3.2. Mixture Name Product identifier % GHS-US classification

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1 Date of issue: 09/05/2016 Version: 1.0 SECTION 1: Identification 1.1. Identification Product form Name Product code : Mixture : : LITHAMAÏS 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use : Animal feed 1.3. Details of the supplier of the safety data sheet Distributor TIMAC Agro USA, INC P.O. Box Route 724 & I-176 READING, - USA T info-fds@roullier.com Manufacturer TIMAC Agro France 27 avenue Franklin Roosevelt Saint-Malo cedex, FRANCE T info-fds@roullier.com Emergency telephone number Emergency number : USA POISON CONTROL : SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Not classified 2.2. Label elements GHS-US labelling No labelling applicable 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % GHS-US classification copper sulphate / Sulfuric acid copper(2+) salt (1:1) (CAS No) Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Zinc Oxide (CAS No) Aquatic Acute 1, H400 Aquatic Chronic 1, H410 calcium iodate / Iodic acid (HIO3), calcium salt (2:1) (CAS No) Ox. Sol. 2, H272 Acute Tox. 4 (Oral), H302 Eye Irrit. 2A, H319 STOT SE 3, H335 cobalt carbonate / Carbonic acid, cobalt(2+) salt (1:1) (CAS No) Resp. Sens. 1, H334 Skin Sens. 1, H317 Muta. 2, H341 Carc. 1B, H350 Repr. 1B, H360 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 sodium selenite / Selenious acid, sodium salt (1:2) (CAS No) Acute Tox. 2 (Oral), H300 Acute Tox. 3 (Inhalation), H331 Skin Sens. 1, H317 Aquatic Chronic 2, H411 09/09/2016 EN (English) Page 1

2 Full text of hazard classes and H-statements : see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Get medical advice and attention if you feel unwell. : If you feel unwell, seek medical advice. : Seek medical attention if ill effect or irritation develops. : Rinse eyes with water as a precaution. Consult an ophtalmologist if irritation persists. : Normal use conditions Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire. Unsuitable extinguishing media : None known Special hazards arising from the substance or mixture Fire hazard. Explosion hazard. Reactivity : No dangerous reactions known Advice for firefighters Firefighting instructions Protection during firefighting Other information : Use extinguishing media appropriate for surrounding fire. : Do not enter without an appropriate protective equipment. Self-contained breathing apparatus when in close proximity to fire. : Avoid pouring fire water down the drains. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Refer to protective measures listed in Sections 7 and For non-emergency personnel For emergency responders 6.2. Environmental precautions Do not allow uncontrolled discharge of product into the environment Methods and material for containment and cleaning up For containment : Sweep up or vacuum up the product. Methods for cleaning up : Collect spillage Reference to other sections Concerning personal protective equipment to use, see section 8. Concerning disposal elimination after cleaning, see section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : None known. Avoid all unnecessary exposure. Wash hands as often as necessary. Precautions for safe handling : Normal use conditions. Comply with applicable regulations. Hygiene measures : Read label before use Conditions for safe storage, including any incompatibilities Technical measures : Keep out of reach of children. Storage conditions : Store in dry, well-ventilated area. Storage area : Store in a dry area. Store in a well-ventilated place. 09/09/2016 EN (English) 2/9

