Safety data sheet Issue Date 16-Mar-2018 Revision Date 16-Mar-2018 Version 3. RME - Perstorp BioCaleoÔ
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1 Safety data sheet Issue Date 16-Mar-2018 Version 3 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product Name RME - Perstorp BioCaleoÔ Chemical Name CAS No EC No REACH Registration Number Fatty acids, C16-18 and C18-unsatd., Me , esters Pure substance/mixture Substance 1.2. Relevant identified uses of the substance or mixture and uses advised against Industrial Industrial manufacturing of fatty acid methyl esters. Manufacture: of fuel; Industrial, agricultural, foresty and mining. Distribution and storage. Formulation of preparations (mixtures). Use in coatings. Professional Consumer Application Uses advised against Use in fuel. Use in fuel. Fuels, biodiesel. Not identified Details of the supplier of the safety data sheet Manufacturer Perstorp BioProducts AS Öraveien 2 Gamle Fredrikstad Norway Perstorp Oxo AB SE Stenungsund Sweden Tel Fax address productinfo@perstorp.com 1.4. Emergency telephone number Europe (+) (contract no: ) United Kingdom (+) (contract no: ) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] This substance is not classified as dangerous according to regulation (EC) 1272/2008 [CLP] 2.2. Label elements This substance is not classified as dangerous according to regulation (EC) 1272/2008 [CLP] Symbols/Pictograms Page 1 / 9
2 Signal word None Hazard statements Precautionary Statements 2.3. Other hazards Causes mild skin irritation SECTION 3: Composition/information on ingredients 3.1 Substances Chemical Name EC No CAS No REACH Registration Number Fatty acids, C16-18 and C18-unsatd., Me esters , Weight-% Classification according to Regulation (EC) No. 1272/2008 [CLP] >=99 Not classified Full text of H- and EUH-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion First aid measures not required, but get fresh air for personal comfort. Wash with soap and water. First aid measures not required, but wash exposed skin with soap and water for hygienic reasons. Rinse thoroughly with plenty of water, also under the eyelids. If eye irritation persists: Get medical advice/attention. Do NOT induce vomiting. Clean mouth with water. If a large quantity has been ingested or you feel unwell, get medical advice/attention. Self-protection of the first aider Most important symptoms and effects, both acute and delayed None known 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media High volume water jet Special hazards arising from the substance or mixture Thermal decomposition can lead to release of irritating and toxic gases and vapours. Hazardous combustion products Carbon monoxide (CO), Carbon dioxide (CO2) Advice for firefighters Page 2 / 9
3 Wear self-contained breathing apparatus and protective suit. Additional information Use water spray jet to protect personnel and to cool endangered containers. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Use personal protection recommended in Section 8. Keep unprotected persons away. Ensure adequate ventilation Environmental precautions Minimize the area spreading and cover the drains. Do not allow into any sewer, on the ground or into any body of water. See Section 12 for additional ecological information. Local authorities should be advised if significant spillages cannot be contained Methods and material for containment and cleaning up Methods for containment Small spill Large spill Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal Pump up the product into a spare container suitably labelled. Methods for cleaning up Clean contaminated surface thoroughly. After cleaning, flush away traces with water Reference to other sections See Section 7,8,13 for more information. SECTION 7: Handling and storage 7.1. Precautions for safe handling Ensure adequate ventilation. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Take off all contaminated clothing and wash it before re-use Conditions for safe storage, including any incompatibilities Keep away from heat. Keep in a cool place. Handle and store at temperatures above - 15 C Specific end use(s) This information is supplied in the present Safety Data Sheet. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure Limits Keep personal exposure levels below Derived No Effect Level (DNEL) and national exposure limit values (if existing). Derived No Effect Level (DNEL) - worker Type Exposure route DNEL Remarks Chronic effects, systemic Dermal 10 mg/kg bw/d Chronic effects, systemic Inhalation 6.96 mg/m 3 Derived No Effect Level (DNEL) - Consumer Type Exposure route DNEL Remarks Chronic effects, systemic Oral 5 mg/kg bw/d Page 3 / 9
