SAFETY DATA SHEET Dish Wash Juniper Wood Date of issue: Version: 1 Revision: - Page: 1
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1 Date of issue: Version: 1 Revision: Page: 1 Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 PRODUCT NAME CATALOGUE NO 1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST Cleaning agent. 1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET Supplier: NINE UNITED A/S, Havnen 1, 8700 Horsens, Denmark Telephone: Contact: Kristine Borella kristine.borella@hay.dk 1.4 EMERGENCY TELEPHONE Swedish Poisons Information Centre 112 (acute), +46 (0) (working hours) Section 2. HAZARDS IDENTIFICATION 2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE Based on bridging principles from the DetNet formulations CLP (Regulation (EC) No 1272/2008):, GHS07: : H315 (Causes skin irritation), Eye Irrit. 2: H319 (Causes serious eye irritation) 2.2 LABEL ELEMENTS CLP classification (REGULATION (EC) No 1272/2008) Pictograms: GHS07 Signal word: Hazard statements: H315 Causes skin irritation. H319 Causes serious eye irritation. Precautionary statements: P280 Wear protective gloves. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/attention. Contains: Aqua Sodium Laureth Sulfate Alcohol ethoxylate C1018
2 Date of issue: Version: 1 Revision: Page: 2 Lauryl Glucoside Cocamidopropyl Betaine Amines, C1214 (even numbered)alkyldimethyl, Noxides 2Phenoxyethanol 2.3 OTHER HAZARDS Section 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Mixtures ACCORDING TO CLP (REGULATION (EC) No 1272/2008) Substance name EG Number Reg. Number CAS Number Conc. Pictogram(s) H phrase(s)* Alcohols, C1214, % GHS05 H315 ethoxylated, sulfates, Danger H318 sodium salts H412 Alcohol ethoxylate C1018 DGlucopyranose, oligomeric, C1016 alkyl glycosides Cocamidopropyl betaine Amines, C1214 (even numbered) alkyldimethyl, N oxides 15 % GHS % GHS05 Danger % GHS05 Danger Phenoxyethanol <1 % GHS <1 % GHS07 * For the full text of the HStatements mentioned in this section, see Section 16. H302 H315 H319 H412 H315 H318 H318 H412 H302 H315 H318 H400 H411 H302 H319 Category Chronic 3 Acute Tox. 4 Eye Irrit. 2 Chronic 3 Chronic 3 Acute Tox. 4 Acute 1 Chronic 2 Acute Tox. 4 Eye Irrit. 2 Section 4. FIRST AID MEASURES 4.1 DESCRIPTION OF FIRST AID MEASURES The instructions apply to concentrated product. INHALATION Fresh air. Contact a doctor if the complaints persist. SKIN CONTACT Wash hands with soap and water thoroughly after handling. EYE CONTACT Rinse with lukewarm water for at least 5 minutes. Keep eyelids well apart and remove any contact lenses. Consult a doctor if symptoms persist. INGESTION Wash out mouth with water. Give a glass of milk or water if the victim is fully conscious. Consult a doctor if symptoms persist.
3 Date of issue: Version: 1 Revision: Page: MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED Causes serious eye irritation. Causes skin irritation. 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED Treat symptomatically. Section 5. FIREFIGHTING MEASURES 5.1 EXTINGUISHING MEDIA The product is not flammable. Use extinguishing media suitable for the surrounding fire. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE The product is not flammable. Combustion may give rise to irritating fumes. Used extinguishing media may be irritating. 5.3 ADVICE FOR FIREFIGHTERS In the event of fire, wear selfcontained breathing apparatus. Prevent fire extinguishing water from contaminating surface water or the ground water system. Remove container from danger zone and cool with water. Section 6. ACCIDENTAL RELEASE MEASURES 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES Avoid contact with the eyes. Risk of slippery floor if product is spilled. 6.2 ENVIRONMENTAL PRECAUTIONS Do not empty into drains. Contact local emergency services in case of large spillage. 6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP Collect spills for possible reuse or transfer to suitable waste containers. Absorb wet waste with sand, dry earth or vermiculite. Small spills can be washed away with large amounts of water. Further handling of waste see section REFERENCE TO OTHER SECTIONS See Sections 8 and 13 for information concerning protective equipment and waste treatment methods. Section 7. HANDLING AND STORAGE 7.1 PRECAUTIONS FOR SAFE HANDLING Avoid contact with eyes. 7.2 CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES Keep away from children. Store in a dry area in room temperature. Keep in tightly closed original packaging. 7.3 SPECIFIC END USE(S) See EWCcode under Section 13. Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 CONTROL PARAMETERS OCCUPATIONAL EXPOSURE LIMITS (Directive 2000/39/EC) No occupational exposure limits. DNEL No data available. PNEC No data available. 8.2 INDIVIDUAL PROTECTION MEASURES RESPIRATORY PROTECTION HAND PROTECTION EYE/FACE PROTECTION OTHER PROTECTIVE EQUIPMENT
