MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Bathroom Cream Cleaner RAPIDO Spray 1.2. Relevant identified uses of the substance or mixture and uses advised against To be used on tiles and terracotta, glass, plastic (shower stalls), as well as on chrome and stainless steel surfaces of (kitchen sinks), table tops, hood, sinks, bathtubs, etc. Do not use on marble, wood or porous or damaged surfaces Details of the supplier of the safety data sheet Manufacturer: Zakłady Chemiczne "UNIA" Spółdzielnia Pracy Address: ul. Główna 14, Poznań, Poland Telephone number: Fax number: address of the person responsible for the MSDS: 1.4. Emergency phone number Mon. to Fri., 6 45 AM PM SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Pursuant to the provisions in force, the product is not classified as hazardous Label elements P102 Keep out of the reach of children Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances not applicable 3.2. Mixtures Hazardous component: Classification according to Regulation (EC) No. 1272/2008 of 16 December 2008 on classification, labelling and packaging (CLP) Name % weight aquatic solution of polyoxyethylene glycol ether of synthetic fatty alcohol CAS EC no.(einecs) Index no. Registration no. Classification according to Regulation 1272/2008/EC 1<c< Polymer - - Acute Tox 4, H302 Aquatic Acute 1, H400 citric acid monohydrate c< xxxx Classification compliant with the Council Directive 67/548/ECC Name % weight aquatic solution of polyoxyethylene glycol ether of synthetic fatty alcohol CAS EC no.(einecs) Eye Damage 2, H319 Index no. Hazard symbol Risk phrases 1<c< Polymer - Xn N citric acid monohydrate c< Xi R36 Allergens in the fragrance agent: - R22 R50 Zakłady Chemiczne "UNIA" Spółdzielnia Pracy, ul. Główna 14, Poznań, Poland Page 1 of 5

2 SECTION 4: First aid measures 4.1. Description of first aid measures Inhaling: In case of risk of inhaling the product, remove the injured from the hazardous area Ensure peace and quiet, protect the injured from heat loss. If breathing stops, apply artificial respiration. If necessary, provide medical assistance. Skin contact: In case of contamination of the skin/clothing, take off immediately all contaminated clothing and wash the skin with plenty of water. If necessary, provide medical assistance. Contact with eyes: In case of contact with eyes, rinse immediately with plenty of water for at least 15 minutes with eyelids kept open. In the case of persistent symptoms, provide assistance of an eye doctor. Ingestion: If swallowed, do not induce vomiting. Provide immediately medical assistance Most important symptoms and effects, both acute and delayed Undetermined 4.3. Recommendations for immediate first-aid treatment and further treatment of the injured: Undetermined SECTION 5: Firefighting measures 5.1. Extinguishing media Extinguish fire in the presence of the substance with media suitable for burning materials 5.2. Special hazards arising from the substance or mixture Inflammable liquid 5.3. Advice for firefighters Containers exposed to high temperature should be cooled with water from a safe distance, and if possible, removed from the hazardous area. Flammable after evaporation of water. Wear self-contained breathing apparatuses, protective gloves and clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear rubber gloves, goggles or face cover, protective clothing. In the case of major accidents, remove the people from the hazardous area. The product can make the surface slippery. Avoid ignition sources. Avoid direct contact with the released product. Avoid inhalation of vapour. In the case of a breakdown in a closed space, ensure effective ventilation/airing Environmental precautions Do not allow the product to enter sewage system, sewers, surface- and groundwater and soil. In the case of release of large quantities of product, inform the competent authorities Methods and material for containment and cleaning up If possible stop the leak - shut off and seal the liquid source, place the damaged container in protective packaging. In the case of large spills, dam up the place where liquid accumulates; the spilled liquid should be pumped out or collected with absorbent material (sand, kieselguhr, universal binder, sawdust) into a labelled plastic container, and it should be properly disposed of. Rinse the contaminated surface with water. Neutralise it in compliance with the regulations in force Reference to other sections - SECTION 7: Handling and storage 7.1. Precautions for safe handling The product is non-flammable and non-oxidizing. When working with large amounts of the product, use protective clothing and rubber gloves (in the case of prolonged contact) Conditions for safe storage, including any incompatibilities Store in sealed commercial containers at C in dry, ventilated rooms. The product should be protected from sunlight and heat sources Specific end use(s) Control parameters - not applicable 8.2. Exposure controls SECTION 8: Exposure controls/personal protection Zakłady Chemiczne "UNIA" Spółdzielnia Pracy, ul. Główna 14, Poznań, Poland Page 2 of 5

