stearamides Fatty acids & ammonium salts Assigned Section 3. Hazards Identification Physical State Color Odor Emergency Overview Solid. White. Bland. CAUTION! MAY CAUSE SKIN IRRITATION. Avoid contact with skin and clothing. Wash thoroughly after handling. Possible Carcinogenic Effects Routes of Entry Amides, tallow, hydrogenated: IARC, NTP, OSHA, ACGIH: listed. Fatty acids, tallow, hydrogenated: IARC, NTP, OSHA, ACGIH: listed. (Hydrogenated tallowalkyl) fatty acid, ammonium salts: IARC, NTP, OSHA, ACGIH: listed. Absorbed through skin. Dermal contact. Eye contact. Section 4. First Aid Measures See Toxicological Information (section 11) Eye Contact Skin Contact Inhalation Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention. In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

2 LUTAMIDE SR Page: 2 of 5 Ingestion Medical Conditions Aggravated by Overexposure Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear. Repeated or prolonged exposure is not known to aggravate medical condition. Section 5. Fire Fighting Measures Flammability of the Product Flash Points Products of Combustion Fire Fighting Media and Instructions Protective Clothing (Fire) May be combustible at high temperature. Closed cup: >150 C (302 F). These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...). SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Be sure to use an approved/certified respirator or equivalent. Section 6. Accidental Release Measures Small Spill and Leak Large Spill and Leak Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Section 7. Handling and Storage Handling Storage Avoid contact with skin and clothing. Wash thoroughly after handling. Keep container tightly closed. Keep container in a cool, wellventilated area. Section 8. Exposure Controls, Personal Protection Engineering Controls Personal Protection Eyes Body Respiratory Hands Feet Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Safety glasses. Lab coat. Respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Protective Clothing (Pictograms) Personal Protection in Case of a Large Spill Splash goggles. Full suit. Respirator. Boots. Gloves. A selfcontained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Ingredient Name Exposure Limits United States

3 LUTAMIDE SR Amides Fatty acids (Hydrogenated tallowalkyl) fatty acid, ammonium salts Page: 3 of 5 Section 9. Physical and Chemical Properties Physical State Color Odor Molecular Weight Molecular Formula Melting/Freezing Point Density Vapor Pressure Solubility Dispersion Properties Solid. White. Bland. Weighted average: C (206.1 F) g/cm 3 (100 C / 212 F) <0.01 kpa (<0.1 mmhg) (at 20 C) Very slightly soluble in cold water. Viscosity = 100 o C; 130 o C. Section 10. Stability and Reactivity Stability and Reactivity Incompatibility with Various Substances Hazardous Polymerization The product is stable. Reactive with OXIDIZING AGENTS. Will not occur. Section 11. Toxicological Information Toxicity to Animals Ingredient Name or Product Test Result Route Species name Amides LD50 >5000 mg/kg Oral Rat based on data for: (similar material) Fatty acids, LD mg/kg Oral Rat (based on similar product data) Chronic Effects on Humans Special Remarks on Chronic Effects on Humans Acute Effects Skin MUTAGENIC EFFECTS: Nonmutagenic for bacteria and/or yeast. [Amides, tallow, hydrogenated]. Amides, tallow, hydrogenated: Mutagenic Effects based on data for: (similar material) Moderately irritating to the skin. Section 12. Ecological Information Ecotoxicity Ingredient Name or Product name Species Period Result Amides, tallow, hydrogenated Zebrafish based on data for: 672 hour(s) > mg/l (similar material) (LC50) daphnia based on data for: 672 hour(s) 0.08 mg/l (similar material) (LC50) Biodegradability and Ecotoxicity Remarks Amides, tallow, hydrogenated: 28 day(s) CBT based on data for: (similar material)

4 LUTAMIDE SR Page: 4 of 5 Biodegradable/OECD Products of Degradation Waste Information Readily biodegradable. These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2...). Section 13. Disposal Considerations Section 14. Transport Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Consult your local or regional authorities. Regulatory Information DOT Classification UN number Proper shipping name Class Packing Group Label Additional information TDG Classification IMDG Class IATADGR Class Section 15. Regulatory Information HCS Classification U.S. Federal Regulations Other Regulations State Regulations WHMIS (Canada) controlled under the HCS (United States). TSCA: All intentionally present components are listed on the TSCA inventory. DSL: All intentionally present components are listed on the DSL. CERCLA: Hazardous substances.: SARA 302/304/311/312 extremely hazardous substances: SARA 302/304 emergency planning and notification: SARA 302/304/311/312 hazardous chemicals: SARA 311/312 MSDS distribution chemical inventory hazard identification: SARA 313 Form R Reporting Requirements SARA 313 Supplier ification California prop. 65: controlled under WHMIS (Canada).

5 LUTAMIDE SR Page: 5 of 5 CEPA DSL: Amides, tallow, hydrogenated; Fatty acids, tallow, hydrogenated European Union Other International Lists Component EC Number EC Status EC Annex Amides, tallow, hydrogenated Fatty acids, tallow, hydrogenated (Hydrogenated tallowalkyl) fatty acid, ammonium salts Australia (NICNAS): Amides, tallow, hydrogenated; Fatty acids, tallow, hydrogenated Section 16. Other Information Korea (TCCL): Amides, tallow, hydrogenated; Fatty acids, tallow, hydrogenated Philippines (RA6969): Amides, tallow, hydrogenated; Fatty acids, tallow, hydrogenated Hazardous Material Information System (U.S.A.) Health Fire Hazard Reactivity Personal Protection E National Fire Protection Association (U.S.A.) Health Fire Hazard Reactivity Specific Hazard Other Information is a registered trademark of Sichuan Lutianhua Oleochemical Co., Ltd.. Validation Date 7/30/2003. Previous Validation Date No Previous Validation. ice to Reader The information in the material safety data sheet should be provided to all who will use, handle, store, transport or otherwise be exposed to this product. All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are believed to be reliable as of the date of publication. However, no warranty is made as to the accuracy of and/or sufficiency of such information and/or suggestions or as to the product s merchantability or fitness for any particular purpose, or that any suggested use will not infringe any patent. hing contained herein shall be construed as granting or extending any license under any patent. Buyer must determine for himself, by preliminary tests or otherwise, the suitability of this product for his purposes, including mixing with other products. The information contained herein supersedes all previously issued bulletins on the subject matter covered. If the date on this document is more than three years old, call to make certain that this sheet is current.