Safety Data Sheet acc. to OSHA HCS

Transcription

1 Safety Data Sheet acc. to OSHA HCS Page 1/10 Printing date 10/05/2015 Reviewed on 10/05/ Identification Product identifier Trade name: TECHNOVIT 3040 LIQUID Article number: 14652(L) Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Laboratory chemicals Details of the supplier of the safety data sheet Manufacturer/Supplier: Electron Microscopy Sciences 1560 Industry Road USA-Hatfield, PA Tel: Fax: sgkcck@aol.com Information department: Product safety department Emergency telephone number: ChemTrec Contract CCN Hazard(s) identification Classification of the substance or mixture GHS02 Flame Flam. Liq. 2 H225 Highly flammable liquid and vapor. GHS08 Health hazard STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS07 Acute Tox. 4 H302 Harmful if swallowed. Skin Irrit. 2 H315 Causes skin irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation. Label elements GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS02 GHS07 GHS08 Signal word Danger (Contd. on page 2) US

2 Safety Data Sheet acc. to OSHA HCS Page 2/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID (Contd. of page 1) Hazard-determining components of labeling: methyl methacrylate N,N-dimethyl-p-toluidine Hazard statements Highly flammable liquid and vapor. Harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. Precautionary statements Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use explosion-proof electrical/ventilating/lighting/equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves / eye protection / face protection. Wear protective gloves. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Specific treatment (see on this label). If swallowed: Call a poison center/doctor if you feel unwell. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention. Get medical advice/attention if you feel unwell. Rinse mouth. In case of fire: Use for extinction: CO2, powder or water spray. Take off contaminated clothing and wash it before reuse. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations. Classification system: NFPA ratings (scale 0-4) Health = 1 Fire = 3 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH FIRE REACTIVITY Health = 1 Fire = 3 Reactivity = 0 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. (Contd. on page 3) US

3 Safety Data Sheet acc. to OSHA HCS Page 3/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID vpvb: Not applicable. (Contd. of page 2) 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: methyl methacrylate % N,N-dimethyl-p-toluidine % 4 First-aid measures Description of first aid measures General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: Immediately call a doctor. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water. For safety reasons unsuitable extinguishing agents: Water with full jet Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. (Contd. on page 4) US

4 Safety Data Sheet acc. to OSHA HCS Page 4/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID See Section 13 for disposal information. (Contd. of page 3) 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect from heat. Protect against electrostatic charges. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. Protect from heat and direct sunlight. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: methyl methacrylate PEL Long-term value: 410 mg/m³, 100 ppm REL Long-term value: 410 mg/m³, 100 ppm TLV Short-term value: 410 mg/m³, 100 ppm Long-term value: 205 mg/m³, 50 ppm (SEN) NIC-DSEN N,N-dimethyl-p-toluidine WEEL Long-term value: 0.5 ppm Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the skin. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. (Contd. on page 5) US

5 Safety Data Sheet acc. to OSHA HCS Page 5/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID Protection of hands: (Contd. of page 4) Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Fluid Color: Colorless Odor: Characteristic Odour threshold: Not determined. ph-value: Not determined. Change in condition Melting point/melting range: Boiling point/boiling range: -48 C (-54 F) 100 C (212 F) Flash point: 10 C (50 F) Flammability (solid, gaseous): Not flammable. Ignition temperature: 430 C (806 F) Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible. Explosion limits: Lower: 2.1 Vol % Upper: 12.5 Vol % Vapor pressure at 20 C (68 F): 47 hpa (35 mm Hg) (Contd. on page 6) US

6 Safety Data Sheet acc. to OSHA HCS Page 6/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID Density at 20 C (68 F): 0.94 g/cm³ (7.844 lbs/gal) Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water at 20 C (68 F): 1.6 g/l Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Kinematic: Not determined. Not determined. Solvent content: Organic solvents: 0.0 % Other information No further relevant information available. (Contd. of page 5) 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: methyl methacrylate Oral LD mg/kg (rat) Primary irritant effect: on the skin: Irritant to skin and mucous membranes. on the eye: No irritating effect. Sensitization: Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Irritant Carcinogenic categories IARC (International Agency for Research on Cancer) methyl methacrylate 3 NTP (National Toxicology Program) None of the ingredients is listed. (Contd. on page 7) US

