Material Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH)

Transcription

1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier ( ) 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Wood preservative for outdoor use. Uses advised against No information available. 1.3 Details of the supplier of the safety data sheet Supplier (manufacturer/importer/only representative/downstream user/distributor) Kurt Obermeier GmbH & Co. KG Spezialchemikalien Holzschutz Street : Berghäuser Str. 70 Postal code/city : Bad Berleburg Telephone : 0049 (0) 2751/524-0 Telefax : 0049 (0) 2751/5041 Information contact : sdb@obermeier.de 1.4 Emergency telephone number / (Mo-Fr 08:00-16:00 / 8.00am-4.00pm) SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Directive 67/548/EEC or 1999/45/EC Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. May cause sensitization by skin contact. Risk of serious damage to eyes. N ; R 50/53 R 43 Xi ; R 41 Xi ; R 38 Classification according to Regulation (EC) No. 1272/2008 [CLP] Aquatic Acute 1 ; H400 - Hazardous to the aquatic environment : Category 1 ; Very toxic to aquatic life. Aquatic Chronic 1 ; H410 - Hazardous to the aquatic environment : Category 1 ; Very toxic to aquatic life with long lasting effects. Eye Dam. 1 ; H318 - Serious eye damage/eye irritation : Category 1 ; Causes serious eye damage. Skin Irrit. 2 ; H315 - Skin corrosion/irritation : Category 2 ; Causes skin irritation. Skin Sens. 1 ; H317 - Skin sensitisation : Category 1 ; May cause an allergic skin reaction. 2.2 Label elements Labelling (67/548/EEC or 1999/45/EC) Hazard symbols and hazard statements of dangerous substances and preparations Xi ; Irritant N ; Dangerous for the environment Hazard components for labelling Propiconazole ; CAS No. : Page : 1 / 14

2 R-phrases 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 43 May cause sensitization by skin contact. 41 Risk of serious damage to eyes. 38 Irritating to skin. S-phrases 61 Avoid release to the environment. Refer to special instructions/safety data sheet. 21 When using do not smoke. 51 Use only in well-ventilated areas. 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 24/25 Avoid contact with skin and eyes. Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms Corrosion (GHS05) Environment (GHS09) Exclamation mark (GHS07) Signal word Danger Hazard components for labelling Propiconazole ; CAS No. : Hazard statements H318 Causes serious eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P310 Immediately call a POISON CENTER or doctor/ physician. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P362 Take off contaminated clothing and wash before reuse. P501 Dispose of contents/container to appropriate disposal. 2.3 Other hazards SECTION 3: Composition / information on ingredients 3.2 Mixtures Hazardous ingredients N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; EC No. : ; CAS No. : Weight fraction : 2,5-5 % Classification 67/548/EEC : N ; R50 C ; R35 Xn ; R48/22 Xn ; R22 Classification 1272/2008 [CLP] : Acute Tox. 3 ; H301 STOT RE 2 ; H373 Skin Corr. 1A ; H314 Aquatic Acute 1 ; H400 Page : 2 / 14