3 Personal protective equipment should meet the requirements stipulated in EU legislation. Respiratory protection: Eye/face protection Hand protection: Rubber gloves in the case of prolonged contact with skin. Technical means of protection General room ventilation or local exhaust ventilation. Other protection equipment: In an emergency situation, if the concentration of the substance at the workstation is not known, use personal protective equipment of the highest recommended protection class. An employer shall ensure that the used personal protective equipment, clothing and footwear have protective properties and it shall ensure their proper cleaning, maintenance, repair and decontamination. SECTION 9: Physical and chemical properties 9.1. Information on the basic physical and chemical properties a) Appearance: a white milk liquid b) Odour: characteristic of the used fragrance agent c) Odour threshold: no data d) ph: 2-3 e) Melting point/freezing point no data f) Initial boiling point and boiling range no data g) Flash point not applicable h) Evaporation rate no data i) Flammability (solid, gas) inflammable j) Upper/lower flammability or explosive limits not applicable k) Vapour pressure no data l) Vapour density no data m) Relative density approx. 1.0 g/cm 3 n) Solubility in water, no limitation o) Partition coefficient: n-octanol/water no data p) Auto-ignition temperature not applicable q) Decomposition temperature no data r) Viscosity no data s) Explosive properties not applicable t) Oxidising properties not applicable 9.2. Other information. SECTION 10: Reactivity and stability Reactivity No dangerous reactions are known Chemical stability At temp o C the mixture is stable Hazardous reactions Under normal conditions of storage and use of the mixture unknown Conditions to avoid Under normal conditions of storage and use of the mixture unknown Incompatible materials Hazardous decomposition products Under normal conditions of storage and use unknown Zakłady Chemiczne "UNIA" Spółdzielnia Pracy, ul. Główna 14, Poznań, Poland Page 3 of 5

4 SECTION 11: Toxicological information Information on toxicology effects for: - Citric acid monohydrate Acute toxicity orally LD mg/kg (rat); LD mg/kg (mouse) Acute toxicity after application on skin LD mg/kg (rat); LD mg/kg (mouse) - Alcohol ethoxylates C12-15 Acute toxicity orally LD50 2 g/kg (rat) Local effects of the mixture: - Inhalation - no reports on significant effects or critical hazards - Ingestion - no reports on significant effects or critical hazards - Skin contact - no reports on significant effects or critical hazards - Eye contact - no reports on significant effects or critical hazards SECTION 12: Ecological information Toxicity for: - Citric acid monohydrate Ecotoxicity for fish (LC50/96 h/gold fish) = mg/l - Alcohol ethoxylates C12-15 Acute toxicity EC50 0,7 mg/l fresh water algae Pseudokirchneriella subcapitata exposure 96h Acute toxicity EC μg/l fresh water Daphnia magna exposure 48h Acute toxicity EC μg/l fresh water fish Pimephales promelas-1,15g exposure 96h Persistence and degradability Alcohol ethoxylates C12-15 Test EU 71,3% - 28 days Bioaccumulative potential not applicable Mobility in soil Results of PBT and vpvb assessment Other hazardous effects No reports on significant effects or critical hazards SECTION 13: Disposal considerations Waste treatment methods The product should be completely used up. Empty containers can be disposed in containers for collection of plastic packaging. Do not mix with other types of waste; destroy in accordance with applicable regulations on disposal of waste. Waste code (from European Waste Catalogue): Waste not otherwise specified Plastic packaging (for bottles) Paper and cardboard packaging (for cardboard) SECTION 14: Transport information UN no. - not applicable UN proper shipping name - not applicable Transport hazard class(es) - not applicable Packaging group - not applicable Environmental hazards - none, according to the regulations in force Special precautions for users - not required Transport in bulk according to Annex II to MARPOL 73/78 and the IBC Code - not applicable SECTION 15: Regulatory Information Safety, health and environmental regulations/legislation specific for the substance or mixture - Regulation (EC) No. 648/2004 of the European Parliament and the Council of 31 March 2004 on detergents - Commission Regulation (EC) No. 907/2006 of 20 June 2006 amending Regulation (EC) No. 648/2004 of the European Parliament and the Council on detergents, in order to adapt its Annexes III and VII - Regulation (EC) No. 1907/2006 of the European Parliament and the Council of 18 December 2006 concerning the registration, evaluation, authorisation and restriction of chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No. 793/93 and Commission Regulation (EC) No. 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC. - Regulation (EC) No. 1272/2008 of 16 December 2008 on classification, labelling and packaging (CLP) Zakłady Chemiczne "UNIA" Spółdzielnia Pracy, ul. Główna 14, Poznań, Poland Page 4 of 5

5 15.2. Chemical safety assessment Chemical safety assessment has not been performed for the substance of the mixture. SECTION 16: Other information The information herein applies only to the title product, reflecting the state of knowledge and experience. The information contained herein should be considered only as an aid to safe conduct in transport, distribution, handling and storage. Safety data sheet is not a certificate of product quality. The user of the product is required to comply with all applicable standards and regulations, and shall be responsible for improper use of information contained in the sheet. List of phrases used in point 3: Acute skin Tox. 4, - Acute toxicity - orally, cat. 4 Aquatic Acute 1 - hazardous to the aquatic environment cat. 1 Eye damage 2 - eye irritation, hazard cat. 2 H302 - Harmful if swallowed H319 - Causes serious eye irritation R400 - Very toxic to aquatic life Xn - Harmful Xi - Irritant N - Dangerous for the environment R22 - Harmful if swallowed. R36 - Irritating to eyes R50 - Very toxic to aquatic organisms Trainings: Persons participating in the trade of hazardous substances should be trained in the handling, safety and hygiene. The safety data sheet is based on valid regulations and safety data sheets and supplier's data sheets. Amendments have been made in points: - Zakłady Chemiczne "UNIA" Spółdzielnia Pracy, ul. Główna 14, Poznań, Poland Page 5 of 5