3 SECTION 8: Exposure controls/personal protection 8.1. Control parameters ACGIH ACGIH TWA (mg/m³) 8h 1 mg/m³ Copper (dusts and mists), as Cu ACGIH ACGIH STEL (mg/m³) 8h 1 mg/m³ Copper (dusts and mists), as Cu ACGIH ACGIH Ceiling (mg/m³) 8h 1 mg/m³ Copper (dusts and mists), as Cu OSHA OSHA PEL (TWA) (mg/m³) 8h 1 mg/m³ Copper (dusts and mists), as Cu OSHA OSHA PEL (STEL) (mg/m³) 8h 1 mg/m³ Copper (dusts and mists), as Cu OSHA OSHA PEL (Ceiling) (mg/m³) 8h 1 Copper (dusts and mists), as Cu NIOSH NIOSH REL (STEL) (mg/m³) <10h 1 mg/m³ NIOSH NIOSH REL (ceiling) (mg/m³) <10h 1 mg/m³ ACGIH ACGIH TWA (mg/m³) 8h 0.02 mg/m³ Cobalt (Co) ACGIH ACGIH STEL (mg/m³) 8h 0.02 mg/m³ Cobalt (Co) ACGIH ACGIH Ceiling (mg/m³) 8h 0.02 mg/m³ Cobalt (Co) OSHA OSHA PEL (TWA) (mg/m³) 0.1 mg/m³ Cobalt (Co) OSHA OSHA PEL (STEL) (mg/m³) 8h 0.02 mg/m³ Cobalt (Co) OSHA OSHA PEL (Ceiling) (mg/m³) 8h 0.02 mg/m³ Cobalt (Co) NIOSH NIOSH REL (TWA) (mg/m³) <10h 0.05 mg/m³ NIOSH NIOSH REL (STEL) (mg/m³) <10h 0.05 mg/m³ NIOSH NIOSH REL (ceiling) (mg/m³) <10h 0.05 mg/m³ ACGIH ACGIH TWA (mg/m³) 0.2 mg/m³ ACGIH ACGIH STEL (mg/m³) 0.2 mg/m³ ACGIH ACGIH Ceiling (mg/m³) 0.2 mg/m³ OSHA OSHA PEL (TWA) (mg/m³) 8h 0.2 mg/m³ Selenium and compounds (except H2Se and SeF6) OSHA OSHA PEL (STEL) (mg/m³) 0.2 mg/m³ OSHA OSHA PEL (STEL) (ppm) Selenium and compounds (except H2Se and SeF6) OSHA OSHA PEL (Ceiling) (mg/m³) 0.2 mg/m³ Selenium and compounds (except H2Se and SeF6) NIOSH NIOSH REL (TWA) (mg/m³) <10h 0.2 mg/m³ Selenium and compounds (except H2Se and SeF6) NIOSH NIOSH REL (STEL) (mg/m³) 0.2 mg/m³ Selenium and compounds (except H2Se and SeF6) NIOSH NIOSH REL (ceiling) (mg/m³) 0.2 mg/m³ Selenium and compounds (except H2Se and SeF6) ACGIH ACGIH TWA (mg/m³) 8h 2 mg/m³ Respirable fraction ACGIH ACGIH STEL (mg/m³) 8h 10 mg/m³ Respirable fraction ACGIH ACGIH Ceiling (mg/m³) 8h 2 mg/m³ Respirable fraction OSHA OSHA PEL (TWA) (mg/m³) 8h 5 mg/m³ Respirable fraction OSHA OSHA PEL (STEL) (mg/m³) 8h 5 mg/m³ Respirable fraction OSHA OSHA PEL (Ceiling) (mg/m³) 8h 5 mg/m³ Respirable fraction 09/09/2016 EN (English) 3/9

4 NIOSH NIOSH REL (TWA) (mg/m³) <10h 5 mg/m³ (dust) NIOSH NIOSH REL (STEL) (mg/m³) <10h 5 mg/m³ (dust) NIOSH NIOSH REL (ceiling) (mg/m³) <10h 15 mg/m³ (dust) 8.2. Exposure controls Appropriate engineering controls Materials for protective clothing Hand protection Eye protection Skin and body protection Respiratory protection Environmental exposure controls : General protective and hygienic measures. : Wear suitable protective clothing. : No special requirements. : No special requirements. : If skin contact or contamination of clothing is likely, protective clothing should be worn. Skin protection appropriate to the conditions of use should be provided. : No special requirements. : Do not allow into drains or water courses. Assure that emissions are compliant with all applicable air pollution control regulations. Conform to current legislation, regulations and orders. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Colour Odour Odour threshold ph Melting point Freezing point Boiling point Flash point Relative evaporation rate (butylacetate=1) Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosive limits Explosive properties Oxidising properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity No dangerous reactions known. : Solid : Mixture contains one or more component(s) which have the following colour(s): Blue Grey dark green : There may be no odour warning properties, odour is subjective and inadequate to warn of overexposure. Mixture contains one or more component(s) which have the following odour(s): odourless Odourless 09/09/2016 EN (English) 4/9