3 L-(+)-2-Hydroxypropionsäure ; EC No. : ; CAS No. : Weight fraction : 1-5 % Classification 67/548/EEC : Xi ; R41 Xi ; R38 Classification 1272/2008 [CLP] : Eye Dam. 1 ; H318 Skin Irrit. 2 ; H315 COCO DIMETHYLAMINE OXIDE ; EC No. : ; CAS No. : Weight fraction : 1-5 % Classification 67/548/EEC : N ; R50 Xi ; R41 Xi ; R38 Classification 1272/2008 [CLP] : Eye Dam. 1 ; H318 Skin Irrit. 2 ; H315 Aquatic Acute 1 ; H400 Propiconazole ; EC No. : ; CAS No. : Weight fraction : 1-2,5 % Classification 67/548/EEC : N ; R50/53 R43 Xn ; R22 Classification 1272/2008 [CLP] : Acute Tox. 4 ; H302 Skin Sens. 1 ; H317 Aquatic Acute 1 ; H400 Aquatic Chronic 1 ; H410 (2-METHOXYMETHYLETHOXY)PROPANOL ; REACH registration No. : xxxx ; EC No. : ; CAS No. : Weight fraction : 1-10 % Classification 67/548/EEC : Substance with a common (EC) occupational exposure limit value. Classification 1272/2008 [CLP] : Substance with a common (EC) occupational exposure limit value. Additional information Full text of R-, H- and EUH-phrases: see section 16. SECTION 4: First aid measures 4.1 Description of first aid measures General information Change contaminated, saturated clothing. When in doubt or if symptoms are observed, get medical advice. Never give anything by mouth to an unconscious person or a person with cramps. In case of inhalation Remove casualty to fresh air and keep warm and at rest. Provide fresh air. In case of skin contact After contact with skin, wash immediately with plenty of water and soap. In case of skin reactions, consult a physician. After eye contact Rinse immediately carefully and thoroughly with eye-bath or water. In case of eye irritation consult an ophthalmologist. After ingestion Do NOT induce vomiting. Rinse mouth thoroughly with water. Self-protection of the first aider First aider: Pay attention to self-protection! Information to physician Treatment Treat symptomatically. 4.2 Most important symptoms and effects, both acute and delayed May cause an allergic skin reaction. Causes serious eye damage. Causes skin irritation. 4.3 Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures Page : 3 / 14

4 5.1 Extinguishing media Suitable extinguishing media Carbon dioxide (CO2) alcohol resistant foam Water spray jet Extinguishing powder Sand Unsuitable extinguishing media 5.2 Special hazards arising from the substance or mixture 5.3 Advice for firefighters In case of fire toxic gases may be formed. Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. Special protective equipment for firefighters Wear a self-contained breathing apparatus and chemical protective clothing. 5.4 Additional information SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Take the precautions customary when handling chemicals. Use personal protection equipment. See protective measures under point 7 and Environmental precautions Do not allow to enter into surface water or drains. Prevent spread over a wide area (e.g. by containment or oil barriers). 6.3 Methods and material for containment and cleaning up For cleaning up Take up mechanically. Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Collect in closed and suitable containers for disposal. 6.4 Reference to other sections 6.5 Additional information SECTION 7: Handling and storage 7.1 Precautions for safe handling Avoid contact with skin and eyes. Protective measures Use only in well-ventilated areas. Do not breathe gas/fumes/vapour/spray. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep/Store only in original container. Hints on joint storage Storage class (TRGS 510) : 12 Further information on storage conditions Protect containers against damage. Protect against : Frost 7.3 Specific end use(s) Page : 4 / 14

5 SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational exposure limit values (2-METHOXYMETHYLETHOXY)PROPANOL ; CAS No. : Limit value type (country of origin) : TRGS 900 ( D ) Limit value : 50 ppm / 310 mg/m 3 Peak limitation : 1(I) Version : Limit value type (country of origin) : TWA ( EC ) Limit value : 50 ppm / 308 mg/m 3 Remark : H Version : Biological limit values DNEL/DMEL and PNEC values DNEL/DMEL PNEC 8.2 Exposure controls Personal protection equipment Eye/face protection Eye glasses with side protection Skin protection Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Suitable material : Butyl caoutchouc (butyl rubber) NBR (Nitrile rubber) Breakthrough time (maximum wearing time) : 480 minutes. Check leak tightness/impermeability prior to use. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. Thickness of the glove material : 0,4 mm Respiratory protection Respiratory protection necessary at: exceeding exposure limit values insufficient ventilation Handling larger quantities. aerosol or mist formation. Suitable respiratory protection apparatus Filtering device with filter or ventilator filtering device of type: A B E K General health and safety measures Avoid contact with skin, eyes and clothes. Remove contaminated, saturated clothing. Wash hands before breaks and after work. Keep away from food, drink and animal feeding stuffs. 8.3 Additional information SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Physical state : liquid Colour : Different according to colour Page : 5 / 14