4 Chronic effects, systemic Dermal 5 mg/kg bw/d Chronic effects, systemic Inhalation 23 mg/m 3 Predicted No Effect Concentration (PNEC) Environmental compartment Predicted No Effect Concentration Remarks (PNEC) Freshwater mg/l Intermittent mg/l Marine water mg/l Impact on Sewage Treatment 520 mg/l 8.2. Exposure controls Appropriate engineering controls Ensure adequate ventilation. Individual protection measures, such as personal protective equipment Eye/face protection Recommendation(s): Wear safety glasses with side shields (or goggles). Hand Protection Protective gloves not really required. However, we recommend using protective gloves made of rubber. Nitrile rubber, NBR. Ensure that the breakthrough time of the glove material is not exceeded. Refer to glove supplier for information on breakthrough time for specific gloves. Skin and body protection Normal work clothes for the chemical industry (long legs and sleeves). Respiratory protection In case of mist, spray or aerosol exposure wear suitable personal respiratory protection and protective suit. Recommended filter type:. A/P2. Environmental exposure controls Prevent product from entering drains. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance liquid yellow, green Odour mild Odour threshold Property Value Remarks Method ph Melting point / freezing point > < C EU Method A.1 Boiling point / boiling range 348 C ASTM E Flash point >101 C EN ISO 3679 Evaporation rate Flammability (solid, gas) Explosive limits Upper explosive limits Lower explosive limits Vapour pressure C EU Method A.4 Vapour density Relative density Water solubility <0.023 g/l Insoluble in 20 C EU Method A.6 Solubility(ies) Partition coefficient >6.7 log Kow OECD 105 Autoignition temperature 240 C ASTM E Decomposition temperature Kinematic viscosity Dynamic viscosity 6.1 mpa s ISO 3219 Explosive properties Not explosive. Oxidising properties Not oxidising. Density 0.88 g/cm 3 ISO Page 4 / 9
5 Bulk density 9.2. Other information. SECTION 10: Stability and reactivity Reactivity There exists no specific test data for this product. For further information, see the subsequent subsections of this chapter Chemical stability Stable under normal conditions Possibility of hazardous reactions None under normal processing Conditions to avoid Keep away from ignition sources Incompatible materials Strong oxidising agents. Acids. Bases Hazardous decomposition products Thermal decomposition can lead to release of irritating and toxic gases and vapours. Carbon monoxide (CO). Carbon dioxide (CO2). SECTION 11: Toxicological information Information on toxicological effects Information on likely routes of exposure Inhalation. Dermal. Symptoms related to the physical, chemical and toxicological characteristics None known. Numerical measures of toxicity Acute toxicity Product does not present an acute toxicity hazard based on known or supplied information. The following values are calculated based on chapter 3.1 of the GHS document Method Species Exposure route Effective dose Remarks OECD Test No. 401: Acute Oral Toxicity Rat Oral >5000 mg/kg LD50 (lethal dose) EPA OPPTS Rabbit Dermal >2000 mg/kg LD50 (lethal dose) read-across from supporting substance (structural analogue) Skin corrosion/irritation Slightly irritating but not relevant for classification. Method Species Exposure route Results: OECD Test No. 404: Acute Dermal Irritation/Corrosion Rabbit Dermal Slightly irritating. No classification according to GHS criteria. Serious eye damage/eye irritation Page 5 / 9
6 Slightly irritating but not relevant for classification. Method Species Exposure route Results: OECD Test No. 405: Acute Eye Irritation/Corrosion Rabbit Eye Slightly irritating. No classification according to GHS criteria. Respiratory or skin sensitisation No sensitising effects known. Method Species Exposure route Results: OECD Test No. 406: Skin Sensitisation Guinea pig Skin Not a skin sensitiser Germ cell mutagenicity Not mutagenic. Method Species Results: OECD Test No. 471: Bacterial Reverse in vitro Negative Mutation Test OECD Test No. 473: In vitro Mammalian Chromosome Aberration Test in vitro Negative Carcinogenicity Animal studies have not shown any carcinogenic potential. Method Species Exposure route Effective dose Remarks EU Method B.32 Mouse Dermal Animal studies have not shown any carcinogenic potential. read-across from supporting substance (structural analogue) Reproductive toxicity This product does not contain any known or suspected reproductive hazards. Method Species Exposure route Effective dose Remarks OECD Test No. 422: Combined Repeated Dose Toxicity Study with the Reproduction/Developmental Toxicity Screening Test Rat Oral >1000 mg/kg bw/d NOAEL No indication of reproductive toxicity according to OECD guideline 422 screening test. STOT - single exposure STOT - repeated exposure No classification according to GHS criteria. No classification according to GHS criteria. Method Species Exposure route Effective dose Remarks OECD Test No. 422: Combined Repeated Dose Rat Oral >1000 mg/kg bw/d NOAEL Page 6 / 9