5 10.2. Chemical stability Stable in use and storage conditions as recommended in item Possibility of hazardous reactions Not established Conditions to avoid Extremely high or low temperatures Incompatible materials None to our knowledge Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Additional information (Based on available data, the classification criteria are not met) No experimental study on the product is available. The information given is based on our knowledge of the components and the classification of the product is determined by calculation LD50 oral rat 481 mg/kg EPA OTS LD50 dermal rat > 2000 mg/kg EPA OTS ATE US (oral) mg/kg bodyweight LD50 oral rat mg/kg bodyweight (OECD 401 method) LD50 dermal rat > 2000 mg/kg (OECD 402 method) LC50 inhalation rat (mg/l) 5.08 mg/kg (OECD 436 method) ATE US (oral) mg/kg bodyweight LD50 oral rat 7 mg/kg bodyweight U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES Public Health Service Agency for Toxic Substances and Disease Registry LC50 inhalation rat (mg/l) 0.51 (OECD 403 method) ATE US (oral) mg/kg bodyweight ATE US (gases) ppmv/4h ATE US (vapours) mg/l/4h ATE US (dust,mist) mg/l/4h LD50 oral rat mg/kg bodyweight (OECD 401 method) ATE US (oral) mg/kg bodyweight LD50 oral rat LC50 inhalation rat (mg/l) Additional information Skin corrosion/irritation Serious eye damage/irritation 7950 mg/kg 5000 µg/m³ 3h Supplier the classification of the product is determined by calculation) the classification of the product is determined by calculation) 09/09/2016 EN (English) 5/9

6 Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity the classification of the product is determined by calculation) the classification of the product is determined by calculation. Contains traces of a (possible) mutagenic substance. cobalt carbonate) the classification of the product is determined by calculation. Contains a substance which is (possibly) carcinogenic. cobalt carbonate) Reproductive toxicity Specific target organ toxicity (single exposure) Additional information the classification of the product is determined by calculation. Contains a toxic to reproduction component (H360FD) at a concentration below the threshold for classifying the mixture) (Based on available data, the classification criteria are not met) LOAEL (oral, rat) 2000 mg/kg bodyweight EU Method B.26 NOAEL (oral, rat) 1000 mg/kg bodyweight EU Method B.26 No experimental study on the product is available. The information given is based on our knowledge of the components and the classification of the product is determined by calculation NOAEL (oral, rat) 300 mg/kg bodyweight (OECD 408 method) Specific target organ toxicity (repeated exposure) Additional information (Based on available data, the classification criteria are not met) No experimental study on the product is available. The information given is based on our knowledge of the components and the classification of the product is determined by calculation NOAEL (oral, rat, 90 days) 0.4 mg/kg bodyweight/day (OECD 408 method) NOAEL (subchronic, oral, animal/male, 90 days) Aspiration hazard mg/kg bodyweight (OECD 408 method) the classification of the product is determined by calculation) SECTION 12: Ecological information Toxicity Ecology - general : Based on available data, the classification criteria are not met. Use this product rationally avoiding to disperse it in nature. LC50 fish 1 16 μg/l 72 h (chlamydomonas reinhardtii) 7 μg/l LC50 fish 2 13 μg/l (Catostomus commersoni) 09/09/2016 EN (English) 6/9