6 Odour light. Safety relevant basis data Solidifying point : ( 1 bar / 1 Pa ) Brookfield Freezing point : Decomposition temperature : Flash point : not relevant Ignition temperature : Lower explosion limit : Upper explosion limit : Density : ( 20 C ) ca. 1 g/cm 3 Bulk density : not relevant Fat solubility : ( 20 C ). Solubility in water Fully miscible ph value: ( 20 C / 10 % ) ca. 7,5 log P O/W : Viscosity : ( 20 C ) Solid content : ca Wt % Odour threshold : Relative vapour density : ( 20 C ) Evaporation rate : Vapourisation rate : Flammable solids : Flammable gases : Oxidising liquids : Explosive properties : Corrosive to metals : 9.2 Other information SECTION 10: Stability and reactivity Reactivity No dangerous reactions known Chemical stability When using the recommended storage and handling conditions (see Section 7) Possibility of hazardous reactions No dangerous reactions known Conditions to avoid No information available Incompatible materials No information available Hazardous decomposition products No information available Additional information SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute effects Acute oral toxicity Page : 6 / 14

7 Parameter : LC50 ( L-(+)-2-Hydroxypropionsäure ; CAS No. : ) Oral 3730 mg/kg Parameter : LD50 ( ETHYL [2-(4-PHENOXYPHENOXY)ETHYL]CARBAMATE ; CAS No. : ) Oral > mg/kg Parameter : LD50 ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Oral 261 mg/kg OECD 401 Parameter : LD50 ( Propiconazole ; CAS No. : ) Oral < 2000 mg/kg Acute dermal toxicity Parameter : LC50 ( L-(+)-2-Hydroxypropionsäure ; CAS No. : ) Dermal Rabbit > 2000 mg/kg Parameter : LD50 ( ETHYL [2-(4-PHENOXYPHENOXY)ETHYL]CARBAMATE ; CAS No. : ) Dermal > 2000 mg/kg Parameter : LD50 ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Dermal > 600 mg/kg OECD 402 Parameter : LD50 ( Propiconazole ; CAS No. : ) Dermal > 4000 mg/kg Acute inhalation toxicity Parameter : LD50 ( ETHYL [2-(4-PHENOXYPHENOXY)ETHYL]CARBAMATE ; CAS No. : ) Inhalation > 4400 mg/kg 4 h Parameter : LD50 ( Propiconazole ; CAS No. : ) Inhalation > 5800 mg/m 3 4 h OECD 403 Specific symptoms in animal studies Irritant and corrosive effects Primary irritation to the skin Page : 7 / 14

8 Causes skin irritation. Irritation to eyes Causes serious eye damage. Irritation to respiratory tract Sensitisation In case of skin contact May cause an allergic skin reaction. In case of inhalation Repeated dose toxicity (subacute, subchronic, chronic) Subacute oral toxicity Parameter : NOAEL(C) ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Oral 9 mg/kg 90 d Parameter : NOAEL(C) ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Oral Dog 20 mg/kg 90 d Subacute dermal toxicity Parameter : NOAEL(C) ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Dermal 15 mg/kg 90 d CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction) Carcinogenicity Germ cell mutagenicity/genotoxicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard 11.2 Toxicokinetics, metabolism and distribution 11.3 Other adverse effects 11.4 Additional information SECTION 12: Ecological information Page : 8 / 14

9 12.1 Toxicity Aquatic toxicity Acute (short-term) fish toxicity Parameter : LC50 ( ETHYL [2-(4-PHENOXYPHENOXY)ETHYL]CARBAMATE ; CAS No. : ) Oncorhynchus mykiss (Rainbow trout) 1,6 mg/l Parameter : LC50 ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Oncorhynchus mykiss (Rainbow trout) 0,68 mg/l OECD 203 Parameter : LC50 ( L-(+)-2-Hydroxypropionsäure ; CAS No. : ) Brachydanio rerio (zebra-fish) 320 mg/l Parameter : LC50 ( Propiconazole ; CAS No. : ) Oncorhynchus mykiss (Rainbow trout) Evaluation parameter : Acute (short-term) fish toxicity 4,3 mg/l OECD 203 Parameter : LC50 ( COCO DIMETHYLAMINE OXIDE ; CAS No. : ) Brachydanio rerio (zebra-fish) mg/l OECD 203 Parameter : LC50 ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Lepomis macrochirus (Bluegill) 0,45 mg/l US-EPA Parameter : LC50 ( ETHYL [2-(4-PHENOXYPHENOXY)ETHYL]CARBAMATE ; CAS No. : ) Cyprinus carpio (Common Carp) 10,3 mg/l Acute (short-term) daphnia toxicity Parameter : EC50 ( ETHYL [2-(4-PHENOXYPHENOXY)ETHYL]CARBAMATE ; CAS No. : ) Daphnia magna (Big water flea) 0,4 mg/l 48 h Parameter : EC50 ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Daphnia magna (Big water flea) 0,073 mg/l 48 h US-EPA Parameter : EC50 ( L-(+)-2-Hydroxypropionsäure ; CAS No. : ) Daphnia magna (Big water flea) 240 mg/l Parameter : EC50 ( COCO DIMETHYLAMINE OXIDE ; CAS No. : ) Daphnia magna (Big water flea) 4,4 mg/l 48 h US-EPA Page : 9 / 14