7 Safety Data Sheet acc. to OSHA HCS Page 7/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID OSHA-Ca (Occupational Safety Health Administration) None of the ingredients is listed. (Contd. of page 6) 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behavior in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. 14 Transport information UN-Number DOT, ADR, IMDG, IATA UN1247 UN proper shipping name DOT Methyl methacrylate monomer, stabilized ADR 1247 Methyl methacrylate monomer, stabilized IMDG, IATA METHYL METHACRYLATE MONOMER, STABILIZED Transport hazard class(es) DOT Class 3 Flammable liquids (Contd. on page 8) US

8 Safety Data Sheet acc. to OSHA HCS Page 8/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID Label 3 ADR, IMDG, IATA (Contd. of page 7) Class 3 Flammable liquids Label 3 Packing group DOT, ADR, IMDG, IATA II Environmental hazards: Marine pollutant: No Special precautions for user Warning: Flammable liquids Danger code (Kemler): 339 EMS Number: F-E,S-D Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport/Additional information: Not applicable. DOT Quantity limitations On passenger aircraft/rail: 5 L On cargo aircraft only: 60 L ADR Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml IMDG Limited quantities (LQ) 1L Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml UN "Model Regulation": UN1247, Methyl methacrylate monomer, stabilized, 3, II 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): methyl methacrylate TSCA (Toxic Substances Control Act): All ingredients are listed. (Contd. on page 9) US

9 Safety Data Sheet acc. to OSHA HCS Page 9/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID Proposition 65 Chemicals known to cause cancer: N,N-dimethyl-p-toluidine Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. Chemicals known to cause developmental toxicity: None of the ingredients is listed. (Contd. of page 8) Carcinogenic categories EPA (Environmental Protection Agency) methyl methacrylate E, NL TLV (Threshold Limit Value established by ACGIH) methyl methacrylate A4 NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS02 GHS07 GHS08 Signal word Danger Hazard-determining components of labeling: methyl methacrylate N,N-dimethyl-p-toluidine Hazard statements Highly flammable liquid and vapor. Harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. Precautionary statements Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use explosion-proof electrical/ventilating/lighting/equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves / eye protection / face protection. Wear protective gloves. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. (Contd. on page 10) US

10 Safety Data Sheet acc. to OSHA HCS Page 10/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID (Contd. of page 9) Specific treatment (see on this label). If swallowed: Call a poison center/doctor if you feel unwell. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention. Get medical advice/attention if you feel unwell. Rinse mouth. In case of fire: Use for extinction: CO2, powder or water spray. Take off contaminated clothing and wash it before reuse. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Date of preparation / last revision 10/05/2015 / - Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Flam. Liq. 2: Flammable liquids, Hazard Category 2 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2 US

11 Safety data sheet according to 1907/2006/EC, Article 31 Page 1/9 Printing date Revision: Identification of the substance/mixture and of the company/undertaking Product identifier Trade name: TECHNOVIT 3040 LIQUID Article number: 14652(L) Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Laboratory chemicals Details of the supplier of the safety data sheet Manufacturer/Supplier: Electron Microscopy Sciences 1560 Industry Road USA-Hatfield, PA Tel: Fax: sgkcck@aol.com ProSciTech Pty Ltd 11 Carlton Street, Kirwan QLD 4817 Australia Telephone Number: (07) :30am - 5:00pm, Monday to Friday (excluding Public Holidays) Emergency Contact: (07) :30am - 5:00pm, Monday to Friday (excluding Public Holidays) Emgrid Australia Pty. Ltd. P.O. Box 118 The Patch VIC 3792 Australia Tel: Fax: Website: Further information obtainable from: Product safety department Emergency telephone number: ChemTrec Contract CCN Hazards identification Classification of the substance or mixture GHS02 flame Flam. Liq. 2 H225 Highly flammable liquid and vapour. GHS08 health hazard STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS07 Acute Tox. 4 H302 Harmful if swallowed. Skin Irrit. 2 H315 Causes skin irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. (Contd. on page 2) AU

