Material Safety Data Sheet acc. to ISO/DIS 11014

Transcription

1 Page 1/8 1 Identification of substance Product details Application of the substance / the preparation Galvanic bath Manufacturer/Supplier: Wieland Dental + Technik GmbH & Co.KG Schwenninger Str Pforzheim Telefon + 49 (07231)-37050, Telefax + 49 (07231) Information department: Abteilung Umweltschutz Marcus.Mueller@wieland-dental.de Emergency information: +49 (07231) ( Be kindly advised that this number can only be contacted at usual office hours.) 2 Composition/Data on components Chemical characterization Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: potassium cyanide Danger: 3.1.O/2, 3.1.D/1, 3.1.I/ % Warning: 4.1.C/ Kupfer(II)-hydroxidcarbonat Basisches Kupferkarbonat Copper(II) carbonate basic Basic Cupric carbonate Kupferblau Danger: 3.1.O/3, 3.2/2, 3.3/2A, 3.8/3 1-5% Additional information: For the wording of the listed risk phrases refer to section Hazards identification Hazard description: Very toxic Dangerous for the environment Information pertaining to particular dangers for man and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Very toxic by inhalation, in contact with skin and if swallowed. Contact with acids liberates very toxic gas. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. NFPA ratings (scale 0-4) Health = 4 Fire = 0 Reactivity = 0 WHMIS-ratings (scale 0-4) HEALTH FIRE REACTIVITY Health = 4 Fire = 0 Reactivity = 0 (Contd. on page 2)

2 Page 2/8 GHS label elements (Contd. of page 1) Danger 3.1/2 - Fatal if swallowed. 3.1/1 - Fatal in contact with skin. 3.1/2 - Fatal if inhaled. 4.1/2 - Toxic to aquatic life with long lasting effects. Response: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Immediately call a POISON CENTER or doctor/physician. Specific treatment is urgent (see on this label). Remove/Take off immediately all contaminated clothing. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with local/regional/national/international regulations. 4 First aid measures General information: Immediately remove any clothing soiled by the product. Remove breathing apparatus only after contaminated clothing have been completely removed. After inhalation: Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. After skin contact: Immediately wash with water and soap and rinse thoroughly. If skin irritation continues, consult a doctor. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; immediately call for medical help. 5 Fire fighting measures Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Protective equipment: Mount respiratory protective device. 6 Accidental release measures Person-related safety precautions: Wear protective equipment. Keep unprotected persons away. Measures for environmental protection: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. (Contd. on page 3)

3 Page 3/8 Ensure adequate ventilation. (Contd. of page 2) 7 Handling and storage Handling: Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Open and handle receptacle with care. Prevent formation of aerosols. Information about protection against explosions and fires: Keep respiratory protective device available. Storage: Requirements to be met by storerooms and receptacles: Store only in the original receptacle. Information about storage in one common storage facility: Do not store together with acids. Further information about storage conditions: Keep receptacle tightly sealed. 8 Exposure controls and personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Store protective clothing separately. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Material of gloves Chloroprene rubber, CR Butyl rubber, BR Fluorocarbon rubber (Viton) Nitrile rubber, NBR Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Not suitable are gloves made of the following materials: Leather gloves Strong gloves (Contd. on page 4)

4 Page 4/8 Eye protection: (Contd. of page 3) Tightly sealed goggles Body protection: Protective work clothing 9 Physical and chemical properties General Information Form: Color: Odor: Fluid Colorless Characteristic Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: Undetermined. Flash point: Not applicable. Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Density at 20 C (68 F): ca g/cm³ Solubility in / Miscibility with Water: Fully miscible. ph-value: Alkaline Solvent content: Water: > 82 % 10 Stability and reactivity Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Dangerous reactions Contact with acids releases toxic gases. Dangerous products of decomposition: Hydrogen cyanide (prussic acid) 11 Toxicological information Acute toxicity: LD/LC50 values that are relevant for classification: potassium cyanide Oral LD50 5 mg/kg (Ratte) Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Very toxic (Contd. on page 5)

5 Page 5/8 Danger through skin absorption. (Contd. of page 4) 12 Ecological information Ecotoxical effects: Remark: Toxic for fish General notes: Also poisonous for fish and plankton in water bodies. Toxic for aquatic organisms Water danger class 3 (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. 13 Disposal considerations Product: Recommendation: Must be specially treated adhering to official regulations. Contact manufacturer for recycling information. Uncleaned packagings: Recommendation: Packaging can be reused or recycled after cleaning. Packagings that cannot be cleansed are to be disposed of in the same manner as the product. Recommended cleansing agent: Water, if necessary with cleansing agents. 14 Transport information DOT regulations: Identification number: UN3413 Packing group: II Proper shipping name (technical name): POTASSIUM CYANIDE SOLUTION Label 6.1 Land transport ADR/RID (cross-border): ADR/RID class: 6.1 (T4) Toxic substances Danger code (Kemler): 60 UN-Number: 3413 Packaging group: II Special marking: Symbol (fish and tree) Description of goods: 3413 POTASSIUM CYANIDE SOLUTION (Contd. on page 6)

6 Page 6/8 Maritime transport IMDG: (Contd. of page 5) IMDG Class: 6.1 UN Number: 3413 Label 6.1 Packaging group: II EMS Number: F-A,S-A Marine pollutant: Yes Symbol (fish and tree) Propper shipping name: POTASSIUM CYANIDE SOLUTION Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 6.1 UN/ID Number: 3413 Label 6.1 Packaging group: II Propper shipping name: POTASSIUM CYANIDE SOLUTION UN "Model Regulation": UN3413, POTASSIUM CYANIDE SOLUTION, 6.1, II 15 Regulations Sara Section 355 (extremely hazardous substances): potassium cyanide Section 313 (Specific toxic chemical listings): potassium cyanide TSCA (Toxic Substances Control Act): All ingredients are listed. Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: Cancerogenity categories EPA (Environmental Protection Agency) IARC (International Agency for Research on Cancer) (Contd. on page 7)

7 Page 7/8 NTP (National Toxicology Program) TLV (Threshold Limit Value established by ACGIH) MAK (German Maximum Workplace Concentration) NIOSH-Ca (National Institute for Occupational Safety and Health) OSHA-Ca (Occupational Safety & Health Administration) (Contd. of page 6) Product related hazard informations: The product has been classified and marked in accordance with directives on hazardous materials. Hazard symbols: Very toxic Dangerous for the environment Hazard-determining components of labelling: potassium cyanide Risk phrases: Very toxic by inhalation, in contact with skin and if swallowed. Contact with acids liberates very toxic gas. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Safety phrases: Keep container tightly closed and in a well-ventilated place. Do not breathe gas/fumes/vapour/spray. After contact with skin, take off immediately all contaminated clothing, and wash immediately with plenty of water. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately. Use appropriate container to avoid environmental contamination. This material and its container must be disposed of as hazardous waste. National regulations: Water hazard class: Water danger class 3 (Self-assessment): extremely hazardous for water. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Department issuing MSDS: Abteilung Umweltschutz Contact: Herr Marcus Müller Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) GHS: Globally Harmonized System of Classification and Labelling of Chemicals ACGIH: American Conference of Governmental Industrial Hygienists NFPA: National Fire Protection Association () HMIS: Hazardous Materials Identification System () (Contd. on page 8)

8 Page 8/8 LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent (Contd. of page 7)