10 Parameter : EC50 ( Propiconazole ; CAS No. : ) Daphnia magna (Big water flea) Evaluation parameter : Acute (short-term) daphnia toxicity 10,2 mg/l 48 h OECD 202 Chronic (long-term) daphnia toxicity Parameter : NOEC ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Daphnia magna (Big water flea) 0,024 mg/l 21 d OECD 211 Acute (short-term) algae toxicity Parameter : EC50 ( ETHYL [2-(4-PHENOXYPHENOXY)ETHYL]CARBAMATE ; CAS No. : ) Scenedesmus subspicatus 1,1 mg/l Parameter : EC50 ( COCO DIMETHYLAMINE OXIDE ; CAS No. : ) Pseudokirchneriella subcapitata Evaluation parameter : Inhibition of growth rate 0,11 mg/l US-EPA Parameter : ErC50 ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Pseudokirchneriella subcapitata 0,054 mg/l US-EPA Parameter : ErC10 ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Desmodesmus subspicatus 0,012 mg/l 72 h OECD 201 Parameter : EC50 ( COCO DIMETHYLAMINE OXIDE ; CAS No. : ) Algae 0,11 mg/l Parameter : EC50 ( Propiconazole ; CAS No. : ) Pseudokirchneriella subcapitata Evaluation parameter : Acute (short-term) algae toxicity 9 mg/l 72 h OECD 201 Bacteria toxicity Parameter : EC50 ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) 18 mg/l 3 h Parameter : EC50 ( COCO DIMETHYLAMINE OXIDE ; CAS No. : ) Pseudomonas putida 190 mg/l 16 h DIN / part 8 Page : 10 / 14

11 Terrestrial toxicity Useful insect toxicity Parameter : LD50 ( ETHYL [2-(4-PHENOXYPHENOXY)ETHYL]CARBAMATE ; CAS No. : ) Apis mellifera (bee) 1022 ppm 24 h Acute earthworm toxicity Parameter : LC50 ( ETHYL [2-(4-PHENOXYPHENOXY)ETHYL]CARBAMATE ; CAS No. : ) Eisenia foetida Effective concentration : 850 ppm 14 d Parameter : LC50 ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Eisenia foetida Effective concentration : > 1000 mg/kg 14 d OECD 207 Effects on soil microorganisms Parameter : NOEC ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Effective concentration : 1000 mg/kg 28 d OECD 216 (nitrogen transformation test) Plant toxicity Chronic plant toxicity Parameter : NOEC ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Effective concentration : 1000 mg/kg 21 d OECD 208 Effects in sewage plants 12.2 Persistence and degradability Abiotic degradation Biodegradation Analytical method : Specific analysis ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Degradation rate : ca. 96 % Time : 12 d OECD 303/ EEC 92/69/V, C10 Analytical method : Specific analysis ( COCO DIMETHYLAMINE OXIDE ; CAS No. : ) Degradation rate : > 80 % OECD 302B/ ISO 9888/ EEC 92/69/V, C.9 Analytical method : Specific analysis ( COCO DIMETHYLAMINE OXIDE ; CAS No. : ) Degradation rate : 80 % Time : 28 d OECD 301B/ ISO 9439/ EEC 92/69/V, C.4-C Analytical method : Specific analysis ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Degradation rate : 91 % Time : 28 d OECD 302B/ ISO 9888/ EEC 92/69/V, C.9 Analytical method : Specific analysis ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine ; CAS No. : ) Page : 11 / 14