12 Safety data sheet according to 1907/2006/EC, Article 31 Page 2/9 Printing date Revision: Trade name: TECHNOVIT 3040 LIQUID STOT SE 3 H335 May cause respiratory irritation. (Contd. of page 1) Label elements GHS label elements The product is classified and labelled according to the Globally Harmonised System (GHS). Hazard pictograms GHS02 GHS07 GHS08 Signal word Danger Hazard-determining components of labelling: methyl methacrylate N,N-dimethyl-p-toluidine Hazard statements Highly flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. Precautionary statements Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical/ventilating/lighting/equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves / eye protection / face protection. Wear protective gloves. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Specific treatment (see on this label). IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention. Get medical advice/attention if you feel unwell. Rinse mouth. In case of fire: Use for extinction: CO2, powder or water spray. Take off contaminated clothing and wash it before reuse. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations. Other hazards Results of PBT and vpvb assessment PBT: Not applicable. (Contd. on page 3) AU

13 Safety data sheet according to 1907/2006/EC, Article 31 Page 3/9 Printing date Revision: Trade name: TECHNOVIT 3040 LIQUID vpvb: Not applicable. (Contd. of page 2) 3 Composition/information on ingredients Chemical characterisation: Mixtures Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: methyl methacrylate % N,N-dimethyl-p-toluidine % Additional information: For the wording of the listed risk phrases refer to section First aid measures Description of first aid measures General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: Call for a doctor immediately. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Firefighting measures Extinguishing media Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water. For safety reasons unsuitable extinguishing agents: Water with full jet Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. (Contd. on page 4) AU

14 Safety data sheet according to 1907/2006/EC, Article 31 Page 4/9 Printing date Revision: Trade name: TECHNOVIT 3040 LIQUID See Section 13 for disposal information. (Contd. of page 3) 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. Protect from heat. Protect against electrostatic charges. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well sealed receptacles. Protect from heat and direct sunlight. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: methyl methacrylate NES Short-term value: 416 mg/m³, 100 ppm Long-term value: 208 mg/m³, 50 ppm Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the skin. Avoid contact with the eyes and skin. Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. (Contd. on page 5) AU

15 Safety data sheet according to 1907/2006/EC, Article 31 Page 5/9 Printing date Revision: Trade name: TECHNOVIT 3040 LIQUID (Contd. of page 4) Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Fluid Colour: Colourless Odour: Characteristic Odour threshold: Not determined. ph-value: Not determined. Change in condition Melting point/melting range: -48 C Boiling point/boiling range: 100 C Flash point: 10 C Flammability (solid, gaseous): Not applicable. Ignition temperature: 430 C Decomposition temperature: Not determined. Self-igniting: Product is not selfigniting. Danger of explosion: Product is not explosive. However, formation of explosive air/vapour mixtures are possible. Explosion limits: Lower: 2.1 Vol % Upper: 12.5 Vol % Vapour pressure at 20 C: 47 hpa Density at 20 C: 0.94 g/cm³ Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. (Contd. on page 6) AU

16 Safety data sheet according to 1907/2006/EC, Article 31 Page 6/9 Printing date Revision: Trade name: TECHNOVIT 3040 LIQUID Solubility in / Miscibility with water at 20 C: 1.6 g/l Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Kinematic: Not determined. Not determined. Solvent content: Organic solvents: 0.0 % VOC (EC) 0.00 % Other information No further relevant information available. (Contd. of page 5) 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity LD/LC50 values relevant for classification: methyl methacrylate Oral LD mg/kg (rat) Primary irritant effect: Skin corrosion/irritation Irritant to skin and mucous membranes. Serious eye damage/irritation No irritating effect. Respiratory or skin sensitisation Sensitisation possible through skin contact. Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Harmful Irritant 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behaviour in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. (Contd. on page 7) AU

17 Safety data sheet according to 1907/2006/EC, Article 31 Page 7/9 Printing date Revision: Trade name: TECHNOVIT 3040 LIQUID (Contd. of page 6) Additional ecological information: General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. 14 Transport information UN-Number ADG, IMDG, IATA UN1247 UN proper shipping name ADG 1247 METHYL METHACRYLATE MONOMER, STABILIZED IMDG, IATA METHYL METHACRYLATE MONOMER, STABILIZED Transport hazard class(es) ADG, IMDG, IATA Class 3 Flammable liquids. Label 3 Packing group ADG, IMDG, IATA II Environmental hazards: Marine pollutant: No Special precautions for user Warning: Flammable liquids. Danger code (Kemler): 339 EMS Number: F-E,S-D Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport/Additional information: ADG Limited quantities (LQ) 1L Not applicable. (Contd. on page 8) AU