4 Date of issue: Version: 1 Revision: Page: 4 HYGIENE MEASURES Change contaminated clothing. Wash hands after working with substance. Section 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 INFORMATION ON FUNDAMENTAL PHYSICAL AND CHEMICAL PROPERTIES Form Liquid Color Clear Odor Perfumed ph Ca 10 (concentrate) Freezing point 0 C Relative density 1040 kg/m 3 Solubility in water Soluble Viscosity cp 9.2 OTHER INFORMATION Section 10. STABILITY AND REACTIVITY 10.1 REACTIVITY The product is chemically stable under standard conditions CHEMICAL STABILITY The product is chemically stable under standard conditions POSSIBILITY OF HAZARDOUS REACTIONS The product is chemically stable under standard conditions CONDITIONS TO AVOID 10.5 INCOMPATIBLE MATERIALS 10.6 HAZARDOUS DECOMPOSITION PRODUCTS Combustion may emit carbon oxides and irritating fumes. Section 11. TOXICOLOGICAL INFORMATION 11.1 INFORMATION ON TOXICOLOGICAL EFFECTS ACUTE EFFECTS CHRONIC EFFECTS SKIN CONTACT Causes skin irritation. Prolonged or repeated exposure may give redness and irritation. EYE CONTACT Causes serious eye irritation. INHALATION INGESTION May cause irritation in mouth/throat and stomach. May give nausea and diarrhea. ACUTE TOXICITY TOXICITY FOR THE COMPONENTS Alcohols, C1214, ethoxylated, sulfates, sodium salts LD50 Oral rat: 4000 mg/kg body weight (no acute toxicity) Alcohol ethoxylate C1018 LD50 Oral rat: mg/kg body weight (harmful) DGlucopyranose, oligomeric, C1016alkyl glycosides LD50 Oral rat: >5000 mg/kg body weight (no acute toxicity) LD50 Dermal rat: >2000 mg/kg body weight (no acute toxicity)
5 Date of issue: Version: 1 Revision: Page: 5 Cocamidopropyl betaine LD50 Oral rat: >5000 mg/kg body weight (no acute toxicity) Amines, C1214 (even numbered)alkyldimethyl, Noxides LD50 Dermal rat: >2000 mg/kg body weight (no acute toxicity) 2Phenoxyethanol LD50 Oral rat: 1260 mg/kg body weight (harmful) LD50 Dermal rat: 5000 mg/kg body weight (no acute toxicity) LD50 Dermal rabbit: 5500 mg/kg body weight (no acute toxicity) IRRITATION Causes serious eye irritation. Causes skin irritation. CORROSIVE EFFECT No corrosive effect known. SENSITISATION TOXICITY AT REPEATED EXPOSURE CANCEROGENICITY MUTAGENICITY REPRODUCTIVE TOXICITY INTERACTIVE EFFECTS ABSENCE OF DATA Section 12. ECOLOGICAL INFORMATION 12.1 TOXICITY Not classified as hazardous to the environment. ECOTOXICITY FOR INGREDIENTS Alcohols, C1214, ethoxylated, sulfates, sodium salts IC50 Algae 72h: 27,7 mg/l (harmful) Biodegradation: 90 % degradation in 28 days OECD 301D Accumulation: Log Pow: <3 (no accumulation) Alcohol ethoxylate C1018 Biodegradation: >60 % degradation in 28 days OECD 301B DGlucopyranose, oligomeric, C1016alkyl glycosides Biodegradation: 100 % degradation in 28 days OECD 301B Cocamidopropyl betaine Biodegradation: % degradation in 28 days. OECD TG 301A/B/D/E). Amines, C1214 (even numbered)alkyldimethyl, Noxides LC50 Fish 96h: 1,26 mg/l (Sp: Oncorhynchus mykiss) (toxic) 2Phenoxyethanol LC50 Fish 96h: 135 mg/l (Sp: Pimephales promelas) (no acute toxicity) EC50 Daphnia 48h: >500 mg/l (Sp: D. magna) (no acute toxicity) IC50 Algae 72h: >500 mg/l (Sp: Scenedesmus subspicatus) (no acute toxicity) Accumulation: BCF: 2 and Log Pow: 1,16 (no accumulation) 12.2 PERSISTENCE AND BIODEGRADATION Expected to be easily degraded. The surfactants in this mixture meet the criteria for biodegradation contained in EC Regulation No. 648/2004 on detergents BIOACCUMULATIVE POTENTIAL Not expected to accumulate MOBILITY IN SOIL AND WATER Soluble in water RESULTS OF PBT AND vpvb ASSESSMENT
6 Date of issue: Version: 1 Revision: Page: 6 The product contains no PBT or vpvbsubstances OTHER ADVERSE EFFECTS No other adverse effects known. SUMMARY Not classified as hazardous to the environment. Discharge of larger quantities into the environment should be avoided. Section 13. DISPOSAL CONSIDERATION 13.1 DISPOSAL FROM EXCESS/UNUSED PRODUCT In accordance with directive 2008/98/EC unused product is hazardous waste. Suggestion of EWCcode: 20 MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND INSTITUTIONAL WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS Detergents containing dangerous substances. CONTAMINATED PACKAGE Should be recycled in accordance with local, state or national regulations. Section 14. TRANSPORT INFORMATION Not classified as dangerous goods in accordance with ADR/RID/IMO/DGR. Section 15. REGULATORY INFORMATION 15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCE OR MIXTURE Safety data sheet and classification in accordance with CLP (directive 1272/2008/EC and directive 830/2015/EC, appendix II. CHEMICAL SAFETY ASSESSMENT Chemical Safety Assessment (CSA) is available for the product (in Swedish). Section 16. OTHER INFORMATION FULL TEXT OF HSTATEMENTS REFERRED TO UNDER SECTION 3 H302 Harmful if swallowed. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H400 Very toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. EXPLANATIONS TO ABBREVIATIONS REFERENCES TO LITTERATURE AND DATABASES See Chemical Safety Assessment (CSA). REVISION Version 1 ( ): Original document. OTHER INFORMATION This information is complementary. However, the user should independently decide whether the information is sufficient. Responsible for the product safety and facts is Tangent Garment Care AB. Safety Data Sheet has been established with the participation of Amasis Konsult AB, Solna.
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