12 Degradation rate : 79 % Time : 28 d OECD 301D/ EEC 92/69/V, C.4-E 12.3 Bioaccumulative potential No indication of bioaccumulation potential Mobility in soil 12.5 Results of PBT and vpvb assessment This substance does not meet the PBT/vPvB criteria of REACH, annex XIII Other adverse effects 12.7 Further ecological information Additional information Discharge into the environment must be avoided. SECTION 13: Disposal considerations 13.1 Waste treatment methods The allocation of waste identity numbers/waste descriptions must be carried out according to the EEC, specific to the industry and process. SECTION 14: Transport information 14.1 UN number UN UN proper shipping name Land transport (ADR/RID) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine Propiconazole ) Sea transport (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine COCO DIMETHYLAMINE OXIDE Propiconazole ) Air transport (ICAO-TI / IATA-DGR) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( N-(3-aminopropyl)-N-dodecylpropane-1,3-diamine Propiconazole ) 14.3 Transport hazard class(es) Land transport (ADR/RID) Class(es) : 9 Classification code : M6 Hazard identification number (Kemler No.) : 90 Tunnel restriction code : E Special provisions : LQ 7 E 1 Hazard label(s) : 9 / N Sea transport (IMDG) Class(es) : 9 EmS-No. : F-A / S-F Special provisions : LQ 5 l E 1 Hazard label(s) : 9 / N Air transport (ICAO-TI / IATA-DGR) Page : 12 / 14

13 Class(es) : 9 Special provisions : E 1 Hazard label(s) : 9 / N 14.4 Packing group III 14.5 Environmental hazards Land transport (ADR/RID) : Yes Sea transport (IMDG) : Yes (P) Air transport (ICAO-TI / IATA-DGR) : Yes 14.6 Special precautions for user SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or 15.1 mixture National regulations Water hazard class (WGK) Class : 2 (Hazardous to water) Classification according to VwVwS 15.2 Chemical Safety Assessment No information available. SECTION 16: Other information 16.1 Indication of changes 02. Labelling (67/548/EEC or 1999/45/EC) - Hazard components for labelling 08. Occupational exposure limit values 16.2 Abbreviations and acronyms REACH - Registration, Evaluation, Authorisation of Chemicals GHS - Globally Hamonised System of Classifikation and Labeling CLP - Classification, Labeling and Packaging of Substances and Mixtures CAS - Chemical Abstract Service TWA - Time Weighted Average DNEL/DMEL - Derived No Effect Level PNEC - Predicted No Effect Concentration STP - Sewage Treatment Plant TRGS - Technical Rules for Hazardous Substances (German Regulations) STEL - Short-term Exposure Limit TLV - threshold limit valueagw - threshold limit value RCP - Reciprocal Calculation Procedure ATE - Acute Toxicity Estimate MAK threshold limit value LD50 - Lethal Dosie, 50% LC50 - Lethal concentration, 50% OECD - Organization for Economic Cooperation and Developmen NOAEL - No Observed Adverse Effect Level EC50 - half maximal effective concentration NOEC - No Observed Effect Concentration PBT - Persistent, Bioaccumulative, Toxic vpvb - very Persistent, very Bioaccumulative ADR/RID - European Agreement concerning the International Carriage of Dangerous Goods by Road (Accord européen relatif au transport international des marchandises Dangereuses par Route)/Regulations Concerning the International Transport of Dangerous Goods by Rail (Règlement concernant le transport International ferroviaire de marchandises Dangereuses) IMDG - International Maritime Dangerous Goods Code Page : 13 / 14

14 ICAO - International Civil Aviation Association IATA - International Air Transport Association VwVws - German administrative regulation on the classification of substances hazardous to water into water hazard classes 16.3 Key literature references and sources for data 16.4 Relevant R-phrases (Number and full text) H301 H302 H314 H315 H317 H318 H373 H400 H410 Toxic if swallowed. Harmful if swallowed. Causes severe skin burns and eye damage. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. 22 Harmful if swallowed. 35 Causes severe burns. 38 Irritating to skin. 41 Risk of serious damage to eyes. 43 May cause sensitization by skin contact. 48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed. 50 Very toxic to aquatic organisms. 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Training advice 16.6 Additional information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. Page : 14 / 14