18 Safety data sheet according to 1907/2006/EC, Article 31 Page 8/9 Printing date Revision: Trade name: TECHNOVIT 3040 LIQUID Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml Transport category 2 Tunnel restriction code D/E IMDG Limited quantities (LQ) 1L Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml (Contd. of page 7) UN "Model Regulation": UN1247, METHYL METHACRYLATE MONOMER, STABILIZED, 3, II 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Australian Inventory of Chemical Substances All ingredients are listed. Standard for the Uniform Scheduling of Medicines and Poisons methyl methacrylate S6, S10 GHS label elements The product is classified and labelled according to the Globally Harmonised System (GHS). Hazard pictograms GHS02 GHS07 GHS08 Signal word Danger Hazard-determining components of labelling: methyl methacrylate N,N-dimethyl-p-toluidine Hazard statements Highly flammable liquid and vapour. Harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. Precautionary statements Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical/ventilating/lighting/equipment. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves / eye protection / face protection. Wear protective gloves. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash thoroughly after handling. (Contd. on page 9) AU

19 Safety data sheet according to 1907/2006/EC, Article 31 Page 9/9 Printing date Revision: Trade name: TECHNOVIT 3040 LIQUID (Contd. of page 8) Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Specific treatment (see on this label). IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention. Get medical advice/attention if you feel unwell. Rinse mouth. In case of fire: Use for extinction: CO2, powder or water spray. Take off contaminated clothing and wash it before reuse. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations. Directive 2012/18/EU Named dangerous substances - ANNEX I None of the ingredients is listed. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Flam. Liq. 2: Flammable liquids, Hazard Category 2 Acute Tox. 4: Acute toxicity, Hazard Category 4 Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2 Skin Sens. 1: Sensitisation - Skin, Hazard Category 1 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2 AU

20 Safety Data Sheet acc. to OSHA HCS Page 1/10 Printing date 10/05/2015 Reviewed on 10/05/ Identification Product identifier Trade name: TECHNOVIT 3040 LIQUID Article number: 14652(L) Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Laboratory chemicals Details of the supplier of the safety data sheet Manufacturer/Supplier: Electron Microscopy Sciences 1560 Industry Road USA-Hatfield, PA Tel: Fax: sgkcck@aol.com Information department: Product safety department Emergency telephone number: ChemTrec Contract CCN Hazard(s) identification Classification of the substance or mixture GHS02 Flame Flam. Liq. 2 H225 Highly flammable liquid and vapor. GHS08 Health hazard STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS07 Acute Tox. 4 H302 Harmful if swallowed. Skin Irrit. 2 H315 Causes skin irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. STOT SE 3 H335 May cause respiratory irritation. Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. Harmful Harmful if swallowed. Irritant Irritating to respiratory system and skin. May cause sensitisation by skin contact. Highly flammable Highly flammable. (Contd. on page 2) CA

21 Safety Data Sheet acc. to OSHA HCS Page 2/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID (Contd. of page 1) Information concerning particular hazards for human and environment: The product has to be labeled due to the calculation procedure of international guidelines. Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. Label elements Labelling according to EU guidelines: The product has been classified and marked in accordance with directives on hazardous materials. Code letter and hazard designation of product: Harmful Highly flammable Hazard-determining components of labeling: methyl methacrylate N,N-dimethyl-p-toluidine Risk phrases: Highly flammable. Harmful if swallowed. Irritating to respiratory system and skin. May cause sensitisation by skin contact. Safety phrases: Keep container in a well-ventilated place. Avoid contact with skin. Wear suitable gloves. This material and its container must be disposed of as hazardous waste. Hazard description: WHMIS-symbols: B2 - Flammable liquid D2B - Toxic material causing other toxic effects Classification system: NFPA ratings (scale 0-4) Health = 1 Fire = 3 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH FIRE REACTIVITY Health = 1 Fire = 3 Reactivity = 0 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. (Contd. on page 3) CA