7 Toxicity Study with the Reproduction/Developmental Toxicity Screening Test Aspiration hazard. SECTION 12: Ecological information Toxicity Low toxicity to aquatic organisms. Method Species Exposure route Effective dose Exposure time Remarks OECD Test No. 203: Fish, Acute Toxicity Test Brachydanio rerio Freshwater > h mg/l LC50 (lethal concentration) The substance has no acute effect at concentrations far exceeding its water solubility and thus considered not to be classified as hazardous to aquatic organisms. OECD Test No. 201: Freshwater Algae and Cyanobacteria, Growth Inhibition Test Pseudokirchneriell a subcapitata Persistence and degradability Readily biodegradable Freshwater > h mg/l NOEC Method Value Exposure time Results: OECD Test No. 301B: Ready Biodegradability: CO2 Evolution Test (TG 301 B) 75% 28d Readily biodegradable Bioaccumulative potential Not potentially bioaccumulable. Chemical Name Partition coefficient Bioconcentration factor (BCF) Fatty acids, C16-18 and C18-unsatd., Me esters > Mobility in soil Low mobility in soil Results of PBT and vpvb assessment This substance does not meet the criteria for classification as PBT or vpvb Other adverse effects. SECTION 13: Disposal considerations Waste treatment methods Waste from residues/unused products The product is not classified as hazardous waste. Incinerate at a licensed installation. Page 7 / 9
8 Contaminated packaging Thoroughly emptied and clean packaging may be recycled. Contaminated packaging materials must be disposed of in the same manner as the product. Waste codes / waste designations according to EWC / AVV Recommended Use: Waste from residues/unused products: Other Information Waste codes should be assigned by the user based on the application for which the product was used. SECTION 14: Transport information ADR Road transport 14.1 UN number Not regulated 14.2 UN proper shipping name Not regulated 14.3 Transport hazard class(es) Not regulated 14.4 Packing Group Not regulated 14.5 Environmental hazard 14.6 Special precautions for user None RID Rail transport 14.1 UN number Not regulated 14.2 UN proper shipping name Not regulated 14.3 Transport hazard class(es) Not regulated 14.4 Packing Group Not regulated 14.5 Environmental hazard 14.6 Special precautions for user None IMDG Sea transport 14.1 UN number Not regulated 14.2 UN proper shipping name Not regulated 14.3 Transport hazard class(es) Not regulated 14.4 Packing Group Not regulated 14.5 Marine pollutant 14.6 Special precautions for user None 14.7 Transport in bulk according Product name: Rape seed oil fatty acid methyl esters; Y, P, 2, 2G to Annex II of MARPOL 73/78 and the IBC Code IATA Air transport 14.1 UN number Not regulated 14.2 UN proper shipping name Not regulated 14.3 Transport hazard class(es) Not regulated 14.4 Packing Group Not regulated 14.5 Environmental hazard 14.6 Special precautions for user None SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture International Regulations. European Union Named dangerous substances per Seveso Directive (2012/18/EU) France Occupational Illnesses (R-463-3, France) Germany Page 8 / 9
9 Water hazard class (WGK) slightly hazardous to water (WGK 1) Chemical safety assessment A Chemical Safety Assessment has been carried out for this substance. SECTION 16: Other information Key or legend to abbreviations and acronyms used in the safety data sheet Full text of H-Statements referred to under section 3 H332 - Harmful if inhaled H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H301 - Toxic if swallowed H311 - Toxic in contact with skin H331 - Toxic if inhaled H370 - Causes damage to organs if inhaled H225 - Highly flammable liquid and vapour Issue Date Revision Date 16-Mar Mar-2018 Revision Note SDS sections updated: 3, 8, 15 This safety data sheet complies with the requirements of: Regulation (EC) No. 1907/2006, COMMISSION REGULATION (EU) No. 830/2015 of 20 May Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 9 / 9
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