7 LC50 fish 1 4d 1512 mg/l Oncorhynchus mykiss (Rainbow trout) LC50 other aquatic organisms 1 96h 3.21 mg/l daphnia 72h mg/l Standard Guide for Conducting Static Acute Toxicity Tests with Echinoid Embryos. E In: 2004 ASTM Annual Book of Standards. EC50 other aquatic organisms 1 96h mg/l algae LOEC (acute) 1577 mg/l Oncorhynchus mykiss (Rainbow trout) NOEC (acute) 4d mg/l Oncorhynchus mykiss (Rainbow trout) NOEC (chronic) 34d 0.21 mg/l Minnow LC50 fish mg/l EPA - OPP mg/l EPA-660/ LOEC (chronic) mg/l Oncorhynchus mykiss (Rainbow trout) NOEC (chronic) mg/l Oncorhynchus mykiss (Rainbow trout) NOEC chronic crustacea 24d 0.1 mg/l Hyalella azteca LC50 fish mg/l Quantitative structure-activity relationship (QSAR) mg/l Quantitative structure-activity relationship (QSAR) NOEC (acute) 100 mg/l LC50 fish 1 Additional ecotoxicological information 1.1 mg/l Oncorhynchus mykiss, 96h (ECOTOX database) > 1000 mg/l Daphnia Magna, 48h (ECOTOX database) Supplier Persistence and degradability Persistence and degradability Not established. Persistence and degradability Readily biodegradable. Persistence and degradability (inorganic substance) Bioaccumulative potential Bioaccumulative potential No study has been carried out for the moment on this mixture. Log Pow Bioaccumulative potential No data / information available Mobility in soil Ecology - soil No study has been carried out for the moment on this mixture. Ecology - soil Other adverse effects Other adverse effects Effect on the global warming GWPmix comment Other information No data / information available. : No data / information available. : No known effects from this product. : No known effects from this product. : No study has been carried out for the moment on this mixture. Do not allow into drains or water courses. 09/09/2016 EN (English) 7/9

8 SECTION 13: Disposal considerations Waste treatment methods Regional legislation (waste) Waste disposal recommendations SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT TDG Transport by sea : Disposal must be done according to official regulations. Dispose in a safe manner in accordance with local/national regulations. : Do not allow into drains or water courses. Air transport SECTION 15: Regulatory information US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. Sulfate de cuivre pentahydraté CAS No % sélénite de sodium CAS No % CERCLA RQ 10 lb SARA Section 311/312 Hazard Classes Immediate (acute) health hazard SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard Immediate (acute) health hazard CERCLA RQ 100 lb SARA Section 302 Threshold Planning Quantity (TPQ) SARA Section 311/312 Hazard Classes SARA Section 311/312 Hazard Classes Reactive hazard lb 100lb if the substance is solid in powder form with particle size less than 100 microns, or is in solution or molten form Immediate (acute) health hazard Delayed (chronic) health hazard International regulations CANADA WHMIS Classification Class D Division 2 Subdivision B - Toxic material causing other toxic effects WHMIS Classification Class D Division 2 Subdivision A - Very toxic material causing other toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects WHMIS Classification Class D Division 1 Subdivision A - Very toxic material causing immediate and serious toxic effects Class D Division 2 Subdivision B - Toxic material causing other toxic effects 09/09/2016 EN (English) 8/9

9 WHMIS Classification Class C - Oxidizing Material EU-Regulations National regulations Ensure all national/local regulations are observed US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm SECTION 16: Other information Data sources Training advice : Section 1.2, 8.1, 11 & 12 are based on components' Chemical Safety Report and/or datas from components' supplier. : Normal use of this product shall imply use in accordance with the instructions on the packaging. Full text of H-statements: H272 May intensify fire; oxidiser H300 Fatal if swallowed H302 Harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H331 Toxic if inhaled H334 may cause allergy or asthma symptoms or breathing difficulties if inhaled H335 May cause respiratory irritation H341 Suspected of causing genetic defects H350 May cause cancer H360 May damage fertility or the unborn child H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects H411 Toxic to aquatic life with long lasting effects SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 09/09/2016 EN (English) 9/9

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