22 Safety Data Sheet acc. to OSHA HCS Page 3/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID vpvb: Not applicable. (Contd. of page 2) 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: methyl methacrylate % N,N-dimethyl-p-toluidine 1-5% 4 First-aid measures Description of first aid measures General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: Immediately call a doctor. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water. For safety reasons unsuitable extinguishing agents: Water with full jet Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. (Contd. on page 4) CA

23 Safety Data Sheet acc. to OSHA HCS Page 4/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID See Section 13 for disposal information. (Contd. of page 3) 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect from heat. Protect against electrostatic charges. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. Protect from heat and direct sunlight. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: methyl methacrylate EL Short-term value: 100 ppm Long-term value: 50 ppm S EV Short-term value: 100 ppm Long-term value: 50 ppm Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the skin. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. (Contd. on page 5) CA

24 Safety Data Sheet acc. to OSHA HCS Page 5/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID Protection of hands: (Contd. of page 4) Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Fluid Color: Colorless Odor: Characteristic Odour threshold: Not determined. ph-value: Not determined. Change in condition Melting point/melting range: -48 C Boiling point/boiling range: 100 C Flash point: 10 C Flammability (solid, gaseous): Not flammable. Ignition temperature: 430 C Decomposition temperature: Not determined. Auto igniting: Product is not selfigniting. Danger of explosion: Product is not explosive. However, formation of explosive air/vapor mixtures are possible. Explosion limits: Lower: 2.1 Vol % Upper: 12.5 Vol % Vapor pressure at 20 C: 47 hpa (Contd. on page 6) CA

25 Safety Data Sheet acc. to OSHA HCS Page 6/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID Density at 20 C: 0.94 g/cm³ Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with Water at 20 C: 1.6 g/l Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Kinematic: Not determined. Not determined. Solvent content: Organic solvents: 0.0 % Other information No further relevant information available. (Contd. of page 5) 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: methyl methacrylate Oral LD mg/kg (rat) Primary irritant effect: on the skin: Irritant to skin and mucous membranes. on the eye: No irritating effect. Sensitization: Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Irritant Carcinogenic categories IARC (International Agency for Research on Cancer) methyl methacrylate 3 NTP (National Toxicology Program) None of the ingredients is listed. (Contd. on page 7) CA

26 Safety Data Sheet acc. to OSHA HCS Page 7/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID OSHA-Ca (Occupational Safety Health Administration) None of the ingredients is listed. (Contd. of page 6) 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behavior in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Additional ecological information: General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. 14 Transport information UN-Number DOT, TDG, IMDG, IATA UN1247 UN proper shipping name DOT Methyl methacrylate monomer, stabilized TDG 1247 Methyl methacrylate monomer, stabilized IMDG, IATA METHYL METHACRYLATE MONOMER, STABILIZED Transport hazard class(es) DOT Class 3 Flammable liquids (Contd. on page 8) CA

27 Safety Data Sheet acc. to OSHA HCS Page 8/10 Printing date 10/05/2015 Reviewed on 10/05/2015 Trade name: TECHNOVIT 3040 LIQUID Label 3 TDG, IMDG, IATA (Contd. of page 7) Class 3 Flammable liquids Label 3 Packing group DOT, TDG, IMDG, IATA II Environmental hazards: Marine pollutant: No Special precautions for user Warning: Flammable liquids Danger code (Kemler): 339 EMS Number: F-E,S-D Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport/Additional information: Not applicable. DOT Quantity limitations On passenger aircraft/rail: 5 L On cargo aircraft only: 60 L TDG Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml IMDG Limited quantities (LQ) 1L Excepted quantities (EQ) Code: E2 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 500 ml UN "Model Regulation": UN1247, Methyl methacrylate monomer, stabilized, 3, II 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Sara Section 355 (extremely hazardous substances): None of the ingredients is listed. Section 313 (Specific toxic chemical listings): methyl methacrylate TSCA (Toxic Substances Control Act): All ingredients are listed. Proposition 65 Chemicals known to cause cancer: N,N-dimethyl-p-toluidine (Contd. on page 9) CA